Water Pollution Research Articles

Assessing the Environmental Impact of Oasis Agriculture in the Yarkant River Basin: A Comprehensive Study of Water Use, Carbon Footprint, and Decoupling Index

Studying the relationship between grain planting and the environment is an important means to promote sustainable production. This study takes wheat, a typical grain crop in the Yarkant River oasis irrigation district, the fourth largest agricultural irrigation district in China, as an example to analyze the relationship and changing trends between wheat yield and water footprint (WF), and carbon footprint (CF) from 2001 to 2020. The study found that during the research period, wheat yield, WFgreen,blue,WFgrey, and CF showed a fluctuating but significantly upward trend. Decoupling analysis indicates that the overall decoupling trend between wheat yield and water footprint and carbon footprint is not obvious. This suggests that the rapid development of wheat production in the Yarkant River Oasis has also led to significant water resource consumption, pollution, and greenhouse gas emissions. Among the three sub–irrigation districts, the Shache sub–irrigation district has the best decoupling state, reflecting that the increase in wheat yield in Shache did not lead to more water resource consumption and pollution which is may due to its abundant water resources and agriculture development. Further analysis found that the use of nitrogen fertilizers and irrigation electricity have contributed to water resource pressure and greenhouse gas emissions. This study reveals that there are significant environmental risks in the current wheat planting in the Yarkant River oasis irrigation district, but it also points out the direction for green development in the irrigation district.

Textile Recycling: Efficient Polyester Recovery from Polycotton Blends Using the Heated High-Ethanol Alkaline Aqueous Process.

Textile production has doubled in the last 20 years, but only 1% is recycled into new fibers. It is the third largest contributor to water pollution and land use, accounting for 10% of global carbon emissions and 20% of clean water pollution. A key challenge in textile recycling is blended yarns, such as polycotton blends, which consist of polyester and cotton. Chemical recycling offers a solution, in particular, alkali treatment, which hydrolyzes polyester (PET) into its components while preserving cotton fibers. However, conventional methods require high temperatures, long durations, or catalysts. Our study presents, for the first time, the heated high-ethanol alkaline aqueous (HHeAA) process that efficiently hydrolyzes PET from polycotton at lower temperatures and without a catalyst. A near-complete PET hydrolysis was achieved in 20 min at 90 °C, while similar results were obtained at 70 °C and 80 °C with longer reaction times. The process was successfully scaled at 90 °C for 20 min, and complete PET hydrolysis was achieved, with a significantly reduced liquid-to-solid ratio, from 40 to 7 (L per kg), signifying its potential to be implemented in an industrial context. Additionally, the cotton maintained most of its properties after the treatment. This method provides a more sustainable and efficient approach to polycotton recycling.

Harnessing Novel Reduced Graphene Oxide-Based Aerogel for Efficient Organic Contaminant and Heavy Metal Removal in Aqueous Environments.

Ensuring clean water sources is pivotal for sustainable development and the well-being of communities worldwide. This study represents a pioneering effort in water purification, exploring an innovative approach utilizing modified reduced graphene oxide (rGO) aerogels. These advanced materials promise to revolutionize environmental remediation efforts, specifically removing organic contaminants from aqueous solutions. The study investigates the exceptional adsorption properties of rGO-aerogel, enhanced with cysteamine, to understand its efficacy in addressing water pollution challenges. The characterization methods utilized encompass various analytical techniques, including FE-SEM, BET, FTIR, TGA, DSC, XPS, NMR, and elemental analysis. These analyses provide valuable insights into the material's structural modifications and surface chemistry. The research comprehensively explores the intricacies of adsorption kinetics, equilibrium, and isothermal study to unravel the underlying mechanisms governing contaminant removal. MO and Ni2+ exhibited adsorption of 542.6 and 150.6 mg g-1, respectively, at 25 °C. Ni2+ has unveiled the highest removal at pH 5, and MO has shown high removal in a wide pH range (pH 4-7). Both contaminants have shown fast adsorption kinetic performance on an rGO-aerogel surface. This study aims to identify the synergistic effect of cysteamine and rGO in aerogel formation to remove heavy metals and organic contaminants. These findings mark a significant stride in advancing sustainable water-treatment methods and pioneering in synthesizing innovative materials with versatile applications in environmental contexts, offering a potential solution to the global water pollution crisis.

