Polar Components Research Articles

Polarization-separating Alvarez metalens.

The rapid advancements in optical communication technologies have highlighted traditional optical components' limitations, particularly in size, adaptability, and integration capabilities, underscoring the need for more compact and versatile solutions. Metalenses offer a promising pathway to address these challenges, with their ability to provide high-functionality, miniaturized optical components. We developed a varifocal metalens with a polarization separation function designed for the wavelength of 1550 nm for potential application for next-generation communication technologies. To integrate the varifocal and polarization separation functions, polarization-dependent phase profiles for an off-axis Alvarez lens were derived and encoded by amorphous silicon pillar meta-atoms with rectangular cross sections to provide independent 0-2π phase delays for both orthogonal linear polarization components. The fabricated metalens achieved a varifocal range of 0.75 mm to 10.65 mm and a polarization extinction ratio of 18.5 dB.

The Hydrophilicity of Samama Wood Surface Quality after Boron, Methyl Methacrylate Impregnation, and Heat Treatment

Indicators of surface roughness and surface-free energy can represent the improvement in wood surface quality. In this study, those two indicators were used to determine the change in the samama (Anthocephalus macrophyllus) wood surface following two modification steps, namely impregnation and heat treatment. The first step was boron impregnation in two forms applied separately, i.e., boric acid and borax. The second step was impregnation of methyl methacrylate followed by heat treatment at 90°C and 180°C. Surface roughness was determined following the ISO 4287:1997 standard, and surface free energy was analyzed using the Rabel Method. The results showed that the radial surface of samama wood naturally had a lower roughness than the tangential surface. Impregnation with boric acid, borax, and methyl methacrylate increased the wood surface roughness. However, heat treatment at 180°C tended to smooth the rough surface. Total surface free energy was altered after borax and methyl methacrylate impregnation. However, heat treatment seemingly withdrew the alteration. The polar components and dispersion contributed to total surface free energy with different compositions. In this study, the change in surface roughness was not congruent with the change in total surface free energy. Keywords: boron, heat treatment, impregnation, samama, surface free energy

Characterising the modifying efficiency of polyphosphoric acid to bitumens with different oil sources

ABSTRACT To explore the properties and mechanism of different polyphosphoric acid (PPA)-modified bitumen, this research selected three bitumens with different oil sources and two PPAs with different relative H3PO4 contents (which are 105%, 115%, namely 105 and 115 grade PPA, respectively). A succession of tests and analyses was conducted to explore the performance of the PPA-modified bitumens. The physical performance test results show that PPA improves the high-temperature performance of the bitumens, and it has different modification effects on the three bitumens. When PPA reacted with the bitumen that has a higher content of polar components, the performance variation of the bitumen was higher than the other two kinds of bitumens. Furthermore, the 115-grade PPA seemed to have a better modified efficiency than that of the 105-grade PPA due to the longer molecular chain length. This also leads to the entanglement of molecular chains of PPA-modified bitumen was more significant with the 115-grade PPA. Therefore, the 115-grade PPA-modified bitumen shows a large asphaltene agglomeration in the AFM diagram.

Multiwavelength Spectral Energy Distribution Analysis of X-Ray Selected Active Galactic Nuclei at z = 0.2–0.8 in the Stripe 82 Region

