Polyethylene Terephthalate Glycol-modified Research Articles

Structural integrity of polymers processed by additive manufacturing techniques using residual strength diagrams

Motivated by the increasingly important role that polymers have in structural applications, this study aims to analyse the structural integrity of polymers through residual strength diagrams. The polymers analysed have been thermoplastics, Polylactic acid (PLA), Polyethylene terephthalate glycol-modified (PET-G) and Polyamide 12 (PA-12), as well as a thermosetting resin, processed through different additive manufacturing techniques: Fused Deposition Modelling (FDM) in the case of PLA, PET-G, Selective Laser Sintering (SLS) for PA-12 and Digital Light Processing (DLP) for the thermosetting resin. In addition, PA-12 manufactured by injection moulding was also included in this study. To obtain the residual strength diagrams, mechanical tests have been carried out on smooth specimens and on specimens with cracks of different lengths. From the analysis of the results, a prediction has been obtained by fitting a semi-empirical model that describes the structural integrity in the areas of microstructurally short cracks, long cracks and physically short cracks.

Effects of Attachment Design and Aligner Material on Mandibular Canine Distal Bodily Movement in Aligner Treatment

Abstract Purpose Dental crowding is a result of a mismatch between tooth size and arch dimensions, which leads to malocclusion; treatment often involves premolar extraction before orthodontic alignment. Clear aligners are limited in their ability to achieve canine distal bodily movement, a common orthodontic maneuver. This study investigated the impacts of attachment design and aligner material on the efficacy of canine distal bodily movement. Methods A finite element analysis was conducted to examine the impact of various attachment designs and two aligner materials, thermoplastic polyurethanes/polycarbonate (TPU/PC) and polyethylene terephthalate glycol-modified (PETG), on mandibular canine distal bodily movement. The investigation focused on the biomechanical responses in the periodontal ligament (PDL) and surrounding alveolar bone. Results Attachment configuration exerted a strong influence on mandibular canine movement. Vertically oriented attachment pairs positioned mesially (mesial occlusal–mesial cervical) resulted in the most effective canine distal bodily movement, followed by a rectangular attachment. TPU/PC aligners induced slightly higher principal stresses in the PDL and von Mises stress and strain in the surrounding alveolar bone compared with PETG aligners; however, the difference was negligible, amounting to less than 6%. Conclusion Attachment design, specifically vertically oriented pairs positioned mesially (mesial occlusal–mesial cervical), was determined to be the crucial factor influencing the efficacy of canine distal bodily movement. The choice of aligner material (TPU/PC or PETG) has minimal impact on this orthodontic procedure.

Structural behaviour of adhesive bonds in 3D printed adherends

Additive manufacturing (AM) processes, also known as 3D printing, are experiencing growth and more industries are seeking solutions in these types of processes due to their advantages, including reducing the manufacturing time, sustainability, and the freedom to execute complex geometries. However, the dimensions of components are still quite small. Thus, it is necessary to find solutions for cases where assembly and joining of manufactured components are necessary. This work studies the tensile performance of adhesively bonded single-lap joints (SLJ) between AM adherends of polylactic acid (PLA), Polyethylene Terephthalate Glycol-modified (PETG), and Acrylonitrile Butadiene Styrene (ABS), bonded with the adhesives Araldite® 2015 and Sikaforce® 7752. The adherends’ mechanical elastic, plastic and fracture properties are determined prior to the assessment of the adhesive performance in SLJ. Failure modes, joint strength, assembly stiffness, and failure energy are obtained experimentally and compared to Cohesive Zone Model (CZM) predictions, aiming to provide the best material/adhesive combination that maximises the joint performance. In terms of strength and stiffness, PLA joints bonded with the Araldite® 2015 provided the best results, although the behaviour was different for the dissipated energy. The CZM approach showed to be a reliable design approach for bonded AM joints.

