Poly Vinyl Acetate Research Articles

Influence of The Type of Laying Joint on The Mechanical Behavior of Prisms Made With Ecological Bricks

Objective: This paper proposes the study of the influence of laying joints on the mechanical behavior of masonry prisms made with ecological bricks. Method: To this end, an experimental program was developed including prisms constructed with different types of joints: laying mortar, adhesive mortar and PVA glue (polyvinyl acetate). Results and Discussion: The adhesive mortar and the conventional mortar were characterized in terms of their compressive strength, obtaining a resistance approximately 1.36 times the compressive strength of the brick (6.92±0.51 MPa), while the settlement was close (0.99%). The average compressive strengths of the prisms were very different, demonstrating that the laying joint has a significant influence on cement-based masonry. It was found that the use of adhesive mortar made it possible to increase the resistance capacity of the prisms to compression by 75%, when compared to prisms made with joints that used PVA glue. However, the laying mortar showed a similar result, at 53%. The rupture mode observed in the prisms made with sticky and conventional mortar was due to traction cracking in the brick units. Research Implications: In this study, it can be concluded that when using ecological bricks with different types of joints, the thickness and type of mortar can have a significant influence on the final strength of the materials, however thin joints tend to maximize the effects defects and reduce the resistant capacity of these masonries.

Wall Drawing #736: Revealing Sol LeWitt’s Ink Mural Technique Using a Multi-Analytical Approach

Sol LeWitt, a pioneer of conceptual art, created during his career over 1350 wall drawings, including the Wall Drawing #736 (1993) at the Center for Contemporary Art Luigi Pecci in Prato (Prato, Italy). The painting, executed by Andrea Marescalchi and Antony Sansotta under LeWitt’s instructions, features a grid of coloured rectangles obtained by overlapping different layers of inks. During a 2021 restoration by the Wall Paintings and Stuccoes Department of the Opificio delle Pietre Dure (Firenze, Italy), an in-depth investigation of the composition and the materials used by LeWitt’s assistants in producing Wall Drawing #736 was performed. A multi-analytical approach entailing Raman spectroscopy, high-performance liquid chromatography coupled to diode array and high-resolution mass spectrometry, gas chromatography–mass spectrometry (GC–MS), and pyrolysis coupled with GC–MS was applied. Our results revealed the use of animal glue, shellac resin, paraffin wax, linseed oil, and various organic pigments. The binder in the preparation layer was identified as poly(vinyl acetate), while poly(n-butyl methacrylate) was determined as a fixative. This research provided valuable insights into LeWitt’s techniques. The acquired knowledge on the paint technique is highly relevant in supporting conservators in restoration and consolidating the many wall drawings produced exploiting the same technique all over the world.

