Platinum Group Research Articles

Dual-Intermetallic Heterostructure on Hierarchical Nanoporous Metal for Highly Efficient Alkaline Hydrogen Electrocatalysis.

Constructing well-defined active multisites is an effective strategy to break linear scaling relationships to develop high-efficiency catalysts toward multiple-intermediate reactions. Here, dual-intermetallic heterostructure composed of tungsten-bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high-performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column-nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel-supported Co3W-WNi4 heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm-2) and hydrogen evolution reaction (current density of ≈1.45 A cm-2 at overpotential of 200 mV). Such atom-ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide-exchange-membrane water electrolyzers and fuel cells.

Optimizing TCAD Model and Temperature-Dependent Analysis of Pt/AlN Schottky Barrier Diodes for High-Power and High-Temperature Applications

This research presents a comprehensive investigation and optimization of the Pt/AlN Schottky Barrier diode (SBD) using technology computer-aided design (TCAD) modeling. The study explores the electrical characteristics of AlN SBDs with various metal contacts, including Aluminum (Al), Silver (Ag), Tungsten (W), Gold (Au), Nickel (Ni), and Platinum (Pt). Through the comparative analyses of different metal/AlN Schottky contacts, the Pt/AlN structure emerges as the most promising due to its superior barrier height and lower leakage current. At [Formula: see text]K, the diode demonstrates a barrier height of 2.72[Formula: see text]V, a nearly ideal leakage current of 0.046[Formula: see text]pA, and a breakdown voltage of 363[Formula: see text]V. The research extends to examining the temperature-dependent electrical behavior of Pt/AlN Schottky diodes, particularly for high-power and high-temperature applications. Analysis carried out across temperatures ranging from [Formula: see text]K to [Formula: see text]K reveals a trend of increasing ON resistance and consistently lower leakage current with rising temperature. Importantly, the study indicates that the impact of temperature on the barrier height and breakdown voltage of the diode is negligible, thus rendering it suitable for high-temperature operation. Leveraging the unique properties of AlN as an ultra-wide bandgap material within the III-V compound semiconductor family, this research provides valuable insights into the potential applications of Pt/AlN Schottky contact. The study highlights that the Pt/AlN Schottky contact is effective not only for high-power, high-temperature SBDs but also as superior metal/semiconductor gate contacts for field-effect transistors (FETs). Their suitability is attributed to their ability to handle high voltages, minimize reverse leakage current, and demonstrate improved thermal stability.

Ultrahigh Pt-mass-activity catalyst for alkaline hydrogen evolution synthesized by microwave method in air

Platinum (Pt) metal is widely acknowledged as a highly efficient electrocatalyst for hydrogen evolution reaction (HER) in acidic electrolyte. However, its performance in alkaline environments is significantly lower owing to the sluggish water dissociation step. Herein, we synthesized an ultrahigh Pt-mass-activity alkaline HER catalyst using microwave reduction method in air. Our catalyst, PtRu@CNT, comprises PtRu alloy nanoparticles uniformly loaded on carbon nanotubes, with Pt and Ru contents of 12.3 wt% and 4.5 wt%, respectively. The PtRu alloy nanoparticles have an average diameter of about 3 nm and a face-centered cubic structure, and the introduction of Ru has led to a modified electronic structure in Pt. As a result, an impressively low HER overpotential of 13 mV was achieved, significantly lower than commercial 20 wt% Pt/C (61 mV). PtRu@CNT exhibited a high turnover frequency based on metal mass of 3.06 s−1 at 100 mV, about 6 times higher than commercial Pt/C (0.46 s−1 at 100 mV), highlighting its excellent intrinsic activity. The HER mechanism of PtRu@CNT is a Volmer-Tafel mechanism, where the rate-limiting step changed to the recombination of hydrogen atoms from initial water dissociation, attributed to the presence of Ru. The alkaline HER activity of PtRu@CNT ranks among the best of currently reported Pt-based catalysts.