Sustainable Compositions and 3D Printing Technologies for Characterizing and Optimizing Recycled PETG

The packing industry makes extensive use of terephthalate polyesters because of their chemical durability and optical qualities. Examples of these materials are polyethylene terephthalate (PET) and glycol-modified PET (PETG). They also supply building materials, medical technology, technical polymers, and the textile sector. PET is made of terephthalic acid as well as ethylene glycol, whereas 30% of the diol moles in PETG are replaced with CHDM during synthesis. Detailed structural analyses of polyethylene terephthalate glycol-modified (PETG) are presented in this study. In two directions, PETG square blocks were tested with a load of 12,200 N to determine their durability and mechanical response. This block experienced a total deformation of 0.2318 mm under vertical loading, with the outer layer experiencing 33.93 MPa, and the middle layer experiencing 23.148 MPa. According to its performance under vertical stress, PETG had a maximum fatigue life of approximately 572,540 cycles and a minimal safety factor of 0.035116. A deformation of 0.23192 mm was recorded under horizontal loading. The bottom layer had a stress of 46.317 MPa and the top layer had a stress of 20.174 MPa, with a better fatigue life of 616,880 cycles and a safety factor of 0.35979.

The tooth movement efficiency of different orthodontic thermoplastics for clear aligners: study protocol for a randomized controlled clinical trial

IntroductionWith regard to the esthetics and comfort of orthodontic treatment, the requirement for removable clear aligners (CAs) is increasing. Unlike conventional fixed orthodontic appliances, CAs were made of thermoplastic film by thermoforming on the personalized dental models. The construction of orthodontic thermoplastic is a critical factor for orthodontic tooth movement (OTM). Polyethylene terephthalate glycol-modified (PETG) and thermoplastic polyurethane (TPU) are the most commonly orthodontic thermoplastics; however, the evidence of the differences between different orthodontic thermoplastic are limited to vitro environment and the evidence in vivo environment is not available. Therefore, this trial aims to provide reliable evidence for orthodontists’ personalized treatment plans whether the two most commonly used orthodontic thermoplastics of PETG and TPU have differences in the efficiency of OTM.Methods and analysisThis randomized controlled clinical study will recruit 44 orthodontic patients for orthodontic treatment. All the subjects will be randomized into two groups (PETG and TPU, n = 22 for each group). In the first stage (M0 to M1), clear aligners will be made of two orthodontic thermoplastics and move the maxillary first or second premolars 2 mm. In the second stage, patients will take the standard orthodontic treatments. The primary outcome will be the efficiency of clear aligners made of different materials on the digital models. The secondary outcome will be the efficiency of clear aligners made of different materials on the cone-beam computed tomography (CBCT). The efficiency will be calculated through the superimposition of the digital models and CBCT.DiscussionThe results from this trial will serve as evidence for orthodontists and manufacturers and clarify whether the difference in orthodontic thermoplastics significantly impacts the efficiency of OTM.Trial registration numberChiCTR2300070980. Registered on 27 April 2023.https://www.chictr.org.cn/showproj.html?proj=186253

Biomechanical effects of a hard insert and air space in mouthguards on the shock absorption and protection against fractures of direct resin composite veneers from trauma.

Mouthguards (MTG) are used to prevent dental trauma. However, their protective effect on esthetic restorations and whether modified MTGs are beneficial is uncertain. The aim of this study was to evaluate the effect of hard inserts and air spaces in MTGs in protecting direct resin composite veneers during impact. Twenty resin composite veneers (1.0 mm) were prepared on upper right central incisors on printed maxilla models using polyether. The effect of the MTGs was evaluated in four groups (n = 5): Con-MTG, conventional custom-fit MTGs made with two layers of ethylene vinyl acetate (EVA); Air-MTG, MTGs with the insertion of 2.0 mm air space between the two layers of EVA and tooth surface; PETG-MTG, MTGs with 1.0 mm of polyethylene terephthalate glycol-modified (PETG) inserted between the EVA layers; and No-MTG, comprising resin composite veneers without MTG. The printed models were fixed in a pendulum device, and the impact was performed at 30°. The strain (μS) and shock absorption (%) of the MTG were recorded using strain gauges. Failure modes and cracks were evaluated using macro photography and transillumination and analyzed using the chi-square test. Strain and shock absorption data were analyzed using the one-way analysis of variance followed by Tukey's test (α = 0.05). Mouthguards reduced strain and enhanced shock absorption, regardless of the MTG type (p < .001). Con-MTG, Air-MTG, and PETG-MTG had shock absorption rates of 76.1%, 72.3%, and 33.4%, respectively (p < .001). The single No-MTG model had a root fracture, while all the others had superficial damage. None of the MTG models had cracks or fractures. Mouthguards protected the resin composite veneers. The Con-MTG and Air-MTG groups had lower strain and greater shock absorption than the PETG-MTG. Resin veneers had no cracks or damage following MTG use. However, 80% of the veneers had surface damage when no MTG was used.

