Polycyclic Aromatic Hydrocarbon Emission Research Articles

Laboratory method for investigating the influence of industrial process conditions on the emission of polycyclic aromatic hydrocarbons from carbonaceous materials

This work is dedicated to developing a laboratory method for assessing emissions of polycyclic aromatic hydrocarbons (PAHs) from different carbon-based materials at elevated temperatures. The method will additionally contribute to enhancing the fundamental knowledge about the formation and decomposition of these compounds during various process conditions. Developing a method entails designing a setup for laboratory-scale experiments utilizing different furnace configurations and off-gas capturing media. To demonstrate the method's applicability, different carbon materials were tested under identical conditions, and analysis results for the same material in different furnace setups were compared. In this article, we have focused on the procedure for obtaining the “fingerprint” of PAH emissions under conditions characteristic of industrial processes.•Two setups for investigation of the influence of temperature on PAH emissions were designed and tested for three types of carbon materials.•The collected off-gas samples underwent analysis in two different laboratories to capture intra-laboratory differences and to evaluate the significance of the instrument detection limit.•The results of PAH 16 (16 EPA PAH) and PAH 42 analysis were compared to showcase the influence of the expanded list on the overall emission of PAH.The novel methodology enables the determination and comparison of PAH emissions during the thermal treatment of individual carbon materials under laboratory conditions. This could potentially be a new approach for predicting the PAH emissions in metallurgical industries that use these carbon materials as reducing agents in their processes and their control by optimizing process parameters and raw materials used. In addition to being suitable for simulating various conditions in the metallurgical industry, the utilization of low-hazard PAH solvents makes it a promising method.

Multiwavelength Observations of the Infrared Dust Bubble N75 and its Surroundings

Infrared dust bubbles play an important role in the study of star formation and the evolution of the interstellar medium. In this work, we study the infrared dust bubble N75 and the infrared dark cloud G38.93 mainly using the tracers C18O, HCO+, HNC and N2H+ observed by the 30 m IRAM telescope. We also study the targets using data from large-scale surveys: GLIMPSE, MIPSGAL, GRS, NRAO VLA Sky Survey and Bolocam Galactic Plane Survey. We found that the C18O emission is morphologically similar to the Spitzer IRAC 8.0 μm emission. The 1.1 mm cold dust emission of G38.93 shows an elongated structure from southwest to northeast. The ionized gas from G38.93 is surrounded by polycyclic aromatic hydrocarbon emission, which may be excited by radiation from G38.93. We found that the identified young stellar objects tend to cluster around G38.93 and are mostly in class II, with several class I cases distributed around N75, but no class II examples. We also found evidence of expanding feedback, which could have triggered star formation.

JWST MIRI MRS Images of Disk Winds, Water, and CO in an Edge-on Protoplanetary Disk

We present JWST MIRI MRS observations of the edge-on protoplanetary disk around the young subsolar-mass star Tau 042021, acquired as part of the Cycle 1 GO program “Mapping Inclined Disk Astrochemical Signatures.” These data resolve the mid-IR spatial distributions of H2, revealing X-shaped emission extending to ∼200 au above the disk midplane with a semiopening angle of 35° ± 5°. We do not velocity-resolve the gas in the spectral images, but the measured semiopening angle of the H2 is consistent with a magnetohydrodynamic wind origin. A collimated, bipolar jet is seen in forbidden emission lines from [Ne ii], [Ne iii], [Ni ii], [Fe ii], [Ar ii], and [S iii]. Extended H2O and CO emission lines are also detected, reaching diameters of ∼90 and 190 au, respectively. Hot molecular emission is not expected at such radii, and we interpret its extended spatial distribution as scattering of inner disk molecular emission by dust grains in the outer disk surface. H i recombination lines, characteristic of inner disk accretion shocks, are similarly extended and are likely also scattered light from the innermost star–disk interface. Finally, we detect extended polycyclic aromatic hydrocarbon (PAH) emission at 11.3 μm cospatial with the scattered-light continuum, making this the first low-mass T Tauri star around which extended PAHs have been confirmed, to our knowledge. MIRI MRS line images of edge-on disks provide an unprecedented window into the outflow, accretion, and scattering processes within protoplanetary disks, allowing us to constrain the disk lifetimes and accretion and mass-loss mechanisms.

