The primary pollutants emitted from mobile sources have become one of the main sources of urban air pollution. In this study, the primary pollutants CO, HC, NOx and PM from mobile sources in Zibo city, China are studied. Firstly, the localized mobile-source pollutant emission factors are corrected using vehicle emission experiments; secondly, multi-source data fusion is performed using road network data, road traffic data, air quality and meteorological data; then, the corrected pollutant emission factors and multi-source data are used to construct a localized emission measurement model and dispersion simulation model, visualize the emission distribution and propose residual concentration correction to accurately obtain the pollutant sharing rate. The results show that the pollutant emission trends are highly coupled with the distribution of urban residents’ working hours. Based on the localized dispersion model used to analyze the pollutant traceability at air monitoring stations, the emission sharing rate of NOx is the largest, and according to the analysis of the changing trend of mobile-source emission sharing rate, the mobile source pollutants in Zibo are mainly influenced by pollutant emissions from road motor vehicles. This study provides data support and a theoretical basis for the management of the transportation industry to carry out exhaust gas control of motor vehicles and non-road mobile machinery and to make decisions related to improving the air environment (delineating the scope of low emission zones).