Dielectric spectroscopy of PETG/TiO2 composite intended for 3D printing

ABSTRACT 3D-printed electronics belong to new approaches to how to build a complex object with multiple desired functions. For that purpose, materials with specific electric properties are needed: conductors, insulators, magnetics, or dielectrics with high permittivity. However, such materials are not commonly available in the form of filament for fused deposition modelling since the development is still ongoing. This paper describes the electrical properties of PETG-ceramic composite filaments. PETG (polyethylene terephthalate glycol-modified) was filled with titanium dioxide (10 and 20 wt.%) to increase the dielectric constant and, simultaneously, to preserve printing simplicity as the material key advantage. Dielectric spectroscopy and measurement of volume resistivity were performed on printed samples. Relative permittivity increased by 50% for a composite filled with 20 wt.% of ceramic particles (ϵr = 2.5÷4.4) against pure PETG. Permittivity and dielectric loss exhibited frequency and temperature independence. The prepared composite can be used for dielectric applications in electronics.

Transmission laser welding of thermoplastics by using carbon nanotube web

Laser welding of transparent and semi-transparent thermoplastics using layers of carbon nanotube (CNT) web as absorbant is reported. Single lap shear specimens were manufactured placing the layers of CNT-web between two polyethylene terephthalate glycol-modified (PETG) sheets, that were successively irradiated with laser power at a wavelength of 1064 nm. Optical analyses were performed to assess the transmittance of the joint under different configurations; for the single layer of CNT web a transmittance of 83 %, in the visible range, was obtained after welding. Single-lap shear tests were performed and a shear strength of 23 MPa was obtained when using one layer of CNT-web. The investigated technology allows using a solid film as laser absorbing material, replacing conventional liquid or dye that need to be processed and applied on the surface before welding, thus speeding up the manufacturing process.

Research on the Influence of Processing Parameters on the Specific Tensile Strength of FDM Additive Manufactured PET-G and PLA Materials.

Fused deposition modeling (FDM) is one of the most accessible additive manufacturing (AM) technologies for processing polymeric materials. It allows processing most of thermoplastic polymers, with polyethylene terephthalate glycol-modified (PET-G) and polylactic acid (PLA). AM parts tend to display anisotropic behavior because of layer-by-layer fabrication and various technological parameters that can be set for 3D print, so it is hard to predict and analyze how the manufactured parts would behave under load. This research presents results of classic tensile strength tests performed on 57 PET-G specimens and 57 PLA specimens manufactured with varying technological parameters such as: printing temperature, print orientation, layer height, and infill percentage. Afterward, a comparative analysis is performed, proposing specific tensile strength (STS) as a benchmark to determine how 3D printed parts strength is varying due to beforementioned parameters, eliminating bias induced by varying weight of specimens. The biggest relative increase of UTS and the biggest relative decrease of STS was noted for variable infill percentage (increasing infill—PLA: 37.27% UTS increase and 30.41% STS decrease; PET-G: 24.42% UTS increase and 37.69% STS decrease). The biggest relative increase of STS between examined parameters was observed for both materials as the printing temperature was increased (27.53% for PLA and 12.69% for PET-G). Similar trends in STS changes were observed for both materials. Obtained data shows which FDM AM parameters are the most important to obtain the biggest UTS of manufactured parts, and those do not overlap with parameters needed to obtain optimal strength-to-weight ratio.

Emission Profiles of Volatiles during 3D Printing with ABS, ASA, Nylon, and PETG Polymer Filaments.

