Plastic Properties Research Articles

Damage Characteristics and Mechanical Properties of DD6 Single‐Crystal Alloy Based on Crystal Plasticity Theory under Uniaxial Tensile Conditions

Herein, the mechanical behavior and damage characteristics of DD6 nickel‐based single crystal alloy under different crystal orientation conditions are studied based on the theory of crystal plasticity coupled with damage constitutive equations using the crystal plasticity finite‐element method. The results indicate that the crystal plastic finite‐element model coupled with damage constitutive equations can well describe the entire deformation process from elasticity to damage. Under the reference orientation condition, the damage starts from the center position inside the test specimen and extends to the surrounding areas. The stress value in the damaged area decreases gradually from the periphery to the center of the test specimen, and an external stress reduction zone is formed. The crystal exhibits the best elasticity properties in the [0, 1, 1] orientation and the best plasticity properties in the [0, tan22.5°, 1] orientation. As the rotation angle of crystal orientation increases, the damage zones of X‐Z, Z‐Y, and X‐Y sections all exhibit clockwise rotation characteristics.

PHYSICAL-MECHANICAL PROPERTIES OF DYNAMICALLY VULCANIZED BASALT CONTAINING PLASTICS BASED ON COMPATIBILIZED POLYPROPYLENE

The influence of the content of basalt and Exxelor PО1020 compatibilizer on the main physical-mechanical and thermophysical characteristics of composites based on polypropylene is considered. It has been established that the use of a compatibilizer in an amount of 1.0–3.0 wt. % can significantly improve such properties of basalt plastics as tensile strength, yield strength, elongation at break, flexural strength, Vicat softening temperature, and melt flow rate. The possibility of cross-linking basalt plastics with sulfur and dicumyl peroxide is considered, and their role in changing their basic physical-mechanical parameters is determined. A theoretical analysis is given of the formation of an interfacial region with the participation of a compatibilizer and basalt. A micrograph showing the redistribution of basalt in the composition of compatibilized polypropylene is given by electron microscopy. The optimal concentrations of vulcanizing agents are determined, at which the highest strength properties are achieved, provided that elongation at break and the melt flow rate are maintained at a satisfactory level. It has been established that the optimal content of dicumyl peroxide is 0.25–0.5% wt

Research on Mechanical Properties of High‐Manganese Steel Coating Manufactured by Coaxial Powder‐Feeding Laser Cladding

Due to the process complexity of the high‐carbon high‐manganese steel (HMnS) in casting and arc welding, this article propose the coaxial powder‐feeding laser cladding (LC) of HMnS coating using self‐developed HMnS powders. Firstly, high‐carbon HMnS coatings are prepared on the 16Mn substrate using coaxial powder‐feeding LC technology. It has a single austenite phase, without large defects such as pores and cracks. Then, ultrasonic shock peening is used to harden the HMnS coating, and the mechanical properties such as microhardness, impact toughness, wear and tensile properties are measured, which prove that HMnS coating has excellent working hardening, plasticity, toughness, and wear resistance properties. Finally, transmission electron microscopy is used to investigate the coupling effects such as dislocations, multiple twinning, and stacking faults on the HMnS coating after tensile fracture (true strain 39.2%). The deformation strengthening mechanism based on the dynamic Hall–Petch effect is revealed. The research results provide a new method for the preparation of high‐carbon HMnS coatings, and a new idea for expanding the application of high‐carbon HMnS.

Obtaining Symmetrical Gradient Structure in Copper Wire by Combined Processing

Traditionally, structural wire is characterized by a homogeneous microstructure, where the average grain size in different parts of the wire is uniform. According to the classical Hall–Petch relationship, a homogeneous polycrystalline metal can be strengthened by decreasing the average grain size since an increase in the volume fraction of grain boundaries will further impede the motion of dislocations. However, a decrease in the grain size inevitably leads to a decrease in the ductility and deformability of the material due to limited dislocation mobility. Putting a gradient microstructure into the wire has promising potential for overcoming the compromise between strength and ductility. This is proposed a new combined technology in this paper in order to obtain a gradient microstructure. This technology consists of deforming the wire in a rotating equal-channel step die and subsequent traditional drawing. Deformation of copper wire with a diameter of 6.5 mm to a diameter of 5.0 mm was carried out in three passes at room temperature. As a result of such processing, a gradient microstructure with a surface nanostructured layer (grain size ~400 nm) with a gradual increase in grain size towards the center of the wire was obtained. As a result, the microhardness in the surface zone was 1150 MPa, 770 Mpa in the neutral zone, and 685 MPa in the central zone of the wire. Such a symmetrical spread of microhardness, observed over the entire cross-section of the rod, is a direct confirmation of the presence of a gradient microstructure in deformed materials. The strength characteristics of the wire were doubled: the tensile strength increased from 335 MPa to 675 MPa, and the yield strength from 230 MPa to 445 MPa. At the same time, the relative elongation decreased from 20% to 16%, and the relative contraction from 28% to 23%. Despite the fact that the ductility of copper is decreased after cyclic deformation, its values remain at a fairly high level. The validity of all results is confirmed by numerous experiments using a complex of traditional and modern research methods, which include optical, scanning, and transmission microscopy; determination of mechanical properties under tension; and measurement of hardness and electrical resistance. These methods allow reliable interpretation of the fine microstructure of the wire and provide information on its strength, plastic, and electrical properties.

Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex

AbstractAn original way of elaborating vertical metal/molecules/metal memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The molecule of interest is a FeII coordination complex with ter‐pyridine ligands, having a diazonium anchoring group. The resulting junction exhibits a memristive behavior characterized by a high ON/OFF ratio and plasticity property. Through the application of advanced techniques such as UV–vis and Raman time‐resolved spectroelectrochemistry, the study demonstrates the significant role of switchable azo bonds derived from diazo electrografting in memristive behavior.

Improving the roller screen efficiency to classify green iron pellets using DEM simulation, novel roll design and implementing banana configuration

Roller screens play a decisive character in the efficiency of pelletizing circuits and induration furnaces. Unlike vibrating screens, there have been no studies on roller screens to determine their capacity and dimensions. Most studies have utilized the discrete element method (DEM) simulation to assess roller screen performance by employing a spherical shape and the Hertz-Mindlin elastic model. However, this approach is unsuitable due to green pellets’ non-spherical shape and elastic–plastic properties. This study introduces the incorporation of the actual shape of green pellets and a hysteretic spring elastoplastic contact model. In this research work, a novel design of rolls with a grooved surface was recommended for the first time, resulting in a Total Screening Efficiency (TSE) of 96.4% compared to 87.1% for rolls with a smooth surface. Additionally, while exploring the impact of the decks number on the roller screen, a new design, known as the banana roller screen, was introduced. Under similar conditions, the TSE increased by 1.22% compared to the general roller screen type. It was also found that the roller screen’s capacity is directly related to the diameter, speed of rotation, and the number of rolls, while it has a reverse relationship with TSE and deck angle.

Argon Ion Implantation as a Method of Modifying the Surface Properties of Wood-Plastic Composites.

Wood-plastic composites (WPCs) combine the properties of plastics and lignocellulosic fillers. A particular limitation in their use is usually a hydrophobic, poorly wettable surface. The surface properties of materials can be modified using ion implantation. The research involved using composites based on polyethylene (PE) filled with sawdust or bark (40%, 50%, and 60%). Their surfaces were modified by argon ion implantation in three fluencies (1 × 1015, 1 × 1016, and 1 × 1017 cm-2) at an accelerating voltage of 60 kV. Changes in the wettability, surface energy, and surface colour of the WPCs were analysed. It was shown that argon ion implantation affects the distinct colour change in the WPC surface. The nature of the colour changes depends on the filler used. Implantation also affects the colour balance between the individual variants. Implantation of the WPC surface with argon ions resulted in a decrease in the wetting angle. In most of the variants tested, the most significant effect on the wetting angle changes was the ion fluence of 1 × 1017 cm-2. Implantation of the WPC surface also increased the surface free energy of the composites. The highest surface free energy values were also recorded for the argon ion fluence of 1 × 1017 cm-2.

Accounting of Deformation Heating During Upsetting of AMg6 Alloy

The AMg6 alloy, which belongs to the Al–Mg–Mn system, has high corrosion resistance in various environments, good weldability, and good mechanical properties. During analytical and experimental studies, it was established that the AMg6 alloy, when deformed in the temperature range of 130–175 °C, has high plastic properties and can withstand large degrees of deformation without destruction and crack formation. At the same time, its microstructure retains the texture of deformation, and the hardness of the alloy increases, which indicates its deformation hardening. The article presents the results of numerical and laboratory experiments on upsetting of 20 mm diameter workpieces from a heating temperature of 20, 130, 260 and 390 °C. Using numerical experiments, the dependences of deformation heating on the upsetting rate and the initial temperature of the workpiece were obtained. Deformation heating should be taken into account when choosing heating before deformation since it can be critical in terms of overburning and loss of plastic properties and corrosion resistance of finished products. The deformation behavior of the AMg6 alloy at a heating temperature of the workpiece up to 130–175 °C, revealed in this study, indicates the prospects for conducting additional research on the study of changes in the microstructure and mechanical properties of this alloy during warm deformation.

