ABSTRACT The paper proves the possibility of providing magnetic properties in the process of saturation of textile fibers with a nanomixture of divalent and trivalent iron oxides. The mechanisms of interaction of nanostructures with natural and synthetic fibers are analyzed. The peculiarities of the introduction of magnetic components into flax, cotton, polyamide, and polyester fibers are determined. The relative number of particles with nanoscale in the total was statistically proved. To evaluate the macro effects of saturation, the relative amount of the accumulated mixture of divalent and trivalent iron oxides was determined, taking into account the previous fiber weight. Two basic constants characterizing the properties of textile fibers to magnetic interaction are proposed. It is proved that flax fibers exhibit the highest magnetic efficiency. The average size of iron oxide nanoparticles is 80–90 nanometers, which is confirmed by studies using electron microscopy. The final magnetization of the obtained textile materials provides an attractive magnetization of 20–30 mPascal. The magnetic field of magnetic textile fibers acts at a height of up to 6–7 mm. The directions of the use of fibers with magnetic properties are shown as a prospect for the development of textile smart products.