Oxygen Reduction Reaction Coupled Electro‐Oxidation for Highly‐Efficient and Sustainable Water Treatment

AbstractElectro‐oxidation (EO) technology demonstrates significant potential in wastewater treatment. However, the high energy consumption has become a pivotal constraint hindering its large‐scale implementation. Herein, we design an EO and 4‐electron oxygen reduction reaction coupled system (EO‐4eORR) to replace the traditional EO and hydrogen evolution reaction (HER) coupled system (EO‐HER). The theoretical cathodic potential of the electrolytic reactor is tuned from 0 V (vs. RHE) in HER to 1.23 V (vs. RHE) in 4eORR, which greatly decreases the required operation voltage of the reactor. Moreover, we demonstrate that convection can improve the mass transfer of oxygen and organic pollutants in the reaction system, leading to low cathodic polarization and high pollutant removal rate. Compared with traditional EO‐HER system, the energy consumption of the EO‐4eORR system under air aeration for 95 % total organic carbon (TOC) removal is greatly decreased to 2.61 kWh/kgTOC (only consider the electrolyzer energy consumption), which is superior to previously reported EO‐based water treatment systems. The reported results in this study offer a new technical mode for development of highly efficient and sustainable EO‐based treatment systems to remove organic pollutants in waste water.

Domestic Pollution Havens: Linking Interregional Capital Flight and Water Pollution Regulation in China

Domestic Pollution Havens: Linking Interregional Capital Flight and Water Pollution Regulation in China

Microbial remediation of heavy metal-polluted water

Heavy metal pollution in water has become a global environmental problem, threatening aquatic ecosystems and human health. Physical and chemical methods can effectively remove heavy metal pollutants, while their applications are limited due to the high costs, complex operation, and susceptibility to secondary pollution. Bioremediation is the most promising method for eliminating toxic pollutants. Microorganisms including bacteria, fungi, and algae can convert toxic heavy metals into less toxic forms, which has become an effective and environmentally friendly solution for the remediation of heavy metal pollution in water environments. This paper expounds the toxicity and mechanism of heavy metal pollution, microbial remediation mechanisms, and primary microbial remediation strategies, providing a reference for the removal or reduction of metal pollutants in water environments as well as the development of related technologies.

Ethical and Legal Protection of Drinking Water Resources in Islamic Jurisprudence (with Emphasis on Drinking Water Resources in Kabul)

Water is a vital resource for all living beings. The increase in population and decrease in rainfall in many cities around the world have led to serious water scarcity and pollution of wells and water resources in countries. The expansion of industrial production has resulted in the release of pollutants into surface and groundwater in cities and farmlands of countries. Therefore, this research has been conducted in a library way to examine the views and solutions of Islamic jurisprudence on resolving the problems and preserving the health of drinking water resources and wells, especially in Kabul. The findings of this research are that to preserve the health of water resources, a legal or spatial boundary between neighboring wells or farmers is required to be 500 meters in soft land, but in hard land, at least 250 meters between them is necessary to prevent the resulting damages. However, the distance between a well and a septic tank is 2.5 meters in hard land, and at least 7 cubits or 3.5 meters in soft areas. This is to purify water pollutants and prevent the resulting damages to neighbors. The legal boundary approach has been stated to compensate for the damage caused by a well or a water canal. Moral boundary means the growth of human responsibility to prevent water and environmental pollution in Islamic jurisprudence. Natural pollutant filters for well and canal water are the elements of soil, sand, abundant or flowing water, and oxygen present in water in Islamic jurisprudence.