(Invited) Novel Brush Design for Post CMP Cleans

Chemical Mechanical Polishing (CMP) process is one of the key processes in semiconductor wafer processing. A sub 10nm wafer fabrication process may require more than 40 dielectric and metal CMP steps. As CMP process requirements get more stringent, CMP slurries are formulated with smaller and smaller metal oxide abrasive particles. The abrasive particles may also be surface modified or doped with other metal oxides. Post CMP cleaning chemistry formulations are designed to remove polish byproducts, pad residues and abrasive particles from wafer surface. Chemical composition and PH are tuned for modulating wafer surface-particle interactions so brushes can mechanically “sweep” them off the surface. PVA brushes, used of post CMP cleans, are a highly porous network of crosslinked polyvinyl acetate with pore size in the range of 30 – 100 um and 80% - 90% porosity, depending on the type of brush being used. While PVA brushes have largely met the process capability requirements, they have limitations for advanced cleans such as nano-particle removal. As CMP process continues to expand to new dielectric and metal films for different process steps in wafer fabrication, there is a need for customized brush material and surface design for optimal cleaning efficiency.We discuss a new engineered post CMP brush design that shows high efficiency in nano-particle cleans and allows high level of material tunability. New brush design is an engineered composite with an open cell microporous core, overlaid with engineered fibers in form of loops. Brush design is compatible with existing post CMP cleans. Figure 1(a) shows the new design, where in DIW enters the brush through the center of microporous core and flows outwards to the surface. As water exits the surface, it flows over and across the loops and contacts the wafer surface. Flow resistance through core and loops can be independently tuned, which allows better fluid distribution and more effective cleans. Figure 1(b) show a close-up schematic of interaction between loop and particle. Flexing of the loops on brush surface provides improved contact as well as cleaning ability Brush design can be optimized for chemical and mechanical properties with choice of fiber material, fiber diameter and loop height. Figure 2 shows the Zeta potential of PVA and different loop materials. The fiber material maybe selected such that zeta potential of the loops can enhance mechanical action in removing particle. Mechanical action of the Loops can be modeled as a cantilever and force on the particle is exerted by flexing of the loops.Deflection of loops can be approximated with flexure stiffness of rods with point load at free end. For initial purposed loop is approximated as single element. The equation can be rewritten to calculate cleaning force P at the free end for given loop deflection (Y), P = 3EIY/L3 (1)Where E is elastic modulus, I = moment, L = length of fiber and for rod shapes; I = Pi*(r4/4)The adhesion of particles on the surface is due to the effect of van der Waals and electrostatic forces. The total adhesion force on the surface can be written as: F=F vdw + F edl (2) where Ft is total adhesion force, Fvdw is the van der Waals force, and Fedl is the electrostatic force.Fvdw = AR/6r2 (3)Where A is the Hamaker constant, R is particle radius, r is the separation distanceFor effective removal of particles, P >/= F (4)Flex force and adhesion force were modeled based on equation (1) and (3) and are shown in Figure 3. New brush design was used for post CMP cleaning of silicon dioxide wafers polished with ceria slurry. Two different brush designs were tested for cleaning efficiency. Modeling data and comparison with experimental results is presented. Figure 1

Environmentally-Friendly Recycled Leather‑Reinforced Composite: Thermal and Acoustic Properties

Increase in energy consumption and environmental pollution are some of the main problems of today. One of the ways to overcome these problems is to increase the use of recycled materials. Heat and sound insulation in buildings can play an important role in saving energy and reducing environmental pollution with composite materials made from recycled leather. This study investigates the possibility of reusing leather scraps. Composite material was produced by cutting leather waste for thermal and sound insulation of buildings into small pieces and pressing them in a mechanical mold using polyvinyl acetate binder. The effect of the thickness of the developed new leather-added composite materials on their thermal and acoustic insulation properties was examined. When the thermal and acoustic properties of the composites were evaluated, it was determined that the PVA/skin thicknesses forming the mixture varied depending on the mean temperature and frequency (Hz). As a result of the measurements, it was seen that the sound at the 3000 Hz frequency, to which the human ear is most sensitive, was absorbed by 61%.

Exploring the optical and electric features of PMMA/PVAc blended polymers doped with TBAI/MWCNTs fillers for different applications

The present study focuses on the production of poly (methyl methacrylate)/poly (vinyl acetate)/tetrabutylammonium iodide/multi-walled carbon nanotubes (PMMA/PVAc/TBAI/x wt %MWCNTs) blended polymers. These blends show great potential for use in advanced optical, energy storage and electronics applications. X-ray diffraction (XRD) and scanning electron microscopy techniques was used to explore the structure and morphology of PMMA/PVAc/TBAI with x wt% MWCNTs blended polymers. The optical transmittance lowered to a minimum value of 53–63 % within the specific wavelength range as the blend contained 0.55 wt % multi-walled carbon nanotubes (MWCNTs). The sample containing 0.11 wt% MWCNTs demonstrated the highest reflectance (R) values, whereas the sample with 0.55 wt% MWCNTs showed the lowest R values. As the concentration of MWCNTs increased, these values consistently decreased. The smallest direct (4.55 eV) and indirect (4.45 eV and 2.48 eV) optical band gap (Eg) values were achieved when wt% of MWCNTs were 0.44 % and 0.55 %, respectively. The doped blend with wt% of 0.11 exhibited the highest refractive index values. Blend with x = 0.55 wt % MWCNTs has the highest dielectric constant. The energy density (U) increased non-uniformly as the blend was infused with MWCNTs. Elevating the temperature enhances the values of U for all blends. All blends adhered to the correlated barrier hopping (CBH) model. The effects of MWCNTs doping amount and temperature on the impedance and electric modulus of the host blend were investigated. The dc conductivity of the doped samples was observed to be greater than that of the undoped blend, except for the blend with x = 0.44, where it diminished. The undoped blend displayed activation energy (Ea) values of 1.71 eV and 0.6 eV, depending on the temperature range. When the host blend is doped with MWCNTs, the Ea values either rise or fall depending on the quantity of MWCNTs. All samples have non-ohmic characteristics.

