Plastic Film Research Articles

Strain-engineered stretchable substrates for free-form display applications

With the growing potential of the Internet of Things, displays are being utilized to provide various types of information in every aspect of daily life, leading to the expansion of form-factor-free displays. Stretchable displays are considered the ultimate goal in form factor innovation, and they are not limited to rectangular shapes with deformation characteristics suited to target applications. Because reliable stretchable displays should be robust under uniaxial and biaxial strain, there have been efforts to tailor mechanical stress with promising strategies from structural and material perspectives. This review focuses on strain-engineering stretchable substrates for free-form display applications. First, we introduce deformable substrates with structural stretchability, achieved by incorporating buckling and Kirigami structures into plastic films, and we systematically analyze the tensile deformation characteristics based on design elements. In addition, we examined intrinsically stretchable elastomeric substrates, which have gained considerable attention due to recent advances in material and processing technologies. Their spatial modulus patterning is studied by applying optimized design principles, achieved through network alignment and crosslinking control in homogeneous elastomers, as well as by incorporating heterogeneous structures within the elastomer materials. Finally, we discussed state-of-the-art stretchable display applications employing strain-engineered stretchable substrates, focusing on advantageous materials and structures based on the display components, processes, and target deformation characteristics. Building on this foundation, we discuss the development of next-generation free-form displays and aim to contribute to their application in various static and dynamic deformation environments.

A scientific report on heat transfer analysis due to generated and absorbed heat over an oscillatory stretching sheet: a finite difference-based study.

A non-Newtonian liquid motion across a stretchable surface is relevant to various industrial applications, including extruding plastic sheets and stretching plastic films. In connection with this, the impact of endothermic and exothermic chemical reactions on the flow of rate-type liquid via an oscillatory stretching sheet in the presence of permeable media with the Maxwell liquid model is elucidated in the present study. Scientists and engineers may enhance the efficiency of chemical reactions or heat transmission by optimising system flow and investigating the effect of reactions on flow dynamics. The present study's governing partial differential equations (PDEs) are transformed into their non-dimensional form using similarity variables. The resulting equations are numerically solved using the finite difference method (FDM). Outcomes disclose that the temperature profile declines as the activation energy and unsteadiness parameters increase. The influence of the Maxwell and unsteadiness parameters on the fluid's velocity with respect to time is represented. The rise in the values of chemical reaction parameter upsurges the thermal profile. As the activation energy and unsteadiness parameters upsurge, the thermal profile declines. As the chemical reaction parameter and the ratio of oscillation frequency to stretching rate values rise, the concentration profile falls.

Plasticizer Design Principle of "Like Dissolves Like": Semiconductor Fluid Plasticized Stretchable Fully π-Conjugated Polymers Films for Uniform Large-Area and Flexible Deep-Blue Polymer Light-Emitting Diodes.

Physical blending of fully π-conjugated polymers (FπCPs) is an effective strategy to achieve intrinsically stretchable films for the fabrication of flexible optoelectronic devices, but easily causes phase separation, nonuniform morphology and uncontrollable photo-electronic processing. This may cause low efficiency, unstable and nonuniform emission, and poor color purity, which are undesirable for deep-blue flexible polymer light-emitting diodes (FPLEDs). Herein, a "Like Dissolves Like" design principle to prepare semiconductor fluid plasticizers (SFPs) is established and intrinsically stretchable FπCPs films via external plasticization for high-performance deep-blue FPLEDs are developed. Three fundamental requirements are proposed, "similar conjugated skeleton, similar molecular polarity, and similar electronic structures," to prepare model-matched nonpolar M1 and polar M2 plasticizers for poly(9,9-dioctylfluorene) (PFO). Large-area plasticized PFO films exhibit an efficient, narrowband, and stable ultra-deep-blue electroluminescence (FWHM < 40nm, CIE: 0.12, 0.04), uniform morphology, and excellent intrinsic stretchability (fracture strain >20% and crack-onset strain >120%). Efficient and uniform deep-blue FPLEDs based on stretchable PFO films are fabricated with a high brightness of ≈3000cd cm-2. Finally, blended PFO films exhibit outstanding stretch-deformation cycling stability of their deep-blue electroluminescent behavior, confirming the effectiveness of the "Like Dissolves Like" principle to design matched SFPs for stretchable FπCP films in flexible electronics.