Research progress of nanoscale zero-valent iron in synergistic combinations of denitrifying bacteria for nitrate removal

Nitrate (NO3--N) is a common inorganic nitrogen pollutant in water. Excessive NO3--N can lead to water eutrophication and threaten human health. Nanoscale zero-valent iron (nZVI) has attracted much attention in NO3--N removal due to its high specific surface and excellent electron donor properties. The combination of nZVI and denitrifying bacteria (DNB) demonstrates high efficiency in converting NO3--N into N2. This approach not only substantially enhances the removal rate of NO3--N but also exhibits superior environmental sustainability compared with conventional chemical denitrification methods. Accordingly, it holds substantial promise for mitigating NO3--N pollution and warrants further exploration in the pollution control. Therefore, it is necessary to understand the interaction mechanism between nZVI and DNB for NO3--N removal. This paper details the factors affecting the removal of NO3--N by nZVI combined with DNB, reviews the latest research progress in this field, elaborates on the interaction mechanism between nZVI and DNB for NO3--N removal, and discusses the challenges and future research directions of NO3--N removal by nZVI combined with DNB. This review aims to provide a theoretical basis for the development of efficient approaches for the remediation of NO3--N pollution.

Evaluating the Photocatalytic Activity of Green Synthesized Iron Oxide Nanoparticles

Water pollution from dyes is a major environmental challenge, demanding advanced materials for efficient degradation. In this study, we synthesized iron oxide nanoparticles (IONPs) using an aqueous extract of Senegalia catechu leaves and evaluated their photocatalytic activity in methylene blue (MB) dye degradation under sunlight irradiation. The IONPs were characterized by UV-visible spectroscopy (UV–vis), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive X-ray Spectroscopy (EDS). XRD pattern showed a highly crystalline structure with an average crystallite size of 34.7 nm, while SEM images revealed predominantly spherical particles with uneven surface texture. Photocatalytic efficiency exceeded 80% MB dye degradation after 120 min of sunlight exposure. Optimization of catalyst dose, pH, dye concentration, and other parameters is essential for maximizing degradation efficiency. The IONPs demonstrated reusability over four degradation cycles, retaining effective photocatalytic performance. This study underscores the potential of green-synthesized IONPs as eco-friendly photocatalysts for wastewater treatment and environmental remediation.

Oxygen Reduction Reaction Coupled Electro-Oxidation for Highly-Efficient and Sustainable Water Treatment.

Electro-oxidation (EO) technology demonstrates significant potential in wastewater treatment. However, the high energy consumption has become a pivotal constraint hindering its large-scale implementation. Herein, we design an EO and 4-electron oxygen reduction reaction coupled system (EO-4eORR) to replace the traditional EO and hydrogen evolution reaction (HER) coupled system (EO-HER). The theoretical cathodic potential of the electrolytic reactor is tuned from 0 V (vs. RHE) in HER to 1.23 V (vs. RHE) in 4eORR, which greatly decreases the required operation voltage of the reactor. Moreover, we demonstrate that convection can improve the mass transfer of oxygen and organic pollutants in the reaction system, leading to low cathodic polarization and high pollutant removal rate. Compared with traditional EO-HER system, the energy consumption of the EO-4eORR system under air aeration for 95 % total organic carbon (TOC) removal is greatly decreased to 2.61 kWh/kgTOC (only consider the electrolyzer energy consumption), which is superior to previously reported EO-based water treatment systems. The reported results in this study offer a new technical mode for development of highly efficient and sustainable EO-based treatment systems to remove organic pollutants in waste water.