Photophysical properties of benzo[i]dipyrido[3,2-a:2′,3′-c] phenazine (dppn) – A prospective ligand for light-activated anticancer complexes

Benzo[i]dipyrido[3,2-a:2′,3′c]phenazine (dppn) is a prospective ligand for constructing light-activated anticancer complexes of platinum metals. In spite of practical importance, only scarce information on the dppn photophysics and photochemistry was found in the literature. In this work photophysical properties of dppn in acetonitrile solutions were studied by means of stationary and laser flash photolysis, time-resolved luminescence, time-resolved singlet oxygen detection and ultrafast TA spectroscopy. Quantitative characteristics of luminescence (quantum yield 0.26, lifetime 52 ns in deaerated solutions) were measured. Triplet state of the initial compound 3dppn* is formed with the quantum yield estimated as 0.4 from the singlet oxygen production; the main channels of 3dppn* are quenching by dissolved oxygen and self-quenching by the ground state of dppn. Combining the data of ultrafast TA absorption and time-resolved luminescence, we detected the formation of “dark” (not emissive) excited state of dppn with the decay time ca. 150 ps. Two hypotheses on the nature of the dark state were put forward.

A σ-Poor, π-Rich Pyridonate Pincer Ligand Designed To Enhance C–H Oxidative Addition at Platinum Group Metals: Experimental and Computational Studies

A σ-Poor, π-Rich Pyridonate Pincer Ligand Designed To Enhance C–H Oxidative Addition at Platinum Group Metals: Experimental and Computational Studies

Improvement in ORR Durability of Fe Single-Atom Carbon Catalysts Hybridized with CeO2 Nanozyme.

FeNC catalysts are considered one of the most promising alternatives to platinum group metals for the oxygen reduction reaction (ORR). Despite the extensive research on improving ORR activity, the undesirable durability of FeNC is still a critical issue for its practical application. Herein, inspired by the antioxidant mechanism of natural enzymes, CeO2 nanozymes featuring catalase-like and superoxide dismutase-like activities were coupled with FeNC to mitigate the attack of reactive oxygen species (ROS) for improving durability. Benefiting from the multienzyme-like activities of CeO2, ROS generated from FeNC is instantaneously eliminated to alleviate the corrosion of carbon and demetallization of metal sites. Consequently, FeNC/CeO2 exhibits better ORR durability with a decay of only 5 mV compared to FeNC (18 mV) in neutral electrolyte after 10k cycles. The FeNC/CeO2-based zinc-air battery also shows minimal voltage decay over 140 h in galvanostatic discharge-charge cycling tests, outperforming FeNC and commercial Pt/C.

Beyond the First Coordination Sphere─Manipulating the Excited-State Landscape in Iron(II) Chromophores with Protons.

Molecular transition metal chromophores play a central role in light harvesting and energy conversion. Recently, earth-abundant transition-metal-based chromophores have begun to challenge the dominance of platinum group metal complexes in this area. However, the development of new chromophores with optimized photophysical properties is still limited by a lack of synthetic methods, especially with respect to heteroleptic complexes with functional ligands. Here, we demonstrate a facile and efficient method for the combination of strong-field carbenes with the functional 2,2'-bibenzimidazole ligand in a heteroleptic iron(II) chromophore complex. Our approach yields two isomers that differ predominantly in their excited-state lifetimes based on the symmetry of the ligand field. Deprotonation of both isomers leads to a significant red-shift of the metal-to-ligand charge transfer (MLCT) absorption and a shortening of excited-state lifetimes. Femtosecond transient absorption spectroscopy in combination with quantum chemical simulations and resonance Raman spectroscopy reveals the complex relationship between protonation and photophysical properties. Protonation is found to tip the balance between MLCT and metal-centered (MC) excited states in favor of the former. This study showcases the first example of fine-tuning of the excited-state landscape in an iron(II) chromophore through second-sphere manipulations and provides a new perspective to the challenge of excited-state optimizations in 3d transition metal chromophores.

Re−Os Isotope and PGE Abundance Systematics of Coast Range Ophiolite Peridotites and Chromitite, California: Insights into Fore-Arc Magmatic Processes