Macro- and micro-plastic accumulation in soils under different intensive farming systems: a case study in Quzhou county, the North China Plain.

The macroplastics (MaPs) and microplastics (MiPs) polluting agricultural soils raise great concerns. Unfortunately, scientists know little about the occurrence of MaPs/MiPs in soil among different farming systems. In this study, we analyzed MaPs/MiPs in soils (0‒30 cm) collected from six different farming systems (wheat-maize rotations, cotton, vegetables, permanent orchards, greenhouses with and without mulching) in Quzhou county, the North China Plain, by using fluorescence microscope and micro-Fourier transform infrared spectroscopy. The results showed that the abundance of MaPs and MiPs ranged from 0.2 to 46.8 kg ha‒1, and 4.1×103‒3.7×104 items kg‒1, respectively. The prominent colors of the MaPs were white and black. The predominant shape, size and chemical composition of soil MiPs were fragments (45‒62%), < 1 mm (98‒99%), and polyethylene (38‒43%), respectively. MaPs were mainly detected in the 0‒10 cm soil layer. MiP abundance in the 0‒10 cm soil layer was significantly higher than that in the 20‒30 cm soil layers among different farming systems, except for the fields with wheat-maize rotations and permanent orchards (p < 0.05). Overall, cotton fields showed the highest MaP and MiP abundance, followed by vegetable fields and orchards. Redundancy analysis revealed that tillage practices and plastic film management greatly influence the size distribution of MiPs. A strong negative correlation between large-sized plastic fractions (0.2‒1 mm) and tillage frequency was tested while the years of application of plastic films and the abundance of plastic residues showed a strong positive correlation with small-sized plastic fractions (< 0.2 mm). Our findings conclude that agricultural mulch films are an important source of MaPs and MiPs in agricultural soil and distributions are strongly influenced by agricultural management practices and farming systems. Further studies should take farming systems and farming practices into account, thereby exploring the potential mechanisms of plastic fragmentation and granularization in agricultural soil.

Adsorption of Arsenic and Cadmium on Biodegradable and Non-Biodegradable Microplastics in Soil: Comparison Based on Batch Experiment

In the present study, the adsorption of arsenic(V) and cadmium(II) onto microplastics from poly(butylene succinate-co-butylene adipate) (PBSA) and low-density polyethylene (LDPE) plastic mulch films was investigated through batch experiment. The surface morphology and elemental composition of soil and microplastics were analyzed with scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (SEM-EDX) and Fourier-transform infrared (FTIR) spectroscopy. The results show that the adsorption of As(V) and Cd(II) on microplastics led to surfaces with coarseness and more cracks, and many small particles. Under the conditions added with 100 pieces of microplastic, PBSA enhanced the adsorption capacity of As(V) (from 0.43 to 0.49 mg/g), and LDPE increased the adsorption of Cd(II) (from 0.174 to 0.176 mg/g) due to the “superimposed effect” caused by hydrogen bonds. Conversely, LDPE reduced the adsorption of As(V) (from 0.44 to 0.40 mg/g) due to a “dilution effect” of PE. Particularly, PBSA exhibited an insignificant effect on the adsorption of Cd(II) in soil during the present study. Overall, our findings provide new insights into the impacts of microplastics on the fate and behavior of heavy metals in the soil system.

Evaluation of interferents in sampling materials for analysis of post-explosion residues (explosive emulsion/ANFO) using gas chromatography-mass spectrometry (GC/MS).

