Polarization Layer Research Articles

Polarity‐Driven Atomic Displacements at the 2D Mg2TiO4‐MgO (001) Oxide Interface for Hosting Potential Interlayer Excitons

AbstractInterlayer excitons in solid‐state systems have emerged as candidates for realizing novel platforms ranging from excitonic transistors and optical qubits to exciton condensates. Interlayer excitons have been discovered in 2D transition metal dichalcogenides, with large exciton binding energies and the ability to form various van der Waals heterostructures. Here, an oxide system consisting of a single unit cell of Mg2TiO4 on MgO (001) is proposed as a platform for hosting interlayer excitons. Using a combination of density functional theory (DFT) calculations, molecular beam epitaxy growth, and in situ crystal truncation rod measurements, it is shown that the Mg2TiO4‐MgO interface can be precisely controlled to yield an internal electric field suitable for hosting interlayer excitons. The atoms in the polar Mg2TiO4 layers are observed to be displaced to reduce polarity at the interface with the non‐polar MgO (001) surface. Such polarity‐driven atomic displacements strongly affect electrostatics of the film and the interface, resulting in localization of filled and empty band‐edge states in different layers of the Mg2TiO4 film. The DFT calculations suggest that the electronic structure is favorable for localization of photoexcited electrons in the bottom layer and holes in the top layer, which may bind to form interlayer exciton states.

Improved Simulation of the Polar Atmospheric Boundary Layer by Accounting for Aerodynamic Roughness in the Parameterization of Surface Scalar Exchange Over Sea Ice

AbstractA new, simple parameterization scheme for scalar (heat and moisture) exchange over sea ice and the marginal ice zone is tested in a numerical weather and climate prediction model. This new “Blended A87” scheme accounts for the influence of aerodynamic roughness on the relationship between momentum and scalar exchange over consolidated sea ice, in line with long‐standing theory and recent field observations, and in contrast to the crude schemes currently operational in most models. Using aircraft observations and Met Office Unified Model simulations of cold‐air outbreak (CAO) conditions over aerodynamically rough sea ice, we demonstrate striking improvements in model performance when the Blended A87 scheme replaces the model's operational treatment for surface scalar exchange, provided that the aerodynamic roughness over consolidated ice is appropriately prescribed. The mean biases in surface sensible heat flux, surface latent heat flux, near‐surface air temperature, and surface temperature reduce from 25 to 11 W m−2, 22 to 12 W m−2, 0.8 to 0.0 K, and 1.4 to 0.8 K, respectively. We demonstrate that such impacts on surface exchange over sea ice can have a marked impact on the evolution of the atmospheric boundary layer across hundreds of kilometres downwind of the sea ice during CAO conditions in the model. Our results highlight the importance of spatiotemporal variability in the topography of consolidated sea ice for both momentum and scalar exchange over sea ice; accounting for which remains a key challenge for modeling polar weather and climate.

Mechanism of Chromium Separation and Concentration from Tannery Wastewater by Membrane Methods

The article specifies conditions for a nanofiltration process employing a diafiltration method with a constant volume diafiltration (NF-CVD) for exhausted chromium tannery wastewater treatment and describes a mechanism of the examined process carried out for model wastewater. The authors prove that a decrease in salt concentration in the NF-CVD process is an important factor that enables effective concentration of chromium. Based on the proposed chromium separation and concentration mechanisms, it was found that this effect may be achieved by (1) limiting the formation of an ionic adsorption-polarization layer and (2) reducing the increase in the osmotic pressure caused by a change in the separation properties of the membrane. The article shows that in the analyzed system a higher amount of the solvent introduced at the diafiltration stage and a lower process pressure that ensures a reduction in salt retention translate to a high level of salt removal. In regenerates, after the NF-CVD processes in which at least the same volume of a washing diluent as the volume of the retentate after the pre-concentration step was used, salt concentration below 10 g L-1 and chromium concentration about three times higher than in the case of the feed solution were obtained. Therefore, the proposed solution implements the circular economy strategy in the tannery.

Bifunctional Separator with Ultra-Lightweight MnO2 Coating for Highly Stable Lithium-Sulfur Batteries.