Apparel Supply Chain Management and Practice under the Perspective of Sustainable Development

Abstract: This study explores the challenges faced by the apparel industry and the means of attaining sustainable development via effective supply chain management amidst the backdrop of global economic integration and the evolving information technology landscape.Firstly, the current situation of the apparel industry is analyzed, including factors such as the increase in consumers' personalized demands, the increasingly fierce competition, the rising costs of labor and raw materials, and the growing consciousness of environmental preservation. The development status and problems of apparel supply chain management are then analyzed, including the excessively long supply chain, the lack of flexibility and adaptability in management, the opacity of information, the lack of a supplier evaluation system, and the neglect of sustainable development by enterprises. It further discusses achieving sustainable development in the apparel industry, including reducing water consumption and pollution, addressing the adverse consequences arising from the rapid turnover of fashion trends, promoting the construction of a circular supply chain, etc. Corresponding solutions are proposed. Finally, this study concludes how supply chain management and sustainable development practices can inject new vitality into apparel enterprises and achieve the industry's sustainable development goals.

Enhanced Assessment of Water Quality and Pollutant Source Apportionment Using APCS-MLR and PMF Models in the Upper Reaches of the Tarim River

To evaluate the pollution sources and dynamics of the upper reaches of the Tarim River, 10 typical sampling points were selected, and 23 water quality parameters from 2020 to 2022 were analyzed using one-way analysis of variance, the comprehensive Water Quality Identification Index (WQI), and Principal Component Analysis (PCA). The pollution status, sources, and contribution rates of water quality were investigated using the Absolute Principal Component-Multiple Linear Regression Model (APCS-MLR) and Positive Matrix Factorization (PMF). The results indicated that the water quality parameters of dissolved oxygen (DO), chemical oxygen demand (CODMn), biochemical oxygen demand after 5 days (BOD5), total nitrogen (TN), total phosphorus (TP), fluoride ions (F-), and ammonia-nitrogen (NH3-N) in the upper reaches of the Tarim River exceed standards, with noticeable spatial variations observed for each parameter. The water quality evaluation grades in the upper reaches of Tarim River primarily indicate “moderate” and “good” levels, with DO, TN, NH3-N, and electrical conductivity (EC) being the key parameters influencing variations in water quality. The source analysis results from APCS-MLR and PMF yielded similar outcomes, identifying six potential pollution sources. Among these, soil weathering, livestock and poultry breeding, and agricultural activities exhibited higher contribution rates. Specifically, the contribution rates for these sources according to APCS-MLR were 44.11%, 19.63%, and 11.67%, respectively; while according to PMF they are 24.08%, 17.88%, and 27.54%, respectively. Furthermore, industrial pollution sources contributed at a rate of 6.01% according to APCS-MLR, while urban living sources contributed at a rate of 2.13%. However, based on PMF analysis, the contribution rates for industrial pollution sources increased significantly to 16.71%. Additionally, APCS-MLR identified natural sources as contributing at a rate of 16.45%, whereas PMF suggested that a combination of agricultural activities and natural sources contributed at a lower rate of only 9.52%. In conclusion, the water quality within the upper reaches of the Tarim River is predominantly satisfactory. Nonetheless, localized pollution, primarily attributable to human activities, presents a substantial challenge. These observations provide critical insights into improving and protecting the fragile water quality of the Tarim River.

Facile synthesis of ZnO/RGO/Fe2O3 using macroalgae Caulerpa taxifolia as green reductor and its application as malachite green removal