Chemical analysis aimed at identifying post-explosion residues is critical for investigating crimes or accidents involving explosives, establishing it as a vital area of forensic chemistry. In general, only trace amounts remain in samples analyzed for this purpose, making the presence of interferents a constant concern. Therefore, understanding the materials used from collection to sample preparation is essential for this type of analysis. This study focuses on organic contaminants in collection and laboratory materials analyzed by gas chromatography/mass spectrometry (GC/MS), complementing a previous study by Mauricio etal. (2020), which addressed inorganic contaminants in materials used for similar purposes in ion chromatography (IC). No prior studies have specifically investigated the potential organic interferences introduced by various materials commonly used in forensic laboratories for sample pre-processing, storage, and evidence collection in this context. Plastic films, bottle caps, disposable gloves, syringes, swabs, disposable cups, plastic tubes, and plastic pipettes were examined. GC/MS analyses revealed that certain materials, particularly syringe plungers, gloves, and plastic films, can interfere with the detection of post-explosion residues from explosive emulsions and ANFO (ammonium nitrate-fuel oil). These findings emphasize the importance of evaluating materials for potential interferences prior to sample collection and processing to minimize contamination risks. This study provides significant insights into how commonly used laboratory materials can impact forensic analysis, thereby enhancing the reliability of post-explosion residue analysis and supporting more accurate forensic investigations.

Fabrication and electroadhesion properties of parylene-coated carbon fiber arrays

Parylene-coated carbon fiber (CF) arrays with tunable inclination angles and heights were fabricated using oxygen plasma etching of composite wafers with embedded parallel CFs, followed by parylene coating via chemical vapor deposition. The effective elastic modulus of the CF arrays was found to decrease approximately in proportion to the square of the fiber length (5-60μm), with the parylene coating (∼2μm) further slightly reducing the modulus. Both experimental measurements and finite element simulations indicated that CF arrays with inclination angles below 75° exhibit ideal contact with glass wafers during electrostatic adhesion. However, the measured electrostatic adhesion between CF arrays and A4 paper was significantly lower than the predicted value for ideal contact, likely due to the porous nature of the paper. Electrostatic chuck prototypes based on the parylene-coated CF arrays demonstrated effective pick-and-place capabilities for A4 paper, plastic films, and glass wafers at voltages ranging from 500 to 900 V, without causing surface damage or leaving residue. These results highlight the potential of the parylene-coated CF arrays for applications in high-precision manufacturing and automated handling systems.

Real-time autonomous control of a continuous macroscopic process as demonstrated by plastic forming.

To meet the need for more adaptable and expedient approaches in research and manufacturing, we present a continuous autonomous system that leverages real-time, in situ characterization and an active-learning-based decision-making processor. This system was applied to a plastic film forming process to demonstrate its capability in autonomously determining process conditions for specified film dimensions without human intervention. Application of the system to nine film dimensions (width and thickness) highlighted its ability to explore the search space and identify appropriate and stable process conditions, with an average of 11 characterization-adjustment iterations and a processing time of 19 minutes per width, thickness combination. The system successfully avoided common pitfalls, such as repetitive over-correction, and demonstrated high accuracy, with R2 values of 0.87 and 0.90 for film width and thickness, respectively. Moreover, the active learning algorithm enabled the system to begin exploration with zero training data, effectively addressing the complex and interdependent relationships between control factors (material supply rate, applied force, material viscosity) in the continuous plastic forming process. Given that the core concept of this autonomous process can, in principle, be transferred to other continuous material processing systems, these results have implications for accelerating progress in both research and industry.

Dry cleaning process and mechanism of gas–solid fluidized bed for waste film plastics

Dry cleaning process and mechanism of gas–solid fluidized bed for waste film plastics

Transparent, Sprayable Plastic Films for Luminescent Down‐Shifted‐Assisted Plant Growth

