Polycyclic Aromatic Hydrocarbon Bands Research Articles

A Comparative Study of Mid-infrared Star Formation Rate Tracers and Their Metallicity Dependence

Abstract We present a comparative study of a set of star formation rate (SFR) tracers based on mid-infrared emission in the 12.81 μm [Ne ii] line, the 15.56 μm [Ne iii] line, and emission features from polycyclic aromatic hydrocarbons (PAHs) between 5.2 and 14.7 μm. We calibrate our tracers with the thermal component of the radio continuum emission at 33 GHz from 33 extranuclear star-forming regions observed in nearby galaxies. Correlations between mid-IR emission features and thermal 33 GHz SFRs show significant metallicity-dependent scatter and offsets. We find similar metallicity-dependent trends in commonly used SFR tracers such as Hα and 24 μm. As seen in previous studies, PAH emission alone is a poor SFR tracer owing to a strong metallicity dependence: lower-metallicity regions show decreased PAH emission relative to their SFR compared to higher-metallicity regions. We construct combinations of PAH bands, neon emission lines, and their respective ratios to minimize metallicity trends. The calibrations that most accurately trace SFR with minimal metallicity dependence involve the sum of the integrated intensities of the 12.81 μm [Ne ii] line and the 15.56 μm [Ne iii] line combined with any major PAH feature normalized by dust continuum emission. This mid-IR calibration is a useful tool for measuring SFR, as it is minimally sensitive to variations in metallicity and is composed of bright, ubiquitous emission features. The Mid-Infrared Instrument (MIRI) on the James Webb Space Telescope will detect these features from galaxies as far as redshift z ∼ 1. We also investigate the behavior of the PAH band ratios and find that subtracting the local background surrounding a star-forming region decreases the ratio of PAH 11.3 μm to 7.7 μm emission. This implies that PAHs are more ionized in star-forming regions relative to their surroundings.

Polycyclic Aromatic Hydrocarbons with Armchair Edges: Potential Emitters in Class B Sources

We have systematically investigated a series of polycyclic aromatic hydrocarbons (PAHs) with armchair edges that maximize the aromaticity, denoted as Clar PAHs, using density functional theory. Their structures fall into three major categories: branched, intermediate, and armchair. Branched PAHs contain up to 60 carbons, they are eroded and the least stable, and their spectra are the most complex. Armchair PAHs are the most stable and their spectra differ from the nominal PAH spectra by lacking a 11.2 μm band and having their 7.8 and 8.2 μm bands coalesce as their size increases. Only intermediate and armchair PAHs have 12.7/13.5 μm PAH band intensity ratios that are consistent with observations. The fitting results show that Clar PAH spectra are more consistent with class B than class A sources, with only a few small Clar PAHs contributing to the fit of the class A source IRAS 23133+6050 and large Clar PAHs contributing to the fit of the class B source IRAS 17347−3139, and NGC 7027. Overall, our study suggests that large Clar PAHs are potential emitters in class B sources.

Revisiting the dust properties in the molecular clouds of the Large Magellanic Cloud