Disentangling the association of PAH molecules with star formation

Context. Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous complex molecules in the interstellar medium and are used as an indirect indicator of star formation. On the other hand, the ultraviolet (UV) emission from young massive stars directly traces the star formation activity in a galaxy. The James Webb Space Telescope (JWST), along with the UltraViolet Imaging Telescope (UVIT), opened up a new window of opportunity to better understand the properties of PAH molecules that are associated with star-forming regions. Aims. We investigate how the resolved scale properties of PAH molecules in nearby galaxies are affected by star formation. Methods. We analyzed the PAH features observed at 3.3, 7.7, and 11.3 μm using F335M, F770W, and F1130W images obtained from the JWST. These images helped us identify and quantify the PAH molecules. Additionally, we used UVIT images to assess the star formation associated with these PAH-emitting regions. Our study focused on three galaxies, namely NGC 628, NGC 1365, and NGC 7496, which were selected based on the availability of both JWST and UVIT images. Bright PAH emission regions were identified in the JWST images, and their corresponding UV emission was estimated using the UVIT images. We quantified the star formation properties of these PAH emitting regions using the UVIT images. Furthermore, we investigated the relation between the star formation surface density (ΣSFR) and the PAH ratios to better understand the impact of star formation on the properties of PAH molecules. Results. Based on the resolved scale study of the PAH-bright regions using JWST images, we found that the fraction of ionized PAH molecules is high in the star-forming regions with high ΣSFR. We observed that emission from smaller PAH molecules is higher in star-forming regions with higher ΣSFR. Conclusions. Our study suggests that the PAH molecules excited by the photons from star-forming regions with higher ΣSFR are dominantly smaller and ionized molecules. UV photons from the star-forming regions could be the reason for the higher fraction of the ionized PAHs. We suggest that the effect of the high temperature in the star-forming regions and the formation of smaller PAH molecules in the star-forming regions might also result in the higher emission in the F335MPAH band.

Giant Biconical Dust Filaments in the Starburst Galaxy NGC 1808

We present the results from an analysis of multiwavelength archival data on the multiphase outflow in the starburst galaxy NGC 1808. We report the detection at 70 and 100 μm of dust filaments that extend up to ∼13 kpc from the galactic midplane and trace an edge-brightened biconical structure along the minor axis of the galaxy. The inner filaments are roughly cospatial with previously identified optical dust filaments, extraplanar polycyclic aromatic hydrocarbon emission, and neutral and ionized gaseous outflows. The 70/160 μm flux ratio, a proxy for the dust temperature, is elevated along the edges of the cones, indicating that the dusty medium has been driven out of the central regions of these cones and is possibly shock-heated by a large-scale outflow. We establish lower limits on the extraplanar dust mass and mean height above the stellar disk of log(Md/M⊙)=6.48 and ∣ z ∣ ∼ 5 kpc. The energy requirement of (5.1–9.6) × 1056 erg needed to lift the dusty material, assuming a Milky Way–like dust-to-gas ratio, can be supplied by the current starburst, with a measured star formation rate of 3.5–5.4 M ⊙ yr−1 over a timescale of (4–26) ξ −1 Myr, where ξ is the efficiency of energy transfer. We conclude that a starburst-driven outflow is the most likely mechanism by which the dust features were formed.

Particulate matter emissions from light-duty gasoline vehicles under different ambient temperatures: Physical properties and chemical compositions

Fine particulate matter (PM2.5) from vehicle exhaust is typically emitted at breathing height and thus imposes severe adverse effects on human health and air quality. However, there is currently limited knowledge on the characteristics of PM2.5 in exhaust, specifically its chemical components, at different ambient temperatures. Particulate emissions from typical light-duty gasoline vehicles (LDGVs) were investigated on a chassis dynamometer according to the Worldwide Harmonized Light-Duty Test Cycle at ambient temperatures of 38 °C, 28 °C, 15 °C, 5 °C and − 7 °C. The results showed a significant increase in particulate mass (PM) and particle number (PN) emissions with decreasing ambient temperature, particularly during cold starts below 5 °C. The particle size distributions exhibited distinct bimodal patterns, with accumulation-mode (AM) particles (60–125 nm) dominating the gasoline direct injection (GDI) distribution and nucleation-mode (NM) particles (8–12 nm) dominating the port fuel injection (PFI) distribution. AM particles were more temperature-sensitive than NM particles. Lower temperatures produced higher emissions of elements, carbonaceous components, and large-ring polycyclic aromatic hydrocarbons, while water-soluble ions showed an opposite trend. The total toxic equivalent, primarily influenced by benzo[a]pyrene, was significantly higher at −7 °C. The penalty distribution of LDGV PM and PN, defined by comparing the emissions at the various temperatures to those at regulated temperatures (23–30 °C), exhibited notable temporal heterogeneity (winter > autumn > spring > summer) and spatial heterogeneity (northern China > southern China). These findings are essential for establishing more stringent vehicle emission standards and improving emission models in cold environments.