Exploring green environmental composites as hosts for shielding materials using experimental, theoretical and Geant4 simulation methods

Rice straw is considered an agricultural waste harmful to the environment, which is abundant in most parts of the world. From this point, the present study is devoted to preparing new composites of two types of glue based on rice straw as a plentiful, low-cost matrix. Straw glue samples were prepared by mixing 20% wt. of rice straw with 80% wt. of animal glue (RS-An) and polyvinyl acetate (RS-PVAC) at different thicknesses of 1, 2, and 3 cm. The chemical composition of the prepared samples was identified by energy dispersive X-ray analysis and their morphology was examined using a scanning electron microscope. The mechanical test explored that RS-An and RS-PVAC respectively required a stress of 25.2 and 25.5 MPa before reaching the breaking point. γ-ray shielding performance was analyzed and determined at numerous photon energies from 0.059 to 1.408 MeV emitted from five-point γ-rays sources using NaI (Tl). Linear attenuation coefficient was calculated by obtaining the area under the peak of the energy spectrum observed from Genie 2000 software in the presence and absence of the sample. The experimental results of mass attenuation coefficient were compared with theoretical data of XCOM software with relative deviation ranging from 0.10 to 2.99%. Geant4 Monte Carlo simulation code was also employed to validate the experimental results. The relative deviation of XCOM and Geant4 outcomes was 0.09–1.77%, which indicates a good agreement between them. Other radiation shielding parameters such as half value layer (HVL), tenth value layer, and mean free path were calculated in three ways: experimentally, theoretically from the XCOM database, and by simulation using Geant4 code. Additionally, effective atomic number (Zeff), effective atomic number (Neff), equivalent atomic number (Zeq), and buildup factors were evaluated. It was confirmed that the γ-ray shielding properties were further boosted by mixing rice straw with the animal glue compared to the synthetic one.

Synergism in the electrocatalytic properties of cobalt phthalocyanine-carbon nanotube-polymeric electrospun nanofibers immobilized on a gold electrode for the detection of lead(II) ions

Core-shelled electrospun nanofibers (ENFs) comprising of a polyvinyl acetate (PVA) shell encapsulating a composite of polyaniline (PANI), tetra-4-(3-oxyflavonephthalocyaninato)cobalt(II) (CoPc-flav), carboxylic acid functionalized multiwalled carbon nanotubes (f-MWCNTs) and an annealed conductive top layer of Nafion (Nf) were used to fabricated a chemically modified gold electrode (Au|ENFs-1-Nf) via the adsorption method. The electrocatalytic sensing capabilities of the Au|ENFs-1-Nf electrode towards Pb(II) ions were evaluated. In comparison to the bare gold electrode and other chemically modified electrodes (CMEs), the Au|ENFs-1-Nf electrode was less prone to fouling showing more stable analyte signal and less compromised background electrolyte currents. The Au|ENFs-1-Nf electrode could detect the Pb(II) cations in a reproducible manner ranging from 8 to 125 μM where limits of detection and quantification of 0.51 and 1.55 μM were obtained, respectively. The analytical performance of the aforementioned CME rendered a comparable percentage recovery (103 %) with that of Inductively coupled plasma-optical emission spectroscopy (ICP-OES) (115 %).