This study presents the synthesis of a novel ZnO/rGO/Fe₂O₃ composite using Caulerpa taxifolia as a green reductant for the effective removal of Malachite Green from aqueous solutions. Characterization techniques, including FTIR, SEM, and XRD, confirmed the successful incorporation of ZnO and Fe₂O₃ onto the rGO matrix, enhancing its adsorption properties. The composite achieved an exceptional maximum adsorption capacity of 454.5 mg/g at pH 9, significantly outperforming rGO alone and other adsorbents. The adsorption kinetics followed a pseudo-second-order model, indicating chemisorption as the dominant mechanism, with a high correlation coefficient (R² = 0.999). The adsorption isotherms were best described by the Langmuir model, suggesting monolayer adsorption. Thermodynamic parameters revealed that the process was spontaneous and exothermic, with a Gibbs free energy (ΔGo) of -10.93 kJ/mol at 25 °C. The composite's high adsorption capacity, rapid kinetics, and favorable thermodynamics highlight its potential as an efficient and sustainable adsorbent for dye removal. This research offers a promising approach to water treatment, aligning with environmentally friendly practices and providing a viable solution for mitigating water pollution caused by organic dyes. KEY WORDS: Reduced graphene oxide, Water treatment, Caulerpa taxifolia, Isothermal and kinetic studies, Malachite Green Bull. Chem. Soc. Ethiop. 2025, 39(1), 29-47. DOI: https://dx.doi.org/10.4314/bcse.v39i1.3

Convenient Au@Ag Double‐Layer Nanoarray Fabricated by Rapid Thermal Annealing and Chemical Replacement Method for Surface‐Enhanced Raman Spectroscopy Sensing

Surface‐enhanced Raman spectroscopy (SERS) has a wide range of applications in molecular recognition, environmental pollutant detection, and other fields. However, the intensity and number of “hot spots” in 1D and 2D nanostructures are limited due to the scale‐dependent localized plasmonic effect of nanostructures, making it difficult to increase the detection limit. Herein, a kind of 3D substrate called Au@Ag double‐layer nanoarray (Au@Ag DLA) is prepared using rapid thermal annealing and chemical replacement methods. The energy‐dispersive spectrometer spectra confirm the successful growth of AgNPs on the gold nanoarray (Au SLA) by showing no presence of the copper element, indicating complete replacement of the Cu film deposited on Au SLA by Ag atoms. The detection limit of malachite green in Au@Ag DLA is 10−8 mol L−1, four and three orders of magnitude higher than that of Au SLA and AgNPs, respectively. This stronger SERS effect of Au@Ag DLA arises from the larger number of intense hot spots generated not only on the horizontal surface but also in the vertical direction. This finding provides a method for developing efficient and stable 3D SERS substrate, which can be utilized for the trace detection of water pollutants and pesticide residue.

Assessment of Microplastic Pollution in Sediments and Water of River Soan, Punjab, Pakistan

Assessment of Microplastic Pollution in Sediments and Water of River Soan, Punjab, Pakistan

Enhancing food sustainability in the acute hospital setting - a nurse-led study of patient food.

Intensive global food production causes soil, water and air pollution, which has a negative impact on our health and future ability to produce sufficient nutritious food. Plant-based diets have the potential to reduce the environmental damage associated with the global food chain. The project sought to understand drivers of food waste and to improve food sustainability in a busy, tertiary referral hospital in England. Ward-level food waste was quantified. Qualitative data were collected using informal interviews with staff and additional data utilised the patient feedback survey. Ward-level food packaging waste and patient food choices were quantified using data on patient menu choices. The carbon footprint of patient food choices was calculated. Beef was the most popular menu choice, and was the main contributing factor to the high environmental impact of the hospital food chain. Increasing the visibility of vegetarian options on the menu led to a four-fold rise in these meals being chosen, which reduced the carbon footprint of the patient meal service. Recycling food packaging was also started, but there are challenges to widespread implementation. The project was successful, but it remains a starting point from which to increase food sustainability across the NHS and care sector catering provision.