Abstract We report platinum-group element (PGE) and Re concentrations, and Re−Os isotopic data for peridotites and podiform chromitite from the mid-Jurassic Coast Range ophiolite (CRO), California. Our aim is to provide insights into the formation and evolution of the CRO in a fore-arc tectonic setting. The CRO peridotites are divided into two groups: abyssal and supra-subduction zone (SSZ). They have Ir-group PGE concentrations similar to estimates for the primitive mantle and nearly chondritic relative abundances [(Os/Ir)N ≈ 1.1]. Abyssal-type peridotites have slightly subchondritic Pd-group PGE (PPGE)−Re abundances and flat chondrite-normalized patterns, whereas the SSZ-type ones are depleted overall with highly fractionated PPGE−Re patterns. The CRO peridotites have 187Os/188Os values of 0.1188 to 0.1315 (γOs = −8.3 to 1.4) and 187Re/188Os ranging from 0.022 to 0.413. The oxygen fugacity based on the V/Yb ratios of the CRO peridotites is equivalent to the fayalite−magnetite−quartz buffer. The abyssal-type peridotites are residues after ≤5% melting of the primitive upper mantle and represent a remnant of oceanic lithosphere trapped in an SSZ setting but before it was re-melted or modified by subduction processes. The abyssal-type peridotites yield an aluminachron model age of ~1.5 Ga, implying that the CRO mantle had experienced episode(s) of melt extraction before the CRO crust was formed. The SSZ-type peridotites are refractory residues after ~5% to 15% melting. Extraction of fore-arc basalts generated mainly by decompression melting resulted in the SSZ-type peridotites. The chromitite has 187Os/188Os value of 0.1250 (γOs = −3.5) and PGE−Re patterns complementary to that of boninite, indicating a genetic link to fore-arc magmatism.

The Surface/Interface Modulation of Platinum Group Metal (PGM)-Free Catalysts for VOCs and CO Catalytic Oxidation.

Effective management of volatile organic compounds (VOCs) and carbon monoxide (CO) is critical to human health and the ecological environment. Catalytic oxidation is one of the most promising technologies for achieving efficient VOCs and CO emission control. Platinum group metal (PGM)-free catalysts are recently receiving sustainable attention in catalyzing VOCs and CO removal due to their low cost, superior catalytic activity, and excellent stability, but PGM-free catalysts face challenges in low-temperature catalytic efficiency. In this mini-review, starting with discussing the catalytic mechanism of VOCs and CO oxidation, we summarize the surface/interface modulation strategies of PGM-free catalysts to promote oxygen and VOCs/CO molecule activation for enhanced low-temperature oxidation activity, including oxygen vacancy engineering, heteroatom doping, surface acidity modification, and active interface construction. We highlight the currently remaining challenges and prospects of advanced PGM-free catalyst development for highly efficient VOCs and CO emission control in practical applications.

Corundum ± magnesium‐deltalumite ± hibonite‐bearing objects in the CH chondrite Sayh al Uhaymir 290

AbstractIsolated corundum grains and corundum ± Mg‐deltalumite [(Al,Mg)(Al,◻)2O4] ± hibonite assemblages were investigated in the CH3.0 metal‐rich carbonaceous chondrite Sayh al Uhaymir (SaU) 290. Although very refractory inclusions containing abundant Zr‐ and Sc‐rich oxides and silicates, hibonite, grossite, or perovskite have been previously described in CH chondrites, this is the first discovery of corundum and Mg‐deltalumite in CHs and the first discovery of Mg‐deltalumite in nature. Magnesium‐deltalumite can be indexed by the Fd3m spinel‐type structure and gives a perfect fit to the synthetic Al‐rich spinel cells. Corundum‐Mg‐deltalumite grains, 5–20 μm in size, are occasionally rimmed by a thin layer of hibonite replacing corundum. Some corundum grains contain tiny inclusions of ultrarefractory Zr,Sc‐rich minerals and platinum‐group element (PGE) nuggets. All corundum, hibonite, and Mg‐deltalumite grains studied have 16O‐rich compositions (average Δ17O ± 2SD = −22 ± 3‰). Two corundum grains show evidence for significant mass‐dependent fractionation of oxygen isotopes: Δ18O ~ +34‰ and ~ +19‰. We suggest that the SaU 290 corundum‐rich objects were formed by evaporation and/or condensation in a hot nebular region close to the proto‐sun where the ambient temperature was close to the condensation temperature of corundum. A corundum grain with tiny inclusions of Zr‐ and Sc‐rich phases and PGE metal nuggets recorded formation temperatures higher than the condensation temperature of corundum. Two corundum‐rich objects with highly fractionated oxygen isotopes must have crystallized from a melt that experienced evaporation. Corundum grains corroded by hibonite recorded gas–solid interaction in this region during its cooling. The Mg‐deltalumite ± corundum ± hibonite objects were formed by rapid crystallization of high‐temperature (>2000°C) refractory melts. The lack of minerals with condensation temperatures below those of corundum and hibonite in the SaU 290 corundum‐rich objects suggests that after formation, these objects were rapidly removed from the hot nebular region by disk wind and/or by turbulent diffusion and disk spreading.

