Polarization Of Light Research Articles

Chiral Symmetry Breaking in Colloidal Metal Nanoparticle Solutions by Circularly Polarized Light.

Shape symmetry breaking in the formation of inorganic nanostructures is of significant current interest. It was typically achieved through the growth of colloidal nanoparticles with adsorbed chiral molecules. Photochemical processes induced through asymmetric plasmon excitation by circularly polarized light in surface immobilized nanostructures also led to symmetry breaking. Here, we show that chiral symmetry breaking can be achieved by randomly rotating gold@silver core-shell nanobars in colloidal solution using circularly polarized illumination, where orientational averaging does not eliminate the symmetry breaking of an asymmetric plasmon-induced galvanic replacement reaction. Different morphological effects that are produced by circularly vs linearly polarized light illumination demonstrate the intricate effect of light polarization on the localized plasmonic-induced photochemical response. The essential features of this symmetry breaking, such as illumination wavelength dependence, were reproduced by simulations of circularly polarized light-excited-plasmon-induced hot-electron generation as the source for asymmetric metal deposition. The symmetry breaking becomes smaller in more symmetric geometrical shapes, such as triangular nanoprisms and nanocubes, and down to zero in spherical ones. The degree of symmetry breaking rises when the nanobars are immobilized on a substrate and illuminated from a single direction.

Ultrathin metasurface for super multi-view 3D display with linear and circular polarization control

Multiview 3D display technologies are advantageous due to their smooth motion parallax, visual discomfort alleviation, and wide depth of focus. However, the potential applications of this technology are constrained by its bulky size and limited light modulation capability. Metasurfaces offer diverse wavefront control by manipulating the phase, amplitude, and polarization of light. They provide design freedom and high image quality for multiview 3D display technologies. Here, we propose an ultrathin metasurface-based super multiview 3D display that can effectively modulate the flexibility of linearly polarized (LP) and circularly polarized (CP) electromagnetic waves. Numerical results demonstrate that it can produce 24 views together for LP and CP waves and high-quality reconstructed 3D images are obtained. The suggested metasurface for super multiview 3D display is promising to underpin the advancement of meta-optics-based operations in 3D display, imaging and integrated optics.

Comparison of rigorous scattering models to accurately replicate the behaviour of scattered electromagnetic waves in optical surface metrology

Rigorous scattering models are based on Maxwell's equations and can provide high-accuracy solutions to model electromagnetic wave scattering from objects. Being able to calculate the scattered field from any surface geometry and considering the effect of the polarisation of the incident light, make rigorous models the most promising tools for complex light-matter interaction problems. The total intensity of the electric near-field scattering from a silicon cylinder illuminated by the transverse electric and transverse magnetic polarisation of the incident light is obtained using various rigorous models including, the local field Fourier modal method, boundary element method and finite element method. The intensity of the total electric near-field obtained by these rigorous models is compared using the Mie solution as a reference for both polarisation modes of the incident light. Additionally, the intensity of the total electric near-field scattered from a silicon sinusoid profile using the same rigorous models is analysed. The results are discussed in detail, and for the cylinder, the deviations in the intensity of the total electric field from the exact Mie solution are investigated.

From [Ba3S][GeS₄] to [Ba₃CO₃][MS₄] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation

