Polarization optical detection has been widely used in the detection and identification of particle containing media such as clouds, aerosols, fire plumes, and volcanic smoke. Solid rocket plume is a typical high-temperature gas–solid two-phase medium. Polarization optical detection of solid rocket plume has attracted much attention in recent years. The polarized radiation transfer mechanism of solid rocket plume is complex, especially in the infrared band, with both the scattering radiation transfer from external incident light and the scattering radiation transfer from the high-temperature region inside the jet flame to the outside. The research on the polarization scattering characteristics of solid jet flame still needs to be further developed. Therefore, this study focuses on modeling the infrared polarization scattering mechanism and the simulation of polarization transfer characteristics of a solid rocket gas–solid two-phase plume, which can guide the usability analysis of solid rocket plume polarization detection. A novel model based on Semi-analytic Monte Carlo Method is proposed to simulate polarized radiation transfer of solid rocket plume. The wavelength and angle dependence of the self-radiation polarization characteristic of a solid rocket plume is simulated based on the proposed model. Note that the overall polarization degree of the plume shows wavelength selectivity and angle sensitivity at different wavelengths. The spatial distribution of polarization degree at 1.55 μm, 2.2 μm, and 2.75 μm shows that the plume edge's polarization degree is higher than the plume center. The findings suggest that the ratios of the relative contribution of self-radiation, direct solar radiation, and background polarization radiation components to the total polarization characteristics are 0.47 %, 70.50 %, 29.03 % at 1.55 μm and 20.43 %, 79.55 %, 0.02 % at 2.75 μm.