Polar Regions Research Articles

Global Variability of Degree Distribution in Marine Food Webs

ABSTRACTAimIn complex networks, the degree distribution varies and provides an insight into the general structure of the system. For example, it may show scale‐free characteristics of the network, indicating higher vulnerability against non‐random disturbances. However, investigating its spatio‐temporal variability, degree distribution in marine food webs remains an unresolved issue. In this paper, we focus on describing the global variability of degree distribution in marine food webs.LocationGlobal.MethodsWe studied 105 marine food webs. By Kolmogorov–Smirnov test, and kernel density estimation, we determined the degree distribution of each food web, described its spatio‐temporal pattern and quantified the correlation between relevant parameters as a function of the scale‐free property of the degree distribution.ResultsMarine food webs around the globe did not strictly exhibit scale‐free characteristics in most regions, and only below 5% of the food webs entered the “strongest fit” level of the scale‐free network. We also find food webs in the polar regions indicate relatively high goodness‐of‐fit to scale‐free networks. The upwelling ecosystem related to ocean currents is prone to form a scale‐free web, which exhibits periodic scale‐free characteristics. The ecosystem types with relatively ‘low fit’ levels were mainly concentrated in the ecosystems heavily influenced by human activities.Main ConclusionsThis research will enhance the research in terms of (a) classifying degree distribution in marine food webs; (b) revealing the variability in the spatial pattern of particular distributions, for example, the scale‐free characteristics and (c) exploring the distribution of in‐degree in space, quantifying the proportion of generalist and specialist species, as a potential indicator of adaptive potential of ecosystems. This research contributes to our understanding of the scale‐free features of marine food webs globally. It also offers a real systems‐based conservation approach to assess the spatial heterogeneity of the structural vulnerability of marine ecosystems.

A call to strengthen international collaboration to assess climate change effects in polar regions

A call to strengthen international collaboration to assess climate change effects in polar regions

Investigating the exciton dynamics in InGaN/GaN core-shell nanorods using time-resolved cathodoluminescence.

This study examines the exciton dynamics in InGaN/GaN core-shell nanorods using time-resolved cathodoluminescence (TRCL), which provides nanometer-scale lateral spatial and tens of picoseconds temporal resolutions. The focus is on thick (>20 nm) InGaN layers on the non-polar, semi-polar and polar InGaN facets, which are accessible for study due to the unique nanorod geometry. Spectrally integrated TRCL decay transients reveal distinct recombination behaviours across these facets, indicating varied exciton lifetimes. By extracting fast and slow lifetime components and observing their temperature trends along with those of the integrated and peak intensity, the differences in behaviour were linked to variations in point defect density and the degree and density of localisation centres in the different regions. Further analysis shows that the non-polar and polar regions demonstrate increasing lifetimes with decreasing emission energy, attributed to an increase in the depth of localisation. The semi-polar facet instead showed a spectral independence of the lifetime which could not be rationalised by an absence of exciton localisation. This investigation provides insights into the intricate exciton dynamics in InGaN/GaN nanorods, offering valuable information for the design and development of optoelectronic devices.

Sediment runoff formation in a small periglacial catchment on the King George (Vaterloo) island, Antarctica