Context. Some Galactic molecular clouds show signs of dust evolution as compared to the diffuse interstellar medium, most of the time through indirect evidence such as color ratios, increased dust emissivity, or scattering (coreshine). These signs are not a feature of all Galactic clouds. Moreover, molecular clouds in the Large Magellanic Cloud (LMC) have been analyzed in a previous study based on Spitzer and IRIS data, at 4′ angular resolution, with the use of one single dust model, and did not show any signs of dust evolution. Aims. In this present analysis we investigate the dust properties associated with the different gas phases (including the ionized phase this time) of the LMC molecular clouds at 1′ angular resolution (four times greater than the previous analysis) and with a larger spectral coverage range thanks to Herschel data. We also ensure the robustness of our results in the framework of various dust models. Methods. We performed a decomposition of the dust emission in the infrared (from 3.6 to 500 μm) associated with the atomic, molecular, and ionized gas phases in the molecular clouds of the LMC. The resulting spectral energy distributions were fitted with four distinct dust models. We then analyzed the model parameters such as the intensity of the radiation field and the relative dust abundances, as well as the slope of the emission spectra at long wavelengths. Results. This work allows dust models to be compared with infrared data in various environments for the first time, which reveals important differences between the models at short wavelengths in terms of data fitting (mainly in the polycyclic aromatic hydrocarbon bands). In addition, this analysis points out distinct results according to the gas phases, such as dust composition directly affecting the dust temperature and the dust emissivity in the submillimeter and different dust emission in the near-infrared (NIR). Conclusions. We observe direct evidence of dust property evolution from the diffuse to the dense medium in a large sample of molecular clouds in the LMC. In addition, the differences in the dust component abundances between the gas phases could indicate different origins of grain formation. We also point out the presence of a NIR-continuum in all gas phases, with an enhancement in the ionized gas. We favor the hypothesis of an additional dust component as the carrier of this continuum.

Examining the Class B to A Shift of the 7.7 μm PAH Band with the NASA Ames PAH IR Spectroscopic Database

Abstract We present insights into the behavior of the astronomical 7.7 μm polycyclic aromatic hydrocarbon (PAH) emission complex as gleaned from analyzing synthesized spectra, utilizing the data and tools from the NASA Ames PAH IR Spectroscopic Database. We specifically study the influence of PAH size, charge, aliphatic content, and nitrogen substitution on the profile and peak position of the 7.7 μm feature (λ 7.7). The 7.7 μm band is known to vary significantly from object to object in astronomical observations, but the origin of these variations remains highly speculative. Our results indicate that PAH size can accommodate the largest shift in λ 7.7 (≃0.4 μm), where relatively small PAHs are consistent with class A spectra ( ≤ 60), while large PAHs are consistent with red/very red class B spectra. Aliphatic PAHs, of which our sample only contains a few, can produce redshifts typically around 0.15 μm; changes in ionization fraction, depending on the species, produce shifts of up to 0.1 μm; and nitrogen substitution has no effect on λ 7.7. Within the limits of our study, the class B → A transition is best explained with a changing PAH size distribution, with a relatively minor role assigned to aliphatic content and varying charge states. The resulting astronomical picture is that the photochemical evolution of PAHs moving from shielded class C/B environments into exposed ISM-like class A environments may be intrinsically different from the reverse class A → B transition of interstellar PAHs being incorporated into newly forming star systems.

Whipping IC 63/IC 59

Context. IC 63 and IC 59 are a pair of cometary-shaped nebulae in the vicinity of the star γCas (also known as Tsih, “the Whip”). Both nebulae have very different optical appearances, despite the fact that both objects lie at similar projected distances from the star: IC 63 shows bright rims and filaments, while IC 59 looks more homogeneous and faint. Aims. We aim to perform a general description of the two nebulae from an observational standpoint in order to study the physical conditions at the UV-illuminated surfaces of these objects. Methods. We used the available data on both nebulae taken with Spitzer and Herschel to study the infrared emission at the tip of both clouds, and derive the intensity of the UV radiation field. Using the photodetector array camera and spectrometer (PACS) in line spectroscopy mode, we obtained the intensity of the cooling lines [C II] 157 μm and [O I] 63 μm, and we used these to estimate the density in these regions. Excitation diagrams of molecular hydrogen were obtained to derive the gas temperature. We also used [C II] 157 μm velocity maps of IC 59 taken with German REceiver for Astronomy at Terahertz frequencies (GREAT) on board SOFIA to explore the gas dynamics in this nebula. Results. We find that the IR emission from polycyclic aromatic hydrocarbons (PAHs) is very similar at the tip of both nebulae. Even though it varies in intensity between the two, the derived PAH band ratios are remarkably similar. These ratios are similar to those found in the more shielded regions of other nebulae such as NGC 7023 and NGC 2023. Regarding the physical conditions, we get that while in IC 63 the intensity of the UV field, G0, is a factor of approximately ten higher than in IC 59, the density n at the tip of IC 59 is lower than in IC 63 by a similar factor. For both objects we derive G0 values significantly lower than what previous works have so far assumed. Comparison with other reflection nebulae photo-dissociation regions (PDRs) and known correlations support our claim that both IC 63 and IC 59 are low-UV irradiated environments. Conclusions. We conclude that the tips of IC 63 and IC 59 are about three and five times farther away from the star than their respective projected distances. The similarity of the mid-infrared emission between the two nebulae is consistent not only with both objects being overdensities within the same region around γCas, but it is also consistent with the similar G0/n and ionization parameters, which altogether rule the evolution of the hydrogenation and ionization level of the emitting population of PAHs. Finally, regarding the kinematics of the material in IC 59, we find evidence of photo-evaporation due to the incident radiation from γCas.

