Plasmonic Metamaterial Absorber Research Articles

Plasmonic metamaterial absorber for MWIR and LWIR bispectral microbolometers

Plasmonic metamaterial absorbers (PMAs) designed for multispectral imaging in the infrared (IR) with uncooled microbolometers are investigated. The study presents Fourier transform infrared spectroscopy (FTIR) measurements of PMAs consisting of metal-insulator-metal-stacks (MIM) with square-shaped micropatches as top metal layers. The measurements reveal high absorptances of 82% to 99% for distinct wavelengths within a range from 2 μm to 9.2 μm. The spectra are evaluated with respect to the lateral dimensions of the patches and to the refractive indices of the used dielectrics SiO2, Al2O3 and Ta2O5. Numerical simulations and analytical calculations of the TM010-mode using the transmission line model (TLM) for microstrip antennas show good qualitative agreement with the measurement results. Additionally, bispectral PMAs were fabricated consisting of fields of PMAs with two different patch sizes arranged in a chessboard pattern. The individual fields of this pattern correspond to microbolometers with 12 μm pitch in shape and size. Two distinct absorption maxima can be seen in the spectra measured by FTIR. The choice of materials, deposition methods and patterning processes is suitable for the integration into the existing Fraunhofer IMS's nanotube microbolometer technology to realize multispectral infrared imaging. The fabrication process is CMOS-compatible and carried out on 8-in. wafers.

A plasmonic metamaterial flexible absorber design and analysis in optical regime

A plasmonic metamaterial flexible absorber design and analysis in optical regime

Multifunctional and switchable metamaterial for terahertz polarization modulation in the reflection mode.

In this paper, a broadband multi-layered active metamaterial design is investigated, which can achieve a high polarization conversion efficiency over a wide band of frequencies in the terahertz regime. The design can be switched to an efficient metamaterial absorber using the phase transition property of vanadium dioxide (V O 2). Additionally, the designed structure can convert the linear polarization of the incoming wavefronts to its cross-polarization and linear polarization to circular polarization in the reflection mode. The broadband characteristic is achieved due to the strong anisotropic behavior of the metasurface. The structure is robust to a wide range of incident angles as well. The proposed switchable multifunctional design can contribute to the development of active plasmonic polarization devices and metamaterial absorbers.

Near- and Mid- Infrared Quintuple-Band Plasmonic Metamaterial Absorber

Near- and Mid- Infrared Quintuple-Band Plasmonic Metamaterial Absorber

Visible-Range Multiple-Channel Metal-Shell Rod-Shaped Narrowband Plasmonic Metamaterial Absorber for Refractive Index and Temperature Sensing.

Multiple resonance modes in an optical absorber are necessary for nanophotonic devices and encounter a challenge in the visible range. This article designs a multiple-channel plasmonic metamaterial absorber (PMA) that comprises a hexagonal arrangement of metal-shell nanorods in a unit cell over a continuous thin metal layer, operating in the visible range of the sensitive refractive index (RI) and temperature applications. Finite element method simulations are utilized to investigate the physical natures, such as the absorptance spectrum, magnetic flux and surface charge densities, electric field intensity, and electromagnetic power loss density. The advantage of the proposed PMA is that it can tune either three or five absorptance channels with a narrowband in the visible range. The recorded sensitivity and figure of merit (S, FOM) for modes 1-5 can be obtained (600.00 nm/RIU, 120.00), (600.00 nm/RIU, 120.00 RIU-1), (600.00 nm/RIU, 120.00 RIU-1), (400.00 nm/RIU, 50.00 RIU-1), and (350.00 nm/RIU, 25.00 RIU-1), respectively. Additionally, the temperature sensitivity can simultaneously reach 0.22 nm/°C for modes 1-3. The designed PMA can be suitable for RI and temperature sensing in the visible range.

Investigating the Absorption Spectra of a Plasmonic Metamaterial Absorber Based on Disc-in-Hole Nanometallic Structure.