Behaviour of M. aeruginosa–Microplastic composite pollutants in coagulation and sludge storage

Microcystis aeruginosa (M. aeruginosa) blooms and microplastics pollution have been major global water pollution concern in lakes and reservoirs. In this study, the behaviour of M. aeruginosa–microplastic composite pollutants in inorganic coagulant (PACl) and organic coagulant (HTCC) treatment was investigated. Results showed that, in coagulation stage, the dissolved extracellular polymers secreted by M. aeruginosa could promote the adhesion of microplastics to algae, so as to combine them into the algal flocs, thus improving the sedimentation and removal efficiency of microplastics. On the other hand, whilst microplastics increased the size of algal flocs in PACl coagulation and improved algal removal efficiency, they had the opposite effect on HTCC coagulation. And the removal of algal metabolites including microcystins were improved by the presence of microplastics.In sludge storage stage, the oxidative and mechanical damage effects of microplastics promoted the rupture of M. aeruginosa cells in PACl sludge but not in HTCC sludge, which mean more potential risks in recycling of PACl sludge water. Besides, microplastics promoted the proliferation of beneficial bacteria such as Poterioochromonas and Coccomyxa, which contributed to the control of sludge pollution.

Temporal variations of N and P losses via surface runoff from Chinese farmland after fertilisation

The loss of nitrogen (N) and phosphorus (P) via surface runoff induced by fertilisation leads to water pollution and aggravates water scarcity. Studies estimating N and P losses from farmland have focused on the efficacy of agricultural management actions at reducing the amount of N and P lost. However, a gap remains in understanding the dynamics of N and P losses from farmland, especially differences among types of farmland, crop and fertiliser. Thus, the temporal variations of N and P losses via surface runoff from farmland induced by fertilisation were estimated using 5530 groups of paired observations collected in China. The results showed that N and P losses via surface runoff from paddy fields associated with fertilisation were greater than losses from upland fields. However, after > 90 days post-fertilisation, the effects of fertilisation on N and P loss from paddy fields were non-significant, while the effects of fertilisation on N and P losses from upland fields remained significant. Organic fertilisation decreased N losses from upland and paddy fields, but at more than 60 days post-fertilisation, N and P losses from upland fields were greater with organic than chemical or combined fertilisation. Increasing the fertilisation rate led to higher N and P losses from upland and paddy fields and extended the occurrence time of N and P loss from paddy fields. Overall, this study demonstrates the dynamic processes associated with fertilisation underlying N and P losses from farmland via surface runoff.

Reprocessible, Reusable, and Self-Healing Polymeric Adsorbent for Removing Perfluorinated Pollutants.

Here, we report a reprocessible, reusable, self-healing, and form-switching polymeric adsorbent for remediating fluorinated pollutants in water. The copolymer hydrogel is designed to contain fluorophilic segments and cationic segments to induce strong binding with perfluorinated pollutants. The sorption performance reveals rapid and quantitative removal of these pollutants, driven by the synergistic effect of fluorophilic and electrostatic interaction. Importantly, a disulfide-containing dynamic crosslinker plays a crucial role in imparting multifunctionality. This enables self-healing by the restoration of crosslinks at the cut surfaces by disulfide exchange reactions and allows for the repeated use of the adsorbent via multiple adsorption-desorption cycles. Furthermore, the adsorbent is reprocessible by cleaving the crosslinks to afford linear copolymers, which can be repolymerized into a hydrogel network on demand. Also, form-switching capability is showcased through the aqueous self-assembly of linear copolymers into a fluorinated micelle, serving as another form of adsorbent for pollutant removal.

Environmentalism around the globe. An introduction to the 2020 ISSP environment module and selected country-level findings

Environmental problems such as climate change, air and water pollution, and biodiversity loss affect humans globally. The International Social Survey Programme (ISSP) recently released its 4th survey on environmental behavior and attitudes, measuring individuals’ views on various environmental topics. The most recent data were collected between 2020 and 2023 in 28 countries worldwide. This introduction offers an overview of the development of the questionnaire, its content, and the data collection process. It also includes some descriptive results on attitudes toward climate change, behaviors that directly impact climate change, trust in various social and political institutions, the appreciation of nature, as well as nationalism and environmentalism. It concludes with an outlook on the substantive papers in this special issue, which address different relevant environmental topics and analyze the individual and national factors influencing specific environmental views and behaviors.