Fundamental aspects of plasma-assisted etching processes can be investigated in a well-defined and controllable manner by ion-beam techniques. We review here our experiments aimed at simulating a plasma environment using beams to investigate the effects of a number of fundamental parameters of plasma processes, such as the chemical identity of bombarding ions, flux of ions and neutrals to a surface, and ejection of products from a surface. Enhanced ion etching due to reactions of neutral gases with surfaces is demonstrated, and product ejection mechanisms are shown to be possible rate limiting factors in reactive etching processes. A simple chemically enhanced sputtering model suffices to account for the main features of ion-induced etching. Applications of this model to bulk plasma processes, dependence of etch yield on ion angle of incidence, and surface composition modification are suggested.