Characterization of polycyclic aromatic hydrocarbon from open burning of disposable COVID-19 facemask: Spatial distribution and risk assessment

The use of facemasks as a preventive measure against infection of the COVID-19 virus has some associated environmental impacts, especially in Subs-Saharan African countries where the used facemasks are being disposed of using open burning. Hence this study characterized Polycyclic Aromatic Hydrocarbons (PAHs) emissions from different COVID-19 facemask materials and determined the associated risk of open burning of facemask. Facemasks of different materials were sourced from open dump sites. Each material was combusted in an open reactor and the emissions were collected using A filter-sorbent sampling system. Analysis of PAHs in the sample was carried out using GCMS. The associated health risk was assessed using Incremental Life Cancer Risk (ILCR) and Hazard Quotient (HQ). The result showed the concentration of PAHs emission ranged ∑ PAHs 73.33 –368.16 µg/m3 while carcinogenic PAHs ranged ∑ CarPAHs 26.79–179.74 µg/m3. The result also showed the surgical and N95 facemask emits the highest concentration of PAHs. The modeled annual ground-level PAHs Isopleth reveals the presence of a high concentration of PAHs around the vicinity of the burning site after a year. Proper disposal of these facemask using controlled medical incinerator is highly recommended.

Global trade-driven transfer of atmospheric polycyclic aromatic hydrocarbon emissions and associated human inhalation exposure risk

Polycyclic aromatic hydrocarbons (PAHs) are of significant public concern because of their toxicity and long-range transport potential. Extensive studies have been conducted to explore the source-receptor relationships of PAHs via atmospheric transport. However, the transfer of trade-driven regional and global PAHs is poorly understood. This study estimated the virtual PAHs emission transfer embodied in global trade from 2004 to 2014 and simulated the impact of international trade on global contamination and associated human inhalation exposure risk of PAHs. Results show that trade-driven PAHs flowed primarily from developed to less-developed regions, particularly in those regions with intensive heavy industries and transportation. As the result, international trade resulted in an increasing risk of lung cancer induced by exposure to PAHs (27.8% in China, 14.7% in India, and 11.3% in Southeast Asia). In contrast, we found decreasing risks of PAHs-induced lung cancer in Western Europe (63.2%) and the United States (45.9%) in 2004. Our findings indicate that final demand and emission intensity are the key driving factors contributing to rising and falling consumption-based PAHs emissions and related health risk respectively. The results could provide a useful reference for global collaboration in the reduction of PAHs pollution and related health risks.

Drivers distinguishing of PAHs heterogeneity in surface soil of China using deep learning coupled with geo-statistical approach

Although numerous studies have reported the influencing factors of polycyclic aromatic hydrocarbons (PAHs) in surface soil from source, process or soil perspectives, the mechanism of PAHs heterogeneity in surface soil are still not well understood. In this study, the effects of 16 PAHs in surface soil of China sampled between 2003 and 2020 with their 17 “source-process-sink” factors at 1 km resolution (N = 660)) were explored using deep learning (eXtreme Gradient Boosting) to mine key information from complex dataset under the optimized parameters (i.e., learning rate = 0.05, maximum depth = 5, sub-sample = 0.8). It was observed that top five factors of 16 PAH had the largest cumulative contribution (i.e., from 84.8% to 98.1%) on their soil concentrations. PAH emission was the predominant driver, and its effect on soil PAH increases with increasing logKow. Soil was the second driver, in which clay can promote the partition of PAHs with low or middle logKow. However, sand can accumulate those congeners with high logKow. Moreover, the deep learning plus geo-statistical models (with low deviation for testing dataset (N = 283)) were capable of predicting soil PAH concentrations using their drivers with high accuracy. This study improved the understanding of the environmental fate and spatial variability of soil PAHs, as well as provided a novel technique (i.e., deep learning coupled with geo-statistics) for accurate prediction of soil pollutants.