In this work, we present and explore the characteristics of a plasmonic metamaterial absorber based on a metal–insulator–metal functional stack. The proposed structure consists of glass “sandwiched” between a silver reflector and a titanium metallic disc, embedded inside a Ti periodic nano-hole array, as an outside layer. In the visible and infrared regimes, the optical absorption spectra of such structures have been investigated using the finite difference time domain method. The impact of modifying nano-hole and embedded disc diameters on the absorber’s performance has been investigated. Changing these two distinct structural parameters tunes the coupling effect between the localized and propagating surface plasmons. The adequate bandwidth, average spectral absorption rate, and short circuit current density are calculated to determine the performance of the designated absorber. The proposed structure of the plasmonic metamaterial absorber reaches an average absorption of over 94% in a bandwidth of 0.81 µm and near-perfect absorption of 98% around the wavelength of 0.7 µm, with an almost 100% relative absorption bandwidth and 41 mA/cm2 short circuit current density. In addition, the results show that the disc-in-hole absorber’s structural parameters can be changed precisely and facilely to tailor to the absorption spectra.

Exploring the Absorption Spectra of an Ultra-Wideband Metamaterial Absorber in the Visible and Near-Infrared Regions.

This paper investigates the absorption spectra of a plasmonic metamaterial absorber in the visible and near-infrared regimes by utilizing a metal-dielectric-metal (MDM) functional stack. A periodic metal-dielectric cap is introduced on top of a metallic substrate to excite surface plasmon modes. The shape of this cap and the glass coating modifies the absorbance bandwidth. Although the circular cap exhibits less broadening in the absorbance than the square one, the circular cap’s glass coating boosts the bandwidth’s expansion in the near-infrared region to about 1.65 µm. In the visible and near-infrared regimes, absorption bandwidth and spectral ratio can be tailored by modifying four distinct structural parameters. The finding shows that one can achieve an ultra-broad bandwidth that extends from 0.3 µm to 1.65 µm at 90% absorbance. The thickness of the top titanium layer, the silicon dioxide spacer thickness, the Ti-SiO2 cap diameter, and the sliver substrate pitch are selected to be 20 nm, 60 nm, 215 nm, and 235 nm, respectively. Furthermore, the influence of using various metals on absorption spectra has been explored in the visible and near-infrared regimes. The d metals considered for the top layer are titanium, nickel, chromium, silver, copper, gold, aluminum, and gold.

Enhanced Broadband Metamaterial Absorber Using Plasmonic Nanorods and Muti-Dielectric Layers Based on ZnO Substrate in the Frequency Range from 100 GHz to 1000 GHz

A broadband thin film plasmonic metamaterial absorber nanostructure that operates in the frequency range from 100 GHz to 1000 GHz is introduced and analyzed in this paper. The structure consists of three layers: a 200 nm thick gold layer that represents the ground plate (back reflector), a dielectric substrate, and an array of metallic nanorods. A parametric study is conducted to optimize the structure based on its absorption property using different materials, gold (Au), aluminum (Al), and combined Au, and Al for the nanorods. The effect of different dielectric substrates on the absorption is examined using silicon dioxide (SiO2), aluminum oxide (Al2O3), titanium dioxide (TiO2), and a combination of these three materials. This was followed by the analysis of the effect of the distribution of Al, and Au nanorods and their dimensions on the absorption. The zinc oxide (ZnO) layer is added as a substrate on top of the Au layer to enhance the absorption in the microwave range. The optimized structure achieved more than 80% absorption in the ranges 100–280 GHz, 530–740 GHz and 800–1000 GHz. The minimum optimized absorption is more than 65% in the range 100 GHz to 1000 GHz.