We perform a systematic, multiwavelength spectral energy distribution (SED) analysis of X-ray detected active galactic nuclei (AGNs) at z = 0.2–0.8 with Sloan Digital Sky Survey (SDSS) counterparts in the Stripe 82 region, consisting of 60 type 1 and 137 type 2 AGNs covering a 2–10 keV luminosity range of 41.6<logLx<44.7 . The latest CIGALE code, where dusty polar components are included, is employed. To obtain reliable host and AGN parameters in type 1 AGNs, we utilize the image-decomposed optical SEDs of host galaxies by Li et al. based on the Subaru Hyper-Suprime Cam images. The mean ratio of black hole masses (M BH) and stellar masses (M stellar) of our X-ray detected type 1 AGN sample, log(MBH/Mstellar)=−2.7±0.5 , is close to the local relation between BH and stellar masses as reported by Li et al. for SDSS quasars. This ratio is slightly lower than that found for more luminous ( logLbol>45 ) type 1 AGNs at z ∼ 1.5. This can be explained by the AGN luminosity dependence of log(MBH/Mstellar) , which little evolves with redshift. We confirm the trend that the UV-to-X-ray slope (α OX) or X-ray-to-bolometric correction factor (κ 2–10) increases with AGN luminosity or Eddington ratio. We find that type 1 and type 2 AGNs with the same luminosity ranges share similar host stellar mass distributions, whereas type 2s tend to show smaller AGN luminosities than type 1s. This supports the luminosity-dependent (or Eddington-ratio-dependent) unified scheme.

Switchable multi-wavelength coherent polarization manipulation component based on single-layered hollowed S-shaped metasurface

High-performance metasurface polarization manipulation components have important applications in the fields of polarization imaging, polarization detection, and communication. Single-layered metasurface components have attracted a great deal of interest, but it is still a challenge to realize high-efficiency and dynamic polarization manipulation. Combined with coherent control techniques, we propose a single-layered hollowed S-shaped metasurface design that may accomplish multi-wavelength polarization switching in the optical to near-infrared band. The single-layered metasurface enables a real-time switchable effect between dual-wavelength and single-wavelength polarization properties by controlling the phase difference between two coherent counter-propagating lights. The physical mechanism of switchable multi-wavelength coherent polarization manipulation is elucidated based on the electric field distribution of the hollowed S-shaped structure. The effect of metal layer thickness on the switchable coherent polarization properties is investigated in detail. The proposed hollowed S-shaped metasurface significantly improves the polarization performance of the single-layered structure, which is expected to facilitate the development of switchable and compact polarization components.

Development of Synthetically Accessible Glycolated Polythiophenes for High‐Performance Organic Electrochemical Transistors

AbstractFour glycolated polythiophene‐based organic mixed ionic‐electronic conductors (OMIECs), PE2gTT, PE2gT, PT2gTT, and PT2gT are prepared by atom‐efficient direct arylation polymerization, avoiding the need for toxic organometallic precursors. PE2gT, PT2gTT, and PT2gT are operable in p‐type accumulation mode organic electrochemical transistors (OECTs), with PT2gT displaying the best device performance with a µC* product figure‐of‐merit of 290 F cm−1 V−1 s−1. A record volumetric capacitance among p‐type glycolated polythiophene OMIECs of 313 F cm−3 is observed for PE2gT, ascribed to the high proportionality of polar components in its materials design. The good OECT performance of PE2gT with µC* = 84.2 F cm−1 V−1 s−1, comparable with state‐of‐the‐art poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) devices, coupled with its synthetic accessibility and favorable accumulation mode operation makes PE2gT an ideal glycolated alternative to PEDOT:PSS in bioelectronics. PE2gT with the least negative threshold voltage also displays the best OECT operational cycling stability, linked to better resistance of its oxidized state against parasitic redox side reactions . Shelf life stability of OECTs stored (without bias) is observed to be better for materials with a more negative threshold voltage and higher average molecular weight (PT2gT), that are less susceptible to ambient auto‐oxidation and film delamination.

Superhydrophilic and oleophobic sponges prepared based on Mussel-Inspired chemistry for efficient oil-water separation.