Assessment of PAH exposure and health risks among South Korean firefighters based on urinary PAH metabolites

Polycyclic aromatic hydrocarbons (PAHs) comprise a group of compounds resulting from the incomplete combustion of organic matter. Firefighters engaged in fire suppression are highly exposed to PAHs. This study centered on evaluating the exposure levels and health risks of PAHs in South Korean firefighters involved in firefighting activities. The concentrations of 10 PAH metabolites in the urine of firefighters were measured immediately after, and two weeks post their engagement in extinguishing a large tire factory fire. The levels of OH-PAHs in urine samples immediately after fire suppression were elevated by a factor of 1.01–1.84 compared to urine samples from non-exposed period. The median concentration of total PAH metabolites (OH-PAHs) was higher in urine samples immediately after fire suppression (5910 ng/g creatinine) than in urine samples from non-exposed periods (5020 ng/g creatinine). However, the ∑OH-PAH levels in firefighters’ urine were related to personal habits such as smoking. The concentrations of all individual OH-PAHs in the urine samples of nonsmokers exhibited a substantial increase, ranging from 1.37 to 2.3 times, clearly demonstrating that firefighting activities were a substantial source of PAH exposure. The calculated values associated with the health risks stemming from exposure to PAHs, including carcinogenic risk, total estimated daily intake (TEDI), and hazard quotients/index (HQs/HI), all fell within acceptable limits, indicating negligible risk. However, the HQ/HI values and TEDI for individual and total PAH exposures, except those for naphthalene, were 1.36–2.00 times higher in firefighters' samples taken after firefighting operations compared to those during regular duty. This underscores the need for more comprehensive investigations to comprehend the singular impact of firefighting activities due to the diverse sources of PAH emissions in the environment.

Emissions of polycyclic aromatic hydrocarbons in PM2.5 emitted from motor vehicles exhaust (PAHs-PM2.5-MVE) under the plateau with low oxygen content

Emissions of PAHs and their derivatives from motor vehicles exhaust are mainly due to inadequate combustion of fossil fuels, the combustion efficiency of engine is lower under the plateau with low oxygen content, which will exacerbate the emission of pollutants, especially organic substance. In order to investigate the emission of PAHs-PM2.5-MVE under the plateau with low oxygen content, tunnel experiments and bench tests were conducted in a typical plateau region in Yunnan Province. The study indicated the concentrations of PAHs-PM2.5-MVE in the tunnels of Caohai and Xidu reached 548.11 ± 307.12 and 1241.19 ± 197.54 ng/m3, respectively. The emission factor of PAHs-PM2.5-MVE in the Caohai Tunnel was estimated to be 438.61 ± 296.86 μg/veh/km, and that for gasoline and diesel vehicles in bench tests were 442.83 ± 82.57 and 4098.04 ± 551.21 μg/kg fuel. Meanwhile, the emission factors of carbonaceous component, CO and PAHs-PM2.5-MVE were at a high level that were higher than those in plain which due to the inadequate combustion of fuels in engine. A probabilistic risk assessment framework was integrated to quantitatively estimate the exposure risk for the population of the tunnels, the HPAHs-PM2.5-MVE had potential carcinogenic risk. The study can improve our understanding of the influence of organic substance from inadequate combustion of fuels on the environment and human.

Spatiotemporal variations in soil pollution by polycyclic aromatic hydrocarbons over a 20-year economic boom in different districts of a heavy industrial city in North China

Urbanization-related human activities, such as population aggregation, rapid industrial expansion, and intensified traffic, are key factors that impact local polycyclic aromatic hydrocarbon emissions and their associated health risks. Consequently, regions with varying degrees of urbanization within a megacity may exhibit diverse spatiotemporal patterns in the presence and distribution of soil polycyclic aromatic hydrocarbons, resulting in different levels of ecological risks for local inhabitants following the same period of development. In this study, we measured the concentrations of 16 polycyclic aromatic hydrocarbons in soil samples collected from industrial district and rural district in Tianjin (China) in 2018, and compared with polycyclic aromatic hydrocarbon data in 2001 from a previous study to characterize these regional variations in occurrence, source, and human risk of polycyclic aromatic hydrocarbons induced by urbanization with time and space. The results indicate the 20-year rapid urbanization and industrialization has differentially affected the composition, distribution and sources of polycyclic aromatic hydrocarbons in soils from different economic functional zones in Tianjin. Additionally, its impact on health risks in rural district appeared to be more significant than that in industrial district.

