Planktonic δ18O Research Articles

Oceanography of the Eastern Equatorial Pacific Ocean Across the Oligocene‐Miocene Transition

AbstractThe functioning of the Pacific Ocean—the world's largest ocean—during a warmer‐than‐present paleoclimate state remains underexplored. We present planktonic and benthic foraminiferal stable oxygen (δ18O) and carbon (δ13C) isotope records from Integrated Ocean Drilling Program (IODP) Site U1334 that span the Oligocene‐Miocene Transition (OMT) interval, from 24.15 to 21.95 million years ago (Ma). We reconstruct (sub‐)surface and deep‐water conditions and provide better constraints on the physical and chemical oceanography of the eastern equatorial Pacific Ocean (EEP). Positive trends in planktonic and benthic foraminiferal δ18O values, mark a largely uniform imprint of increased land‐ice volume/global cooling on surface‐ and deep‐waters. We document a delayed planktonic foraminiferal δ18O increase across the OMT as well as an increase in the amplitude variability of planktonic foraminiferal δ18O values on eccentricity timescales during the early Miocene. We interpret this as an enhanced glacioeustatic sea‐level control on Atlantic‐Pacific salinity exchange through the Central American Seaway (CAS) or as the onset of more variable surface currents and oceanic fronts in the EEP. Positive trends in planktonic and benthic foraminiferal δ13C values characterize the whole‐ocean depletion in 12C linked to organic carbon burial during the Oligocene‐Miocene carbon maximum (CM‐OM). However, this depletion is more pronounced in the planktonic foraminiferal δ13C record, especially during ∼400 Kyr eccentricity minima, reflecting an increase in nutrient upwelling and the efficacy of the biological carbon pump (BCP) when global temperatures decreased across the OMT and during the early Miocene. Our study highlights the dynamic behavior of the EEP in a warmer‐than‐present unipolar icehouse state.

Paleoenvironmental Controls on the Abundances of Magnetofossils in the Southwestern Iberian Margin

AbstractMagnetofossils are nanosized magnetic fossil remnants of magnetotactic bacteria (MTB) that are widely distributed in marine and freshwater sediments. Past studies have revealed that changes in the morphology and abundance of magnetofossils are linked with diverse paleoenvironmental changes, such as glacial‐interglacial variation, redox conditions associated with primary productivity and organic matter supply, chemical weathering and diagenesis. Besides, it has long been speculated that changes in geomagnetic field intensity could also affect the abundance of magnetofossils. However, it is not yet clear, how these environmental factors controlled past MTB populations in combination. To answer this question, we studied magnetofossils‐rich sediments from cores MD01‐2443 and 2444 off the Southwest Iberian Margin. The paleomagnetic records of our samples reveal geomagnetic excursions corresponding to the Laschamp, Blake, Iceland Basin, and Pringle Falls events. We estimated the relative abundance of magnetofossils in the samples based on isothermal remanent magnetization unmixing and found it to increase during warmer periods and decrease during colder periods, while not covary with changes in the geomagnetic field intensity. To further distinguish the role of different paleoenvironmental factors, we compared magnetofossil abundance with planktonic δ18O, δ13C of organic matter, K/Al and Si/Al, which indicate continental ice volume (paleotemperature), organic matter origin, run‐off intensity and productivity, respectively. The results indicate that less continental ice volume (higher paleotemperature), enhanced productivity and run‐off intensity are closely related and jointly promoted magnetofossil production and preservation. Our study offers a comprehensive approach to understanding how magnetofossil assemblages relate to paleoenvironmental changes off the SW Iberian Margin.

An 800 kyr planktonic δ18O stack for the Western Pacific Warm Pool

Abstract. The Western Pacific Warm Pool (WPWP) exhibits different glacial–interglacial climate variability compared to high latitudes, and its sea surface temperatures are thought to respond primarily to changes in greenhouse forcing. To better characterize the orbital-scale climate response covering the WPWP, we constructed a planktonic δ18O stack (average) of 10 previously published WPWP records of the last 800 kyr, available at https://doi.org/10.5281/zenodo.10211900 (Bowman et al., 2023), using the new Bayesian alignment and stacking software BIGMACS (Lee et al., 2023b). Similarities in stack uncertainty between the WPWP planktonic δ18O stack and benthic δ18O stacks, also constructed using BIGMACS, demonstrate that the software performs similarly well when aligning regional planktonic or benthic δ18O data. A total of 65 radiocarbon dates from the upper portion of five of the WPWP cores suggest that WPWP planktonic δ18O change is nearly synchronous with global benthic δ18O during the last glacial termination. However, the WPWP planktonic δ18O stack exhibits a smaller glacial–interglacial amplitude and less spectral power at all orbital frequencies than benthic δ18O. We assert that the WPWP planktonic δ18O stack provides a useful representation of orbital-scale regional climate response and a valuable regional alignment target, particularly over the 0 to 450 ka portion of the stack.