Superhydrophilic/oleophobic materials are considered to be the best materials for achieving oil-water separation, but their preparation is difficult and the existing methods are not universal. In this paper, a two-step modification strategy was used to prepare superhydrophilic/oleophobic sponges by adjusting the polar and nonpolar components of the materials using mussel-inspired chemistry. While remaining superhydrophilic, the modified sponge surface has a maximum contact angle of 135° with different oils in air. The modified sponge exhibited superoleophobicity in water, and the contact angle of oil could reach more than 150°. In addition, the modified sponges were also reusable, chemically stable, and mechanically durable. Its oil-water separation flux was up to 24900 Lm-2 h-1 bar-1 , and the separation efficiency was above 97 %. We believe that this method will provide an environmentally friendly and efficient way to prepare the superhydrophilic/oleophobic materials.

Nanotexture and crystal phase regulation for synergistic enhancement in re-endothelialization on medical pure titanium surface

Re-endothelialization has been recognized as a promising strategy to address the tissue hyperplasia and subsequent restenosis which are major complications associated with vascular implant/interventional titanium devices. However, the uncontrollable over-proliferation of smooth muscle cells (SMCs) limits the clinical application of numerous modified strategies. Herein, a novel modified strategy involving with a two-step anodic oxidation and annealing treatment was proposed to achieve rapid re-endothelialization function regulated by regular honeycomb nanotexture and specific anatase phase on the titanium surface. Theoretical calculation revealed that the presence of nanotexture reduced the polar component of surface energy, while the generation of anatase significantly enhanced the polar component and total surface energy. Meanwhile, the modified surface with regular nanotexture and anatase phase produced positive effect on the expression of CD31, VE-Cadherin and down-regulated α-SMA proteins expression, indicating excellent capacity of pro-endothelial regeneration and inhibition of SMCs proliferation and migration. One-month in vivo implantation in rabbit carotid arteries further confirmed that modified tube implant surface effectively accelerated confluent endothelial monolayer formation and promoted native-like endothelium tissue regeneration. By contrast, original titanium tube implant induced a disorganized tissue proliferation in the lumen with a high risk of restenosis. Collectively, this study opens us an alternative route to achieve the function that selectively promotes endothelial cells (ECs) growth and suppresses SMCs on the medical titanium surface, which has a great potential in facilitating re-endothelialization on the surface of blood-contacting titanium implant.

Effect of the Addition of Naringenin Derived from Citrus on the Properties of Epoxy Resin Compositions.

This research concerns the modification of commercially available epoxy resin with flame retardants in order to obtain aging-resistant and antimicrobial polymeric materials with a plant stabilizer dedicated to use in rail transport. Polymer compositions based on epoxy resin, fiberglass fabric, and naringenin were prepared. Naringenin was added as a natural stabilizer at 2, 4, and 8 phr. The materials were subjected to solar aging lasting 800 h. The hardness of the samples, surface energy, and carbonyl indexes were determined, and the color change in the composition after aging was analyzed. In addition, microscopic observations, analyses of mechanical properties, and microbiological tests were performed. The hardness determination showed that the samples retained their functional properties after solar aging. The increase in the polar component of the surface energy of all materials indicated the beginning of the degradation process of the composites. The tensile one-directional tests were carried out for plane samples taken in three directions (0, 90, and 45 degrees referred to a plate edge) before and after the aging process. The addition of naringenin did not affect the functional and surface properties of the epoxy resin-based materials. Polyphenol stabilized polymer composites, as evidenced by the results of carbonyl indexes. Moreover, the obtained samples showed good antimicrobial properties for E. coli and C. albicans in the field of testing the viability of microbial cells in contact with the tested surfaces.