Deciphering the hidden structures of HH 216 and Pillar IV in M16: results from JWST and HST

ABSTRACT To probe the star formation process, we present an observational investigation of the Pillar IV and an ionized knot HH 216 in the Eagle Nebula (M16). Pillar IV is known to host a Class I protostar that drives a bipolar outflow. The outflow has produced the bow shock, HH 216, which is associated with the red-shifted outflow lobe. The JWST near- and mid-infrared images (resolution ∼0${_{.}^{\prime\prime}}$07–0${_{.}^{\prime\prime}}$7) reveal the protostar as a single, isolated object (below 1000 au). The outer boundary of Pillar IV is depicted with the 3.3 $\mu$m Polycyclic aromatic hydrocarbon (PAH) emission. HH 216 is traced with the 4.05 $\mu$m Brα and the radio continuum emission; however, it is undetected with 4.693 $\mu$m H2 emission. HH 216 seems to be associated with both thermal and non-thermal radio emissions. High-resolution images reveal entangled ionized structures (below 3000 au) of HH 216, which appear to be located towards termination shocks. New knots in 4.693 $\mu$m H2 emission are detected and are mainly found on Pillar IV’s northern side. This particular result supports the previously proposed episodic accretion in the powering source of HH 216. One part of the ionized jet (extent ∼0.16 pc) is discovered on the southern side of the driving source. Using the 12CO(J = 1–0), 12CO(J = 3–2), and 13CO(J = 1–0) emission, observational signposts of cloud-cloud collision (or interacting clouds) towards Pillar IV are investigated. Overall, our results suggest that the interaction of molecular cloud components around 23 and 26 km s−1 might have influenced star formation activity in Pillar IV.

Corelease of Genotoxic Polycyclic Aromatic Hydrocarbons and Nanoparticles from a Commercial Aircraft Jet Engine - Dependence on Fuel and Thrust.

Jet engines are important contributors to global CO2 emissions and release enormous numbers of ultrafine particles into different layers of the atmosphere. As a result, aviation emissions are affecting atmospheric chemistry and promote contrail and cloud formation with impacts on earth's radiative balance and climate. Furthermore, the corelease of nanoparticles together with carcinogenic polycyclic aromatic hydrocarbons (PAHs) affects air quality at airports. We studied exhausts of a widely used turbofan engine (CFM56-7B26) operated at five static thrust levels (idle, 7, 30, 65, and 85%) with conventional Jet A-1 fuel and a biofuel blend composed of hydro-processed esters and fatty acids (HEFA). The particles released, the chemical composition of condensable material, and the genotoxic potential of these exhausts were studied. At ground operation, particle number emissions of 3.5 and 0.5 × 1014 particles/kg fuel were observed with highest genotoxic potentials of 41300 and 8800 ng toxicity equivalents (TEQ)/kg fuel at idle and 7% thrust, respectively. Blending jet fuel with HEFA lowered PAH and particle emissions by 7-34% and 65-67% at idle and 7% thrust, respectively, indicating that the use of paraffin-rich biofuels is an effective measure to reduce the exposure of airport personnel to nanoparticles coated with genotoxic PAHs (Trojan horse effect).

The Atacama Cosmology Telescope: Galactic Dust Structure and the Cosmic PAH Background in Cross-correlation with WISE