The severe shuttling behavior in the discharging-charging process largely hampers the commercialization of lithium-sulfur (Li-S) batteries. Herein, we design a bifunctional separator with an ultra-lightweight MnO2 coating to establish strong chemical adsorption barriers for shuttling effect alleviation. The double-sided polar MnO2 layers not only trap the lithium polysulfides through extraordinary chemical bonding but also ensure the uniform Li+ flux on the lithium anode and inhibit the side reaction, resulting in homogeneous plating and stripping to avoid corrosion of the Li anode. Consequently, the assembled Li-S battery with the MnO2-modified separator retains a capacity of 665 mA h g-1 at 1 C after 1000 cycles at the areal sulfur loading of 2.5 mg cm-2, corresponding to only 0.028% capacity decay per cycle. Notably, the areal loading of ultra-lightweight MnO2 coating is as low as 0.007 mg cm-2, facilitating the achievement of a high energy density of Li-S batteries. This work reveals that the polar metal oxide-modified separator can effectively inhibit the shuttle effect and protect the Li anode for high-performance Li-S batteries.

Rotation-Invariant Feature Learning via Convolutional Neural Network With Cyclic Polar Coordinates Convolutional Layer

Convolutional neural networks (CNNs) have been demonstrated to be powerful tools to automatically learn effective features from large datasets. Though features learned in CNNs are approximately scale-, translation-, and position-invariant, and their capacity in dealing with image rotations remains limited. In this article, a novel cyclic polar coordinate convolutional layer (CPCCL) is proposed for CNNs to handle the problem of rotation invariance for feature learning. First, the proposed CPCCL converts rotation variation into translation variation using polar coordinates transformation, which can easily be handled by CNNs. Moreover, cyclic convolution is designed to completely handle the translation variation converted from rotation variation by conducting convolution in a cyclic shift mode. Note that the proposed CPCCL is capable of generalization and can be used as a preprocessing layer for classification CNNs to learn the rotation-invariant feature. Extensive experiments over three benchmark datasets demonstrate that the proposed CPCCL can clearly handle the rotation-sensitive problem in traditional CNNs and outperforms several state-of-the-art rotation-invariant feature learning algorithms.

Impact of the mutual direction of Polarizer and Free Layer on the auto-oscillation mode of magnetic tunnel junctions (MTJs) of different geometry

In this work we studied the auto-oscillation mode of structures based on magnetic tunnel junctions. During the experiment we studied how different values and orientation of the magnetic field affect the efficiency of the auto-oscillations regime for samples of various shapes. The auto-oscillation mode in samples was observed near the transition from one state of magnetization of the free layer to another. It was found that the maximum value of the power spectral density and its position relative to the frequency axis can be controlled by changing the magnitude and orientation of the external magnetic field. Keywords: Magnetic tunnel junction (MTJ), auto-oscillations, power spectral density, nanooscillator.

Multilayer nanocomposites with ultralow loadings of nanofillers exhibiting superb capacitive energy storage performance

Multilayered nanocomposites with ultra-low loading of nanofillers exhibit ultrahigh comprehensive energy storage performances, excellent dielectric stability and reliability.

Electrodialysis desalination: The impact of solution flowrate (or Reynolds number) on fluid dynamics throughout membrane spacers

The incorporation of a spacer among membranes has a major influence on fluid dynamics and performance metrics. Spacers create feed channels and operate as turbulence promoters to increase mixing and reduce concentration/temperature polarization effects. However, spacer geometry remains unoptimized, and studies continue to investigate a wide range of commercial and custom-made spacer designs. The in-depth discussion of the present systematic review seeks to discover the influence of Reynolds number or solution flowrate on flow hydrodynamics throughout a spacer-filled channel. A fast-flowing solution sweeping one membrane's surface first, then the neighboring membrane's surface produces good mixing action, which does not happen commonly at laminar solution flowrates. A sufficient flowrate can suppress the polarization layer, which may normally require the utilization of a simple feed channel rather than complex spacer configurations. When a recirculation eddy occurs, it disrupts the continuous flow and effectively curves the linear fluid courses. The higher the flowrate, the better the membrane performance, the higher the critical flux (or recovery rate), and the lower the inherent limitations of spacer design, spacer shadow effect, poor channel hydrodynamics, and high concentration polarization. In fact, critical flow achieves an acceptable balance between improving flow dynamics and reducing the related trade-offs, such as pressure losses and the occurrence of concentration polarization throughout the cell. If the necessary technical flowrate is not used, the real concentration potential for transport is relatively limited at low velocities than would be predicted based on bulk concentrations. Electrodialysis stack therefore may suffer from the dissociation of water molecules. Next studies should consider that applying a higher flowrate results in greater process efficiency, increased mass transfer potential at the membrane interface, and reduced stack thermal and electrical resistance, where pressure drop should always be indicated as a consequence of the spacer and circumstances used, rather than a problem.