Birefringent crystals are crucial for manipulating light's phase and polarization, making them vital components in various optical devices. Traditionally, strategies for designing high-performance birefringent crystals have focused on modifying the parent structure. However, there are limited examples demonstrating how changing functional groups can effectively enhance birefringence (Δn), as such changes often significantly alter the crystal structure. In this study, we propose a “functional group implantation” strategy aimed at significantly improving birefringent performance within the chalcogenide system. This involves replacing the isotropic [S]2⁻ ions with anisotropic π-conjugated [CO₃]2⁻ groups. We validated this approach through comprehensive comparisons between the chalcogenide [Ba₃S][GeS₄] and the oxychalcogenide [Ba₃CO₃][MS₄] (where M ​= ​Ge and Sn), both of which adopt the same space group and feature the same arrangements of functional groups. Experimental characterization and theoretical calculations confirm that the [CO₃]2⁻ groups exhibit significantly greater polarization anisotropy than the [S]2⁻ groups. This difference leads to a marked increase in Δn in [Ba₃CO₃][MS₄] (ranging from 0.088 to 0.112 ​at 546 ​nm) compared to [Ba₃S][GeS₄] (0.021 ​at 546 ​nm). This finding not only broadens the structural chemistry of π-conjugated chalcogenides but also illustrates the potential of functional group implantation for designing infrared birefringent crystals with enhanced optical anisotropy.

Afterglow Linear Polarization Signatures from Shallow GRB Jets: Implications for Energetic GRBs

Gamma-ray bursts (GRBs) are powered by ultrarelativistic jets. The launching sites of these jets are surrounded by dense media, which the jets must cross before they can accelerate and release high-energy emission. Interaction with the medium leads to the formation of a mildly relativistic sheath around the jet, resulting in an angular structure to the jet’s asymptotic Lorentz factor and energy per solid angle, which modifies the afterglow emission. We build a semi-analytical tool to analyze the afterglow light curve and polarization signatures of jets observed from a wide range of viewing angles, and focus on ones with slowly declining energy profiles known as shallow jets. We find overall lower polarization compared to the classical top hat jet model. We provide an analytical expression for the peak polarization degree as a function of the energy profile power-law index, magnetic field configuration, and viewing angle, and show that it occurs near the light-curve break time for all viewers. When applying our tool to GRB 221009A, suspected to originate from a shallow jet, we find that the suggested jet structures for this event agree with the upper limits placed on the afterglow polarization in the optical and X-ray bands. We also find that at early times the polarization levels may be significantly higher, allowing for a potential distinction between different jet structure models and possibly constraining the magnetization in both forward and reverse shocks at that stage.

Nanoscale Chemical Imaging of Amyloid Fibrils in Water Using Total-Internal-Reflection Tip-Enhanced Raman Spectroscopy.

Total-internal-reflection tip-enhanced Raman spectroscopy (TIR-TERS) imaging of amyloid-β (Aβ1-42-L34T) fibrils is performed with nanoscale spatial resolution in water, using TERS tips fabricated by bipolar electrodeposition. Ideal experimental parameters are corroborated by both theoretical simulations and TIR-TERS measurements. TIR-TERS imaging reveals the predominant parallel β-sheet secondary structure of Aβ1-42-L34T fibrils as well as the nanoscale spatial distribution of tyrosine, histidine, and phenylalanine aromatic amino acids. Their proportion in TERS spectra can be qualitatively explained by the combined effect of their localization in the Aβ1-42-L34T fibril structure and their molecular orientation with respect to the excitation laser light polarization. Conclusions drawn from the TERS experiments in water corroborate and significantly enrich our previous study in ambient air, thus confirming that hydration has only a marginal impact on the structure of such amyloid fibrils. This first TIR-TERS study in liquid opens fascinating perspectives for future applications in biology.

High-Performance Planar Broadband Hot-Electron Photodetection through Platinum-Dielectric Triple Junctions.

Recently, planar and broadband hot-electron photodetectors (HE PDs) were established but exhibited degraded performances due to the adoptions of the single-junction configurations and the utilizations of absorbable films with thicknesses larger than the electronic mean free path. In this work, we present a five-layer design for planar HE PDs assisted by triple junctions in which an ultrathin Pt layer dominates the broadband and displays strong optical absorption (>0.9 from 900 nm to 1700 nm). Optical studies reveal that the optical admittance matching between optical admittances of designed device and air at all interested wavelengths is responsible for broadband light-trapping that induces prominent energy depositions in Pt layers. Electrical investigations show that, benefitting from suppressed hot-electron transport losses and increased hot-electron harvesting junctions, the predicted responsivity of the designed HE PD is up to 8.51 mA/W at 900 nm. Moreover, the high average absorption (responsivity) of 0.96 (3.66 mA/W) is substantially sustained over a broad incidence angle regardless of the polarizations of incident light. The comparison studies between five-layer and three-layer devices emphasize the superiority of five-layer design in strong optical absorption in Pt layers and efficient hot-electron extraction.