Global climate change has most significantly affected the Polar Regions. The increase in air temperature has stimulated the melting of glaciers in the Arctic and Antarctic, which has contributed to changes in the formation of water and sediment runoff. However, there are very few quantitative estimates of the sediment redistribution in the periglacial catchments of the Polar Regions. Specific features of water and sediment runoff were studied within the catchment area of the Korabelnyj Stream located on the Fildes Peninsula in Antarctica near the Bellingshausen Ice Dome. The main aim of the study was to investigate the conditions for the formation of water and sediment runoff and to identify the proportional contribution of washout and erosion material coming from the periglacial and maritime parts of the catchment area to the sediment runoff of the stream. A set of methods and approaches, including: a) estimates of the sediment flow connectivity index; b) fingerprinting technique; c) hydrometeorological observations; d) large-scale geomorphological survey and others, was ap[1]plied to identify the conditions for the formation of surface runoff and washout, the mechanisms of sediment redistribution in various parts of the fluvial network and to quantify the proportional contribution of two main sediment sources to the sediment runoff of the stream. A fraction with a particle size of ≤63 μm was used for geochemical and spectrometric analyzes of soils and sediments. In total, the content of 34 elements was analyzed, i.e. 6 radioisotopes and 28 stable elements. It has been established that despite the significant differences in the relief of the near-glacial and maritime parts of the catchment area, the indices of sediment connectivity are quite close and amount to –1,79 and –1,35, respectively. A significant part of the material transported by temporary streams from the slopes of the catchment area is redeposited in relief depressions partially occupied by water bodies. The main volume of sediments, which is at least 60–66% of the total sediment runoff in the outlet section of the Korabelnyj Stream, comes from the periglacial part of the catchment area. This is due to the increased water discharge relative to the non-glacial part of the catchment area, which results from the melting of snow and ice accumulated on the ice dome, the high erosion of moraine deposits unprotected by vegetation, and the presence of an ice core in moraines, which prevents water filtration.

Measurement report: In situ vertical profiles of below-cloud aerosol over the central Greenland Ice Sheet

Abstract. Surface radiative cooling in polar regions can generate persistent stability in the atmospheric boundary layer. Stable layers below clouds can decouple the cloud layer from the near-surface environment. Under these conditions, surface aerosol measurements are not necessarily representative of the near-cloud or intra-cloud aerosol populations. To better understand the variability in the vertical structure of aerosol properties over the central Greenland Ice Sheet, in situ measurements of aerosol particle size distributions up to cloud base were made at Summit Station in July and August 2023. These measurements identified distinct vertical aerosol layers between the surface- and cloud-base-associated thermodynamic decoupling layers. Such decoupling layers occur 49 % of the time during the summer in central Greenland, suggesting that surface aerosol measurements are insufficient for describing the cloud-relevant aerosol population half of the time. Experience during this first measurement season demonstrated the ability of a tethered-balloon platform to operate effectively under icing conditions and at low surface pressure (< 680 hPa). The results presented here illustrate the value of vertically resolved in situ measurements of aerosol properties in developing a nuanced understanding of the aerosol effects on cloud properties in polar regions.

Dynamic fluid-structure interaction between the projectile and the light-thin ice under the motion state in the polar environment

The interaction between projectiles and ice during water entry is crucial for advancing polar resource exploration and military operations in polar regions. This study introduces a fluid-structure interaction (FSI) model to simulate the dynamics between projectiles and light-thin ice under a motion state, validated through laboratory experiments. It examines the cavity evolution patterns during water entry and analyzes the motion states and dynamic characteristics of both the projectile and the floating ice. The influence of the horizontal-to-vertical velocity ratio (u*) and the initial pitch angle (φ) on the water entry process and collision dynamics has also been considered. The results reveal that as the projectile approaches the floating ice, it generates a wave-making effect, impacting the formation of the water entry splash crown and the deflection motion of the ice. Additionally, the hydrodynamic force acting on the projectile increases by 40 % compared to free water entry conditions. After the collision between the projectile and the light-thin ice, the pinch-off characteristics of the water entry cavity alter. This collision influences the motion state and dynamic characteristics of the projectile, while the ice experiences both collision and hydrodynamic forces, leading to passive motion. With an increasing water entry velocity ratio, the light-thin ice forms an expanding cavity during passive water entry, affecting the cavity pinch-off of the projectile. When u* > 1, the projectile exhibits circuitous motion post-collision with the ice. Variations in water entry angles of the projectile alter the collision mode between the projectile and the ice, resulting in changes to their motion states and dynamic characteristics. A critical pitch angle exists during the cavity pinch-off process.