We present a cross-correlation analysis between resolution total intensity and polarization observations from the Atacama Cosmology Telescope (ACT) at 150 and 220 GHz and 15″ mid-infrared photometry from the Wide-field Infrared Survey Explorer (WISE) over 107 12.°5 × 12.°5 patches of sky. We detect a spatially isotropic signal in the WISE×ACT TT cross-power spectrum at 30σ significance that we interpret as the correlation between the cosmic infrared background at ACT frequencies and polycyclic aromatic hydrocarbon (PAH) emission from galaxies in WISE, i.e., the cosmic PAH background. Within the Milky Way, the Galactic dust TT spectra are generally well described by power laws in ℓ over the range 103 < ℓ < 104, but there is evidence both for variability in the power-law index and for non-power-law behavior in some regions. We measure a positive correlation between WISE total intensity and ACT E-mode polarization at 1000 < ℓ ≲ 6000 at >3σ in each of 35 distinct ∼100 deg2 regions of the sky, suggesting that alignment between Galactic density structures and the local magnetic field persists to subparsec physical scales in these regions. The distribution of TE amplitudes in this ℓ range across all 107 regions is biased to positive values, while there is no evidence for such a bias in the TB spectra. This work constitutes the highest-ℓ measurements of the Galactic dust TE spectrum to date and indicates that cross-correlation with high-resolution mid-infrared measurements of dust emission is a promising tool for constraining the spatial statistics of dust emission at millimeter wavelengths.

Probing Disk Ice Content and Polycyclic Aromatic Hydrocarbon Emission through Multiband MagAO+Clio Images of HD 141569

We present resolved images of the inner disk component around HD 141569A using the Magellan adaptive optics system with the Clio2 1–5 μm camera, offering a glimpse of a complex system thought to be in a short evolutionary phase between protoplanetary and debris disk stages. We use a reference star along with the Karhunen–Loéve image projection (KLIP) algorithm for point-spread function subtraction to detect the disk inward to about 0.″24 (∼25 au assuming a distance of 111 pc) at high signal-to-noise ratios at L′ (3.8 μm), Ls (3.3 μm), and narrowband Ice (3.1 μm). We identify an arc or spiral arm structure at the southeast extremity, consistent with previous studies. We implement forward modeling with a simple disk model within the framework of a Markov Chain Monte Carlo sampler to better constrain the geometrical attributes and photometry using our KLIP-reduced disk images. We then leverage these modeling results to facilitate a comparison of the measured brightness in each passband to find a reduction in scattered light from the disk in the Ice filter, implying significant absorption due to water ice in the dust. Additionally, our best-fit disk models exhibit peak brightness in the southwestern, back-scattering region of the disk, which we suggest to be possible evidence of 3.3 μm polycyclic aromatic hydrocarbon emission. However, we point out the need for additional observations with bluer filters and more complex modeling to confirm these hypotheses.

China's economic restructuring reduced emissions of polycyclic aromatic hydrocarbons (PAHs) in the post-global financial crisis era

Polycyclic aromatic hydrocarbons (PAHs) emissions driven by transboundary supply-chain activities across Chinese provinces are largely unknown. In this study, we comprehensively assessed the dynamics of production-, consumption-, and income-based PAHs emissions from individual Chinese provinces in China from 2007 to 2017. We also examined the critical supply-chain paths and socioeconomic drivers behind the changes in PAHs emissions and explored their correlations with China's economic restructuring during this period. We found that production-, consumption-, and income-based PAHs emissions have decreased to lower levels in 2017 (45.6, 36.2, and 40.1 kt, respectively) than those (52.8, 37.5, and 43.6 kt, respectively) in 2007. The dominant contributors of trade-driven PAHs emissions were located in the northern inland provinces with rich coal resources and the southeastern coastal provinces with dense populations and developed economies. China's economic restructuring reduced PAHs emissions in these provinces in the post-global financial crisis era, benefiting from improvements in emission intensity and trade structure. Concurrently, migrating energy- and emission-intensive industries into less affluent provinces (e.g., Xinjiang, Jiangxi, Henan, Anhui, and Yunnan) changed the roles of emission factors (from the demand side), primary input structure and energy mix (from the supply side) from driving down to driving up PAHs emissions. These changing drivers exerted a greater upward influence on PAHs emissions than the overall downward influence exerted by other drivers, thereby causing emissions outsourcing and leakage. This study explored the effects of economic structural transition on interprovincial trade-driven PAH emission transfer, offering valuable insights for policymakers to formulate policies for mitigating PAHs emissions.

