Manually harvesting hydroponic leafy vegetables from a cultivation pipeline is labor-intensive and expensive. Rapidly grabbing hydroponic leafy vegetables grown in different positions and orientations in the planting hole is the primary issue for efficient mechanical harvesting. Thus, a novel grabbing mechanism with double-pivot rotation cross fingers is proposed. The fingers’ inner surfaces could envelop the grabbable area of the leafy vegetable in the grasping process and position each leafy vegetable stalk to the center of the planting hole before taking it out. A grabbing mechanism for harvesting hydroponic Chinese kale was designed and optimized with less than 1 mm of grasping error, enough enveloping range, and no collision with the extended leaves. Laboratory experiments were conducted to investigate centering and grabbing at different initial positions and inclination angles of the hydroponic Chinese kale and varied finger deflection speeds. It was indicated that for the grasping inclination angle and grabbing success rate, the initial inclination angle was a significant factor, as was the position, whereas the finger deflection speed was insignificant. As the initial inclination angle of matured hydroponic Chinese kale in different initial positions is mostly larger than 60°, the best results were achieved with a finger deflection speed in the range of 40° s−1 to 60° s−1 and grasping inclination angles of 85° to 95°, with a grabbing success rate of more than 95%. This showed the promising applicability of the studied grabbing mechanism for harvesting hydroponic Chinese kale or other varieties of leafy hydroponic vegetables with similar growth characteristics.