Thousands of shallow, relict gullies indicate thermo-erosion on the sandy uplands of northern Lower Michigan during the Late Pleistocene

We build on previous work which explained the origin of myriad gullies and incised channels on the dry, sandy uplands of northern Lower Michigan by invoking widespread permafrost. Indicators of permafrost (ice-wedge casts and patterned ground) are known from many sites across the region. Our study area, within an extensive reentrant of the retreating Laurentide Ice Sheet, had been particularly well positioned, geographically, for permafrost. Our goal was to characterize the geomorphic characteristics of the gullies on 72 large ridges, to address the hypothesis that they had formed in association with permafrost. Across the study area, thousands of dry, narrow channels and gullies occur in dense networks, typically with channels aligned directly downslope, in parallel drainage patterns. Most of the gullies exhibit only a minimal amount of incision (ca. 2–3 m), a nearly straight longitudinal profile, and lack a clear depositional fan at their mouth. Even where small fans are present, they are subtle and exhibit little down-fan textural sorting, as would be present in larger, more mature fluvial systems. Gully morphologies did not exhibit strong morphological differences as a function of aspect, as we would have expected for an erosional, periglacial system forming on fairly steep slopes. Nonetheless, in these sandy/gravelly sediments, we could find no other scenario that would have allowed for runoff and gully formation, except ice-rich permafrost that limited infiltration and promoted saturation of the active layer, and eventually, runoff. We conclude that the gullies formed via thermo-erosion into ice-rich permafrost, involving mostly fluvial processes but also some slope failure. Even though thermo-erosion can rapidly form deep gullies, our study area has mainly weak gully forms, perhaps because: (1) permafrost existed here only briefly, (2) the landscape was so cold and the permafrost so ice-rich that runoff was rare, (3) the permafrost on the sandy slopes remained somewhat permeable, limiting runoff, and/or (4) the paleoclimate was so dry that little water was available for sediment transport. We could find no evidence that the gullies developed within preexisting polygonal networks, as is happening today in polar regions under a warming climate. Thus, our study has implications for areas of the Arctic and Antarctic that are, today, experiencing rapid hydrological changes.

DSSBU: A novel mass spectrometry-cleavable analogue of the BS3 cross-linker

Protein cross-linking has assumed an irreplaceable role in structural proteomics. Recently, significant efforts have been made to develop novel mass spectrometry (MS)-cleavable reagents. At present, only water-insoluble MS-cleavable cross-linkers are commercially available. However, to comprehensively analyse the various chemical and structural motifs making up proteins, it is necessary to target different protein sites with varying degrees of hydrophilicity. Here we introduce the new MS-cleavable cross-linker disulfodisuccinimidyl dibutyric urea (DSSBU), which we have developed in-house for this purpose. DSSBU contains an N-hydroxysulfosuccinimide (sulfo-NHS) reactive group, so it can serve as a water-soluble counterpart to the widely used cross-linker disuccinimidyl dibutyric urea (DSBU). To investigate the applicability of DSSBU, we compared the efficacy of four similar cross-linkers: bis[sulfosuccinimidyl] suberate (BS3), disuccinimidyl suberate (DSS), DSBU and DSSBU with bovine serum albumin. In addition, we compared the efficacy of DSBU and DSSBU with human haemoglobin. Our results demonstrate that the sulfo-NHS group ensures the superior water solubility of DSSBU and thus negates the need for organic solvents such as dimethyl sulfoxide while preserving the effectivity of urea-based MS-cleavable crosslinkers such as DSBU. Additionally, it makes it possible to target polar regions in proteins. The data gathered are available via ProteomeXchange under identifier PXD055284. SignificanceWe have synthesized the novel protein cross-linker DSSBU, which combines sulfo-NHS ester chemistry with a mass spectrometry-cleavable urea group. This makes DSSBU a water-soluble, MS-cleavable cross-linker that reacts with amino groups. To our knowledge, it is the first cross-linker which combines all three of these characteristics. We have tested the performance of our novel cross-linker on bovine serum albumin, a model widely used by the cross-linking mass spectrometry community, and on human haemoglobin. We have comprehensively assessed the performance of DSSBU and compared its efficacy with that of three other cross-linkers in current use (BS3, DSS and DSBU). We conclude that our novel cross-linker surpasses its MS-non-cleavable analogue BS3 in performance and that its water solubility eliminates the need for organic solvents while its hydrophilicity allows for the targetting of polar regions in proteins. Therefore, it will likely become a significant addition to the portfolio of N-hydroxysuccinimide ester cross-linkers.