Plasmonic Metamaterial Absorbers Design Based on XGBoost and LightGBM Algorithms

Plasmonic Metamaterial Absorbers Design Based on XGBoost and LightGBM Algorithms

3D printed metamaterial absorbers for mid-infrared surface-enhanced spectroscopy

The resonant nature and geometric scalability make metamaterials an ideal platform for an enhanced light–matter interaction over a broad frequency range. The mid-infrared (IR) spectral range is of great importance for vibrational spectroscopy of molecules, while IR metamaterials created from lithography-based planar nanostructures have been used to demonstrate enhanced molecular detection. Compared with visible and near-infrared, the relative long wavelengths of IR light make it possible to achieve three-dimensional (3D) IR metamaterials via the state-of-the-art 3D fabrication techniques. Here, we design and fabricate a 3D printed plasmonic metamaterial absorber (MMA), and by performing Fourier-transform IR spectroscopy, we demonstrate that a series of molecular fingerprint vibrations of glycine can be significantly enhanced by the high absorption mode supported by the 3D meta-atoms of the MMA. The observed enhanced IR detection can also be partially attributed to the improved accessibility offered by the 3D architecture of the MMA. In particular, due to capillary forces during the drying process, the microscale 3D printed features lead to selective analyte deposition in high-field regions, which provides another degree of freedom in the design of the 3D printed structures for surface-enhanced IR detection. Our study shows the flexibility of metastructures based on advanced 3D printing technology in tailoring the interaction between IR light and materials on a subwavelength scale.

Graphene-Integrated Plasmonic Metamaterial for Manipulation of Multi-Band Absorption, Based on Near-Field Coupled Resonators

We demonstrated a multi-band plasmonic metamaterial absorber (MA), based on the near-field coupled resonators. In addition to the individual resonances of resonators in the proposed structure, which were split-ring resonator (SRR) and cross-shape structures, another resonance was also excited owing to the coupling of resonators, revealing a triple-band absorption. Furthermore, to control the absorption behavior, on the top of the SRRs, the identical SRRs made of graphene ink were pasted. By increasing the resistance of graphene ink, the coupling strength was weakened, changing the triple-band absorption to a dual-band one. Our work might be useful as the controllable devices, based on graphene-integrated plasmonic MA, such as filters, detectors and energy harvesters.

Graphene-Based Plasmonic Metamaterial Perfect Absorber for Biosensing Applications

Graphene as a mono-atomic sheet has recently grabbed attention as a material with enormous properties. It has also been examined for enhancing absorbance in the current plasmonic structure. This has led to an increment in the sensitivity of the plasmonic sensors. In this paper, we present theoretical investigation of the novel graphene-based plasmonic metamaterial perfect absorber for biosensing applications. The simulation study performs the analysis of the novel plasmonic metamaterial absorber structure by adding coatings of graphene sheets. Each sheet of graphene enhances absorbance of the structure. In this study, we demonstrate three layers of graphene sheets lead to perfect absorbance (100%) for multiple bands in the visible and near-infrared regions. Furthermore, we also computed the sensitivity of the graphene-based proposed structure by varying the refractive index (RI) of the sensing region from 1.33–1.36 with RI change of 0.01. Proposed fabrication steps for realization of the device are also discussed.

Multi-resonant absorptions in asymmetric step-shaped plasmonic metamaterials for versatile sensing application scenarios.

Plasmonic nanostructures have attracted remarkable attention in label-free biosensing detection due to their unprecedented potential of high-sensitivity, miniaturization, multi-parameter, and high throughput screening. In this paper, we propose a plasmonic metamaterial absorber consisting of an asymmetrical step-shaped slit-groove array layer and an opaque gold film, separated by a silica dielectric layer, which demonstrates three-resonant perfect absorption peaks at near-infrared frequencies in an air environment.This is equivalent to three reflection dips due to the opaque gold membrane underneath the structure. Originating from the coupling and hybridization of different plasmonic modes, these three absorption peaks show different linewidths and distinctive excellent sensing performance. The surface lattice resonance (SLR) at the short wavelength range enables an ultra-narrow absorption peak of merely 2 nm and a high bulk refractive index sensitivity of 1605 nm/RIU, but occurring with comparatively low surface sensitivity. Compared to the above-mentioned narrowband SLR mode, the other two absorption peaks, respectively stemming from the coupling between slit-cavity mode and the plasmon resonance of different orders, possess relatively broad linewidths and low bulk refractive index sensitivities, yet outstanding surface sensitivities. The complementary sensing performance among these absorption peaks presents opportunities for using the designed plasmonic metamaterial absorber for multi-parameter detection and various complex application scenarios.