In this short communication we characterize the emission of volatile organic compounds (VOCs) from fused filament fabrication (FFF) 3D printing using four polymer materials, namely polyethylene terephthalate glycol-modified (PETG), acrylonitrile styrene acrylate (ASA), Nylon, and acrylonitrile butadiene styrene (ABS). Detailed emission profiles are obtained during thermal degradation of the polymers as a function of temperature and also in real-time during 3D printing. Direct quantitative measurement was performed using proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS). Qualitative determination of the volatiles emitted from the printed elements at various temperatures was accomplished using gas chromatography-mass spectrometry (GC-MS). The emission rates of VOCs differ significantly between the different polymer filaments, with the emission from Nylon and PETG more than an order of magnitude lower than that of ABS.

Heat treatment of 3D printed polyethylene terephthalate glycol in a supporting powder bed

Material extrusion 3D printing is a fabrication process that produces layered polymer parts with complex geometry but with inferior mechanical properties compared to parts made with other methods such as injection molding. Post fabrication heat treatment is a valid post-processing method that reduces the internal thermal stresses and improves layer adhesion in 3D printed polymers, resulting in superior mechanical properties. This study investigates the mechanical changes produced in 3D printed PETG (polyethylene terephthalate glycol-modified) parts after heat treatment. A novel technique is used, where the parts are embedded into a bed of sodium chloride powder in order to prevent deformation during postprocessing. Fully filled 3D printed PETG parts with various geometries are tightly packed in a bed of powder. The parts are subjected to heat treatment at a temperature above the material’s glass transition temperature but below its melting temperature. Destructive and non-destructive testing performed on the treated 3D printed samples shows a substantial improvement of mechanical properties. Tensile strength testing reveals an increase of tensile strength by 40% for parts printed horizontally and by over 100% for parts printed vertically. Increased stiffness is also observed in treated parts. Compressive strength testing shows a strength increase of 43% after treatment. Dimensional measurements made prior to and after treatment show significantly reduced deformation when using the supporting powder method versus unsupported treatment. Scanning electron microscopy (SEM) analysis is used to assess internal structural changes in the polymer after post-processing. This analysis reveals changes in internal void shape and distribution, increased interlayer adhesion and increased interface area of deposited filaments, providing insight into the mechanisms that lead to the improved properties observed in destructive testing. The supporting powder heat treatment allows the fabrication of parts with complex geometry through material extrusion 3D printing while mitigating the inherent disadvantage of the fabrication process of producing parts with inferior mechanical properties.

Effects of Topology and Material on Mechanical Properties of Structures Produced by the Additive Manufacturing Method

The usage area of 3D printers from architecture to heavy industry has been increasing in recent decades. By this process, it is possible to manufacture structures having different geometric configurations to improve the mechanical, vibration, impact, and acoustic properties of the structures. In this study, three-point test specimens with different topologies were produced by the 3D printing method in order to see the effect of the geometric configuration. The specimens having 100% infill density were produced using PLA (Polylactic Acid), ABS (Acrylonitrile Butadiene Styrene) and PETG (Polyethylene terephthalate glycol-modified) filament materials with the additive manufacturing method, which is the most widely used method in three-dimensional production. Numerical and experimental results are compared for loading conditions at specific force values.

Mechanical properties comparison between new and recycled polyethylene terephthalate glycol obtained from fused deposition modelling waste

The recycling of materials and the efficient use of resources are nowadays fundamental in a circular economy perspective. This concept also applies to additive manufacturing (AM) where waste can be reused to produce new material. Using mostly thermoplastic polymers, fused deposition modeling (FDM) is an AM technique that allows to melt waste materials and, successively, using a suitable extruder, obtain new filament. In the process, polymers are subject to multiple re-melting and polymer orientations by extrusion operations. The aim of this work is to evaluate the influence of the recycling process over polyethylene terephthalate glycol-modified (PETG) mechanical properties by tensile testing of samples produced using pure and recycled material. Furthermore, filament itself has been tested to evaluate recycle process influence before FDM printing.

Development of Thermoplastic Composite Reinforced Ultra-High-Performance Concrete Panels for Impact Resistance.