The Charge State of Polycyclic Aromatic Hydrocarbons across a Reflection Nebula, an H ii Region, and a Planetary Nebula

Abstract Low-resolution Spitzer-IRS spectral map data of a reflection nebula (NGC 7023), H ii region (M17), and planetary nebula (NGC 40), totaling 1417 spectra, are analyzed using the data and tools available through the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbon (PAH) emission is broken down into PAH charge and size subclass contributions using a database-fitting approach. The resulting charge breakdown results are combined with those derived using the traditional PAH band strength ratio approach, which interprets particular PAH band strength ratios as proxies for PAH charge. Here the 6.2/11.2 μm PAH band strength ratio is successfully calibrated against its database equivalent: the ratio. In turn, this ratio is converted into the PAH ionization parameter, which relates it to the strength of the radiation field, gas temperature, and electron density. Population diagrams are used to derive the density and temperature. The bifurcated plot of the 8.6 versus 11.2 μm PAH band strength for the northwest photo dissociation region in NGC 7023 is shown to be a robust diagnostic template for the ratio in all three objects. Template spectra for the PAH charge and size subclasses are determined for each object and shown to favorably compare. Using the determined template spectra from NGC 7023 to fit the emission in all three objects yields, upon inspection of the Structure SIMilarity maps, satisfactory results. The choice of extinction curve proves to be critical. Concluding, the distinctly different astronomical environments of a reflection nebula, H ii region, and planetary nebula are reflected in their PAH emission spectra.

Embedded AGN and star formation in the central 80 pc of IC 3639

Aims. Our goal is to probe the inner structure and the nature of the mid-IR emission in the active galaxy IC 3639, which hosts a Seyfert 2 nucleus and shows signatures of strong star-forming activity. Methods. We used interferometric observations in the N-band with VLTI/MIDI to resolve the mid-IR emission of this nucleus. The origin of the nuclear infrared emission is determined from: (1) the comparison of the correlated fluxes from VLTI/MIDI with the fluxes measured at subarcsecond resolution (VLT/VISIR, VLT/ISAAC); (2) diagnostics based on IR fine-structure line ratios, the IR continuum emission, IR bands produced by polycyclic aromatic hydrocarbons (PAH) and silicates; and (3) the high-angular resolution spectral energy distribution. Results. A large fraction of the total mid-IR emission of IC 3639 is produced in the innermost ≲80 pc with only ~1% of the total luminosity released in the UV/optical range. The unresolved flux of IC 3639 is 90 ± 20 mJy at 10.5 μm, measured with three different baselines in VLTI (UT1–UT2, UT3–UT4, and UT2–UT3; 46–58 m), making this the faintest measurement so far achieved with mid-IR interferometry. The correlated flux is a factor of 3–4 times fainter than the VLT/VISIR total flux measurement. The observations suggest that most of the mid-IR emission has its origin on spatial scales between 10 and 80 pc (40–340 mas). The emission confined within the inner 80 pc is either dominated by a starburst component or by the AGN core. The brightness distribution could be reproduced by a single component associated with the AGN, although this scenario would imply a very extended dust distribution when compared to other nearby Seyfert galaxies detected with MIDI. The extended component could also be associated with polar dust emission, that is, with a dusty wind blown by the AGN. However, a mixed contribution dominated by the star formation component over the AGN is favoured by the diagnostics based on ratios of IR fine-structure emission lines, the shape of the IR continuum, and the PAH and silicate bands. Conclusions. A composite AGN-starburst scenario is able to explain both the mid-IR brightness distribution and the IR spectral properties observed in the nucleus of IC 3639. The nuclear starburst would dominate the mid-IR emission and the ionisation of low-excitation lines (e.g. [Ne II]12.8 μm) with a net contribution of ~70%. The AGN accounts for the remaining ~30% of the mid-IR flux, ascribed to the unresolved component in the MIDI observations, and the ionisation of high-excitation lines (e.g. [Ne V]14.3 μm and [O Iv]25.9 μm).