Constructing carbon nanotube (CNTs)/silica superhydrophobic coating with multi-stage rough structure for long-term anti-corrosion and low-temperature anti-icing in the marine environment

The rough superhydrophobic surface is beneficial for capturing more gases underwater, which enhances corrosion and ice resistance for marine equipment. In this work, a PVAc-PVDF-FMCS (PPFMCS) multi-stage rough superhydrophobic coating was manufactured by a cold spraying method, significantly improving the anti-corrosion and anti-icing of aluminium alloy. The point-line structure was designed by cross-linking between multi-walled carbon nanotubes (MWCNTs) and silicon dioxide (SiO2), which facilitated the formation of multi-stage rough surface. The porous skeleton and interfacial adhesion of the PPFMCS coating were attributed to the introduction of polyvinylidenefluoride (PVDF) and polyvinylacetate (PVAc), respectively. The PPFMCS coating had good superhydrophobicity with a water contact angle of 163.5°, while exhibiting the outstanding performance of long-term anti-corrosion and anti-icing. The |Z|0.01 Hz value of the PPFMCS coating was still 9.62 × 109 Ω cm2 in 3.5 wt% NaCl solution for 35 days, only two orders of magnitude lower than that of the original coating, the equivalent circuits were further investigated and the metal protection is evaluated on the shore or in the deep ocean of the South China Sea. The PPFMCS coating was able to obviously delay icing for 5 min at −20 °C, the ice adhesion of its surface was as low as 85.5 kPa. The icing phase transition was analysed by a thermodynamic method. The coating also had good stability and drag reduction performance. This high-performance coating based on point-line structural design is expected to have practical applications in marine transportation, oil exploration and polar exploration.

Structural, optical and electrical conduction characteristics of PMMA/PVAc/TBAI blended polymers

This study aims to create tetra-n-butylammonium iodide (TBAI) doped poly(methyl methacrylate) (PMMA)/polyvinyl acetate (PVAc) blended polymers for utilize in a diversity of optoelectronic applications. By the casting technique, the films of (PMMA/PVAc/x wt % TBAI) were formed. The structure and morphology characteristics of the blended materials were studied using X-ray diffraction and scanning electron microscopy techniques. The optical transmittance declined to a minimum value when the blend was loaded with 38 wt % TBAI. The blend containing 38 % TBAI exhibits the highest reflectance values in the visible range. The lowest direct optical bandgap energies (4.20 eV) and indirect optical bandgap energies (3.71 eV, 3.13 eV) were achieved when TBAI reached 38 wt%. The addition of TBAI leads to an enhancement of the refractive index values of PMMA/PVAc in the visible spectrum. The effect of TBAI doping amount on the optical dielectric constant, energy loss functions, optical conductivity, nonlinear optical parameters and emitted color of the host blend was explored. The maximum values of the optical dielectric constant and energy loss functions were achieved after the TBAI level reached 38 wt%. The three non-linear optical (NLO) parameters for PMMA/PVAc blended polymers were enhanced as the amount of TBAI increased. An increase in voltage (V) or temperature results in a significant increase in electric current (I). Raising the amount of TBAI doping also caused the electric current to rise irregularly, with the exception of the blend with x = 11 %, where it fell. The samples exhibited the non-ohmic characteristics of the current-voltage (I–V) properties. The conduction mechanism of all blended materials was studied in detail. Finally, the outcomes supported the optical and electric properties studies, which suggested that a range of nanoelectronics applications could make use of the PMMA/PVAc/x weight percent TBAI blended polymers.

Waste Tyre Textile Fibre Composite Material: Acoustic Performance and Life Cycle Assessment

The development of new sound absorbing materials and the transition to net zero emissions production have become inseparable. This paper investigates a new type of composite sound absorbing material made of waste tyre textile fibre (WTTF) and different binders: polyurethane resin (PU), polyvinyl acetate (PVA), and starch (POS). Non-acoustic and acoustic parameters were studied, and life cycle assessment was performed for the considered composite sound absorbing materials. The airflow resistivity was determined according to the ISO 9053-1 standard, while the sound absorption coefficient was determined according to the ISO 10534-2 standard, and the LCA was performed based on the ISO 14040 and ISO 14044 standards. Composite sound absorbing materials subjected to sound absorption coefficient tests showed results in the range of 0.04 to 0.99 and peaking in the frequency range of 800 to 2000 Hz, while airflow resistivity varied between 17.4 and 83.6 kPa⋅s/m2. The combination that gave the highest sound absorption coefficient was experimentally found to be PU composite material. Life cycle assessment results revealed that the lowest potential impact on the environment is obtained when composite materials are produced using starch as a binder and its total potential impact on the environment varied between 0.27 and 0.55 Pt, while the highest potential impact was observed by PU composites (0.33 ÷ 0.64 Pt). The results obtained experimentally and by LCA modelling revealed great attractiveness and promising development of composites using WTTF and different binders’ potential for sound absorbing applications.