In order to improve flexural and impact performance, thin panels of steel fiber-reinforced ultra-high performance concrete (UHPC) were further reinforced with external layers of continuous fiber-reinforced thermoplastic (CFRTP) composites. CFRTP sheets were bonded to 305 × 305 × 12 mm UHPC panels using two different techniques. First, unidirectional E-glass fiber-reinforced tapes of polyethylene terephthalate glycol-modified (PETG) were arranged in layers and fused to the UHPC panels through thermoforming. Second, E-glass fiber woven fabrics were placed on the panel faces and bonded by vacuum infusion with a methyl methacrylate (MAA) polymer. Specimens were cut into four 150 mm square panels for quasi-static and low-velocity impact testing in which loads were applied at the panel centers. Under quasi-static loading, both types of thermoplastic composite reinforcements led to a 150–180% increase in both peak load capacity and toughness. Impact performance was measured in terms of both residual deformation and change in specimen compliance, and CFRTP additions were reduced both by 80% to 95%, indicating an increase in damage resistance. While both reinforcement fabrication techniques provided added performance, the thermoforming method was preferable due to its simplicity and fewer specialized tool requirements.

Investigation of 3D printing strategy on the mechanical performance of coextruded continuous carbon fiber reinforced PETG

AbstractFused filament fabrication (FFF) has been used to create prototypes and functional parts for various applications using plastic filaments. It has also been extended to the use of continuous fibers for reinforcing thermoplastic polymers. This study aims to optimize the deposition design of a coextruded continuous carbon fiber (CCF) composite filament with a polyethylene terephthalate glycol‐modified (PETG) filament. The characterizations on the raw materials revealed that the matrix polymer in CCF composite filament had similar physicochemical properties as PETG, and carbon fibers were homogeneously distributed in CCF filament. The effect of raster orientation and shells number on the mechanical properties of non‐reinforced and coextruded CCF‐reinforced PETG was investigated. The highest mechanical properties were obtained at a raster orientation of 0° for both reinforced and non‐reinforced materials. With the increase of raster orientation, Young's modulus and ultimate tensile strength decreased. The presence of shells improved the tensile strength of non‐reinforced PETG. For composite samples printed with unreinforced shells, Young's modulus decreased due to decrease in fibers content, and elongation at break and ultimate tensile strength increased. Tomographic observations showed that the mechanical behavior of printed specimens depended on the anisotropy of porosity in printed specimens.

S-N Curve Characterisation for Composite Materials and Prediction of Remaining Fatigue Life Using Damage Function

S-N curve characterisation and prediction of remaining fatigue life are studied using polyethylene terephthalate glycol-modified (PETG). A new simple method for finding a data point at the lowest number of cycles for the Kim and Zhang S-N curve model is proposed to avoid the arbitrary choice of loading rate for tensile testing. It was demonstrated that the arbitrary choice of loading rate may likely lead to an erroneous characterisation for the prediction of the remaining fatigue life. The previously proposed theoretical method for predicting the remaining fatigue life of composite materials involving the damage function was verified at a stress ratio of 0.4 for the first time. Both high to low and low to high loadings were conducted for predicting the remaining fatigue lives and a good agreement between predictions and experimental results was found. Fatigue damage consisting of cracks and whitening is described.

Study of the interfacial adhesive strength of a heat‐shrinkable multilayer film

AbstractA heat‐shrinkable multilayer film is widely employed as labels of plastic bottles. A new heat‐shrinkable multilayer film without an adhesive layer was designed in this study. The interfacial adhesive strength between the layers was controlled to avoid layer separation. We assumed a polyethylene terephthalate glycol‐modified (PETG)/styrene‐co‐butadiene block copolymer/PETG shrinkable film substitute as the general poly(ethylene terephthalate) (PET)/polystyrene/PET shrinkable film. The interlayer adhesive strength between the layers was retained for industrial utilization even after drawing. Additional polybutadiene (PB) infiltrated the butadiene layer in the microphase‐separated structure. Further addition of PB could not infiltrate the butadiene layer. The excessive PB contents coexisted with the interface between the layers, as observed by transmission electron microscopy (TEM). The segregated PB enhanced the interfacial adhesive strength. We concluded that the selective distribution of adhesive functional materials along the interface could appropriately retain its adhesive strength.