Search for polycyclic aromatic hydrocarbons in the outflows from dust-producing Wolf–Rayet stars

A combined mid-IR spectrum of five colliding-wind, massive, dust-producing Population I Wolf-Rayet (WR) binaries shows a wealth of absorption and emission details coming from the circumstellar dust envelopes, as well as from the interstellar medium. The prominent absorption features may arise from a mix of interstellar carbonaceous grains formed in high- (e.g., 3.4, 6.8, 7.2 $\mu$m) and low-temperature (3.3, 6.9, 9.3 $\mu$m) environments. The broad emission complexes around $\sim$6.5, 8.0 and 8.8 $\mu$m could arise from ionized, small polycyclic aromatic hydrocarbon (PAH) clusters and/or amorphous carbonaceous grains. As such these PAH emissions may represent the long sought after precursors of amorphous Carbon dust. We also detect a strong $\sim$10.0 $\mu$m emission in the spectra of WR48a and WR112, that we tentatively link to ionized PAHs. Upon examining the available archival spectra of prodigious individual WR dust sources, we notice a surprising lack of 7.7 $\mu$m PAH band in the spectrum of the binary WR19, in contrast to the apparent strength of the 11.2, 12.7 and 16.4 $\mu$m PAH features. Strong PAH emissions are also detected in the $\lambda>$10 $\mu$m spectrum of another dust-producing system, WR118, pointing to the presence of large, neutral, presumably interstellar PAH molecules towards WR19 and WR118.

The PAH Emission Characteristics of the Reflection Nebula NGC 2023

Abstract We present 5–20 μm spectral maps of the reflection nebula NGC 2023 obtained with the Infrared Spectrograph SL and SH modes on board the Spitzer Space Telescope, which reveal emission from polycyclic aromatic hydrocarbons (PAHs), C60, and H2 superposed on a dust continuum. We show that several PAH emission bands correlate with each other and exhibit distinct spatial distributions that reveal a spatial sequence with distance from the illuminating star. We explore the distinct morphology of the 6.2, 7.7, and 8.6 μm PAH bands and find that at least two spatially distinct components contribute to the 7–9 μm PAH emission in NGC 2023. We report that the PAH features behave independently of the underlying plateaus. We present spectra of compact, oval PAHs ranging in size from C66 to C210, determined computationally using density functional theory, and we investigate trends in the band positions and relative intensities as a function of PAH size, charge, and geometry. Based on the NASA Ames PAH database, we discuss the 7–9 μm components in terms of band assignments and relative intensities. We assign the plateau emission to very small grains with possible contributions from PAH clusters and identify components in the 7–9 μm emission that likely originate in these structures. Based on the assignments and the observed spatial sequence, we discuss the photochemical evolution of the interstellar PAH family as the PAHs are more and more exposed to the radiation field of the central star in the evaporative flows associated with the Photo-Dissociation Regions in NGC 2023.

