Plasmon Hybridization Research Articles

Mid-Infrared Wavelength Light Transmission in a Suspended Cylindrical Nanowire Hybrid Plasmonic Waveguide

Mid-Infrared Wavelength Light Transmission in a Suspended Cylindrical Nanowire Hybrid Plasmonic Waveguide

Electrophoretic Microplate Protein Identification Based on Gold Staining of Molybdenum Disulfide Hydrogels.

Numerous high-performance nanotechnologies have been developed, but their practical applications are largely restricted by the nanomaterials' low stabilities and high operation complexity in aqueous substrates. Herein, we develop a simple and high-reliability hydrogel-based nanotechnology based on the in situ formation of Au nanoparticles in molybdenum disulfide (MoS2)-doped agarose (MoS2/AG) hydrogels for electrophoresis-integrated microplate protein recognition. After the incubation of MoS2/AG hydrogels in HAuCl4 solutions, MoS2 nanosheets spontaneously reduce Au ions, and the hydrogels are remarkably stained with the color of as-synthetic plasmonic Au hybrid nanomaterials (Au staining). Proteins can precisely mediate the morphologies and optical properties of Au/MoS2 heterostructures in the hydrogels. Consequently, Au staining-based protein recognition is exhibited, and hydrogels ensure the comparable stabilities and sensitivities of protein analysis. In comparison to the fluorescence imaging and dye staining, enhanced sensitivity and recognition performances of proteins are implemented by Au staining. In Au staining, exfoliated MoS2 semiconductors directly guide the oriented growth of plasmonic Au nanostructures in the presence of formaldehyde, showing environment-friendly features. The Au-stained hydrogels merge the synthesis and recognition applications of plasmonic Au nanomaterials. Significantly, the one-step incubation of the electrophoretic hydrogels leads to high simplicity of operation, largely challenging those multiple-step Ag staining routes which were performed with high complexity and formaldehyde toxicity. Due to its toxic-free, simple, and sensitive merits, the Au staining integrated with electrophoresis-based separation and microplate-based high-throughput measurements exhibits highly promising and improved practicality of those developing nanotechnologies and largely facilitates in-depth understanding of biological information.

Compact unidirectional waveguide grating emitter with enhanced wavelength sensitivity based on the hybrid plasmonic mode

Waveguide grating antennas are widely adopted in beam-steering devices, typically enabling the beam steering in longitudinal direction within a two-dimensional scanning optical array by changing the input wavelength. However, traditional waveguide grating antennas suffer from limited tuning range due to low dispersion of the gratings. In this paper, a compact silicon grating waveguide antenna array is proposed with enhanced wavelength sensitivity by introducing a periodically modulated hybrid plasmonic mode. The hybrid plasmonic mode is supported by the hybrid plasmonic waveguides (HPWs) composed of silicon waveguides and periodic subwavelength silver strips. In order to convert the guided waves to the radiated waves, a series of silicon emitting segments are deposited above the HPWs. Additionally, the horizontally arranged array of HPWs also acts as a reflector of the downward radiation, resulting in an effective unidirectional emission. Through the optimization of physical parameters, the proposed antenna array achieves a wavelength-length tuning efficiency up to 0.3°/nm within the wavelength range of 1500∼1600 nm, exhibiting a significant improvement compared with traditional ones. Moreover, an average upward emissivity exceeding 80% with a maximum value of 89% within the 100 nm bandwidth is demonstrated through the numerical simulations. The proposed compact antenna array provides an alternative solution in realizing large-scale integrated high-tuning-efficiency optical beam-steering devices.

Arrayed electro-optic modulators for novel WDM multiplexing

In this paper, a novel silicon-on-chip integrated 4 × 1 wavelength division multiplexing (WDM) multiplexer has been developed. This is the first time that the multiplexer design incorporates arrayed electro-optical modulators with crosstalk cancellation. The design utilizes two types of electro-optic modulators in each channel. The first modulator, based on 1D-PhCNBC, extracts the desired wavelengths from the WDM spectrum. The second modulator, based on coupled hybrid plasmonics, acts as a switch to eliminate crosstalk of the desired optic wavelength signal at the multiplexer output. By combining the advantages of electro-optical modulators and crosstalk cancellation techniques, we anticipate that our proposed design contributes to the advancement of WDM multiplexing technology and facilitates the implementation of efficient and compact optical communication systems. Additionally, this synergy enables enhanced performance, reduced signal interference, and improved signal quality, leading to more reliable and high-speed data transmission in optical networks. The functionality of the device is theoretically simulated using 3D-FDTD (Finite-Difference Time-Domain) method.