Vertical GaN/InGaN/GaN heterostructure tunnel field-effect transistor: DC and analog/RF performance

This work reports an [Formula: see text]-type GaN/InGaN/GaN heterostructure vertical double-gate tunnel field-effect transistor (VTFET) using exhaustive calibrated simulation for the first time. Investigation has been done for the proposed structure by including a polarization layer of InGaN near the source-channel junction. From the analysis, it has been observed that after the introduction of polarization layer near the source-channel interface, drain current increases due to the increase in charge concentration (2DEG) near the interface due to inter-band tunneling. Value of 2DEG concentration achieved post introducing the polarization layer is [Formula: see text] [Formula: see text]. The reported structure is optimized using parametric sweep optimization technique. Here, a detailed dc and analog/RF performance estimation has been done for the structure with heterostructure. In-depth sensitivity analysis has been done for the structure with the polarization layer. It is reported that the structure with HfO2 as the dielectric material with [Formula: see text] of 2 nm and with gate metal work function of 5.8 eV gives the optimum performance at 300 K. Further, it demonstrates high cutoff frequency ([Formula: see text] and gain bandwidth product (GBW) as 1000 GHz and 300 GHz, respectively. Hence, the reported structure is a better alternative for high-power steep switching analog and RF applications.

Significantly Enhanced Breakdown Strength and Energy Density in Nanocomposites by Synergic Modulation of Structural Design and Low-Loading Nanofibers.

Polymer-based dielectric nanocomposites have attracted great attention due to the advantages of high-power density and stability. However, due to the limited breakdown strength (Eb) of the dielectrics, the unsatisfactory energy density becomes the bottleneck that restricts their applications. Here, newly designed sandwich-structured nanocomposites are proposed, which includes the introduction of low-loading 0.4BiFeO3-0.6SrTiO3 (BFSTO) nanofibers into the poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) matrix as the polarization layer (B-layer) to offer high permittivity and the selection of poly(methylmethacrylate) (PMMA)/P(VDF-HFP) all-organic blend film as the insulation layer (P-layer) to improve Eb of the nanocomposites. The optimized sandwich-structured PBP nanocomposite exhibits significant enhancement in Eb (668.6 MV/m), generating a discharged energy density of 17.2 J/cm3. The dielectric and Kelvin probe force microscope results corroborate that the outer P-layer has a low surface charge density, which can markedly impede the charge injection from the electrode/dielectric interface and thereby suppress the leakage current inside the nanocomposite. Furthermore, both the finite element simulations and capacitive series models demonstrate that the homogenized distribution of electric field in the PBP sandwich-structured nanocomposite favors the improvement of energy storage performance. This work not only provides insightful guidance into the in-depth understanding of the dielectric breakdown mechanism in sandwich-structured nanocomposites but also offers a novel paradigm for the development of polymer-based nanocomposites with high Eb and discharged energy density.

Micellar enhanced ultrafiltration of phenol with dodecylpyridinium chloride and sodium dodecylbenzene sulfonate

AbstractMicellar enhanced ultrafiltration is a surfactant‐based separation process for wastewater treatment. The ultrafiltration of dodecyl pyridinium chloride (DPC) and sodium dodecyl benzene sulfonate (SDBS) solutions was realized with 5 kDa and 15 kDa molecular weight cut‐off ceramic membranes. Surfactant concentrations under and over the micellar critical concentration at three different pressures were studied, and their effects on permeate flux and retention are reported. It was found that an increase in pressure operation, in 0.8–1.8 bar range, causes a lower surfactant concentration in permeate by the presence of a polarization layer. These systems were studied for phenol removal. DPC/phenol system (73.5 mM/0.53 mM) reaches a 61% removal of organic solute. SDBS/phenol system (14.7 mM/0.58 mM) reaches a 25% removal, both with 5 kDa membrane at 1.8 bar. In the case of the cationic surfactant the micelle's positive charge plays a preponderant role in attracting the phenol molecules, while the SDBS does not present this electrostatic interaction.