Effect of polyvinyl alcohol on the mechanical and sound properties of recycled rubber mortar

Recycled rubber mortar is a novel green construction material which alleviates the environmental impact of waste rubber tires and greatly improves the sound insulation performance. Existing cement mortar with high rubber content exhibits poor mechanical properties, limiting its application in construction field. In this study, polyvinyl acetate (PVA) was introduced to modify recycled rubber mortar and the effect of PVA contents on its fluidity, flexural, compressive, impact strengths, and drying shrinkage was analyzed. To improve the analytical accuracy, analytic hierarchy process (AHP) was used to select the optimal mix proportion. The results indicate that PVA has positive effects on the mechanical properties of recycled rubber mortar. Further, comparing the trend of the normalized impact sound pressure level with an increase in frequency and the weighted normalized impact sound pressure level revealed that mixing 50 % recycled rubber particles and 8 % polyvinyl acetate effectively improved the sound insulation performance of cement mortar. These findings can promote the application of recycled rubber mortar in housing construction projects and having environmental benefits.

Application and toxicological study of polyvinyl acetate (PVAc) coating on lemon (Citrus limon L.) fruit to extend the shelf life

The objective of the present study is to examine how different concentrations of polyvinyl acetate (PVAc) coating (2.5%, 5.0%, 7.5%, 10.0%, and 12.5%) affect the quality of lemons during storage at (27 ± 2)°C, with the aim of extending their shelf life. Lemons are known for being a rich source of citric acid, ascorbic acid, and dietary fiber. During the study, the coated lemons were regularly assessed for various parameters such as weight loss, respiration rate, firmness, decay incidence, total soluble solids, pH, ascorbic acid, and juice content. The results revealed that lemons coated with 10.0% and 12.5% concentrations of PVAc exhibited a significant (P < 0.05) impact in reducing the respiration rate, ethylene production rate, weight loss, and maintaining firmness compared to the control sample. Furthermore, the study also investigated the potential acute toxicological and histological effects of the PVAc (12.5%) coated sample on mice. The results indicated that there were no harmful or lethal effects observed in the experimental mice. Therefore, the PVAc coating at concentrations of 10.0% and 12.5% proves to be beneficial in preserving the natural color of lemons and minimizing senescence during storage at (27 ± 2)°C.

Various handcrafted artificial vessels: Evaluation of practicality and feasibility for supermicrosurgery training

BackgroundSupermicrosurgery demands more refined skills compared to traditional microsurgery, necessitating comprehensive training prior to clinical implementation. Despite the existence of various training models, they often fall short in terms of cost, ethical considerations, and infection risk. Our objective was to develop and evaluate novel training models for supermicrosurgery that are cost-effective, ethical, and risk-free. MethodsWe fabricated tubes using polyvinyl alcohol (PVA) liquid glue, polyvinyl acetate resin (PAR) wood glue, and hydrocolloid dressing (HCD), aiming to identify suitable, low-cost candidates for a supermicrosurgery training model. These tubes were anastomosed under a microscope using 10-0 or 11-0 nylon sutures. We assessed the time and cost involved in tube creation, their diameters, and the overall feasibility of the models. ResultsThe average time and cost to fabricate a 15-mm-long luminal tube were 33.5minutes and $0.02 USD for the PVA group, 23minutes and $0.02 USD for the PAR group, and 63seconds and $0.40 USD for the HCD group, respectively. The average diameter of the tubes was 0.49mm in the PVA group, 0.58mm in the PAR group, and 1.55mm in the HCD group. The PVA and PAR tubes, with their transparent and thin walls, facilitated easier evaluation of anastomosis patency compared to the HCD tubes. ConclusionWe have successfully developed new supermicrosurgery training models using non-living materials, characterized by their low cost, absence of ethical concerns, and elimination of infection risk. The PAR and PVA tubes, in particular, are suitable for residents' training in supermicrosurgery.