Multi-component oil–water two phase flow in quartz and kerogen nanopores: A molecular dynamics study

Two-phase flow of oil and water frequently occurs within shale nanopores. Unique phenomena, like liquid–liquid slip at the oil–water interface, have been noted within the alkane-water system. However, in the case of realistic crude oil, the presence of highly polar components like asphaltene and toluene may introduce intricate migration behaviors near phase interfaces. Consequently, it is imperative to thoroughly explore the influence of these realistic crude oil components on flow behavior. This paper employs a comparative approach to examine the impact of polar components present in crude oil on two-phase nanoflow by molecular dynamic simulations. The investigation employs a mixed alkanes model (encompassing methane, propane, octane, and tetradecane) and a black oil model (comprising a range of alkanes, toluene, and asphaltene) to analyze the behavior of oil–water two-phase flow within quartz and kerogen nanopores, respectively. Four water adsorption layers near the quartz with an individual thickness of 0.23 nm and three alkane adsorption layers near the kerogen surface with an individual thickness of 0.45 nm were observed. Near the oil–water interface region, it indicated that toluene and asphaltene tend to accumulate, leading to a reduction of alkane aggregation in that region. Such aggregation of toluene and asphaltene imparts an interfacial viscosity increase of 2.67 to 3.47 times, substantially diminishing the enhancement of liquid–liquid slip. Based Hagen-Poiseuille equation, we proposed a simplified mathematical model in which the liquid–liquid slip was neglected and the oil–water interface region was omitted. Compared with the results from molecular dynamic simulations, such a simplified model is validated and effective for the description of oil–water two-phase nanoflows containing toluene and asphaltene, and ensures that the relative error of flow rate remains below 0.5 %. This study provides valuable insights into the two-phase flow of oil–water in nanopores, particularly measuring the effect of liquid–liquid slip under the different crude oil components conditions.

Folded interferometer to measure coherence-polarization matrix.

We present and experimentally demonstrate a new, to the best of our knowledge, technique to quantitatively measure coherence-polarization (BCP) matrix with correlations of only two Stokes fluctuations. The BCP matrix is a square matrix with four elements that involves two-point correlations among orthogonal polarization components. A theoretical framework of the technique is developed, and its viability is demonstrated by a proof of principle experiment. Experimental tests and measurement of the elements of the BCP matrix of statistically stationary beams are demonstrated.

Machine Learning Based Automatic Mode-Locking of a Dual-Wavelength Soliton Fiber Laser

Recent years have witnessed growing research interest in dual-wavelength mode-locked fiber lasers for their pivotal role in diverse applications and the exploration of nonlinear dynamics. Despite notable progress in their development, achieving reliable mode-locked dual-wavelength operation typically necessitates intricate manual adjustments of the cavity’s polarization components. In this article, we present the realization of automatic mode-locking in a dual-wavelength soliton fiber laser. To provide guidance for the algorithm design, we systematically investigated the impact of polarization configurations and initial states on the laser’s operation through numerical simulations and linear scan experiments. The results indicate that operational regimes can be finely adjusted around the wave plate position supporting the mode-locked dual-wavelength solution. Furthermore, the laser exhibits multiple stable states at the mode-locked dual-wavelength point, with critical dependence on the initial conditions. Accordingly, we developed a two-stage genetic algorithm that was demonstrated to be effective for realizing automatic dual-wavelength mode-locking. To further improve the performance of the algorithm, a feedforward neural network was trained and integrated into the algorithm, enabling accurate identification of the dual-wavelength states. This study provides valuable insights into understanding how polarization configurations and initial conditions impact the operational regimes of dual-wavelength mode-locked fiber lasers. The algorithm developed can be extended to optimize other systems with multiple stable states supported at the same parameter point.

Batik Waste Degradation Using Heterogeneous Fenton Method Using Catalysts To Reduce Environmental Pollution

The batik industry is one of the industries that develops from time to time. Among the problems that are still a concern today is industrial waste, especially the content of dyes. Reactive dyes found in batik wastewater are very harmful in the environment, and so far only a few industries process the batik waste before disposing of it into the environment. AOPs technology is a combination of several processes such as ozone (O3), hydrogen peroxide, UV light, titanium oxide, photocatalyst, electrolysis, electron beam, electrical discharge, and several others to produce hydroxyl radicals. One method of AOPs is the process of using fenton reagents. This study aims to identify the impact of variations that occur on the active components of batik color waste. The results showed that the use of zeolite catalysts tends to be more effective in absorbing polar components and less effective in absorbing organic matter. This statement is supported by a higher percentage of removal from natural zeolite than activated carbon which is 100%.