Impact Pattern of Energetic Particle Precipitation on Polar Mesospheric Ozone

AbstractThe upper atmosphere of polar regions exhibits two distinct patterns of energetic particle precipitation that can lead to ozone destruction by ionizing the atmosphere: one is the energetic proton precipitation in the polar cap region during solar proton events (SPEs), and the other is the energetic electron precipitations (EEPs) in the auroral oval region from the radiation belt. In this study, we conduct case studies and statistical analyses of ozone observations from the Aura satellite to present the quantitative difference in the impact patterns of SPEs and EEPs on polar mesospheric ozone. According to our statistical analysis of 13 SPEs and 19 EEPs during the MLS time frame, the magnitude of ozone depletion during SPEs is greater than during EEPs. The ozone depletion during SPEs is more pronounced at higher geomagnetic latitudes and negatively correlates with the proton flux, while during EEPs the ozone depletion is more in favor of the geomagnetic latitude band of 60–70° but independent of the electron count rates. In addition, hydroxyl enhancement also exhibits different patterns during SPEs and EEPs, similar to that of ozone depletion. This study further validates the physical link between the magnetosphere and atmosphere and promotes our understanding of the solar influence on Earth's climate.

The thermal impact of the self-heating effect on airless bodies. The case of Mercury’s north polar craters

Thermal models are essential for studying airless planetary surfaces, as the interaction between topography and thermophysical properties plays a crucial role in determining a surface’s response to localized illumination. Accurate temperature distribution calculations require a comprehensive investigation of sunlight scattering, a process that, despite its computational challenges, cannot be overlooked, especially when high resolution is necessary. Furthermore, thermal analysis is fundamental for assessing the stability of volatiles in polar regions. In this study, we introduce a novel approach by discretizing the Sun into 100 individual elements, allowing for a highly precise simulation of solar flux—an innovation crucial for accurately capturing temperature distributions in Mercury’s polar craters, given the planet’s proximity to the Sun. This level of discretization significantly enhances the accuracy of the thermal model, ensuring a more realistic depiction of how sunlight interacts with crater topography. We developed a dual-model approach that simulates both direct solar illumination and its scattering on two craters, Laxness and Fuller, located at Mercury’s north pole. The illumination and thermal model predict temperature distribution and heat transfer based on the material’s thermal properties and topography. The study examines the interaction between direct sunlight, causing localized heating, and scattered light, which influences the thermal response of surface materials. Detailed illumination maps and temperature profiles were generated over two Hermean years, revealing the significant impact of the self-heating effect on temperature distribution. The results show that specific regions experience indirect solar flux due to the craters’ morphology, particularly in permanently shadowed regions (PSRs) that are heated exclusively by scattered radiation. Maximum temperature profiles for the Laxness and Fuller craters show a substantial temperature increase within PSRs compared to areas exposed to direct illumination. However, while self-heating does not affect the stability of water ice in the Laxness crater, in the Fuller crater, a section within the radar-bright material reaches temperatures of up to 210 K, potentially threatening the stability of water ice. Further investigation with the onboard SIMBIO-SYS instrument on the BepiColombo mission will help to better understand the current state of these craters and their volatile deposits.