Hybrid Plasmonic Waveguides with Tunable ENZ Phenomenon Supported by 3D Dirac Semimetals

AbstractBy depositing a dielectric fiber on top of 3D Dirac semi‐metal (DSM) and Au layers, the tunable propagation properties of hybrid modes are systematically investigated in the mid‐infrared regime, including the effects of the temperatures, the Fermi levels, and rotation angles. Interestingly, due to the importance of inter‐band transition in the mid‐infrared spectral regime, a strong temperature related epsilon‐near‐zero (ENZ) phenomenon has manifested near the transition frequency. Namely, below room temperature, the real part of the effective refractive index (propagation length) shows a peak (valley). Particularly, at 77 K, the according abruption ratio (ratio of maximum to minimum in ENZ region) is 9.71 (204.1). Additionally, the propagation properties are also closely associated with the Fermi level. When the Fermi level varies in the range of 0.08–0.15 eV, the peak position of the real part of the effective refractive index shifts blue from 21.3 to 38.2 THz, and the according abruption ratio of the propagation length can be modulated in the range of 3.81–45.3. These results are very useful for designing tunable plasmonic devices, such as cutting‐edge modulator, filter, and resonators.

In-Depth Analysis of Plasmon Modes on Silver Nanotriangular Flakes with Plasmon Hybridization

In-Depth Analysis of Plasmon Modes on Silver Nanotriangular Flakes with Plasmon Hybridization

Boosting sunlight driven photocatalytic and catalytic performance of ZnFe2O4-ZnO nanohybrids by loading Ag nanoparticles

We report facile fabrication of magnetically separable Ag@ZnFe2O4-ZnO plasmonic hybrid nanostructures by a simple wet chemical route combined with cost-effective photodeposition. The successful formation of Ag@ZnFe2O4-ZnO hybrid nanostructures was confirmed using XRD, Raman, FESEM, TEM, HRTEM and SAED characterizations. The catalytic and photocatalytic capabilities of the synthesized magnetic Ag@ZnFe2O4-ZnO plasmonic hybrid nanostructures were evaluated with regard to 4-NP to 4-AP reduction in dark and photodecomposition of major anionic and cationic pollutants (MB, MG, MO, RhB) and emerging pollutant levofloxacin antibiotic under sunlight illumination, respectively. Results showed that Ag@ZnFe2O4-ZnO hybrid nanostructures exhibit excellent catalytic as well as photocatalytic response and reduced 98.1 % of 4-NP in only 6 min and decolorized 92.9, 93, 43.4 and 73.3 % of MB, MG, MO and RhB within only 18 min and 90.5 % of levofloxacin in 40 min of sun light irradiation, respectively. Further, the synthesized nanohybrids possess high stability and can be magnetically recovered due to its good magnetic response. In addition, the trapping experiments indicated that the main active compounds for the photodegradation of dyes are OH radicals. We demonstrate that the prepared Ag@ZnFe2O4-ZnO plasmonic hybrid nanostructures have potential application towards decomposition of organic pollutants and other emerging pollutants in wastewater for environmental remediation.

Polarization‐directed nanophotonic routers based on two‐dimensional inorganic molecular crystals

AbstractPhotonic and plasmonic hybrid nanostructures are the key solution for integrated nanophotonic circuits with ultracompact size but relative low loss. However, the poor tunability and modulability of conventional waveguides makes them cumbersome for optical multiplexing. Here we make use of two‐dimensional molecular crystal, α‐Sb2O3 as a dielectric waveguide via total internal reflection, which shows polarization‐sensitive modulation of the propagating beams due to its large polarization mode dispersion. Both experiments and simulations are performed to verify such concept. These Sb2O3 nanoflakes can be coupled with plasmonic nanowires to form nanophotonic beam splitters and routers which can be easily modulated by changing the polarization of the incidence. It thus provides a robust, exploitable and tunable platform for on‐chip nanophotonics.image