High-quality N-polar GaN optimization by multi-step temperature growth process

We report growth optimization of Nitrogen (N)-polar GaN epitaxial layers by hot-wall metal–organic vapor phase epitaxy on 4H-SiC (0001̄) with a misorientation angle of 4° towards the [112̄0] direction. We find that when using a 2-step temperature process for the N-polar GaN growth, step bunching is persistent for a wide range of growth rates (7 nm/min to 49 nm/min) and V/III ratios (251 to 3774). This phenomenon is analyzed in terms of anisotropic step-flow growth and the Ehrlich–Schwöebel barrier, and their effects on the surface step height and step width. The N-polar GaN growth is further optimized by using 3-step and 4-step temperature processes and the layers are compared to those using the 2-step temperature process in terms of surface morphology and defect densities. It is shown that a significantly improved surface morphology with a root mean square of 1.4 nm and with low dislocation densities (screw dislocation density of 2.8 × 108 cm−2 and edge dislocation density of 1.3 × 109 cm−2) can be achieved for 4-step temperature process. The optimized growth conditions allow to overcome the step-bunching problem. The results are further discussed in view of Ga supersaturation and a general growth strategy for high-quality N-polar GaN growth is proposed.

Optimization of high temperature energy storage properties of PEI‐based composite dielectric based on rapid in‐situ growth of inorganic functional layer

AbstractThe serious deterioration of the energy density of polymer energy storage dielectrics in high temperature environment is the main reason to curb the in‐depth application of dielectric film capacitors in the field of modern electrical and electronic engineering. Here, aiming at the problem of low dielectric constant of polymer dielectric, a simple, low‐cost method is proposed to grow inorganic polar functional layer on surface of polymer film in situ, which effectively improves the polarization characteristics of polymer dielectric at high temperature. The in situ growth of Ti(OH)4 inorganic polar functional layer on surface of polyetherimide (PEI) film noteworthy to improve the energy storage performance of dielectric film. The energy storage density of 4.59 J/cm2 is obtained at 150°C and 600 MV/m, which is 1.18 times that of PEI film under the same condition. The significant enhancement of high temperature energy storage density can be attributed to introduction of functional layer, which effectively improves the dielectric properties and polarization intensity of dielectric film. Furthermore, the facile preparation method provided in this paper can be applied to various thin films under the premise of controllable cost, which is of great significance to improve the high temperature energy storage characteristics of polymer dielectric.

Strategic approach for achieving high indoor efficiency of perovskite solar Cells: Frustration of charge recombination by dipole induced homogeneous charge distribution

Indoor-light harvesting-technology based on perovskite solar cells have attracted significant attention owing to their promising photovoltaic properties as indoor power generators. We investigated the effect of interfacial dipoles on the performance of perovskite solar cells in low-intensity indoor light environments. Interfacial dipoles were controlled by inserting different polar layers with different molecular dipole moments (BCP, QPPO and QDPPO) on top of electron transport layers (ETLs). Significantly improved uniformity of interfacial dipoles, in the QDPPO layer, effectively reduced charge recombination and enabled persistent fill factors (FF’s) under low-intensity light environments. Perovskite solar cells based on QDPPO exhibited indoor power density (iPD) and indoor power conversion efficiency (iPCE) of 65.63 μW/cm2 and 27.49 % under 800 lux LED, which were further enhanced up to 88.09 μW/cm2 and 36.90 % by employing additional passivation layer under 800 lux LED. Finally, using QDPPO, we successfully demonstrated perovskite photovoltaic mini-modules with a high power output of 2.4 mW under a 1,000 lux halogen, which can be applied in Internet-of-Things sensors under indoor light conditions.

Regulation effect of koumine on T-helper cell polarization in rheumatoid arthritis