Corundum ± magnesium‐deltalumite ± hibonite‐bearing objects in the CH chondrite Sayh al Uhaymir 290

AbstractIsolated corundum grains and corundum ± Mg‐deltalumite [(Al,Mg)(Al,◻)2O4] ± hibonite assemblages were investigated in the CH3.0 metal‐rich carbonaceous chondrite Sayh al Uhaymir (SaU) 290. Although very refractory inclusions containing abundant Zr‐ and Sc‐rich oxides and silicates, hibonite, grossite, or perovskite have been previously described in CH chondrites, this is the first discovery of corundum and Mg‐deltalumite in CHs and the first discovery of Mg‐deltalumite in nature. Magnesium‐deltalumite can be indexed by the Fd3m spinel‐type structure and gives a perfect fit to the synthetic Al‐rich spinel cells. Corundum‐Mg‐deltalumite grains, 5–20 μm in size, are occasionally rimmed by a thin layer of hibonite replacing corundum. Some corundum grains contain tiny inclusions of ultrarefractory Zr,Sc‐rich minerals and platinum‐group element (PGE) nuggets. All corundum, hibonite, and Mg‐deltalumite grains studied have 16O‐rich compositions (average Δ17O ± 2SD = −22 ± 3‰). Two corundum grains show evidence for significant mass‐dependent fractionation of oxygen isotopes: Δ18O ~ +34‰ and ~ +19‰. We suggest that the SaU 290 corundum‐rich objects were formed by evaporation and/or condensation in a hot nebular region close to the proto‐sun where the ambient temperature was close to the condensation temperature of corundum. A corundum grain with tiny inclusions of Zr‐ and Sc‐rich phases and PGE metal nuggets recorded formation temperatures higher than the condensation temperature of corundum. Two corundum‐rich objects with highly fractionated oxygen isotopes must have crystallized from a melt that experienced evaporation. Corundum grains corroded by hibonite recorded gas–solid interaction in this region during its cooling. The Mg‐deltalumite ± corundum ± hibonite objects were formed by rapid crystallization of high‐temperature (>2000°C) refractory melts. The lack of minerals with condensation temperatures below those of corundum and hibonite in the SaU 290 corundum‐rich objects suggests that after formation, these objects were rapidly removed from the hot nebular region by disk wind and/or by turbulent diffusion and disk spreading.

ZIF-8-derived nanocarbon composite-based highly active platinum group metal-free bimetallic electrocatalysts for oxygen reduction reaction in proton exchange membrane fuel cells

Non-precious metal catalysts are ideal low-cost substitutes of Pt/C for the sluggish oxygen reduction reaction (ORR), despite the serious stability challenges in proton exchange membrane fuel cells (PEMFC) to alleviate the energy crisis and environmental problems. Platinum group metal (PGM)-free bimetallic composite electrocatalysts are assumed to be an interesting route to be investigated to address the stability and ORR selectivity related issues in PEMFC conditions. In this regard, we propose a simple and facile synthesis route by a composite of multi-walled carbon nanotubes and zeolitic imidazolate framework (ZIF)-8 followed by impregnating dual transition metals (FeMn, FeCo, and CoMn) and evaluate their ORR activity in acid media and PEMFC performance. Various catalyst materials are prepared and optimized to achieve the highest electrocatalytic performance. The prepared catalysts are characterized by various physico-chemical methods to elucidate their textural, structural, and morphological properties. The high ORR electrocatalytic activity and selectivity of the catalyst are reported in terms of half-wave potential and low H2O2 yield as determined by the rotating ring-disk electrode method. The significant electrochemical stability under accelerated durability test and high peak power density (787 mW cm−2) in H2-O2 PEMFC made these catalysts as potential candidates for efficient alternatives to PGMs in the fuel cell cathodes.

Operando Electrodeposition of Nonprecious Metal Copper Nanocatalysts on Low-Dimensional Support Materials for Nitrate Reduction Reactions.