Multi-mode plasmonic resonance broadband LWIR metamaterial absorber based on lossy metal ring.

Broadband perfect infrared wave absorption of unpolarized light over a wide range of angles in an ultrathin film is critical for applications such as thermal emitters and imaging. Although many efforts have been made in infrared broadband absorption, it is still challenging to cover the perfect absorption of broadband in the long-wave infrared band. We propose a long-wave infrared broadband, polarization, and incident angle insensitivity metamaterial absorber based on the supercell with four rings of two sizes. Broadband absorption covering the long-wave infrared band is realized by combining four PSPRs and LSPRs absorption peaks excited by the supercell structure. The absorptivity of our absorber exceeds 90% in the wavelength range of 7.76∼14µm, and the average absorptivity reaches 93.8%. The absorber maintains more than 80% absorptivity as the incident angle of unpolarized light reaches 60°, which may have promising applications for thermal emitters, infrared imaging, thermal detection.

Broadband absorber using ultra-thin plasmonic metamaterials nanostructure in the visible and near-infrared regions

In this work, an ultra-thin plasmonic metamaterial nanostructure absorber is simulated using the finite difference time domain method in the visible and near-infrared regions. A periodic square titanium-silica cap coated with glass medium is mounted on top of a silver substrate. The presence of the glass host enhances the absorption bandwidth by 276%. With an almost perfect metal–insulator-metal absorber, over 90% absorbance has been obtained for wavelengths from 440 to 1850 nm, producing an absorption bandwidth of 1410 nm. The impact of changing dimensions and using different materials on the absorption spectra has been investigated in both visible and near-infrared regimes. The considered metals for the top layer are titanium, nickel, silver, aluminum, and gold; however, the insulators are silica, quartz, vanadium dioxide, methyl methacrylate, and aluminum dioxide. In addition, aluminum, silver, copper, and gold are then simulated as a substrate. The optimum structure, which produces the maximum absorber bandwidth, 1410 nm, with a higher absorption, over 90%, is Glass-Ti–SiO2–Ag. The finding illustrates that the optimum dimensions of the Ti–SiO2 cab and the square base unit cell of the silver substrate are 250 nm and 200 nm, respectively. Finally, the absorption bandwidth is calculated using different polarization angles ranges from 10° to 70° with a step10°.

Plasmonic metamaterial absorbers with strong coupling effects for small pixel infrared detectors

Here we report a metal-insulator-metal (MIM) based infrared plasmonic metamaterial absorber consisting of deep subwavelength meander line nanoantennas. High absorption composed of two-hybrid modes from 11 μm to 14 μm is experimentally demonstrated with a pixel pitch of 1.47 μm corresponding to a compression ratio of 8.57. The physical mechanisms responsible for novelty spectral absorption, including the strong coupling between the plasmon resonances and the phonon vibrations, material loss from the dielectric spacer, localized surface plasmon resonance (LSPR), and Berreman mode excited by oblique incidence, have been systematically analyzed by finite-difference time-domain (FDTD) method, Fabry-Perot resonance model and two-coupled damped oscillator model. At oblique incidence, a spectral splitting related to the strong coupling between LSPR mode and Berreman mode is also observed. The distribution of local electromagnetic fields and ohmic loss are numerically investigated. Moreover, we evaluate the absorption performances with finite-sized arrays. We also show that the absorber can maintain its absorption with a 2 × 2 nanoantenna array. Such a miniaturized absorber can adapt to infrared focal plane arrays with a pixel size smaller than 5 μm, and thermal analysis is also performed. Our approach provides an effective way to minimize the antenna footprint without undermining the absorber performances, paving the way towards its integration with small pixels of infrared focal plane arrays for enhanced performances and expanded functionalities.

Enhancement of refractive index sensing for an infrared plasmonic metamaterial absorber with a nanogap.