ALBATROSS: Advancing Southern Ocean tide modelling with high resolution and enhanced bathymetry

The knowledge of bathymetry and ocean tides plays a pivotal role at the crossroads of various scientific fields, especially in the Polar regions. Its significance extends to ocean circulation modeling and understanding the coupled dynamical response of the ocean, sea-ice and ice-sheet systems. In the Southern Ocean, conventional satellite altimetry measurements are rare below the 66° parallel. Hydrodynamic models are thus useful tools to provide spatially continuous information about ocean tides. However, the accuracy of ocean tide models around the Antarctic continent is currently limited by the quality of bathymetry. Recent reprocessing of decade-long CryoSat-2 data has facilitated a new computation of bathymetry around Antarctica, bringing innovative information on bathymetry gradients. This, combined with new compilations of bathymetry, ice draft, coastline, and grounding line datasets in ice-shelf regions, allows improving models and knowledge of ocean tides in the Southern Ocean. We developed a new high-resolution tidal model that implements the improved bathymetry data and includes data assimilation of satellite-altimetry tidal retrievals computed from CryoSat-2, filling the gap between the 66°S-limited coverage of the TOPEX-Jason suite missions and the Antarctic coast. Comparisons with tidal estimates derived from tide gauge measurements showed very good consistencies with an RMSE of 3 cm.

Global integrated navigation position correction algorithm and virtual polar region technology based on normal vector

To achieve the inherent uniformity of all-earth navigation for autonomous underwater vehicles (AUV), a global integrated navigation position correction algorithm based on the normal vector (n-vector) is proposed. First, a four-element vector comprising the non-singular n-vector and height represents the carrier’s position in the Earth-centered Earth-fixed (ECEF) frame. The integrated navigation systems are designed with the strapdown inertial navigation system (SINS), Doppler velocity log (DVL), and other equipment. Secondly, the reverse navigation algorithm in the ECEF mechanization is derived, and the results of forward and reverse navigation are fused to correct the AUV’s underwater position. Additionally, a virtual polar region technology based on the ECEF attitude, velocity, and height invariant method (E-AVHIM) is proposed to convert the actual test data obtained at low and middle latitudes into high latitudes for more convincing polar region algorithm verification. Simulations and lake trial demonstrated the excellence and efficiency of the proposed algorithm.

Green Economy from a Regional Perspective – a Polish Case Study

The article presents the elaboration and specification of the green economy concept, where resource scarcity, global climate change and environmental degradation are paving a new path towards sustainable development. The article addresses the issue of implementing the principles of green economy at the regional level. The implementation of a green economy at a regional level provides an excellent space for scientific deliberations. The aim of the research is to identify and assess the level of regional disparities in green economy development across Polish regions using a synthetic measure. The basis for the analysis was a set of substantively and statistically analyzed diagnostic variables from the years 2012-2022. The synthetic indicator of the green economy was calculated for every Polish region (NUTS 2) and the regions were ranked based on their score from highest to lowest. As a result of the analysis, the regional polarization and the ordering of regions in Poland in terms of the synthetic metric - green economy development - were discussed. Keywords: green economy, green growth, sustainable development, taxonomic methods.

Nutrient dynamics and biogeochemical processes at the Polar front of Indian sector of the Southern Ocean: Influence of Circumpolar deep water intrusion

The Circumpolar Deep water (CDW) is one of the largest water masses in the Southern Ocean. The cross-frontal flow of the CDW is a vital mode of redistribution and transport of heat, salts, nutrients, etc. in the ocean. The present study aims to understand the role of the CDW intrusion on nutrient dynamics and biogeochemical processes at the Polar frontal region. The study noted a patch of high nutrients layer at ∼300-400 m in the Polar Front-II, underlying the dicothermal layer or the temperature minimum layer. This high nutrient patch was attributed to the intrusion of the CDW at the Polar front, influencing the physico-chemical processes in the water column. It was evident that, the density gradient, stratification and overall, the combined effect of physico-chemical and biological factors as a consequence of intrusion of the CDW contributed to the formation of the high nitrate patch at the Polar Front-II. Even though, the CDW intrusion did not significantly impact the photic layer dynamics during this study, the possible barrier effect during austral summer contribute to the formation of the high nitrate layer. This feature may be responsible for trapping nutrients in the subsurface due to stratification, made available to the photic region via upwelling processes, consequently triggering changes in the biological community structure and biogeochemical processes.