Koumine, an alkaloid, exerts therapeutic effects against rheumatoid arthritis (RA), and thus may have a potential application in novel treatment strategies against this disease. Herein, we investigated the regulatory effect of koumine on Th cell polarization using a “pyramid” structure model to elucidate the mechanism underlying its therapeutic effect on RA. The third layer of the model comprises the cytokine secretion layer, in which the effects of koumine on the balance of Th-related cytokines were investigated in mice with collagen-induced arthritis (CIA). Koumine showed significant therapeutic effects and reversed the imbalance of Th1/Th2 and Th17/Treg cytokines. In the Th cell polarization layer, the effects of koumine on the relative numbers of Th cell subsets in splenocytes of rats with CIA were examined. Koumine attenuated both of the increased Th1/Th2 and Th17/Treg subset ratios accompanied with its therapeutic effects. Finally, the primary cultured splenocytes from BALB/c mice were used to further investigate the effect of koumine on Th cell activation by evaluating cell proliferation induced by concanavalin A (Con A), lipopolysaccharides (LPS) and phytohemagglutinin (PHA). Koumine inhibited the cell proliferation responses and its effects on proliferation induced by Con A and PHA were greater than those by LPS, showing the relatively selective inhibition on the proliferation of Th cells. Our results suggest that koumine might restore the homeostasis of the network system with Th subsets and cytokines by inhibiting the activation of T cells, subsequently regulating the polarization of Th subsets and the downstream imbalance of pro/anti-inflammatory cytokines in RA.

Searching for the sources of ice block falls at the martian north polar scarps

We searched for the sources of ice block falls at the steep scarps of the martian North Polar Layered Deposits (NPLD). We focused on two study areas at the NPLD, i.e., Scarp 1 (centered at 85.0°N, 151.5°E with a length of ∼20 km) and Scarp 2 (centered at 83.8°N, 235.5°E with a length of ∼12.5 km). Repeat High Resolution Imaging Science Experiment (HiRISE) observations with image scales of up to 0.25 m/pixel were used. Specifically, we identified changes in the shadow patterns at the scarps which attest to block fall activity. An automated change detection method, which searches for the grayscale difference between multi-temporal images, was developed to identify these patches where shadows have changed. The method was evaluated in six areas of Scarp 1 over all detection periods, and achieved an average true positive rate of 97.6% and false discovery rate of 9.4%. The spatio-temporal distribution showed that ice block falls were an active process. Along Scarp 1, about 129 ice block falls occurred per Mars year per km2, mostly at elevations 0–300 m of the 500 m high scarp, where the slope is over 30°. The amount of ice block falls increased with steeper slope angles. Along Scarp 2, about 237 ice block falls occurred per Mars year per km2, resting in the form of smaller blocks and fine particles, or spreading outward in fan-shaped patterns. We compared the detected source areas at Scarp 2 with the fresh ice blocks observed on the underlying Basal Unit (BU) between MY 30 and MY 31 to analyze the dynamic process of ice block falls. Underneath the areas with large numbers of detached ice-fragments, many fresh ice blocks were found on the BU. On the other hand, some regions of Scarp 2 did not show evidence of detached ice-fragments despite fresh ice blocks on the BU areas below. Our comparison proved that both the NPLD and the BU scarps are active source areas of ice block falls. The detections of block fall sources at the NPLD scarps can help to distinguish events from the NPLD and those from the BU and refine the estimates of active polar scarp retreat, which will improve the understanding of the polar cap evolution.

On the morphology of electrostatic solitary waves in the Earth’s aurora

Electrostatic solitary waves (ESWs) have been detected in abundance in Space plasma observations, both by satellites in near-Earth plasma environments as well as by planetary missions, e.g. Cassini in Saturn or MAVEN in Mars. In their usual form, these are manifested as a bipolar electric field corresponding to a bell-shaped pulse in the electrostatic potential. Recent studies have suggested the existence of alternative forms of ESWs, including flat-top solitary waves (FTSWs) and supersolitary waves (SSWs), both of which are often encountered in Space observations such as in polar cap boundary layer, the auroral acceleration region and elsewhere. This article focuses on the existence and characterization of different types of electrostatic solitary waves in multicomponent Space plasmas. Relying on a multi-fluid plasma model, comprising two types of ions and two different electron populations, we have identified the conditions for existence of flat-top solitary waves and supersolitons, in contrast to “standard" solitary waves. Both ion species are models as cold fluids, for simplicity. Our analysis reveals that the coexistence of the two electron populations is pivotal for the formation of such non-standard electrostatic structures, and that their characteristic parameters (temperature, density ratio) plays a decisive role in their generation and structural characteristics. Nonetheless, while supersolitary waves may exist in a wide range of parameter values (as confirmed by earlier theoretical studies), it appears that flat-top solitary waves will occur in a narrow window in the parameter region, which may explain their scarce (but non-negligible) frequency of observation. Our theoretical findings confirm and validate the existence of alternative (non-conventional) ESW waveforms in auroral plasma (in addition to the ubiquitous bipolar electric field form), where such an electron coexistence is typically observed.