Critical review on the formations and exposure of polycyclic aromatic hydrocarbons (PAHs) in the conventional hydrocarbon-based fuels: Prevention and control strategies

Polycyclic aromatic hydrocarbons (PAHs) are widely present in the atmosphere and primarily originate from the incomplete burning of fossil fuels and biofuels. Exposure to PAHs leads to harmful effects on human health and the environment. Diesel engines are a major source of PAH production in the transportation sector. Various approaches have been employed to reduce PAH emissions from diesel engines, including the use of biodiesel, green gaseous fuels, exhaust gas recirculation, exhaust after-treatment, and genetically modifying biodiesel with nanoparticles. This review focuses on PAH emissions from different generations of fuels and examines the remedial control actions taken to mitigate PAH formation. The study underscores the necessity for effective regulation of emissions from diesel engines, especially in developing countries where the reliance on fossil fuels is significant. Biodiesel has shown promise in reducing PAHs and carcinogenic pollutants, with higher biodiesel concentrations resulting in lower PAH formation. Replacing diesel with biodiesel and optimizing engine operating conditions are feasible methods to reduce PAH levels in the atmosphere. The use of nanoparticles in fuel blends and higher oxygen content in combustion chambers are also considered potential strategies for pollutant reduction. Additionally, the utilization of hydrogen and ammonia as secondary fuels has been explored as promising alternatives to fossil fuels. The study highlights the importance of further research on the presence of residual PAHs in the atmosphere and the implementation of strategies to curtail vehicular emissions.

JWST observations of the Ring Nebula (NGC 6720): I. Imaging of the rings, globules, and arcs

ABSTRACT We present JWST images of the well-known planetary nebula NGC 6720 (the Ring Nebula), covering wavelengths from 1.6 to 25 $\, \mu$m. The bright shell is strongly fragmented with some 20 000 dense globules, bright in H2, with a characteristic diameter of 0.2 arcsec and density nH ∼ 105–106 cm−3. The shell contains a narrow ring of polycyclic aromatic hydrocarbon (PAH) emission. H2 is found throughout the shell and also in the halo. H2 in the halo may be located on the swept-up walls of a biconal polar flow. The central cavity is filled with high-ionization gas and shows two linear structures which we suggest are the edges of a biconal flow, seen in projection against the cavity. The central star is located 2 arcsec from the emission centroid of the cavity and shell. Linear features (‘spikes’) extend outward from the ring, pointing away from the central star. Hydrodynamical simulations reproduce the clumping and possibly the spikes. Around 10 low-contrast, regularly spaced concentric arc-like features are present; they suggest orbital modulation by a low-mass companion with a period of about 280 yr. A previously known much wider companion is located at a projected separation of about 15 000 au; we show that it is an M2–M4 dwarf. NGC 6720 is therefore a triple star system. These features, including the multiplicity, are similar to those seen in the Southern Ring Nebula (NGC 3132) and may be a common aspect of such nebulae.

JWST: Deuterated PAHs, PAH Nitriles, and PAH Overtone and Combination Bands. I. Program Description and First Look

A first look is taken at the NIRSpec 1–5 μm observations from James Webb Space Telescope program 1591 that targets seven objects along the low-mass stellar life cycle with polycyclic aromatic hydrocarbon (PAH) emission. Spectra extracted from a 1.″5 radius circular aperture are explored, showing a wealth of features, including the 3 μm PAH complex, the PAH continuum, and atomic and molecular emission lines from H i, He, H2, and other species. CO2- and H2O-ice absorption and CO emission is also seen. Focusing on the bright-PDR position in M17, the PAH CH stretch falls at 3.29 μm (FWHM = 0.04 μm). Signs of its 1.68 μm overtone are confused by line emission in all targets. Multicomponent decomposition reveals a possible aliphatic deuterated PAH feature centered at 4.65 μm (FWHM = 0.02 μm), giving [D/H]alip. = 31% ± 12.7%. However, there is little sign of its aromatic counterpart between 4.36 and 4.43 μm. There is also little sign of PAH nitrile emission between 4.34 and 4.39 μm. A PAH continuum rises from ∼1 to 3.2 μm, after which it jumps by about a factor of 2.5 at 3.6 μm, with bumps at 3.8, 4.04, and 4.34 μm adding structure. The CO2 absorption band in M17 is matched with 10:1 H2O:CO2 ice at 10 K. The v = 0 pure rotational molecular hydrogen population diagram reveals >2200 K UV-pumped gas. The hydrogen Pfund series runs from levels 10 to >30. Considering Brα/Brβ = 0.381 ± 0.01966 and Case B recombination results in A V ≃ 8. CO emission in IRAS 21282+5050 originates from 258 K gas. In-depth spectral–spatial analysis of all features and targets is planned for a series of forthcoming papers.