Hubble Space Telescope/Wide Field and Planetary Camera 2 (HST/WFPC2) images of Io obtained between 1995 and 2007 between 0.24 and 0.42μm led to the detection of the Pele plume in reflected sunlight in 1995 and 1999; imaging of the Pele plume via absorption of jovian light in 1996 and 1999; detection of the Prometheus-type Pillan plume in reflected sunlight in 1997; and detection of the 2007 Pele-type Tvashtar plume eruption in reflected sunlight and via absorption of jovian light. Based on a detailed analysis of these observations we characterize and compare the gas and dust properties of each of the detected plumes. In each case, the brightness of the plumes in reflected sunlight is less at 0.26μm than at 0.33μm. Mie scattering analysis of the wavelength dependence of each plume’s reflectance signature suggests that range of particle sizes within the plumes is quite narrow. Assuming a normal distribution of particle sizes, the range of mean particle sizes is ∼0.035–0.12μm for the 1997 Pillan eruption, ∼0.05–0.08μm for the 1999 Pele and 2007 Tvasthar plumes, and ∼0.05–0.11μm for the 1995 Pele plume, and in each case the standard deviation in the particle size distribution is <15%. The Mie analysis also suggests that the 2007 Tvashtar eruption released ∼109g of sulfur dust, the 1999 Pele eruption released ∼109g of SO2 dust, the 1997 Pillan eruption released ∼1010g of SO2 dust, and the 1995 Pele plume may have released ∼1010g of SO2 dust. Analysis of the plume absorption signatures recorded in the F255W filter bandpass (0.24–0.28μm) indicates that the opacity of the 2007 Tvashtar plume was 2× that of the 1996 and 1999 Pele plume eruptions. While the sulfur dust density estimated for the Tvashtar from the reflected sunlight data could have produced 61% of the observed plume opacity, <10% of the 1999 Pele F255W plume opacity could have resulted from the SO2 dust detected in the eruption. Accounting for the remaining F255W opacity level of the Pele and Tvasthar plumes based on SO2 and S2 gas absorption, the SO2 and S2 gas density inferred for each plume is almost equivalent corresponding to ∼2–6×1016cm−2 and 3–5×1015cm−2, respectively, producing SO2 and S2 gas resurfacing rates ∼0.04–0.2cmyr−1 and 0.007–0.01cmyr−1; and SO2 and S2 gas masses ∼1–4×1010g and ∼2–3×109g; for a total dust to gas ratio in the plumes ∼10−1–10−2. The 2007 Tvashtar plume was detected by HST at ∼380±40km in both reflected sunlight and absorbed jovian light; in 1999, the detected Pele plume altitude was 500km in absorbed jovian light, but in reflected sunlight the detected height was ∼2× lower. Thus, for the 1999 Pele plume, similar to the 1979 Voyager Pele plume observations, the most efficient dust reflections occurred in the region closest to the plume vent. The 0.33–0.42μm brightness of the 1997 Pillan plume was 10–20× greater than the Pele or Tvashtar plumes, exceeding by a factor of 3 the average brightness levels observed within 200km of 1979 Loki eruption vent. But, the 0.26μm brightness of the 1997 Pillan plume in reflected sunlight was significantly lower than would be predicted by the dust scattering model. Presuming that the 0.26μm brightness of the 1997 Pillan plume was attenuated by the eruption plume’s gas component, then an SO2 gas density ∼3–6×1018cm−2 is inferred from the data (for S2/SO2 ratios ⩽4%), comparable to the 0.3–2×1018cm−2 SO2 density detected at Loki in 1979 (Pearl, J.C. et al. [1979]. Nature 280, 755; Lellouch et al., 1992), and producing an SO2 gas mass ∼3–8×1011g and an SO2 resurfacing rate ∼8–23cmyr−1. These results confirm the connection between high (⩾1017cm−2) SO2 gas content and plumes that scatter strongly at nearly blue wavelengths, and it validates the occurrence of high density SO2 gas eruptions on Io. Noting that the SO2 gas content inferred from a spectrum of the 2003 Pillan plume was significantly lower ∼2×1016cm−2 (Jessup, K.L., Spencer, J., Yelle, R. [2007]. Icarus 192, 24–40); and that the Pillan caldera was flooded with fresh SO2 frost/slush just prior to the 1997 Pillan plume eruption (Geissler, P., McEwen, A., Phillips, C., Keszthelyi, L., Spencer, J. [2004a]. Icarus 169, 29–64; Phillips, C.B. [2000]. Voyager and Galileo SSI Views of Volcanic Resurfacing on Io and the Search for Geologic Activity at Europa. Ph.D. Thesis, Univ. of Ariz., Tucson); we propose that the density of SO2 gas released by this volcano is directly linked to the local SO2 frost abundance at the time of eruption.
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