An infrared plasmonic metamaterial absorber with a nanogap was numerically and experimentally investigated as a refractive index sensor. We experimentally demonstrated large enhancements of both sensitivity (approximately 1091 nm/refractive index unit) and figure of merit (FOM*; approximately 273) owing to the nanogap formation in the metamaterial absorber to achieve perfect absorption (99%). The refractive index sensing platform was fabricated by producible nanoimprint lithography and isotropic dry etching processes to have a large area and low cost while providing a practical solution for high-performance plasmonic biosensors.

A polarization-insensitive dual-band plasmonic metamaterial absorber for a sensor application

A polarization-insensitive dual-band plasmonic metamaterial absorber is proposed, which is constituted by merely the metal nano-cylinder and a continuous metallic ground separated by a middle dielectric layer. Two resonance peaks with over 97% absorbance derived from ‘the fundamental resonance and the surface lattice resonance are realized. The effective medium approach and the transmission line modeling show good agreement with results from numerical simulation. In addition, we demonstrated that proposed dual-absorber retain nearly perfect absorbance for all polarization angles of both TE and TM modes on normal incidence. It is different from previous work that the dual-frequency response is obtained by combining two subunits of different sizes. Importantly, the second absorption peak result from surface lattice resonance with narrow line-width has large sensitivity perform and high quality factor, which has significant potential in the application of biosensors and monitoring.

Graphene-assisted infrared plasmonic metamaterial absorber for gas detection

In this paper, we propose a graphene-assisted plasmonic metamaterial absorber to operate as an ultra-compact optical gas sensor in the infrared (IR) region. The metamaterial absorber is comprised of a thin silicon-dioxide layer that is middling between a gold film and an array of graphene-coated gold nano-disks. Using the finite element method, we investigate the resonance characteristics of the proposed plasmonic metamaterial and show that the metamaterial has three distinct resonances in visible and infrared regions. We demonstrate that the strongest absorption peak of the proposed metamaterial is attributed to a fundamental localized surface plasmon resonance in IR, which has also the highest spectral sensitivity to the refractive index (RI) variations of the surrounding medium. The sensing mechanism is based on evaluation of gaseous medium RI surrounding the nano-disks, by illuminating the metamaterial with IR radiation and subsequently measuring the reflection or absorption spectra of the structure. We show that graphene coating of the gold nano-disks improves the sensitivity of the metamaterial to the gas RI by more than two times. Using the optimized design parameters, an average linear spectral sensitivity of 720 nm/RIU and an approximate detection limit of 1 × 10−5 RIU has been obtained for gas RI variations between 1 and 1.05. We also show that the proposed sensor has a linear response even for extremely small variations in gas RI in the order of 10−5 RIU. The proposed metamaterial configuration is relatively easy to fabricate and can be used to monitor low concentrations of various gases in different applications ranging from environmental monitoring to home safety monitoring systems.

Three-Dimensional Metamaterial for Plasmon-Enhanced Raman Scattering at any Excitation Wavelengths from the Visible to Near-Infrared Range.

Plasmonic materials with highly confined electromagnetic fields at resonance wavelengths have been widely used to enhance Raman scattering signals. To achieve the maximum enhancement, the resonance peaks of the plasmonic materials should overlap with the excitation and emission wavelengths of target molecules, which is difficult for most of the plasmonic materials possessing a few narrow resonance peaks. Here, we report an ultrabroadband plasmonic metamaterial absorber (BPMA) that can absorb 99% of the incident light energy and excite plasmon resonance from the ultraviolet to near-infrared range (250-1900 nm), which allows us to observe efficient plasmon-enhanced Raman scattering (PERS) with any excitation sources. As demonstrated by the investigation on a self-assembled monolayer of the nonresonant molecule 4-mercaptobenzonitrile, the BPMA exhibits high PERS performance with a detection limit of down to 10-12 M under any excitation sources of three different lasers and excellent uniformity (∼5.51%) and reproducibility (∼5.50%), which corroborates the potential for high-throughput production with low cost and at a large scale. This work offers a novel platform for anti-interference PERS analysis in dynamic and complex environments.