Radiation and thermal embrittlement of RPV steels: the links of embrittlement mechanisms, fracture modes and microcrack nucleation and propagation. Part 2. Strength and plasticity properties

The uniaxial tension test results are represented over wide temperature range for smooth round bars of 2Cr–Ni–Mo–V steel and A533 steel used for RPVs of WWER and PWR types. These steels are studied in the following states: (1) the initial (as-produced) state; (2) the thermally embrittled state modelling hardening mechanism of embrittlement; (3) the thermally embrittled state modelling non-hardening mechanism of embrittlement; (4) the irradiated state. The true stress-strain curves are determined over wide temperature range that is required for calculation of the stress-and-strain fields for various specimens. The true stress-strain curves for the investigated steels in the initial and thermally embrittled states are obtained when using standard mechanical characteristics. For the irradiated steels the true stress-strain curves are obtained when using the data of the digital video recording under continuous in-testing monitoring of the cylindrical parts of tensile bars. For the irradiated materials the procedure based on standard characteristics cannot be used as it is connected with very small strain. The procedure based on the digital video recording data is verified by comparison of the stress-strain curves obtained for the initial and thermally embrittled states on the basis of the digital video recording data and standard characteristics.

Effect of Plastic Deformation on Thermal Properties in Twinning-Induced Plasticity Steel.

The effect of plastic deformation induced by wire drawing on thermal properties in twinning-induced plasticity (TWIP) steel has been investigated. The investigation on the relationship between thermal conductivity (k) and the microstructure in the drawn TWIP steel wire was systematically performed to accurately understand the behavior of the k of a metal during wire drawing. The yield and tensile strengths linearly increased with drawing strain owing to the deformation twins and dislocations that were generated during wire drawing. However, the total elongation sharply decreased with drawing strain. The linear thermal expansion coefficient of the TWIP steel exhibited a similar value regardless of drawing strain. The density decreased linearly with temperature, and it was independent of the drawing strain. k increased initially and then decreased after reaching its maximum value with increasing drawing strains. At a nominal drawing strain of 0.26, k increased compared with the state of hot rolling because the increase in k due to grain elongation was greater than the decrease in k due to dislocations generated during wire drawing. However, as the amount of drawing step increased further, the influence of dislocations on k increased more than that of grain elongation, causing k to decrease.

Heat treatment effects on the mechanical properties and cold resistance of medium-carbon medium-alloyed high-strength steels

The paper studies heat treatment effects on the mechanical properties and cold resistance of medium-carbon, medium-alloyed high-strength cold-resistant steels. Kind of changes in strength and plastic properties depending on the tempering temperature have been revealed. It has been established, that tempering in the temperature range 560–580°C provides an optimal combination of strength and plastic properties and makes it possible to increase the cold resistance of the steel.

Optimization of microstructure and mechanical properties of 7075 aluminum alloy by equal channel angular pressing technology

Abstract The equal channel angular pressing technology, as an effective technique for modifying the surface of a material, has had a significant impact on the microstructure and mechanical properties of the 7075 aluminum alloy. The study achieved the refinement of 7075 aluminum alloy grains and the homogenization of the second phase particle distribution through equal channel angular pressing technology, thereby significantly improving the strength and plasticity of the material. Through orthogonal experimental design, the effects of extrusion angle, extrusion speed, and remelting temperature on material properties were studied. The results showed that appropriate ECAP parameters could effectively regulate the microstructure of 7075 aluminum alloy, thereby optimizing its mechanical properties. Especially in the analysis of equivalent strain rate, when the extrusion angle was 50°, the position of the maximum equivalent strain rate at the forefront point remained unchanged, but the equivalent strain rate decreased to 0.107-1. In the aging hardness analysis, when the number of equal channel angular pressing passes was 3, the aging hardness of G group 7075 aluminum alloy increased to 195HV in the first 5 minutes. The equal channel angular pressing technology can optimize the internal structure of 7075 aluminum alloy and improve the material's plasticity and mechanical properties. The research provides important technical support for the application of 7075 aluminum alloy in high-end equipment manufacturing.

Sugar inclusion influences the expansion characteristics of corn starch extrudates.