Observational Evidence Linking Interstellar UV Absorption to PAH Molecules

Abstract The 2175 Å UV extinction feature was discovered in the mid-1960s, yet its physical origin remains poorly understood. One suggestion is absorption by polycyclic aromatic hydrocarbon (PAH) molecules, which is supported by theoretical molecular structure computations and by laboratory experiments. PAHs are positively detected by their 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 μm IR emission bands, which are specified by their modes of vibration. A definitive empirical link between the 2175 Å UV extinction and the IR PAH emission bands, however, is still missing. We present a new sample of hot stars that have both 2175 Å absorption and IR PAH emission. We find significant shifts of the central wavelength of the UV absorption feature, up to 2350 Å, but predominantly in stars that also have IR PAH emission. These UV shifts depend on stellar temperature in a fashion that is similar to the shifts of the 6.2 and 7.7 μm IR PAH bands, that is, the features are increasingly more redshifted as the stellar temperature decreases, but only below ∼15 kK. Above 15 kK both UV and IR features retain their nominal values. Moreover, we find a suggestive correlation between the UV and IR shifts. We hypothesize that these similar dependences of both the UV and IR features on stellar temperature hint at a common origin of the two in PAH molecules and may establish the missing link between the UV and IR observations. We further suggest that the shifts depend on molecular size, and that the critical temperature of ∼15 kK above which no shifts are observed is related to the onset of UV-driven hot-star winds and their associated shocks.

INTERPRETING THE SUBTLE SPECTRAL VARIATIONS OF THE 11.2 AND 12.7 μm POLYCYCLIC AROMATIC HYDROCARBON BANDS

ABSTRACT We report new properties of the 11 and 12.7 μm emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution Spitzer Space Telescope data, we study in detail the spectral and spatial characteristics of the 11 and 12.7 μm emission bands in maps of reflection nebulae NGC 7023 and NGC 2023 (north and south) and the star-forming region M17. Profile variations are observed in both the 11 and 12.7 μm emission bands. We identify a neutral contribution to the traditional 11.0 μm PAH band and a cationic contribution to the traditional 11.2 μm band, the latter of which affects the PAH class of the 11.2 μm emission in our sample. The peak variations of the 12.7 μm complex are explained by the competition between two underlying blended components. The spatial distributions of these components link them to cations and neutrals. We conclude that the 12.7 μm emission originates in both neutral and cationic PAHs, lending support to the use of the 12.7/11.2 intensity ratio as a charge proxy.

Chemical abundances in the PN Wray16-423 in the Sagittarius dwarf spheroidal galaxy: constraining the dust composition

We performed a detailed analysis of elemental abundances, dust features, and polycyclic aromatic hydrocarbons (PAHs) in the C-rich planetary nebula (PN) Wray16-423 in the Sagittarius dwarf spheroidal galaxy, based on a unique dataset taken from the Subaru/HDS, MPG/ESO FEROS, HST/WFPC2, and Spitzer/IRS. We performed the first measurements of Kr, Fe, and recombination O abundance in this PN. The extremely small [Fe/H] implies that most Fe atoms are in the solid phase, considering into account the abundance of [Ar/H]. The Spitzer/IRS spectrum displays broad 16-24 um and 30 um features, as well as PAH bands at 6-9 um and 10-14 um. The unidentified broad 16-24 um feature may not be related to iron sulfide (FeS), amorphous silicate, or PAHs. Using the spectral energy distribution model, we derived the luminosity and effective temperature of the central star, and the gas and dust masses. The observed elemental abundances and derived gas mass are in good agreement with asymptotic giant branch nucleosynthesis models for an initial mass of 1.90 Msun and a metallicity of Z=0.004. We infer that respectively about 80 %, 50 %, and 90 % of the Mg, S, and Fe atoms are in the solid phase. We also assessed the maximum possible magnesium sulfide (MgS) and iron-rich sulfide (Fe50S) masses and tested whether these species can produce the band flux of the observed 30 um feature. Depending on what fraction of the sulfur is in sulfide molecules such as CS, we conclude that MgS and Fe50S could be possible carriers of the 30 um feature in this PN.