КОНЦЕПТОСФЕРА МОВИ ВОРОЖНЕЧІ В ПРОПАГАНДИСТСЬКОМУ ДИСКУРСІ КРАЇНИ-АГРЕСОРА

The article attempts to catalog the key markers of hate speech used in the propaganda narratives of the aggressor country to create an image of the enemy. The article analyzes an array of propaganda material produced by the Russian Telegram channel «SlezhuZa». The most frequent and significant concepts for the propaganda ecosystem of the Russian Federation are identified: «Ukrainianism», «Russophobia», «decaying West», and «Anti-Russia project». The extra-linguistic circumstances of the origin of each concept are characterized; the etymological layer of each concept is revealed to expose its primary meaning; the polar components of the concepts are established through the explanation of lexemes with associative links, mythologemes, culture, and ideologemes. The linguistic picture of the world based on a particular concept is reconstructed. The historical manifestations of concepts that ensure their influence through the diachrony of «visions» of the Russian Federation are understood. The effect of the information bubble, into which the recipients of the Russian network channel «SlezhuZa» fall, is problematized, given the transboundary nature of the Telegram environment and the lack of development of media critical thinking among Ukrainian users. It is noted that hate speech, instrumentally used in hybrid influences, inspired aggression against our country and is now used to legitimize military actions. It is concluded that propaganda campaigns that unfold around precedentsetting narratives exploit the binary opposition of Us/Them, which keeps the image of the enemy in the focus of public attention. It is indicated that the lexical expansion of hate speech occurs through the creation of neologisms and occasionalisms. It is found that the peripheral meanings of the considered concepts are situational in nature of application, have a high level of associativity and allusiveness to the historical past.

Exploring the interplay between thermo-oxidative degradation and asphalt aging in thermoplastic polyurethane-modified asphalt: Mechanisms, properties, and performance evolution

The aging behavior of thermoplastic polyurethane-modified asphalt (TPUMA) is intricate and the mechanisms of its thermal degradation are not well understood. This study examines the viscoelastic, chemical and morphological characteristics of thermoplastic polyurethane modified asphalt (TPUMA) under different aging conditions (RTFOT/PAV). The rheological master curve model of the S parameter was used to analyze the fitting effect on TPUMA, with SBS (styrene–butadiene–styrene) modified asphalt serving as the control group. The relationship between the phase angle plateau area and polymer aging degradation was elucidated. This study investigates the impact of polymer degradation on the high-temperature rheological behavior and medium-temperature fatigue properties of asphalt through temperature sweep, multiple stress creep recovery (MSCR), and linear amplitude sweep (LAS) tests. Fourier transform infrared spectrometer (FTIR) and confocal laser scanning microscopy (CLSM) are used to qualitatively and quantitatively analyze the chemical composition and morphological evolution of TPUMA during thermal-oxidative degradation. The findings suggest that TPUMA's performance changes in the aging environment is result from the dual coupling effect of polymer degradation and asphalt oxidative hardening. The closely arranged isocyanate (-NCO) and polar component molecular chains in asphalt slow down its oxidation speed, which enhances the aging and deformation resistance of TPUMA. The successful blending of TPU and asphalt was confirmed, and the degradation degree of the polymer was quantitatively characterized by the percentage of the degraded area. The results provide insights to better understand the interplay between TPU degradation and asphalt oxidation.

Influence of the structure of the pore space of rocks on the wettability and adsorbed fluids of reservoir rocks

Theoretical and experimental studies of the effect of the geometry of the pore space on the wettability of collectors have been carried out. The special structure of the pore space of the Talinskaya area of the Krasnoleninsky deposit, due to the heterogeneity of the composition of rocks, leads to heterogeneity in the size and geometry of filtration channels and affects wettability. The specificity of the adsorption of polar components of oil causes changes in wettability and affects the amount of adsorbed oil. Keywords: pore space geometry; adsorbed fluids; wettability.