Nonlocal effects in plasmon-emitter interactions

Abstract Nonlocal and quantum mechanical phenomena in noble metal nanostructures become increasingly crucial when the relevant length scales in hybrid nanostructures reach the few-nanometer regime. In practice, such mesoscopic effects at metal–dielectric interfaces can be described using exemplary surface-response functions (SRFs) embodied by the Feibelman d-parameters. Here we show that SRFs dramatically influence quantum electrodynamic phenomena – such as the Purcell enhancement and Lamb shift – for quantum light emitters close to a diverse range of noble metal nanostructures interfacing different homogeneous media. Dielectric environments with higher permittivities are shown to increase the magnitude of SRFs calculated within the specular-reflection model. In parallel, the role of SRFs is enhanced in noble metal nanostructures characterized by large surface-to-volume ratios, such as thin planar metallic films or shells of core–shell nanoparticles, for which the spill-in of electron wave functions enhances plasmon hybridization. By investigating emitter quantum dynamics close to such plasmonic architectures, we show that decreasing the width of the metal region, or increasing the permittivity of the interfacing dielectric, leads to a significant change in the Purcell enhancement, Lamb shift, and visible far-field spontaneous emission spectrum, as an immediate consequence of SRFs. We anticipate that fitting the theoretically modelled spectra to experiments could allow for experimental determination of the d-parameters.

Strong coupling between WS2 monolayer excitons and a hybrid plasmon polariton at room temperature

Abstract Light–matter interactions between plasmonic and excitonic modes have attracted considerable interest in recent years. A major challenge in achieving strong coupling is the identification of suitable metallic nanostructures that combine tight field confinement with sufficiently low losses. Here, we report on a room-temperature study on the interaction of tungsten disulfide (WS2) monolayer excitons with a hybrid plasmon polariton (HPP) mode supported by nanogroove grating structures milled into single-crystalline silver flakes. By engineering the depth of the nanogroove grating, we can change the character of the HPP mode from propagating surface plasmon polariton-like (SPP-like) to localized surface plasmon resonance-like (LSPR-like). Using reflection spectroscopy, we demonstrate strong coupling with a Rabi splitting of 68 meV between the WS2 monolayer excitons and the lower HPP branch for an optimized nanograting configuration with 60 nm deep nanogrooves. In contrast, only weak coupling between the constituents is observed for shallower and deeper nanogratings since either the field confinement provided by the HPP is not sufficient or the damping is too large. The possibility to balance the field confinement and losses render nanogroove grating structures an attractive platform for future applications.

A photoelectrochemical biosensor based on self-calibration platform of carbon-rich plasmonic probe with near-infrared driving signal amplification

Exploring the photochemical (PEC) method induced by low-energy light source makes great significance to achieve high stability and accurate analysis. A sensing platform driven by near-infrared (NIR) light was designed by making the biochemically encoded carbon rich plasmonic hybrid (CPH) probe, the peptide@C–Mo2C. The inherent plasmonic effect of C–Mo2C CPH can directly absorb NIR light, thus starting effective electronic-hole pairs separation. Moreover, the photothermal effect of C–Mo2C CPH also promoted the reaction yield of photothermal catalyst reaction on sensing interface to assist the PEC signal amplification. In the presence of target trypsin, it cleaves the peptides, resulting in the release of peptide@C–Mo2C probe from interface, which leads to a relative decrease in PEC signal. More importantly, a self-calibration system consisting of two independent PEC test channels attempted to eliminate the influence of background signal and baseline drift. The test channel was used to specify the recognition target, while the blank channel was used as a reference. Therefore, the signal difference between two channels was recorded, so as to obtain results with less error and higher stability. In this NIR driven PEC sensor, the carbon rich probe with direct and efficient NIR light conversion promoted the sensitivity and a self-calibration system guaranteed the stability which provided innovative thoughts for developing ingenious PEC sensor.

Tamm and surface plasmon hybrid modes in anisotropic graphene-photonic-crystal structure for hemoglobin detection

We propose Tamm plasmon (TP) and surface plasmon (SP) hybrid modes for hemoglobin (Hb) detection in anisotropic graphene-photonic-crystal (GPC) structures. The proposed GPC sensor shows polarization-dependent responses due to the in-plane anisotropic property. The reflection profiles of the proposed sensor exhibit two reflectivity minima due to the simultaneous excitation of TP and SP modes. When used to detect Hb, the TP mode offers a greater figure-of-merit (FoM) than the SP mode. Using a Fourier mode spectral analysis, we observe energy coupling from the TP to the SP mode when the incident light’s polarization changes, providing an option to enhance the sensor’s sensitivity. We propose a double dips method (DDM) to detect Hb based on the simultaneous excitation of TP and SP modes. Using DDM, the proposed sensor offers a maximum sensitivity of 314.5 degrees/RIU and a FoM of 1746 RIU−1 when the Hb level is 189 g/L. The proposed anisotropic GPC sensor offers possible applications for highly sensitive bio-molecule detection with high FoM.