Supported nonprecious metal catalysts such as copper (Cu) are promising replacements for Pt-based catalysts for a wide range of energy-related electrochemical reactions. Direct electrochemical deposition is one of the most straightforward and versatile methods to synthesize supported nonprecious metal catalysts. However, further advancement in the design of supported nonprecious metal catalysts requires a detailed mechanistic understanding of the interplay between kinetics and thermodynamics of the deposition phenomena under realistic reaction conditions. Here, we study the electrodeposition of Cu on carbon nanotubes and graphene derivatives under electrochemical conditions using in situ liquid cell transmission electron microscopy (TEM). By combining real-time imaging, electrochemical measurements, X-ray photoelectron spectroscopy (XPS), and finite-element analysis (FEA), we show that low-dimensional support materials, especially carbon nanotubes, are excellent for generating uniform and finely dispersed platinum group metal-(PGM)-free catalysts under mild electrochemical conditions. The electrodeposited Cu on graphene and carbon nanotubes is also observed to show good electrochemical activity toward nitrate reduction reactions (NO3RRs), further supported by density functional theory (DFT) calculations. Nitrogen doping plays an important role in guiding nonprecious metal deposition, but its low electrical conductivity may give rise to lower NO3RR activity compared to its nondoped analogue. The development of supported nonprecious metals through interfacial and surface engineering for the design of supported catalysts will substantially reduce the demand for precious metals and generate robust catalysts with better durability, thereby presenting opportunities for solving the critical problems in energy storage and electrocatalysis.

Diversification of Pharmaceutical Manufacturing Processes: Taking the Plunge into the Non-PGM Catalyst Pool.

Recent global events have led to the cost of platinum group metals (PGMs) reaching unprecedented heights. Many chemical companies are therefore starting to seriously consider and evaluate if and where they can substitute PGMs for non-PGMs in their catalytic processes. This review covers recent highly relevant applications of non-PGM catalysts in the modern pharmaceutical industry. By highlighting these selected successful examples of non-PGM-catalyzed processes from the literature, we hope to emphasize the enormous potential of non-PGM catalysis and inspire further development within this field to enable this technology to progress toward manufacturing processes. We also present some historical contexts and review the perceived advantages and challenges of implementing non-PGM catalysts in the pharmaceutical manufacturing environment.

Experimental investigation on accelerated generation of HHO gas using titanium electrodes with platinum and mixed metal oxide coating - A comparative study

HHO gas is an alternate source of fuel that can be used in automobiles as a clean fuel with reduced carbon emissions, replacing the conventional hydrocarbon fuels being used today. Many different methods are involved in the production of this gas. Among these methods, alkaline water electrolysis is one of the easiest and most reliable methods for production. Though there are many limitations in the storage of Hydrogen, the HHO gas has been produced on-site using alkaline water electrolysis. This article mainly focuses on the production of HHO gas for different operating parameters and conditions, such as change of electrolyte, electrode material coating, effect of temperature and the surface area of the electrode. The electrolytes used in the electrolyser are sodium hydroxide (NaOH) and potassium hydroxide (KOH). The electrode material is titanium coated with two different materials namely Mixed Metal Oxide (MMO) and Platinum (Pt) respectively. A maximum yield of 0.9 LPM of HHO gas has been generated when supplying 40 amps of current to the electrolyser unit coated with MMO and KOH as electrolyte. Use of KOH electrolyte results in higher production rate when compared to NaOH. MMO coated titanium electrode produces more HHO gas when compared to platinum coated electrode.

Spatially and temporally differentiated characterization factors for supply risk of abiotic resources in life cycle assessment

Life cycle assessment, a comprehensive tool to evaluate environmental impacts across a product's life cycle, traditionally focuses on "inside-out" impacts caused by the product on the environment, emphasizing resource use, global warming, and other environmental impacts. In contrast, the "outside-in" perspective considers resource availability and accessibility to industry. This second perspective was developed as a way to integrate raw material criticality assessment into LCA. The GeoPolRisk method assesses the supply risk based on global production concentration, import shares, political stability scores, and the average price of the commodity. This article introduces a characterization model for the GeoPolRisk method and calculates the Geopolitical Supply Risk Potential of using 46 raw materials across different countries in multiple years. The characterization factors show the highest values for precious metals, like platinum group metals (PGMs), reflecting their high market prices and concentrated production in geopolitically unstable regions. The results emphasize the significance of spatial and temporal variations in characterization factors, providing a nuanced assessment of supply risk of raw materials associated with the product system. Despite data limitations, the characterization factors offer a good estimate of the supply risk of raw materials available for use in product systems. A case study on photovoltaic laminate production highlights gallium, copper, and tin as significant contributors to supply risk. From an "outside-in" perspective, the case study demonstrates how the GeoPolRisk method complements traditional environmental indicators such as global warming, making it a valuable tool for assessing mineral resource supply risk in Life Cycle Assessment.