Efficient catalyst regeneration through solvent-based wax extraction for Co/Al2O3 Fischer-Tropsch catalysts

The regeneration of Fischer-Tropsch (FT) catalysts plays a crucial role in sustaining their catalytic activity and longevity in sustainable production processes. This research investigates the effectiveness of various solvents, including n-hexane, n-heptane, toluene, xylene, and the liquid fraction of FT products (LF-FT), for catalyst regeneration and extracting wax from the 15 wt%Co/Al2O3 catalyst. Toluene, with a unique combination of key parameters such as polarity, solubility, boiling point, aromatic structure, and chemical interactions, exhibited the highest wax removal efficiency of 90.6%. However, due to its 41 °C lower boiling point compared to toluene and very similar wax removal efficiency, n-hexane appears as a more energy-efficient and cost-effective option for this process. The regenerated catalysts showed comparable characteristics, including the textural properties (surface area, pore size, and pore volume), crystallinity, and reducibility, to fresh catalysts. The slightly lower reduction temperature in the regenerated catalyst indicates a higher possibility for the formation of cobalt active sites during the catalyst reduction process with hydrogen, leading to an increased potential for higher catalytic activity. The LF-FT, comprising paraffins, iso-paraffins, olefins, napthenes, and aromatics, provided a unique combination of aliphatic and aromatic moieties, enhancing the solubility of both polar and nonpolar components in FT wax and improving the wax removal efficiency to 91.5%. The higher boiling point and operating temperature of the LF-FT also contributed to its better performance. Efficient separation of hydrocarbons from solvents allowed for solvent reusability in subsequent FT wax removal cycles, making it advantageous for large-scale applications.

Study on the Characterization of Physical, Mechanical, and Mildew Resistance Properties of Enzymatically Treated Bamboo Fiber-Reinforced Polypropylene Composites

The enhancement of the physical and mechanical properties and the anti-mildew performance of wood–plastic composites are of great significance for broadening their application field. In this research, bamboo fibers underwent treatments with safe, environmentally friendly bio-enzymes. Subsequently, a bamboo–plastic composite (BPC) was developed using the modified bamboo fibers and polyethylene. The effects of biological enzymatic treatments on the surface free energy, the chemical composition of the bamboo fibers, water resistance, thermal stability, bending performance, impact performance, and anti-mildew performance of the BPC samples were analyzed. This study revealed that treating bamboo powder with bio-enzymes (xylanase, lipase, laccase, pectinase, hemicellulase, or amylase) decreased the surface free energy and the polar components of the bamboo fibers while improving the surface O/C atomic ratio of the bamboo fibers. These enzyme treatments enhanced the water resistance, bending performance, and anti-mildew performance of the BPC samples. However, on the whole, the thermal stability of the composites decreased. Particularly, after hemicellulase treatment, the composites had the lowest water absorption, reflecting a decrease of 68.25% compared to the control group. With xylanase modification, the 24 h water absorption thickness swelling rate of the composites was the lowest, reflecting a decrease of 71.27% compared to the control group. After pectinase modification, the static bending strength and elastic modulus of the prepared composites were the highest, with an increase of 15.45% and 13.31%, respectively, compared to the unmodified group. After xylanase modification, the composites exhibited the best anti-mildew effect, with an anti-mold effectiveness of 74.67%. In conclusion, bio-enzyme treatments can enhance the physical and mechanical properties and anti-mildew performance of BPCs. This research provides a theoretical foundation for the preparation of high-performance wood–plastic composites.