Absorption and Laser Induced Fluorescence Spectroscopy of Neutral Polycyclic Aromatic Hydrocarbons in Argon matrices

Polycyclic aromatic hydrocarbons (PAHs) are considered as plausible carriers for the extended red emission (ERE), a photoluminescent process associated with a wide variety of interstellar environments, as well as for broad emission band features seen in cometary spectra. We report the absorption spectra of phenanthrene, anthracene, fluoranthene, pentacene, pyrene, chrysene and triphenylene isolated at 10 K in solid argon matrices together with laser induced fluorescence (LIF) spectra at 355 nm of matrix-isolated anthracene and fluoranthene. LIF spectra are compared with the UV/blue fluorescence spectra of the Red Rectangle Nebula (RR). The LIF spectra measured in solid Ar matrices have been shifted to the predicted position of the PAH band emission in the gas phase for comparison with the astronomical observations (Fig. 1).

PAH EMISSION AT THE BRIGHT LOCATIONS OF PDRs: THE grandPAH HYPOTHESIS

The polycyclic aromatic hydrocarbon (PAH) emission observed in the Spitzer Infrared Spectrograph spectra of bright mid-IR locations of NGC 7023, NGC 2023, and NGC 1333 was analyzed. These objects show large variations in PAH band ratios when studied through spectral mapping. Nevertheless, the mid-IR spectra at these bright spots show a remarkably similar PAH emission. We used the NASA Ames PAH IR Spectroscopic Database to fit the observations and analyze the derived PAH populations. Our results show that PAH emission in the 5–15 μm range appears to be rather insensitive to variations of the radiation field. Similar PAH populations of neutral small to medium-sized PAHs (∼50%), with ionized species contributing in slightly less than 50%, provide very good fits. Analyzing the degeneracy of the results shows that subtle (but intrinsic) variations in the emission properties of individual PAHs lead to observable differences in the resulting spectra. On top of this, we found that variations of <30% in the PAH abundances would lead to noticeable spectral differences between the three photodissociation regions (PDRs). Therefore, PAH populations must be remarkably similar at these different lines of sight. To account for this, we suggest the concept of grandPAHs as a unique mixture of the most stable PAHs emitting at these spots. Using NGC 7023 as an example, the grandPAHs refer to the robust PAH population that results from the intense processing of PAHs at the border limit between the PDR and the molecular cloud, where, due to the UV radiation that destroys the PAH population, the abundance of PAHs starts decreasing as we move toward the star.

Predictions for surveys with the SPICA Mid-infrared Instrument

We present predictions for number counts and redshift distributions of galaxies detectable in continuum and in emission lines with the Mid-infrared (MIR) Instrument (SMI) proposed for the Space Infrared Telescope for Cosmology and Astrophysics. We have considered 24 MIR fine-structure lines, four polycyclic aromatic hydrocarbon bands (at 6.2, 7.7, 8.6 and 11.3 μm) and two silicate bands (in emission and in absorption) at 9.7 and 18.0 μm. Six of these lines are primarily associated with active galactic nuclei (AGNs), the others with star formation. A survey with the SMI spectrometers of 1-h integration per field of view (FoV) over an area of 1 deg2 will yield 5σ detections of ≃ 140 AGN lines and of ≃ 5.2 × 104 star-forming galaxies, ≃ 1.6 × 104 of which will be detected in at least two lines. The combination of a shallow (20.0 deg2, 1.4 × 10−1 h integration per FoV) and a deep survey (6.9 × 10−3 deg2, 635 h integration time), with the SMI camera, for a total of ∼1000 h, will accurately determine the MIR number counts of galaxies and of AGNs over five orders of magnitude in flux density, reaching values more than one order of magnitude fainter than the deepest Spitzer 24 μm surveys. This will allow us to determine the cosmic star formation rate (SFR) function down to SFRs more than 100 times fainter than reached by the Herschel Observatory.