Mie Magnetic Structural Colors from Short Chains of TiO2 Nanospheres.

We demonstrate distinctive structural colors within a small footprint by using a short chain of nanospheres. Rather than using high-index materials like Si (n ∼ 4), which ensure strong modal confinement, TiO2 is employed. TiO2 has an intermediate index (n ∼ 2), promoting stronger modal coupling between the magnetic dipoles of each particle. This approach enables selective engineering of the magnetic response and yields larger spectral changes compared to that of Si. Despite the lower refractive index, the absence of absorption in TiO2 also produces higher scattering intensities than Si. We develop a quasistatic analytical model that describes the dipolar modal coupling in a trimer and use it to reveal distinct magnetic field strengths in the outer or central particle depending on the polarization of incident light. These results suggest pathways to manipulate the magnetic field in chains of particles and create vibrant structural colors with simple configurations.

Probing Majorana Wave Functions in Kitaev Honeycomb Spin Liquids with Second-Order Two-Dimensional Spectroscopy.

Two-dimensional coherent terahertz spectroscopy (2DCS) emerges as a valuable tool to probe the nature, couplings, and lifetimes of excitations in quantum materials. It thus promises to identify unique signatures of spin liquid states in quantum magnets by directly probing properties of their exotic fractionalized excitations. Here, we calculate the second-order 2DCS of the Kitaev honeycomb model and demonstrate that distinct spin liquid fingerprints appear already in this lowest-order nonlinear response χ_{yzx}^{(2)}(ω_{1},ω_{2}) when using crossed light polarizations. We further relate the off-diagonal 2DCS peaks to the localized nature of the matter Majorana excitations trapped by Z_{2} flux excitations and show that 2DCS thus directly probes the inverse participation ratio of Majorana wave functions. By providing experimentally observable features of spin liquid states in the 2D spectrum, our Letter can guide future 2DCS experiments on Kitaev magnets.

Realizing a kilowatt-level fiber amplifier with a 42 μm core diameter fiber for improved multi-mode performance towards single mode operation output through adaptive spatial mode control utilizing a 3×1 photonic lantern

The photonic lantern, a coherent beam combiner capable of controlling the phase, amplitude, and polarization of input light, has been utilized to enhance the brightness of fiber lasers by managing the output beam’s mode. In this work, a 3×1 photonic lantern-based adaptive spatial mode control system is employed to realize kilowatt-level operation in a 42 μm core fiber laser amplifier. Both simulation and experimental outcomes affirm the ability of this approach to manage modes within large-mode-area fiber laser systems through the use of 3 input arms. The experiment not only streamlines the overall system design but also has the potential to reduce production costs and complexities. Additionally, the spectrum width has been optimized to 10 GHz, striking a balance between the SBS threshold and the coherence of the photonic lantern’s input arms. By implementing this system, we have successfully achieved a stable, improved multi-mode performance towards single mode operation output of 1.08 kW, with a beam quality factor M2 of 2.20. This research furthers our understanding of how photonic lanterns can stabilize and enhance beam quality in high-power fiber lasers, paving the way for potential improvements in their performance and applications.