Activated carbon adsorption of heteroatom components from pyrolysis oil for improved chemical recycling

Pyrolysis is a promising technique for managing mixed plastic waste. However, its industrial implementation faces significant challenges due to the presence of heteroatom components in the pyrolysis oil. These impurities are the major hurdle to use these feeds in steam crackers. To address this issue, we evaluated the potential of adsorption on activated carbon as a purification method by measuring the adsorption capacity of nine of the most important heteroatom components in pyrolysis oils. Through single-isotherm experiments and modeling, our aim was to understand the interactions between the adsorbate and the adsorbent as well as the influence of the component-pyrolysis oil interaction. Furthermore, multicomponent isotherm experiments further explored cooperative and competitive interactions among different heteroatom components, providing valuable insights into their behavior in complex systems. Our findings highlight benzoic acid as the most effective adsorbate (qm = 193.4 ± 12.8 mg g−1), while less polar components such as cyclopentanone (qm = 15.9 ± 1.79 mg g−1), hexamethylcyclotrisiloxane (qm = 7.11 ± 1.27 mg g−1), and 1-chloropentane (no detectable removal) pose challenges for pyrolysis oil purification without excessive dosing of the adsorbent, in our case activated carbon. Moreover, multicomponent experiments revealed that pyridine exhibits cooperative adsorption behavior, whereas other components engage in competitive adsorption dynamics. The analysis of six multicomponent models emphasized the importance of considering adsorbate–adsorbate interactions in describing the adsorption behavior in complex mixtures. Models equipped with interaction parameters (correlative model) outperformed those without such parameters (predictive model), as evidenced by higher R2 values (R2 = 0.95–0.99) for the former compared to the latter (R2 = 0.84–0.86).

Influence of the structure of quinoline derivatives on their sorption on hypercrosslinked polystyrene

The article is devoted to the study of the chromatographic behaviour of quinoline and tetrahydroquinoline derivatives. The purpose of the study was to investigate the patterns of sorption of these compounds from aqueous-acetonitrile solutions on hyper-cross-linked polystyrene using reverse-phase high-performance liquid chromatography. The volume, polarizability, lipophilicity, and dipole moment of molecules of quinoline derivatives were calculated, which significantly depended on the nature and position of functional groups and substituents in the main nucleus. It has been established that the appearance of functional groups and substituents leads to an increase in the volume and polarizability of the molecules of quinoline derivatives compared to unsubstituted quinoline and methylquinoline, while the lipophilicity and dipole moment change depending on the nature of the substituent and its position in the main fragment. The dependences of sorption characteristics on the structure and physicochemical properties of sorbates were obtained. It has been shown that, in accordance with the laws of the reversed-phase version of liquid chromatography, the retention of substances changes symbatically with the change in the characteristics of the molecules responsible for dispersion interactions. In this case, the presence in the molecules of halogen atoms, phenyl radicals and other substituents capable of π-interactions with the surface of hyper-cross-linked polystyrene led to a significant increase in retention, and the presence of a carboxyl group or carboxyalkyls prone to interaction with the polar eluent significantly weakens retention. The appearance of an ester group in sorbate molecules generally significantly increased the volume, polarizability and lipophilicity of the corresponding derivatives, but had virtually no effect on retention, and therefore it was suggested that the presence of a carbonyl oxygen atom, capable of interacting with the polar components of the eluent, neutralizes the effect of physical-chemical factors that determine the sorption of these substances due to dispersion interactions. Thus, despite the symmetry in changes in the physicochemical parameters of the studied compounds and their retention, there was no strict proportionality, since, on the one hand, the retention of sorbates was carried out in accordance with the change in their physicochemical parameters, and on the other hand, it was determined by the tendency molecules of these compounds to competitive interactions with the components of the mobile phase. The presented results of the study can be useful in the development and optimization of methods for analysing compounds with similar structures, as well as for developing the theory of sorption of polyfunctional compounds from multicomponent solutions and establishing the relationship between sorption characteristics, other physicochemical parameters and the structure of molecules.