AbstractThe world's steadily growing population and global heating due to climate change are a threat to food security. To meet this challenge, novel technologies are needed to increase crop production in a sustainable way. In this work, the use of luminescent down‐shifting (LDS) materials based on molecular Eu3+‐containing polyoxotitanates for plant growth enhancement is investigated. Using a systematic design strategy to optimize down‐shifting properties, conversion of the ultraviolet spectral range to the photosynthetically active radiation (PAR) is achieved with quantum yields as high as 68%. The prototype Eu3+‐compound can be incorporated into water‐based acrylic varnish that can be spray‐coated onto existing greenhouses. Comparing coated with uncoated greenhouses, basil plants produce 9% more leaf dry weight per plant, and a highly significant 10% increase in individual leaf dry weight. The coating reduces the amount of transmitted PAR by 8% but has advantageous effects on diffuse radiation and in reducing the internal mean temperature. Although there is some uncertainty as to the contribution of down‐shifting, with the bulk of the increase probably being due to higher diffused light and the reduction in maximum daily temperatures, this study establishes a model for the design of LDS paints for real‐world agricultural applications.

Optimizing plastic film mulch to improve the yield and water use efficiency of dryland maize in the Loess Plateau, China.

Knowledge on the variation of yield and water use efficiency under different mulching methods is important for guiding rained maize production in the Loess Plateau area. In this study, eight different plastic film mulching methods was established to analyze the maize growth, soil water content and soil temperature changes of dryland maize, and increase yield and water use efficiency (WUE). The field experiment was conducted in 2019, and eight treatments were set up, including a traditional flat planting without mulching (CK), ridge-furrow with ridges mulching black plastic film and furrows mulching straw (HJ), ridge-furrow with ridges mulching black plastic film and furrows bare (HL), ridge-furrow with ridges mulching liquid plastic film and furrows mulching straw (YJ), ridge-furrow with ridges mulching liquid plastic film and furrows bare (YL), ridge-furrow with ridges mulching biodegradable plastic film and furrows mulching straw (SJ), ridge-furrow with ridges mulching biodegradable plastic film and furrows bare (SL) and ridge-furrow with ridges bare and furrows mulching straw (NJ). Furthermore, the AHP-TOPSIS was employed to evaluate the optimal mulching method for maize. The results showed that compared with CK and NJ treatment, the soil water content and soil storage were significantly changes with other treatments in the reproductive period of maize. Among the six mulching methods, maize yield in HJ, HL, YJ, YL, SJ, and SL treatments were 46.28%, 61.95%, 70.30%, 51.02%, 52.02% and 53.53% significantly greater than CK treatment. In addition, dryland maize WUE was 66.53% and 84.01% higher in the YJ and YL treatments with ridges mulching liquid plastic film than in the CK treatment, respectively. The optimal treatments of economic benefits were YL and HJ. Through AHP-TOPSIS comprehensive analysis, the optimal mulching methods were YL and HJ treatment. Current field trials indicate that YL treatment could serve as a promising option to improve dryland maize yield, WUE, and reducing environmental risks in the Loess Plateau of China.

Fabrication of Flexible Organic Field Effect Transistor Using Patterned Electrospray Deposition

ABSTRACTThe electrospray deposition (ESD) method is a wet process that uses the solution spray formed by an electric field between the needle of a syringe containing the solution and a conductive substrate or an insulated electrode. In this study, we fabricated thin films based on 6,13‐bis(triisopropyl‐silylethynyl) pentacene (TIPS‐pentacene) formed by a new direct patterning ESD method. This method utilizes an electric field applied between the nozzle and patterned electrodes on the substrate. It enables the formation of patterns on materials such as plastic films. Moreover, this ESD method allows for the control of patterned film width using the voltage on a counter‐patterned electrode. These results demonstrate that the patterned TIPS‐pentacene film width can be controlled by controlling voltage. We fabricated a flexible organic field‐effect transistor (OFET) using this method and measured its static electrical characteristics.