Reduced form of statistical equilibrium equations and radiative transfer equations

Abstract An extension of the vector algebra for irreducible spherical tensor operators (ITOs) is proposed, which involves coupling two ITOs into a third one (V (kv)= T (kt)× U (ku)*), with the additional condition that one of the operators is a complex conjugate and therefore is not an ITO. The correctness condition is considered for this extension. The new coupling rule treats the density matrices ρ(Kl) and all tensors related to light polarization (J (Kr) or Τ (K)) equally.
This approach has been applied to rewrite the fundamental statistical equilibrium equations and radiation transfer equations relevant to astrophysical polarimetry. The revised equations are more concise and eliminate the need for the nj symbols. Instead, they utilize vector and scalar products of ITOs. All rate coefficients in the equations consist of two independent factors, the reduced matrix element from dipole moments and the product (vector or scalar) of the tensors ρ(Kl) and J (Kr) (or Τ (K)).

Comparative Analysis of Two Different MIM Configurations of a Plasmonic Nanoantenna

AbstractTwo plasmonic nanoantenna configurations—nanodisk and nanostrip arrays—in a metal–insulator-metal (MIM) setup were proposed, optimized, and compared by simulating their optical properties in three-dimensional models using COMSOL Multiphysics software. The optical responses, including electric field enhancement, absorption, reflection, and transmission spectra, were systematically investigated. Optimized geometrical parameters led to a significant enhancement of the electric field within the gap layers and almost perfect light absorptance for both structures. The results showed that the enhancement of the electric field depends on the polarization of the incident light. For both polarizations, the periodic circular nanodisk array showed a stronger field enhancement with an electric field enhancement factor of 6.6 × 106 and TE polarization, and a larger absorptance of 98% at its dipole resonance wavelength, indicating the fundamental plasmonic mode. In addition, weaker resonant modes were observed in the absorptance and reflectance spectra of both nanostructures, with the nanostrips exhibiting sharper and stronger higher-order modes, making them suitable for applications requiring precise wavelength selectivity and narrow-band responses. Despite their different geometric shapes, both structures exhibited similar optimized metal film thickness and nanoparticle height, comparable modes in number and position, and identical optimized light incidence angles. Furthermore, increasing the dielectric gap layer thickness and optimizing it to a specific value revealed its ability to measure the refractive index, making it a promising candidate for sensing applications.

A Novel Incident Circular Polarized Light Raman Optical Activity (ICP‐ROA) Spectrometer With Advanced Polarization Control

ABSTRACTThe design and setup of a novel and simple backscatter Raman optical activity (ROA) spectrometer with incident light circular polarization (ICP) is presented, constructed from commercially available components. Incident light polarization is controlled using a combination of waveplates, compensating for unwanted birefringence and beam offsets. Realignment of the spectra in post‐processing reduced artifacts caused by spatial offsets. Spurious signals from achiral solvents like toluene and water are almost completely removed. The setup was validated by measuring references samples, including α‐pinene, carvone, and glucose in aqueous solution. The spectra show very good agreement with previously published results.

Research on sensing characteristics of high Q-factor all-dielectric metasurfaces based on geometric breaking

The bound states in the continuum (BIC) are widely used in designing metamaterials with high quality factor (Q-factor) resonances due to their perfect localization in the continuous spectral range coexisting with expanding waves. In this study, a T-shaped nanohole all-dielectric metasurface structure is proposed based on the unique electromagnetic properties of all-dielectric metasurfaces, and the fundamental reason of its coupled state and the theoretical basis of BIC excitation are deeply investigated based on the theory of group theory, and the geometric symmetry is broken from multiple angles, and the coupling relationship between discrete eigenmodes and the external continuum is specifically analyzed during the change of symmetry, its spectral response and near-field distribution are numerically calculated. In addition, based on the modulation mechanism of the incident light polarization angle, the three-channel resonance tuning with two resonances of the same frequency and one of a different frequency is realized under the condition that the resonance position and the Q-factor are not affected. This study not only provides a theoretical basis for the excitation conditions and evolution regularity of symmetry-protected BIC, but also solves the problem in the traditional analysis of resonance phenomena without taking the high Q-factor and stability into account, which can provide new designing methods for optical metasurface devices with multi-channel resonance.