Exploring stratification effects in stable Ekman boundary layers using a stochastic one-dimensional turbulence model

Abstract. Small-scale processes in atmospheric boundary layers are typically not resolved due to cost constraints but modeled based on physical relations with the resolved scales, neglecting expensive backscatter. This lack in modeling is addressed in the present study with the aid of the one-dimensional turbulence (ODT) model. ODT is applied as stand-alone column model to numerically investigate stratification effects in long-lived transient Ekman flows as canonical example of polar boundary layers by resolving turbulent winds and fluctuating temperature profiles on all relevant scales of the flow. We first calibrate the adjustable model parameters for neutral cases based on the surface drag law which yields slightly different optimal model set-ups for finite low and moderate Reynolds numbers. For the stably stratified cases, previously calibrated parameters are kept fixed and the model predictions are compared with various reference numerical simulations and also observations by an exploitation of boundary layer similarity. ODT reasonably captures the temporally developing flow for various prescribed stratification profiles, but fails to fully capture the near-surface laminarization by remaining longer in a fully developed turbulent state, which suggests preferential applicability to high-Reynolds-number flow regimes. Nevertheless, the model suggests that large near-surface turbulence scales are primarily affected by the developing stratification due to scale-selective buoyancy damping which agrees with the literature. The variability of the wind-turning angle represented by the ensemble of stratified cases simulated covers a wider range than reference reanalysis data. The present study suggests that the vertical-column ODT formulation that is highly resolved in space and time can help to accurately represent multi-physics boundary-layer and subgrid-scale processes, offering new opportunities for analysis of very stable polar boundary layer and atmospheric chemistry applications.

Partially‐Saturated Brines Within Basal Ice or Sediments Can Explain the Bright Basal Reflections in the South Polar Layered Deposits

AbstractStrong radar reflections have been previously mapped at the base of the Martian South Polar Layered Deposits. Here, we analyze laboratory measurements of dry and briny samples to determine the cause of this radar return. We find that liquid vein networks consisting of brines at the grain boundaries of ice crystals can greatly enhance the electrical conductivity, thereby causing strong radar reflections. A brine concentration of 2.7–6.0 vol% in ice is sufficient to match the electrical properties of the basal reflection as observed by Mars Advanced Radar for Subsurface and Ionospheric Sounding (MARSIS). When brine is mixed with sediments, the brine‐ice mixture in the pores must be 2–5 times more concentrated in salt, increasing the brine concentration to 6.3–29 vol%. Our best fit of the median observed MARSIS value suggests a salt‐bulk sample concentration of ∼6 wt%. Thus, salt enhancement mechanisms on the order of a magnitude greater than the Phoenix landing site are needed. To form brine, the basal reflector must reach a temperature greater than the eutectic temperature of calcium perchlorate of 197.3 ± 0.2 K, which may be possible if more complex thermal modeling is assumed. Colder metastable brines are possible, but stability over millions of years remains unclear. Conversely, gray hematite with a concentration of 33.2–59.0 vol% possess electrical properties that could cause the observed radar returns, but require concentrations 2–3 times larger than anywhere currently detected. We also argue that brines mixed with high‐surface‐area sediments, or dry red hematite, jarosite, and ilmenite cannot create the observed radar returns at low temperatures.

Using MARSIS signal attenuation to assess the presence of South Polar Layered Deposit subglacial brines

Knowledge of the physical and thermal properties of the South Polar Layer Deposits (SPLD) is key to constrain the source of bright basal reflections at Ultimi Scopuli detected by the MARSIS (Mars Advanced Radar for Subsurface and Ionosphere Sounding) radar sounder. Here we present a detailed analysis of attenuation, based on data acquired by MARSIS at 3, 4, and 5 MHz. We show that attenuation is frequency dependent, and that its behavior is consistent throughout the entire region. This suggests that the SPLD are compositionally homogeneous at Ultimi Scopuli, and our results are consistent with dust contents of 5 to 12%. Using these values as input, and plausible estimates of surface temperature and heat flux, we inferred basal temperatures around 200 K: these are consistent with perchlorate brines within liquid vein networks as the source of the reflections. Furthermore, extrapolation of the attenuation to higher frequencies explains why SHARAD (Shallow Radar) has thus far not detected basal reflections within the SPLD at Ultimi Scopuli.