The influence of plasticizer on the mechanical, structural, thermal and strain recovery properties following stress-relaxation process of silk fibroin/sodium alginate biocomposites for biomedical applications

The influence of plasticizer glycerol (GLY) on the mechanical, structural, and thermal properties of silk fibroin (SF)/sodium alginate (SA) biocomposite films was investigated in detail. As the SF/SA ratio increased up to 65%, the SF content significantly improved the Tensile strength (σT), Young's modulus (Ey) but reduced the elongation at break (εb). To modify and enhance the elasticity and flexibility of the biocomposite films, the GLY as a plasticizer was used at different ratio from 20 to 50% for each SF/SA biocomposite films. Although the extensibility of the films was improved greatly with increasing GLY ratio, σT and Ey reduced significantly. The effect was observed more apparently for the GLY ratio starting from 35%. It was also shown that crystallinity index in the Amide I region increased as the SF/SA ratio increased to 65%. Increasing SF content improved the thermal stability of the SF/SA biocomposites. The XRD results showed that crystallinity was increased as SF/SA ratio increased. Stress-relaxation of SF/SA (30%) biocomposite films plasticized with GLY revealed that each kind of plasticized films showed a viscoelastic behavior and a fast relaxation in the first stage (1–2 min) of the processes and then continued slowly. The GLY increased the extensibility and elasticity limit of the SF/SA (30%) composite films. During the strain recovery processes, the plasticized composite films recovered completely in a quite shorter time than that of unplasticized films. It was observed higher the GLY content, the recovery times became shorter.

Plastic Transport in Rivers: Bridging the Gap Between Surface and Water Column

Rivers act as an important transportation pathway for land-based plastic litter to the ocean. Recently, rivers have also been identified as potential sinks and reservoirs for plastics. Knowledge of plastic transport over different depth profiles in rivers remains limited. In this study, we evaluated the vertical distribution of macro- and mesoplastics, using a larvae net and a trawl net in the river Rhine and its two major branches, i.e. Waal and IJssel. Subsequently, to estimate the relationship between the surface transport of plastic items, i.e., floating items, compared to the transport in deeper layers in the water column, including suspended and bed-transported plastic, an extrapolation factor was derived per day for the middle and bottom nets divided by those found in the surface net. The observed macro- and mesoplastic OSPAR categories collected in different layers in the water column were rather consistent between different sampling techniques. Fragments of soft mesoplastic falling under the category “Plastic film plastics 0-2.5 cm (soft)" were recorded most frequently in the investigated rivers with our monitoring techniques. During larvae net monitoring, hard plastics were more frequently found at the river surface than at the middle or bottom of the river for both macroplastic and mesoplastics, while soft plastics were more frequently detected near the bottom. For larvae net monitoring, the extrapolation factor, reflecting the concentration ratio of macroplastic items transport at different depths, i.e., from the surface downwards to the middle and the bottom ranged between 0.38 to 2.2 and 0.36 to 5.7, respectively. The extrapolation factor of mesoplastic transport from the surface downwards to the middle and the bottom ranged between 0.70 to 1.84 and 0.69 to 2.57. During trawl net monitoring, the extrapolation factor, reflecting the concentration ratio, for macroplastic ranged between 0.82 – 1.30, and for mesoplastic between 0.52 – 1.40. Overall, the findings of this study show that estimates of plastic concentrations solely based on surface transport could result in an under- or overestimation of riverine plastic transport.

Enhancing soil water stability and retention through plastic mulching under atypical climatic conditions on the Chinese loess plateau

Mulching is an agricultural practice that is extensively implemented worldwide to conserve water in soil to enhance agricultural production，and especially in the temperate continental monsoon climate regions. However, the mechanism controlling soil moisture evaporation, infiltration, and retention by mulching is unclear. We assess the impact of various mulching regimes on the soil–water equilibrium in the root zone of corn fields under atypical climate conditions(Excessive Precipitation) from 2020–2021 in five treatments: (1) ridges mulched with plastic film and furrows without mulching (RF), (2) conventional flat planting with full plastic mulching (FPM), (3) conventional flat planting with straw mulching (SM), (4) conventional flat planting with partial plastic mulching (PPM), and (5) conventional (control) flat planting with no mulching (CK). The HYDRUS-2D model was calibrated and validated using experimental data, to assess soil water content, water flux, and soil water balance within a two-dimensional soil profile. This model accurately replicated the root zone within the soil profile under all mulching scenarios, with numerical simulation outcomes closely aligning with observed measurements. Average R² values for FPM, PPM, RF, SM, and CK scenarios were 0.76, 0.75, 0.86, 0.85, and 0.77, respectively. During the 2020 and 2021 growing seasons, characterized by increased rainfall, plastic-covered treatments (FPM, PPM, RF) more efficiently reduced soil evaporation and enhanced soil-water retention. The combined soil drainage and storage changes for FPM, PPM, RF, and SM treatments exceeded those of CK by an average of 114.57, 64.93, 77.38, and 6.74 mm, respectively. FPM, PPM, and RF treatments had substantial water-retention capabilities during years of atypical climate. Notably, FPM ensured adequate water supply, facilitated deep soil water replenishment, and more effectively maintained soil water stability and retention. This underscores the pivotal regulatory function of mulching in mitigating the impacts of consecutive years of unusual climatic conditions.