Photoinduced Birefringence and Liquid Crystal Orientation on Polymers with Different Azobenzene Content in the Main Chain.

In this paper, we give an overview of novel main-chain azobenzene-based fluorinated poly(arylene ether)s with different content of azo groups, aiming at providing a better understanding of the link between a number of N═N bonds and the macroscopic response of the material. We discuss chemical synthesis and molecular structure and report on a comprehensive analysis of the polymer properties, thermal behavior, and mechanical strength. We show that a higher content of azobenzene moieties reduces the mechanical strength of the polymer materials. On the other hand, polymers with a higher content of azobenzene demonstrate higher values of induced birefringence due to a larger number of azobenzene in the trans form. The photoisomerization constants of all polymers fall within a very close range. The minor variations are attributed to the number of azobenzene groups in the polymer composition and the conformational arrangements of the polymer chain packing. The developed light-sensitive polymers were employed for dynamic control and manipulation of the liquid crystal orientation by polarization of the incident light. After the double irradiation of the substrates using appropriate photomasks, we made patterned cells that consist of domains with different high-resolution liquid crystal director orientations.

Effect of mirror system and scanner bed of a flatbed scanner on lateral response artefact in radiochromic film dosimetry.

Radiochromic film, evaluated with flatbed scanners, is used for practical radiotherapy QA dosimetry. Film and scanner component effects contribute to the Lateral Response Artefact (LRA), which is further enhanced by light polarisation from both. This study investigates the scanner bed's contribution to LRA and also polarisation from the mirrors for widely used EPSON scanners, as part of broader investigations of this dosimetry method aiming to improve processes and uncertainties. Alternative scanner bed materials were compared on a modified EPSON V700 scanner. Polarisation effects were investigated for complete scanners (V700, V800, on- and off-axis, and V850 on-axis), for a removed V700 mirror system, and independently using retail-quality single mirror combinations simulating practical scanner arrangements, but with varying numbers (0-5) and angles. Some tests had no film present, whilst others included films (EBT3) irradiated to 6 MV doses of 0-11.3 Gy. For polarisation analysis, images were captured by a Canon 7D camera with 50 mm focal length lens. Different scanner bed materials showed only small effects, within a few percent, indicating that the normal glass bed is a good choice. Polarisation varied with scanner type (7-11%), increasing at 10cm lateral off-axis distance by around a further 6%, and also with film dose. The V700 mirror system showed around 2% difference to the complete scanner. Polarization increased with number of mirrors in the single mirror combinations, to 14% for 4 and 5 mirrors, but specific values depend on angles and mirror quality. Novel film measurement methods could reduce LRA effect corrections and associated uncertainties.

C2H12N6C4O4·2H2O and Na2C4O4·3H2O: Two Ultraviolet Birefringent Compounds with the [C4O4]2- Group.

In modern optics, birefringent materials that can manipulate light polarization play important roles in lasers and information fields. The search for ultraviolet (UV) crystals with large birefringence is the focus of attention in the field of optical materials. In this work, we synthesized two birefringent crystals, C2H12N6C4O4·2H2O and Na2C4O4·3H2O, containing planar π-conjugated [C4O4]2- groups. Attributed to the large structural anisotropy and relatively ordered arrangement of the [C4O4]2- groups, C2H12N6C4O4·2H2O and Na2C4O4·3H2O possess large birefringence of 0.20-0.21 at 1064 nm. Meanwhile, they exhibit short ultraviolet cutoff edges at about 280-300 nm, corresponding to the large band gaps of 4.35 and 4.24 eV, respectively. Using structural analysis and first-principles calculations, the origins of such large birefringence are investigated and discussed. This work provides two potential UV birefringent crystals and prompts the search for novel birefringent materials.