PROPERTIES OF POLYCYCLIC AROMATIC HYDROCARBONS IN THE NORTHWEST PHOTON DOMINATED REGION OF NGC 7023. III. QUANTIFYING THE TRADITIONAL PROXY FOR PAH CHARGE AND ASSESSING ITS ROLE

Polycyclic aromatic hydrocarbon (PAH) emission in the Spitzer/IRS spectral map of the northwest photon dominated region (PDR) in NGC 7023 is analyzed. Here, results from fitting the 5.2–14.5 μm spectrum at each pixel using exclusively PAH spectra from the NASA Ames PAH IR Spectroscopic Database (www.astrochem.org/pahdb/) and observed PAH band strength ratios, determined after isolating the PAH bands, are combined. This enables the first quantitative and spectrally consistent calibration of PAH charge proxies. Calibration is straightforward because the 6.2/11.2 μm PAH band strength ratio varies linearly with the ionized fraction (PAH ionization parameter) as determined from the intrinsic properties of the individual PAHs comprising the database. This, in turn, can be related to the local radiation field, electron density, and temperature. From these relations diagnostic templates are developed to deduce the PAH ionization fraction and astronomical environment in other objects. The commonly used 7.7/11.2 μm PAH band strength ratio fails as a charge proxy over a significant fraction of the nebula. The 11.2/12.7 μm PAH band strength ratio, commonly used as a PAH erosion indicator, is revealed to be a better tracer for PAH charge across NGC 7023. Attempting to calibrate the 12.7/11.2 μm PAH band strength ratio against the PAH hydrogen adjacency ratio (duo+trio)/solo is, unexpectedly, anti-correlated. This work both validates and extends the results from Paper I and Paper II.

The 11.2 μm emission of PAHs in astrophysical objects

The 11.2-μm emission band belongs to the family of the ‘unidentified’ infrared emission bands seen in many astronomical environments. In this work, we present a theoretical interpretation of the band characteristics and profile variation for a number of astrophysical sources in which the carriers are subject to a range of physical conditions. The results of Density Functional Theory calculations for the solo out-of-plane vibrational bending modes of large polycyclic aromatic hydrocarbon (PAH) molecules are used as input for a detailed emission model which includes the temperature and mass dependence of PAH band wavelength, and a PAH mass distribution that varies with object. Comparison of the model with astronomical spectra indicates that the 11.2-μm band asymmetry and profile variation can be explained principally in terms of the mass distribution of neutral PAHs with a small contribution from anharmonic effects.

PROPERTIES OF POLYCYCLIC AROMATIC HYDROCARBONS IN THE NORTHWEST PHOTON DOMINATED REGION OF NGC 7023. II. TRADITIONAL PAH ANALYSIS USINGk-MEANS AS A VISUALIZATION TOOL

Polycyclic aromatic hydrocarbon (PAH) emission in the Spitzer-IRS spectral map of the northwest photon dominated region (PDR) in NGC 7023 is analyzed using the 'traditional' approach in which the PAH bands and plateaus between 5.2-19.5 μm are isolated by subtracting the underlying continuum and removing H{sub 2} emission lines. The spectra are organized into seven spectroscopic bins by using k-means clustering. Each cluster corresponds to, and reveals, a morphological zone within NGC 7023. The zones self-organize parallel to the well-defined PDR front that coincides with an increase in intensity of the H{sub 2} emission lines. PAH band profiles and integrated strengths are measured, classified, and mapped. The morphological zones revealed by the k-means clustering provides deeper insight into the conditions that drive variations in band strength ratios and evolution of the PAH population that otherwise would be lost. For example, certain band-band relations are bifurcated, revealing two limiting cases; one associated with the PDR, the other with the diffuse medium. Traditionally, PAH band strength ratios are used to gain insight into the properties of the emitting PAH population, i.e., charge, size, structure, and composition. Insights inferred from this work are compared and contrasted to those from Boersma et al. (firstmore » paper in this series), where the PAH emission in NGC 7023 is decomposed exclusively using the PAH spectra and tools made available through the NASA Ames PAH IR Spectroscopic Database.« less