Enhancing foamability and flame‐retardancy of polylactic acid bead foams through inter‐beads bulk polymerization and continuous phase dispersion of LDHs

AbstractPoly (lactic acid) (PLA) bead foam has a promising application because of its renewable and naturally degradable nature. However, its processing is greatly limited by inherent shortcomings such as the complex polycrystals‐inducing strategy. Herein, we developed a strategy of bulk polymerization reaction of polyvinyl acetate (PVAc) to sinter PLA beads to prepare EPLA foams accompanied by supercritical CO2 foaming technology. In order to enhance the sintering behavior and flame‐retardancy of EPLA foams, two‐dimensional nanolayered double hydroxides (LDHs) were introduced and dispersed in the continuous phase of the sintering layers. The formation of unique dispersion of LDHs and sintering structure of PVAc generated substantial increase in the crystallinity, melt elasticity, and sintering strength of EPLA foams, which facilitated the growth and stabilization of cells. Thus, the cell‐density and expansion ratio could be increased to 8.62 × 106 cell/cm3 to 9.31‐fold, respectively. Moreover, the mechanical properties of the EPLA foams were improved. The tensile strength and the compression strength increased to 2.96 and 62.5 MPa. Additionally, with adding 7 wt.% LDH, the EPLA foam reached UL‐94 V‐0 rating with high limiting oxygen index value of 29.1% and char residue of 20.4%. This study provides a novel strategy for the preparation of flame‐retardant EPLA foams with low density, three dimensional complex shapes, as well as excellent mechanical properties.

A General Approach for Photo-Oxidative Degradation of Various Polymers.

The escalating demand for plastics has resulted in a surge of plastic waste worldwide, posing a monumental environmental challenge. To address this issue, a versatile photo-oxidative degradation method applicable to seven distinct polymer families is proposed, comprising poly(isobutyl vinyl ether) (PIBVE), poly(2,3-dihydrofuran) (PDHF), poly(vinyl acetate) (PVAc), poly(n-butyl acrylate) (PBA), poly(methyl acrylate) (PMA), poly(vinyl chloride) (PVC), poly(dimethyl acrylamide) (PDMA), poly(ethylene oxide) (PEO), poly(oligo(ethylene glycol) methyl ether acrylate) (PEGMEA), and even poly(methyl methacrylate) (PMMA). This method employs photo-mediated hydrogen atom transfer (HAT) followed by oxidation to promote polymer degradation. This reaction is carried out under aerobic condition in the presence of iron trichloride (FeCl3) as a photocatalyst in combination with low-intensity purple light irradiation. The process can degrade up to 97% of the polymer in less than 3 h. This degradation process can be easily controlled by switching the light off, which allows for precise modulation of the degradation rate, enhancing the effectiveness of the method. Overall, this method provides a sustainable method for degrading various polymer types with low energy input.

PdS-ZnS-Doped Electrospun Polymer Nanofibers as Effective Photocatalyst for Hydrogen Evolution

Poly(vinyl acetate) nanofibers doped with PdS-ZnS nanoparticles (PdS-ZnS/PVAc nanofibers) were fabricated via an electrospinning technique. PdS-ZnS nanoparticles were in situ synthesized by adding (NH4)2S solution to poly(vinyl acetate)/zinc acetate/palladium acetate solution. Electrospinning of the formed colloidal solution led to the formation of poly(vinyl acetate) nanofibers containing uniformly distributed PdS-ZnS nanoparticles. The prepared samples were characterized by field emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy and Fourier transform infrared spectroscopy. In photocatalytic activity investigation, the PdS-ZnS/PVAc nanofibers showed remarkably enhanced performance towards water photosplitting under solar irradiation compared to the ZnS/PVAc nanofibers. This enhanced performance is attributed to the synergistic effects of heterostructured PdS-ZnS nanoparticles, which can improve photogenerated charge migration and solar light absorption.