On chip control and detection of complex SPP and waveguide modes based on plasmonic interconnect circuits

Abstract Optical interconnects, leveraging surface plasmon modes, are revolutionizing high-performance computing and AI, overcoming the limitations of electrical interconnects in speed, energy efficiency, and miniaturization. These nanoscale photonic circuits integrate on-chip light manipulation and signal conversion, marking significant advancements in optoelectronics and data processing efficiency. Here, we present a novel plasmonic interconnect circuit, by introducing refractive index matching layer, the device supports both pure SPP and different hybrid modes, allowing selective excitation and transmission based on light wavelength and polarization, followed by photocurrent conversion. We optimized the coupling gratings to fine-tune transmission modes around specific near-infrared wavelengths for effective electrical detection. Simulation results align with experimental data, confirming the device’s ability to detect complex optical modes. This advancement broadens the applications of plasmonic interconnects in high-speed, compact optoelectronic and sensor technologies, enabling more versatile nanoscale optical signal processing and transmission.

A contactless in situ EFISH method for measuring electrostatic potential profile of semiconductor/electrolyte junctions.

In photoelectrochemical cells, promising devices for directly converting solar energy into storable chemical fuels, the spatial variation of the electrostatic potential across the semiconductor-electrolyte junction is the key parameter that determines the cell performance. In principle, electric field induced second harmonic generation (EFISH) provides a contactless in situ spectroscopic tool to measure the spatial variation of electrostatic potential. However, the total second harmonic generation (SHG) signal contains the contributions of the EFISH signals of semiconductor space charge layer and the electric double layer, in addition to the SHG signal of the electrode surface. The interference of these complex quantities hinders their analysis. In this work, to understand and deconvolute their contributions to the total SHG signals, bias-dependent SHG measurements are performed on the rutile TiO2(100)-electrolyte junction as a function of light polarization and crystal azimuthal angle (angle of the incident plane relative to the crystal [001] axis). A quadratic response between SHG intensity and the applied potential is observed in both the accumulation and depletion regions of TiO2. The relative phase difference and amplitude ratio are extracted at selected azimuthal angles and light polarizations. At 0° azimuthal angle and s-in-p-out polarization, the SHG intensity minimum has the best match with the TiO2 flatband potential due to the orthogonal relative phase difference between bias-dependent and bias-independent SHG terms. We further measure the pH-dependent flatband potential and probe the photovoltage under open circuit conditions using the EFISH technique, demonstrating the capability of this contactless method for measuring electrostatic potential at semiconductor-electrolyte junctions.

Infrared Optical Anisotropy in Quasi‐1D Hexagonal Chalcogenide BaTiSe3

AbstractPolarimetric infrared (IR) detection bolsters IR thermography by leveraging the polarization of light. Optical anisotropy, i.e., birefringence and dichroism, can be leveraged to achieve polarimetric detection. Recently, giant optical anisotropy is discovered in quasi‐1D narrow‐bandgap hexagonal perovskite sulfides, A1+xTiS3, specifically BaTiS3 and Sr9/8TiS3. In these materials, the critical role of atomic‐scale structure modulations in the unconventional electrical, optical, and thermal properties raises the broader question of the nature of other materials that belong to this family. To address this issue, for the first time, high‐quality single crystals of a largely unexplored member of the A1+xTiX3 (X = S, Se) family, BaTiSe3 are synthesized. Single‐crystal X‐ray diffraction determined the room‐temperature structure with the P31c space group, which is a superstructure of the earlier reported P63/mmc structure. The crystal structure of BaTiSe3 features antiparallel c‐axis displacements similar to but of lower symmetry than BaTiS3, verified by the polarization dependent Raman spectroscopy. Fourier transform infrared (FTIR) spectroscopy is used to characterize the optical anisotropy of BaTiSe3, whose refractive index along the ordinary (E ⊥ c) and extraordinary (E ‖ c) optical axes is quantitatively determined by combining ellipsometry studies with FTIR. With a giant birefringence Δn ∼ 0.9, BaTiSe3 emerges as a new candidate for miniaturized birefringent optics for mid‐wave infrared to long‐wave infrared imaging.