The low ductility of titanium aluminide at room temperature has been one of the factors that severely limit its applications. In this study, Ti–6Al–4V (Ti64) alloys were combined with Ti–47Al–2Cr–2Nb (TiAl) alloys to make micro-laminated composites with optimal ply configurations to eliminate crack formation in TiAl and improve the ductility. A dual-material laser powder bed fusion (LPBF) system was used to fabricate the TiAl/Ti64 micro-laminate samples. The presence of cracks, elemental composition and mechanical properties were experimentally characterised and analysed to understand the effect of ply configuration and the mechanism of eliminating cracks. It was found that smaller TiAl ply thickness and lower TiAl volume fraction result in fewer cracks formed in the micro-laminates. Elemental composition analysis reveals that the Al content in the first two powder layers (i.e., 200 μm thick in total) of a TiAl ply is reduced to 10%–35% due to the partial mixture of the TiAl ply and the proceeding Ti64 ply in the LPBF. The reduced Al content leads to combined α-Ti, β-Ti and α2-Ti3Al phases instead of γ-TiAl phases, thus eliminating the formation of cracks within the first 200 μm thick region of the TiAl ply. This study demonstrates that crack-free and dense TiAl/Ti6 micro-laminated composites can be produced with the TiAl ply thickness reduced to 200 μm and the TiAl volume fraction reduced to 25% (Ti64 ply thickness 400 μm). Ductility of the crack-free micro-laminates at room temperature is comparable to or even exceeds the properties of TiAl/Ti64-type laminates made by other manufacturing processes, which may imply good machinability. Note that further research is required to investigate the properties and applications of the micro-laminates at elevated temperatures.
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