Mechanism of Circular Polarization in Giant Pulses and Fast Radio Bursts

Some giant pulses and fast radio bursts (FRBs) exhibit notable circular polarization, which remains unexplained and carries significant implications for their emission mechanisms. In this study, we identify multiple nanoshot pairs uniformly spaced by approximately 21 μs within a giant pulse emitted by the Crab pulsar. Among these pairs, a subset displays left-hand and right-hand circular polarization in two distinct nanoshots. We propose that the occurrence of such nanoshot pairs with dual circular polarizations arises from the fragmentation of a linearly polarized nanoshot along the magnetic field lines under the extreme Faraday effect, leveraging highly asymmetrical pair plasma and the ultra-intense field of nanoshots. The asymmetry in pair plasmas is likely linked to discharge activities in pulsars. Moreover, the intense field of nanoshots induces cyclotron resonance within the magnetosphere, effectively slowing down the propagation velocity of the circularly polarized mode. Our findings suggest that Crab giant pulses composing nanoshots originate in its polar cap region and escape the magnetosphere along the polar magnetic field. This mechanism can also elucidate the origin of circular polarization in some FRBs and thus lends support to their magnetospheric origin.

AniMAIRE‐A New Openly Available Tool for Calculating Atmospheric Ionising Radiation Dose Rates and Single Event Effects During Anisotropic Conditions

AbstractAniMAIRE (Anisotropic Model for Atmospheric Ionising Radiation Effects) is a new model and Python toolkit for calculating radiation dose rates experienced by aircraft during anisotropic solar energetic particle events. AniMAIRE expands the physics of the MAIRE + model such that dose rate calculations can be performed for anisotropic solar energetic particle conditions by supplying a proton or alpha particle rigidity spectrum, a pitch angle distribution, and the conditions of Earth's magnetosphere. In this paper, we describe the algorithm and top‐level structure of AniMAIRE and showcase AniMAIRE's capabilities by analyzing the dose rate maps that AniMAIRE produces when the time‐dependent spectra and pitch angle distribution for Ground Level Enhancement (GLE) 71 are input. We find that the dose rates AniMAIRE produces for the event fall between the dose rates produced by the WASAVIES and CRAC:DOMO models. Dose rate maps that evolve throughout the event are also shown, and it is found that each peak in the input pitch angle distribution generates a dose rate hotspot in each of the polar regions. AniMAIRE has been made available openly online so that it can be downloaded and run freely on local machines and so that the space weather community can easily contribute to it using Github forking.

An Endogenic Origin for Titan's Rampart Craters: Assessment of Explosion Mechanisms

AbstractRampart craters are a class of lakes or depressions in Titan's north polar region that have morphological attributes suggestive of an explosive origin. Two previous studies have proposed that rampart craters form via nitrogen or methane vapor explosions analogous to terrestrial maar explosions. We propose a new terrestrial analog for rampart craters: gas emission craters (GECs) found in permafrost zones. We evaluate the explosive origin of Titan's rampart craters by modeling the dispersal of material from an explosive vent. The dimensions of nine rampart craters with radar‐bright ramparts were used to model the explosion process. The model yields a range of explosion conditions (e.g., gas mass and reservoir depth) producing ejecta dispersal patterns matching the observed features. We find that gas masses of 1011–1014 kg are required to produce a rampart crater. We examine two explosion scenarios: (a) rapid, maar‐like vaporization and explosion of liquid nitrogen or methane, and (b) more gradual gas accumulation and explosion akin to a GEC driven by methane released from destabilizing clathrates. If Titan's crust is composed of pure water ice, the calculated gas pressures are consistent with a rapid, maar‐like explosion mechanism. If the subsurface is predominantly composed of organic materials or clathrate, either scenario may be plausible. Further research on the composition and tensile strength of Titan's subsurface are required to discriminate between hypotheses. Nevertheless, we conclude that explosive dispersal of ejecta from a vent can account for the morphologies of Titan's rampart craters and may contribute to atmospheric methane replenishment.