Rapid Generation of Microplastics and Plastic-Derived Dissolved Organic Matter from Food Packaging Films under Simulated Aging Conditions.

In this study, we show that low-density polyethylene films, a prevalent choice for food packaging in everyday life, generated high numbers of microplastics (MPs) and hundreds to thousands of plastic-derived dissolved organic matter (DOM) substances under simulated food preparation and storage conditions. Specifically, the plastic film generated 66-2034 MPs/cm2 (size range 10-5000 μm) under simulated aging conditions involving microwave irradiation, heating, steaming, UV irradiation, refrigeration, freezing, and freeze-thaw cycling alongside contact with water, which were 15-453 times that of the control (plastic film immersed in water without aging). We also noticed a substantial release of plastic-derived DOM. Using ultrahigh-resolution mass spectrometry, we identified 321-1414 analytes with molecular weights ranging from 200 to 800 Da, representing plastic-derived DOM containing C, H, and O. The DOM substances included both degradation products of polyethylene (including oxidized forms of oligomers) and toxic plastic additives. Interestingly, although no apparent oxidation was observed for the plastic film under aging conditions, plastic-derived DOM was more oxidized (average O/C increased by 27-46%) following aging with a higher state of carbon saturation and higher polarity. These findings highlight the future need to assess risks associated with MP and DOM release from plastic wraps.

Effects of plastic film mulching on soil microbial carbon metabolic activity and functional diversity at different maize growth stages in cool, semi-arid regions.

Plastic film mulching has been widely used to enhance soil hydrothermal conditions and increase crop yields in cool, semi-arid areas. However, its impact on soil microbial carbon metabolic activity and functional diversity during plant growth remains unclear despite their important roles in nutrient cycling and soil quality evaluation. This study used the Biolog EcoPlate technique to investigate the dynamics and driving factors of soil microbial carbon metabolic activity and functional diversity at different maize growth stages following plastic film mulching. The results revealed that film mulching significantly increased microbial carbon metabolic activities [represented by average well color development (AWCD)] by 300% at the seedling stage and by 26.8% at maturity but decreased it by 47.4% at the flowering stage compared to the control (without mulching). A similar trend was observed for the microbial functional diversity index. Redundancy analysis identified soil moisture (SM), soil temperature (ST), dissolved organic carbon (DOC), microbial biomass carbon (MBC), and bacteria amounts as the primary factors influencing changes in soil microbial carbon source utilization. The mulch treatment significantly increased SM at all growth stages, while its warming effect disappeared at the flowering stage. Soil DOC, MBC, and bacterial populations were notably higher under mulching at the seedling and maturity stages but lower at the flowering stage. Pearson correlation analysis showed that changes in SM, ST, DOC, MBC, and bacterial populations positively correlated with the utilization of all carbon source classes, AWCD, and functional diversity indexes after film mulching. Furthermore, maize grain yield and water use efficiency increased by 142 and 129%, respectively, following film mulching. In conclusion, plastic film mulching enhanced soil microbial carbon metabolic activity and functional diversity at the seedling and maturity stages, improving crop yields in cool, semi-arid areas. Furthermore, the decrease in soil carbon metabolic capacity at flowering stage highlights that supplementing soil carbon sources should be considered after continuous film mulching to sustain or enhance farmland productivity and soil quality.