3D printing orthopedic scoliosis braces: a test comparing FDM with thermoforming

In recent years, 3D printing gained considerable attention in the orthopedic sector. This work evaluates the feasibility of producing orthopedic scoliosis braces by 3D printing, comparing performance and costs with classical thermoforming procedures. Critical parameters, such as manufacture time, mechanical properties, weight, and comfort are carefully considered. Polyethylene terephthalate glycol-modified (PETG) was selected among the several filaments materials present on the market. Printed samples were analyzed with electronic microscope, tensile, and impact tests and compared with thermoformed polyethylene (PE) and polypropylene (PP) samples. Moreover, a cost analysis was carried out for the specific application. The thermoformed brace of a volunteer patient affected by scoliosis was reproduced using reverse-engineering techniques. The model was then printed as a single piece and postprocessed by an expert orthotist. Subsequently, the patient wore the brace in a pilot case to compare comfort and mechanical effectiveness. Results show that the 3D printing fabrication method is able to provide a valid alternative to the current fabrication methods, being also very competitive in terms of costs. The morphological analysis does not show critical defects in 3D printed samples, while the mechanical tests highlighted their anisotropy, with an overall brittleness of PETG samples in the direction orthogonal to the fibers. However, in terms of mechanical stresses, a back brace should never reach the polymer yield stress, otherwise the shape would be modified and the therapeutic effect could be compromised. Finally, the patient reported the perception of improved support and no significant comfort differences compared with the thermoformed brace.

A Multimodal Stimulation Cell Culture Bioreactor for Tissue Engineering: A Numerical Modelling Approach

The use of digital twins in tissue engineering (TE) applications is of paramount importance to reduce the number of in vitro and in vivo tests. To pursue this aim, a novel multimodal bioreactor is developed, combining 3D design with numerical stimulation. This approach will facilitate the reproducibility between studies and the platforms optimisation (physical and digital) to enhance TE. The new bioreactor was specifically designed to be additive manufactured, which could not be reproduced with conventional techniques. Specifically, the design suggested allows the application of dual stimulation (electrical and mechanical) of a scaffold cell culture. For the selection of the most appropriate material for bioreactor manufacturing several materials were assessed for their cytotoxicity. Numerical modelling methods were then applied to the new bioreactor using one of the most appropriate material (Polyethylene Terephthalate Glycol-modified (PETG)) to find the optimal stimulation input parameters for bone TE based on two reported in vitro studies.

Mechanical Evaluation Of Unity Elevated Vacuum Suspension System.

Small residual limb-socket displacement is a good indicator of prosthetic suspension system quality. Active vacuum suspension systems can decrease vertical movement inside the socket, compared to non-active suction systems. This study mechanically evaluated limb-socket displacement with the Össur Unity active vacuum system. Forty-eight conditions were evaluated: four cylindrical and four conical sockets (polypropylene, polyethylene terephthalate glycol-modified (PETG), thermoset resin (acrylic), Thermolyn soft materials); two Iceross Seal-In V liners (standard, high profile); three vacuum conditions (active vacuum, inactive vacuum, no suction with valve open). An Instron 4428 test machine applied 0-100N linear ramped tensile loads to each positive mold, with the socket secured in place, while displacement between the mold and socket was recorded. Following the displacement tests, the load before failure (i.e., 10 mm displacement) was measured. Average and standard deviations for movement between the mold and sockets were small. The displacement average for all conditions was 0.30±0.16mm for active vacuum, 0.32±0.16mm for inactive vacuum, and 0.39±0.22mm for no suction. Across all trials, active vacuum systems tolerated significantly (p<0.001) more load before failure (812±221N) compared to inactive vacuum (727±213N), and no suction (401±184N). The maximum load before failure (1142±53N) was for the cylindrical polypropylene socket and high-profile liner. The Unity system successfully controlled pistoning inside the socket for regular activity loads and also controlled the greatest traction loads. While relative movement was smallest for Unity, all conditions (inactive vacuum, no suction) were viable for loads less than 100N. Furthermore, similar results can be achieved when using different socket fabrication materials.