Fast Downflows Observed during a Polar Crown Filament Eruption

Solar filaments can undergo eruptions that result in the formation of coronal mass ejections, which can significantly impact planetary space environments. Observations of eruptions involving polar crown filaments, situated in the polar regions of the Sun, are limited. In this study, we report a polar crown filament eruption (SOL2023-06-12), characterized by fast downflows below the filament. The downflows appear instantly after the onset of the filament eruption and persist for approximately 2 hr, exhibiting plane-of-sky velocities ranging between 92 and 144 km s−1. They originate from the leading edge of the filament, and no clear acceleration is observed. Intriguingly, these downflows appear at two distinct sites, symmetrically positioned at the opposite ends of the conjugate flare ribbons. Based on the observations, we propose that the filament might be supported by a magnetic flux rope (MFR), and these downflows possibly occur along the legs of the MFR. The downflows likely result from continuous reconnections between the MFR and the overlying magnetic field structures and could either be reconnection outflows or redirected filament materials. We also observed horizontal drifting of the locations of downflows, which might correspond to the MFR’s footpoint drifting. This type of downflow can potentially be utilized to track the footpoints of MFRs during eruptions.

Molecular dynamics simulation of the interaction between ionic liquid [OPy][BF4] and SO2

Ionic liquids possess novel properties and can efficiently absorb harmful gases, potentially serving as a new type of absorbent. In this study, the binary system of ionic liquid N-octylpyridinium tetrafluoroborate [OPy][BF4] and sulfur dioxide (SO2) has been selected as the research object, and the structure and properties of the system have been studied by molecular dynamics simulation. The interaction between SO2 and ionic liquids is explored by using the radial distribution functions (RDFs), coordination numbers (CNs) and spatial distribution functions (SDFs). The results of microstructures show that due to the strong interaction with anions, SO2 is mostly orderly distributed around the anions of ionic liquids. However, the coordination ability of the polar region of the ionic liquid and SO2 is nearly equivalent to that of the non-polar region. At the same time, it is found that the addition of SO2 enhanced the order degree of the polar and the non-polar regions of ionic liquids, especially on non-polar regions. Through the discussion of the interaction between [OPy][BF4] and SO2, it can be concluded that the mechanism of SO2 absorption by [OPy][BF4] is the combined effect of anions and cations. This study aims to provide new insights for the potential applications of ionic liquids in industrial fields such as petroleum and flue gas desulfurization.

Calibration of Arctic ice core bromine enrichment records for past sea ice reconstructions

Bromine in ice cores has been proposed as a qualitative sea ice proxy to produce sea ice reconstructions for the polar regions. Here we report the first statistical validation of this proxy with satellite sea ice observations by combining bromine enrichment (with respect to seawater, Brenr) records from three Greenlandic ice cores (SIGMA-A, NU and RECAP) with satellite sea ice imagery, over three decades. We find that during the 1984–2016 satellite-era, ice core Brenr values are significantly correlated with first-year sea ice formed in the Baffin Bay and Labrador Sea supporting that the gas-phase bromine enrichment processes, preferentially occurring over the sea ice surface, are the main driver for the Brenr signal in ice cores. Moreover, in assessing Brenr's capability to record historical sea ice variability, we compare 20th-century Arctic Sea ice historical and proxy records with our reconstructions, based on an autoregressive–moving-average (ARMA) model, finding overall good agreement. While further enhancements are warranted, including site-specific calibrations and a comprehensive investigation into bromine transport-related concerns, this study presents a new method to quantitatively reconstruct past seasonal sea ice variability through bromine enrichment in ice cores.