Abstract Composite materials are increasingly used in 3D metrology, especially for portable measuring devices such as articulated arm coordinate measuring machines (AACMM), 3D scanners, and ball bars. Their use is justified by their interesting mechanical properties including their low density, good rigidity, and especially their light weight, which makes them ideal for portable devices, that are meant to be often transported by the user. However, due to their complex composition, the characterization of the thermal behavior of composite materials remains complicated compared to standard materials and is nowadays an active research subject. In fact, the coefficient of thermal expansion of composite materials is dependent of the very specific composition of the composite material considered. Hence, it is function of several parameters such as the orientation of the fibers, the fiber volume fraction, the ply sequence, the cooling rate, etc. In the other hand, in 3D metrology, and especially in portable 3D metrology, determining the expansion coefficient of the different part of the measurement devices used is necessary. In fact, the portable measurement machines are often integrated and used directly on the shop floor, where the thermal variations can be important and then heavily impact the measurements results. In some cases, the lack of knowledge of the coefficient of thermal expansion of the composite materials that compose the portable measuring machine can significantly increase the measurement uncertainty.