High rubber elasticity and thermal conductivity in plasticized polyvinyl chloride film with flame retardancy and smoke suppression properties

AbstractFor hydrogenated nitrile‐butadiene rubber (HNBR) modified polyvinyl chloride (PVC), magnesium hydroxide and antimony trioxide are frequently employed as flame retardants. Fume silica is thought to be useful reinforced agent for rubber as well as efficient flame retardant for polymer‐based composites. The plasticized PVC and HNBR blend in this work were combined with three fillers mentioned above to create rubber‐plastic composites that performed well overall, with a notable improvement in combustion. The limiting oxygen index of the composites increased from 23.7% to 33.8% with no droplets falling during combustion, the smoke density rating decreased from 23.8% to 7.9%, and the maximum smoke density dropped from 95.5% to 15.5%. The cone calorimetry test findings revealed that the three fillers simultaneously prevented the emission of smoke and heat from combustion. High thermal conductivity is typically linked to excellent flame retardancy. The thermal conductivity of composites rose from 0.193 to 0.583 W m−1 K−1 with the addition of fillers. Furthermore, the low glass transition temperature and permanent set of improved composites reflect its softness and rubber elasticity. Thermogravimetric analysis was used to examine the thermal stability of the composites in nitrogen and air, and the results indicated the addition of fillers improved the thermal stability.

Eco-Friendly and Low-Cost Synthesis of Transparent Antiviral- and Antibacterial-Coated Films Based on Cu2O and MIL-53(Al).

This research presents the development of an innovative antimicrobial coating consisting of cuprous oxide (Cu2O) integrated with the metal-organic framework MIL-53(Al) through an eco-friendly and low-cost synthesis method that employs glucose as a reducing agent under mild conditions. The microstructural properties of the composite materials were characterized by using X-ray diffraction (XRD) and transmission electron microscopy (TEM). The antibacterial efficacy of the Cu2O-MIL-53(Al) (CuM) composite was assessed against Escherichia coli and Staphylococcus aureus, achieving a reduction efficacy of 99.99% with 5% copper incorporated into the MIL-53(Al) framework within a contact time of 24 h. The incorporation of CuM into a macromolecular host matrix of polyurethane-carboxymethylcellulose (CuM/PUD-CMC), applied as a coating on a low-cost plastic film, produced a transparent film with 87.10% transparency. This coating demonstrated a 99.99% reduction in E. coli and S. aureus populations within a contact time of 24 h. The CuM/PUD-CMC coating demonstrated substantial antiviral efficacy, achieving inactivation rates of 99.35% for Human Coronavirus 229E, 99.40% for Influenza A virus, and 97.76% for Enterovirus 71 within a contact time of 5 min. The CuM nanoparticles exhibited low toxicity toward zebrafish while effectively eradicating bacteria and inactivating viruses. The proposed low-cost material and coating method demonstrate significant potential as a broad-spectrum antimicrobial and antiviral agent, highlighting its suitability for various applications in biomedical and healthcare formulations.

An Innovative Approach to Closing the Loop in a Circular Plastic Economy by Upcycling Single-Use Post-consumer Thin Film Plastic Packaging Waste into Durable Plastic Products

AbstractThe waste system requires a circular economy business solution to upcycle millions of tonnes of contaminated post-consumer single-use multi-material, multilayer, plastic packaging films/foils. This waste is rarely collected for recycling, firstly because the market for such waste is new and very small, and secondly due to technical issues and cross-contamination at waste recycling facilities. Conventionally, two linear disposal routs exist, energy recovery through incineration or landfill, both having an economic cost. Being very lightweight, plastics are blown around and end up contaminating terrestrial and marine environments. This paper evaluates intrusion extrusion moulding technology with agglomeration to make products. With a 50-year first lifespan and nine more life cycles, they can be used multiple times as a substitute for wood and concrete. Public bodies can catalyse the intrusion extrusion moulding manufacturing industry by including such products during their procurement processes. The technology works and the business can be profitable.