Corn starch-based direct expanded products incorporated with 2% and 10% (w/w) sugar (fructose, glucose, sucrose, and xylose) were produced using a 20mm co-rotating twin-screw extruder. The pasting and thermal properties of raw corn starch-sugar mixes were analyzed before extrusion processing. The independent variables for extrusion processing included two sugar inclusion levels (2% and 10% w/w) and two screw speeds (150 and 250rpm). The extrudates were characterized by their initial expansion ratio (IER), expansion ratio (ER), and shrinkage. ER values were high for fructose at 2% and 150rpm and 10% glucose and sucrose extrudates at 250rpm. The extrudates with 2% sucrose inclusion shrunk significantly higher than the control. Fourier transform infrared (FTIR) spectroscopy of the extruded blends did not indicate the presence of any new covalent bond formed between starch and sugar post-extrusion. The interactions between sugar concentration and screw speed significantly influenced extrudate expansion characteristics. Due to their thermal and plasticizing properties, sugar inclusion (glucose, fructose, sucrose, and xylose) enhanced the extrudate expansion by altering their melt viscosity. PRACTICAL APPLICATION: The findings of this study can improve the expansion characteristics of high-fiber-based extruded snacks. Ingredients high in fiber generally hinder the starch transformation during extrusion and negatively impact the expansion properties. The presence of sugar at low concentrations can improve melt properties during extrusion processing and, in turn, significantly improve the textural properties of snacks.

Recycling Valuable Phenol from Polycarbonate Plastic Waste Via Direct Depolymerization and Csp2-Csp3 Bond Cleavage Under Mild Conditions.

Upcycling plastic waste into commodity chemicals is recognized as an environmentally benign solution and beneficial for the sustained growth of humanity. Nevertheless, transition metal-free catalysts and energy-efficient conditions pose significant challenges due to the robust mechanical properties of plastics. Here, a strategy for selective production of phenol by upcycling polycarbonate waste via direct depolymerization and Csp2-Csp3 bond cleavage in an aqueous medium under mild conditions is reported. The commercial zeolites efficiently catalyze the depolymerization, Csp2-Csp3 bond hydrolysis, and direct Csp2-Csp3 bond scission at Cα of PC. Among all evaluated zeolites, HY (Si/Al=15) showed excellent catalytic performance, attributed to the ~75 % yield of phenol and ~15 % of acetone. The approach also employs different municipal waste PC for upcycling. Studies reveal that HY (15) exhibits high catalytic efficiency and phenol yield due to its optimum acid sites and textual properties. A scale-up experiment demonstrated that 3.1 g of phenol was produced from 5.0 g of PC, and the mass balance was 90 %. A combination of control experiments, NMR analysis, and DFT studies proposed the reaction pathway. Our findings present a sustainable avenue for upcycling PC waste and offer a new way to produce phenol, contributing to the advancement of a circular economy.

Finite-Strain Elastic-Plastic Circular Shear in Materials with Isotropic Hardening

This study presents an analytical solution to the problem of azimuthal shear in a hollow circular cylinder, isotropic and incompressible, the elastic properties of which are described by the Mooney – Rivlin model, and the plastic properties by the Tresca model with arbitrary monotonic hardening. Both elastic and plastic deformations are assumed to be finite. Sufficient conditions for the existence of the presented solution are given.

Plasticizers: distribution and impact in aquatic and terrestrial environments.

Plasticizers, essential additives for enhancing plastic properties, have emerged as significant environmental and health concerns due to their persistence and widespread use. This study provides an in-depth exploration of plasticizers, focusing on their types, structures, properties, production methods, environmental distribution, and associated risks. The findings reveal that petroleum-based phthalates, particularly di-(2-ethylhexyl) phthalate (DEHP), are prevalent in aquatic and terrestrial environments, primarily due to the gradual degradation of plastic polymers. In the analysis of 39 studies on water contamination during the period of 2022-2023, only 22 works could be extracted due to insufficient details on the numerical value of plasticizer concentrations. Similarly, soil and sediment contamination studies were fewer, with only 11 studies focusing on sediments. These studies reveal that high plasticizer concentrations, notably in industrial and urban areas, often exceed recommended environmental limits, posing risks to ecological integrity and human health through bioaccumulation. Bioaccumulation of these compounds in soil and water could negatively affect the microbial communities, nutrient cycling, and could destabilize the overall ecological integrity. Concerns about their direct uptake by plants and potential risks to human health and food safety are highlighted in this study due to the high concentrations exceeding the threshold values. The review evaluates current treatment technologies, including metal-organic frameworks, electrochemical systems, multi-walled carbon nanotubes, and microbial degradation, noting their potential and challenges related to cost and energy consumption. It underscores the need for improved detection protocols, cost-effective treatments, stricter regulations, public awareness, and collaborative research to mitigate the adverse impacts of plasticizers on ecosystems and human health.