Enhancing broadband terahertz absorption via a graphene-based metasurface absorber featuring a rectangular ring and triple crossbars

This study introduces an innovative strategy to achieve a versatile and adaptive terahertz (THz) absorber by leveraging a graphene-based metasurface. This metasurface comprises a rectangular ring, three crossbars and a grounded gold film, all separated by a thin SiO2 layer. The phenomenon of plasmonic hybridization, involving surface and cavity plasmon resonances, enables the interaction between incident THz waves and the proposed graphene-based metasurface, leading to a substantial enhancement in the absorptance bandwidth of the plasmonic system. The enhancement of absorptance can be finely adjusted by modifying the chemical potential (Fermi energy) in graphene and manipulating the structural parameters of the device. A notable feature of our design is its inherent resistance to variations in incident angles and polarization states of incoming electromagnetic waves. The proposed device achieves an absorptance exceeding 80% across a continuous spectrum, exhibiting a bandwidth of approximately 0.90 THz from 0.94 to 1.84 THz. This robust characteristic ensures consistent and reliable performance in diverse scenarios. Our findings present intriguing prospects for various applications centered on wave modulation, which encompass, but are not limited to, THz imaging, filtering, energy harvesting, and tunable sensors.

Nanomaterials Based on 2,7,12,17-Tetra-tert-butyl-5,10,15,20-tetraaza-21H,23H-porphine Exhibiting Bifunctional Sensitivity for Monitoring Chloramphenicol and Co2.

Monitoring antibiotic retention in human body fluids after treatment and controlling heavy metal content in water are important requirements for a healthy society. Therefore, the approach proposed in this study is based on developing new optical sensors using porphyrin or its bifunctional hybrid materials made with AuNPs to accomplish the accurate detection of chloramphenicol and cobalt. To produce the new optical chloramphenicol sensors, 2,7,12,17-tetra-tert-butyl-5,10,15,20-tetraaza-21H,23H-porphine (TBAP) was used, both alone in an acid medium and as a hybrid material with AuNPs in a water-DMSO acidified environment. The same hybrid material in the unchanged water-DMSO medium was the sensing material used for Co2+ monitoring. The best results of the hybrid materials were explained by the synergistic effects between the TBAP azaporphyrin and AuNPs. Chloramphenicol was accurately detected in the range of concentrations between 3.58 × 10-6 M and 3.37 × 10-5 M, and the same hybrid material quantified Co2+ in the concentration range of 8.92 × 10-5 M-1.77 × 10-4 M. In addition, we proved that AuNPs can be used for the detection of azaporphyrin (from 2.66 × 10-5 M to 3.29 × 10-4 M), making them a useful tool to monitor porphyrin retention after cancer imaging procedures or in porphyria disease. In conclusion, we harnessed the multifunctionality of this azaporphyrin and of its newly obtained AuNP plasmonic hybrids to detect chloramphenicol and Co2+ quickly, simply, and with high precision.

Manipulation of plasmon dephasing time via the coupling between localized surface plasmon resonance and waveguide modes

Manipulation of plasmon dephasing time of the hybrid modes has gained much attention in recent years, which plays critical roles in many important applications of plasmonics. Here, we manipulate the dephasing time of plasmonic field resulting from coupling of the localized surface plasmon (LSP) of the nanosphere array and the waveguide mode supported by the indium tin oxide film with quasi-normal mode-assisted harmonic oscillator model method. It results in the formation of two distinct modes, transverse electric (TE) and transverse magnetic (TM) modes. Such coupling can significantly modify the dynamics of the original plasmonic modes. The dephasing time of the hybrid plasmon modes, encompassing both TE and TM modes, can be extended from 1.25fs to 4.95fs, which is about 2–7 times compared to that of a single localized surface plasmon resonant mode. More importantly, by changing the structural parameters, we can flexibly manipulate either the dephasing time with a fixed wavelength or the resonant wavelength with a fixed dephasing time.