Ionic liquid fluoropolymer membranes for the separation of R-410A: Understanding the effect of ionic liquid on membrane characteristics and separation performance

Environmental legislation such as the American Innovation and Manufacturing Act will phase out today's generation of high-global warming hydrofluorocarbon refrigerants over the next two decades. Energy-efficient technologies are needed to separate these often azeotropic and complex mixtures. Membrane technology and extractive distillation with ionic liquids as entrainers have been individually developed for the separation of azeotropic refrigerant mixtures. This study provides details for the separation of R-410A through combining the benefits of glassy, amorphous polymers with ionic liquids to form ionic liquid polymer membranes. Two different classes of ionic liquid polymer membranes are considered: polyvinyl acetate composite membranes with 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate, and 1-hexyl-3-methylimidazolium chloride, and Hyflon AD 60 with 1-ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide. The membranes are characterized with FTIR, helium pycnometry, differential scanning calorimetry, and a high-pressure view-cell to characterize the effect of ionic liquid on polymer properties. The Hyflon AD 60 composite membranes were evaluated for the separation of R-410A through pure-gas permeability, selectivity, solubility, and diffusivity measurements, which show exceptional selectivity for separation of R-410A. Results provide insights on the effect of ionic liquid on the separation of R-410A and indicate that improved separation performance of glassy polymers can be achieved with the addition of ionic liquid.

Precision Temperature Measurement and Error Analysis for Three-Wire PT100 Resistance Temperature Detector (RTD) using LTSpice

This work focuses on temperature measurement and error extraction for Resistance Temperature Dependence (RTD). RTD is notable for its high accuracy, linearity, and stability. However, obtaining a system error of less than unity in RTD is critical. A platinum RTD is an ideal option if the system requires an accuracy level over a wide temperature range (-200°C to +800°C). Therefore, this work investigated the temperature measurement and extraction of error in RTD by simulating a three-wired PT100 RTD using LTSpice. The analytical calculations were also developed to demonstrate the RTD’s error and were compared with the simulation results for verification purposes. It was discovered that the optimized temperature measurement and percentage errors are 0.01°C and 0.004% respectively. The values of Vc, Sense Resistor (RSENSE), and Reference Resistor (RREF) for the excitation current were found to be significant to maximize the output voltage and mean absolute error (MAE) on the test set, offering insights into the model's overall fit, average deviation, and sensitivity to outliers. Results reveal strong correlations between PV module temperature, irradiance, and AC power generated.

Features of the formation of cohesive and adhesive strengths by non-structured and structured polyvinyl acetate films during wood gluing

The formation of a higher number of hydrogen bonds in the structured polyvinyl acetate film compared to the unstructured one was established by means of infrared spectroscopy method. It was concluded that the structured polyvinyl acetate film has a higher cohesive strength than unstructured. It was revealed that the films subjected to moisture loads (with the amount of sorbed moisture lower than the swelling limit of the adhesive film) would show greater cohesive strength compared to the films which were not subjected to moisture loads due to the formation of a higher number of hydrogen bonds. Based on the obtained results, it was predicted that the system "structured film after moisture loads/wood substrate" would exhibit the highest adhesive strength, explained by an increase in the number of hydrogen bonds between the film components and the wood cellulose. It was theoretically predicted that in order to provide high cohesive and adhesive strengths of polyvinyl acetate adhesive joints of wood ensuring, moisture saturation should be lower than the saturation limit of the wood fiber and the adhesive film simultaneously.

Supertoughened biodegradable poly(L-lactic acid) by multiphase blends system: Crystallization, rheological and mechanical properties

To toughen brittle poly(L-lactic acid) (PLA), poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) and poly(vinyl acetate) (PVAc) were introduced into PLA matrix to prepared PLA/PHBH/PVAc ternary blends. PVAc was electively located in PLA matrix and refined phase morphology owing to better miscibility of PVAc with PLA than with PHBH. Increase in PVAc content decreased the crystallization rate and the crystallinity of PLA due to the dilution effect. More importantly, prominent enhancement of flexibility and toughness of PLA was obtained by the addition of PHBH and PVAc. Elongation at the break and impact strength of ternary blend with 10 wt% PVAc were 277 % and 326 % higher than that of neat PLA. Melt viscoelasticity of PLA was improved by incorporation of PHBH and PVAc. The combination of increased toughness and high melt viscoelasticity established in PLA biodegradable blends represent properties required in a wider range of applications.