Geochemical evidence for a chondritic impactor in altered impact glass from the Stac Fada Member impactite, NW Scotland

The Stac Fada Member (Stoer Group) is a ∼1.2 Ga melt-rich impact breccia whose source crater and, therefore, proximity remains debated. We present a detailed in situ geochemical dataset for altered impact melt clasts within Stac Fada samples from Bay of Stoer and Second Coast. These altered impact melt clasts are now predominantly composed of clinochlore. Geothermometry of this clinochlore indicates formation temperatures within the ejecta blanket at 188-231°C, in agreement with previous estimates. A positive correlation between platinum group elements Ir, Pt, and Rh — apparently independent of Ni — indicates two geochemical sources for platinum group elements enrichment. We propose that these represent an Mg-Ni rich chondritic impactor and a mafic/ultramafic layered body within the target lithology. Spatial variation in Ni content suggests that geochemical data, in combination with field observations, may be instrumental in assessing the likely location of the impact crater.

Water quality dynamics and underlying controls in the Halton Region, Ontario.

We assessed the hydrochemistry of 15 watersheds in the Halton Region, southern Ontario, in high resolution (n > 500 samples across n > 40 streams) to characterize water quality dynamics and governing controls on major and trace element concentrations in this rapidly urbanizing region. In 2022, major water quality parameters were generally in line with historic monitoring data yet significantly different across catchments, e.g., in specific conductance, turbidity, phosphate and chloride, and trace element concentrations. Distinct hydrochemical signatures were observed between urban and rural creeks, with urban stream sections and sites near the river mouths close to Lake Ontario having consistently higher chloride (up to 700mg/L) and occasional enrichment in nutrients levels (up to 8 and 20mg/L phosphate and nitrate, respectively). Particularly upper reaches exhibited hydrochemical signatures that were reflective of the catchment surface lithologies, for instance through higher dissolved Ca to Mg ratios. Unlike for chloride and phosphate, provincial water quality guidelines for trace elements and heavy metals were seldom surpassed (on < 10 occasions for copper, zinc, cadmium, and uranium). Concentrations of other trace elements (e.g., platinum group elements or rare earth elements) were expectedly low (< 0.3µg/L) but showed spatiotemporal concentration patterns and concentration-discharge dynamics different from those of the major water quality parameters. Our results help improve the understanding of surface water conditions within Halton's regional Natural Heritage Systems and demonstrate how enhanced environmental monitoring can deliver actionable information for watershed decision-making.

Sales planning for platinum group metals: Segmentation and optimization

Subject. The article considers sales of platinum group metals on the case of a Russian mining and metallurgical company in the context of tariff barriers in some key markets and increased competition. Objectives. The purpose is to develop a set of methods to ensure the full sale of platinum group metals produced by the company and maximize profits from their sale under the introduction of import duties discriminating against metals of Russian origin and increased competition among suppliers for consumers due to redistribution of commodity flows. Methods. The study employs methods of logical, statistical analysis, and optimization. Results. The paper formulates a methodology for the sale of Russian platinum group metals in the duty-free markets of Europe, China, Japan and the rest of the world, presents a monthly optimization model enabling to calculate the discount rate for the sale of platinum, palladium and rhodium in full. For the Russian mining and metallurgical company, I developed individual recommendations on cooperation tactics and pricing policy for each group of consumers. Conclusions. The demand for platinum and palladium is price elastic. Depending on the degree of market changes, the sales methodology and its tools should provide necessary flexibility, including price, based on the optimality of solving operational and tactical tasks.

Изменение активности оксидоредуктаз чернозема обыкновенного при загрязнении платиной

The automotive industry is the main source of environmental pollution with platinum group metals, which increases the concentration of platinum in road dust, soil, and plants. This can lead to the achievement of toxic levels of this metal in the environment, and consequently, an imbalance of the ecosystem, a reduction in the microbial population, and a decrease in soil fertility. The effects of platinum on the activity of oxidoreductases of ordinary chernozem have been studied: the activity of catalase and dehydrogenase. Platinum was introduced into the soil in the form of chloride. Platinum concentrations were studied – 0.01; 0.1; 1; 10 and 100 mg/kg. The change in the indicators of ordinary chernozem was assessed 10, 30 and 90 days after contamination. The absence of a stimulating effect of platinum chloride on catalase activity, the effect of hormesis on the activity of dehydrogenases of ordinary chernozem has been established. The dependence of the degree of decrease in indicators on the concentration of the pollutant in the soil and the time from the moment of contamination is shown. The study shows the negative effect of even a small concentration (0.1 mg/kg) of platinum chloride on the enzymatic activity of the soil. Early diagnosis of the degree of soil contamination with platinum compounds can be successfully used to promptly assess their impact on soil condition and prevent possible negative consequences.