SO2 ultraviolet (UV) camera technology has been successfully applied to the accurate imaging detection of pollutant gas concentration; however, the actual detection ability of this technology has not been intensively studied, especially the detection accuracy and limit under the influence of the light dilution effect. Here, we theoretically and experimentally investigate the UV scattering on SO2 concentration inversion. The radiation transfer model of the light dilution effect is reconstructed, and the concept of the optimized detection limit is discussed. An outfield experiment is conducted on a ship exhaust, and the results are compared with the theoretical calculations, which indicates that the detection limit of the SO2 UV camera is 15 ppm·m at close range and increases to 25 ppm·m when the detection distance is 3.5 km. This study proves that the detection limit of the SO2 UV camera deteriorates with the decreasing atmospheric visibility, the lengthening detection distance, and the increasing aerosol content within the plume. In addition, the hardware indicators of the camera systems also play a key role in the detection limit, and taking reasonable image processing can significantly release the instruments’ performance and extend the applicability of the SO2 UV camera.