Hybridization of graphene-gold plasmons for active control of mid-infrared radiation

Many applications in environmental and biological sensing, standoff detection, and astronomy rely on devices that operate in the mid-infrared range, where active devices can play a critical role in advancing discovery and innovation. Nanostructured graphene has been proposed for active miniaturized mid-infrared devices via excitation of tunable surface plasmons, but typically present low efficiencies due to weak coupling with free-space radiation and plasmon damping. Here we present a strategy to enhance the light-graphene coupling efficiency, in which graphene plasmons couple with gold localized plasmons, creating novel hybridized plasmonic modes. We demonstrate a metasurface in which hybrid plasmons are excited with transmission modulation rates of 17% under moderate doping (0.35 eV) and in ambient conditions. We also evaluate the metasurface as a mid-infrared modulator, measuring switching speeds of up to 16 kHz. Finally, we propose a scheme in which we can excite strongly coupled gold-graphene gap plasmons in the thermal radiation range, with applications to nonlinear optics, slow light, and sensing.

Momentum space separation of quantum path interferences between photons and surface plasmon polaritons in nonlinear photoemission microscopy

Abstract Quantum path interferences occur whenever multiple equivalent and coherent transitions result in a common final state. Such interferences strongly modify the probability of a particle to be found in that final state, a key concept of quantum coherent control. When multiple nonlinear and energy-degenerate transitions occur in a system, the multitude of possible quantum path interferences is hard to disentangle experimentally. Here, we analyze quantum path interferences during the nonlinear emission of electrons from hybrid plasmonic and photonic fields using time-resolved photoemission electron microscopy. We experimentally distinguish quantum path interferences by exploiting the momentum difference between photons and plasmons and through balancing the relative contributions of their respective fields. Our work provides a fundamental understanding of the nonlinear photon–plasmon–electron interaction. Distinguishing emission processes in momentum space, as introduced here, could allow nano-optical quantum-correlations to be studied without destroying the quantum path interferences.

Bi-path color tunable plasmonic micro-nano hybrid structures for encrypted printing.

Colored information is crucial for humans to perceive the world. Plasmonic spectra modulation can serve as an effective means to create different colors. Although several solutions for plasmonic color-printing have been proposed, further information encryption has not received any attention. Herein, we exhibit a fine color modulation strategy to construct noble-metal-based micro-nano hybrid structures in the bi-path of photo-thermal deformation and liquid-phase-chemical reaction. Ag/Ta2O5 bi-layer films are ablated at the center of the machined lines of nanosecond pulsed laser, while silver nanoparticles are formed in other regions by thermal radiation of the infrared laser, which can be further dissolved and shape-modulated in KCl solution under different periods. The variation of size and spacing of nano-Ag particles results in a precise shift of plasmonic spectra in visible region. Colored information can be hidden by adjusting the scan number and the energy density during laser processing, and will emerge after the subsequent chemical dissolution reactions. The bi-path color adjustment strategy is easy to operate and can play a role in key information protection and color image switching.

Facile fabrication of Ag@CoFe2O4-ZnO hybrid plasmonic nanostructures with enhanced photocatalytic performance

Facile fabrication of Ag@CoFe2O4-ZnO hybrid plasmonic nanostructures with enhanced photocatalytic performance

Impact of Hybrid Plasmonic and Temperature in Random Laser Tuning

This research explores the interaction between silver films and dispersed silver nanowires (Ag NWs) in the context of generating random laser emission. To achieve random lasing, we use a mixture of Rhoda mine B (RhB) dye and a polyvinyl alcohol (PVA) matrix as the gain medium. The combination of silver components plays a crucial role in trapping and controlling light. The surface characteristics of the film, including its roughness and the interplay between localized and extended surface plasmons significantly affect the performance of the random laser (RL). The laser’s threshold is closely linked to the thickness of the film, which is influenced by its surface roughness. Additionally, variations in film thickness lead to wavelength modulation, ranging from 597 nm to 606 nm, primarily due to the reabsorption of RhB. Moreover, this research demonstrates the intriguing capability to tune emission wavelengths in response to temperature changes, promising precise wavelength control for plasmonic devices and potential applications.