THE MID-INFRARED APPEARANCE OF THE GALACTIC MINI-STARBURST W49A

The massive star forming region W49A represents one of the largest complexes of massive star formation present in the Milky Way and contains at least fifty young massive stars still enshrouded in their natal molecular cloud. We employ Spitzer/IRS spectral mapping observations of the northern part of W49A to investigate the mid-infrared (MIR) spatial appearance of the polycyclic aromatic hydrocarbon (PAH) bands, PAH plateau features, atomic lines and continuum emission. We examine the spatial variations of the MIR emission components in slices through two of the ultra compact-HII (UC-HII) regions. We find that the PAH bands reproduce known trends, with the caveat that the 6.2 $\mu$m PAH band seems to decouple from the other ionized PAH bands in some of the UC-HII regions -- an effect previously observed only in one other object: the giant star forming region N66 in the LMC. Furthermore, we compare the nature of the emission surrounding W49A to that of `diffuse' sightlines. It is found that the surrounding emission can be explained by line of sight emission, and does not represent true `diffuse' material. Additionally, we examine the MIR appearance of star formation on various scales from UC-HII regions to starburst galaxies, including a discussion of the fraction of PAH emission in the 8 $\mu$m IRAC filter. We find that the MIR appearance of W49A is that of a starburst on large scales yet its individual components are consistent with other galactic HII regions.

STAR FORMATION AND THE INTERSTELLAR MEDIUM IN NEARBY TIDAL STREAMS (SAINTS):SPITZERMID-INFRARED SPECTROSCOPY AND IMAGING OF INTERGALACTIC STAR-FORMING OBJECTS

A spectroscopic analysis of 10 intergalactic star forming objects (ISFOs) and a photometric analysis of 67 ISFOs in a sample of 14 interacting systems is presented. The majority of the ISFOs have relative polycyclic aromatic hydrocarbon (PAH) band strengths similar to those of nearby spiral and starburst galaxies. In contrast to what is observed in blue compact dwarfs (BCDs) and local giant HII regions in the Milky Way (NGC 3603) and the Magellanic Clouds (30 Doradus and N 66), the relative PAH band strengths in ISFOs correspond to models with a significant PAH ion fraction (<50%) and bright emission from large PAHs (~100 carbon atoms). The [NeIII]/[NeII] and [SIV]/[SIII] line flux ratios indicate moderate levels of excitation with an interstellar radiation field that is harder than the majority of the Spitzer Infrared Nearby Galaxies Survey and starburst galaxies, but softer than BCDs and local giant HII regions. The ISFO neon line flux ratios are consistent with a burst of star formation < 6 million years ago. Most of the ISFOs have ~million solar masses of warm molecular hydrogen with a likely origin in photo-dissociation regions (PDRs). Infrared Array Camera photometry shows the ISFOs to be bright at 8 um, with one third having [4.5] - [8.0] > 3.7, i.e., enhanced non-stellar emission, most likely due to PAHs, relative to normal spirals, dwarf irregulars and BCD galaxies. The relative strength of the 8 um emission compared to that at 3.6 um or 24 um separates ISFOs from dwarf galaxies in Spitzer two color diagrams. The infrared power in two thirds of the ISFOs is dominated by emission from grains in a diffuse interstellar medium. One in six ISFOs have significant emission from PDRs, contributing ~30 % - 60 % of the total power. ISFOs are young knots of intense star formation.