Multi‐branched octopus‐like plasticizers with excellent plasticizing performance in poly(vinyl chloride)

AbstractThe development of alternatives is a priority issue for the plasticizer industry due to the reproductive toxicity and potential carcinogenicity of phthalate plasticizers. Herein we demonstrate the synthesis and characterization of multi‐branched octopus‐like plasticizers applied in poly(vinyl chloride) (PVC). The plasticizers were achieved through a straightforward one‐step esterification reaction, resulting in four polyol ester plasticizers (glyceryl tri‐n‐octanoate [GTOE], pentaerythritol tetra‐n‐octanoate [PQOE], xylitol penta‐n‐octanoate [XPOE], and mannitol hexa‐n‐octanoate [MHOE]). The multi‐branched structure enhances the interactions between plasticizers and PVC molecules leading to superior plasticizing properties, particularly mechanical properties, thermal stability, and migration resistance compared with commercial plasticizers di(2‐ethylhexyl) phthalate (DEHP), dioctyl terephthalate (DOTP), and acetyl tributyl citrate (ATBC). Concretely, the elongation at break of MHOE/PVC (825%) and PQOE/PVC (814.63%) was better than that of DEHP/PVC (670.02%), DOTP/PVC (490.62%) and ATBC/PVC (566.78%). The T5% of GTOE/PVC, PQOE/PVC, XPOE/PVC, and MHOE/PVC were 46.97, 67.24, 60.09 and 48.14°C higher than ATBC/PVC respectively. In the volatility resistance testing after 48 h, the weight loss of GTOE/PVC, PQOE/PVC, XPOE/PVC, and MHOE/PVC was 5.63%, 3.64%, 2.95%, and 8.88% respectively, which was far less than DEHP/PVC (15.58%), DOTP/PVC (11.83%) and ATBC/PVC (18.15%). Consequently, the obtained plasticizers demonstrate enhanced plasticizing efficiency, presenting promising alternatives to phthalate plasticizers and expanding the repertoire of choices within the plasticizer industry.

Complete conversion of eucalyptus wood to dynamic covalent networks: An in-situ plasticising strategy

Ongoing innovation in bio-based plastics aims to meet more economical and diverse societal needs. However, the dependence on a single biomass source and the generally inadequate wet stability and moisture mechanical properties of traditional bio-based plastics severely limit their competitiveness. We have developed a high mechanical performance, fully bio-based, thermoset in-suit plastic from an almost worthless agricultural and forestry waste (eucalyptus) through a simple and environmentally friendly deconstruction-reconstruction strategy. In this process, the hydrogen and covalent bonds in the lignin and cellulose of eucalyptus are broken and then reorganised through dynamic covalent bonds. The resulting eucalyptus-based plastic exhibits high mechanical strength, excellent water resistance, UV ageing resistance, photothermal performance and light/heat controllable shape memory properties. By preserving the original structure of the lignin and cellulose, its natural degradability is ensured. This strategy for developing full-component plastics from solid agricultural and forestry waste offers a new approach to producing more competitive fully bio-based plastics.

Dampak Penggunaan Abu Marmer terhadap Kuat Geser Tanah Lempung

Soil is an important part of the building structure because it has a function as a support for the building. Therefore, soil stability must be considered so that building construction is safe and durable. There are types of clay soils that have high plasticity values and low shear strength. Soils like this require stabilization with the addition of additives such as marble ash. The purpose of this study was to determine whether the addition of marble ash content has an optimal impact on improving the plasticity, density, and shear strength properties. The added material used was marble ash with a content of 3%, 6%, 9%, and 12% by weight of dry soil. The specimens were differentiated based on their curing age before being tested by triaxial. Based on the research results, it was found that the use of marble ash had the maximum impact on improving the plasticity properties and maximum density at an addition of 6%. This was followed by a significant increase in shear strength at the same addition. A good curing age for increasing the angle of internal friction in the soil was obtained at 14 days.

Investigation of the Synthesis and Energetic Properties of an ANTA-Based Energetic Plasticizer.

Energetic plasticizers are being sought for their use in energetic formulations when combined with explosives. An energetic plasticizer based on the insensitive highly explosive 3-amino-5-nitro-l,2,4-triazole (ANTA) was synthesized and characterized by spectroscopy, X-ray crystallography, thermal analyses, and safety testing. Lastly, density functional theory calculations were employed to examine the observed selectivity among the three nucleophilic ring nitrogen atoms of ANTA toward electrophiles such as ANTA acrylate; this selectivity was found to be a combination of steric, electronic, and hydrogen bonding effects.