Assessing atmospheric and oceanic teleconnections between the eastern and western Mediterranean over the past 8000 years

Holocene climate records from the Mediterranean are marked by pervasive millennial to centennial-scale climate variability. Here, we investigate East-West Mediterranean atmospheric and oceanic teleconnections by computing phase-relationships between oxygen isotope (δ18O) records generated on Soreq (East) and Chorchia (West) spelaeothems, as well as between δ18O and carbon isotope (δ13C) records from planktonic and benthic foraminifera from core PS009PC (East, Levantin Basin), ODP Site 963D (Central, Sicily Strait), and core KESC9-14 (West, Ligurian Basin). These marine sites are all located at intermediate water depths (560–460 m depth). Hence, the benthic foraminiferal δ18O records reflect mainly the intermediate ocean temperature/δ18O of the water mass, and the benthic δ13C is a proxy for the intensity of water flowing at the studied depth called Levantine Intermediate Water (LIW). For both western and eastern cores, the planktonic stable isotopic records reflect the climate-induced activity of the nearby river system. We find broadly in-phase relationships between the spelaeothem δ18O records and between the planktonic δ18O and δ13C records at most multi-centennial and millennial periodicities. This is indicative of closely linked (hydro-) climatic conditions in Southern Europe, the Levant, and North Africa over the last 8000 years. Conversely, at intermediate water depths, we find a distinct out-of-phase relationship between the East/Central and West Mediterranean benthic δ18O and δ13C records at 1000–2000 years periodicities. We interpret this see-saw pattern as indicative of a persistent regional influence of LIW on oceanographic conditions in the intermediate depths of the eastern basin. Conversely, we suggest a strong influence of the modified Atlantic Ocean inflow (MAW) in the intermediate water formation in the Western Mediterranean (‘Winter Intermediate Water’; WIW). This WIW overprints, at least partially, the LIW signal that reaches the western Mediterranean causing the out-of-phase relationship between the east and the west oceanographic signals at intermediate depths.

On the timing of megafaunal extinction and associated floristic consequences in Australia through the lens of functional palaeoecology

The timing and cause of megafaunal extinctions are an enduring focus of research interest and debate. Despite the developments in the analysis of coprophilous fungal spores (CFS), the proxy for reconstructing past megaherbivore changes, the environmental consequences of this fauna loss remain understudied. This is partly due to the general obscurity of such a signal in pollen records, as well as limitations in disentangling human and extinction ecological impact, and the lack of spatial information of megafauna changes in site-level sedimentary records. In Australia, the debate centres on the possibility that habitat loss through climate change, vegetation-fire change, human intervention, or a combination of these factors led to the extinction of some large animals during the Late Pleistocene. Pollen and plant isotope studies have also demonstrated that vegetation-fire responses following the Late Pleistocene megafaunal extinctions were characterized by increased vegetation density and fire activity due to reduced grazing/browsing pressure. Here, we use a well-dated marine sedimentary core record from the Murray Darling Basin in southern Australia and apply palynological and functional palaeoecological approaches to reconstruct the Late Pleistocene megafaunal abundance changes, the timing and potential cause of extinction across the basin and investigate if extinction was associated with any signal of trait-based vegetation changes. We infer megafaunal abundance changes from the abundance of CFS and compare this with climatic proxies from the same core. We then link modern observations of fruit, seed and fire response traits of plant genera within the basin to the fossil pollen record to reconstruct palaeo vegetation community traits and determine if extinction was associated with any changes in plant community trait composition. Closely-spaced 14C dates obtained from planktonic foraminifera and δ18O tie points place a major decline in CFS, and thus the timing of extinction, within the basin at ∼43.3 ka. While climate-driven environmental changes largely controlled megafaunal presence, human arrival and frequent landscape burning are considered the most likely primary cause of extinction or, at the very least, megafauna decline in the Murray Darling Basin. We also found that the proposed period of megafaunal decline was also accompanied and followed by a decline in the prevalence of plants with larger seeds and fruits that were likely to have been once dispersed by megaherbivores. Our study supports the idea of a human-driven megafaunal extinction in mainland Australia and that the extinction caused changes in vegetation due to reduced plant dispersal and herbivory. However, high fire activity primarily linked to these vegetation changes was not observed, as humans were already practicing landscape burning before the period of megafaunal extinction and likely continued to do so afterward.

Plumbing systems and associated seafloor fluid seepages in deep-water Nigeria: Factors controlling their architecture and cyclic evolution

A range of plumbing systems has been identified in deep-water Nigeria by interpreting multi-scale seismic data sets (reprocessed 3D exploration seismic reflection data and 2D very high-resolution near-bottom seismic reflection data) as well as sedimentological and geochemical data obtained from a long sediment core recovered by the seafloor drill rig MARUM-MeBo70. The plumbing systems are characterized by diverse fault networks and lie above tectonic features including thrust/fold structures and strike-slip faults linked to gravity-driven deformation caused by underlying over-pressured shales. The plumbing systems are associated with fluid seeping structures at the seafloor such as pockmarks, mud volcanoes and seafloor zonations colonized by living benthic macrofauna typical of active fluid flow. The comparison of seismic stratigraphic sequences with climate and environmental proxies determined for sediments including lithology, element ratios such as Ca/Fe and Zr/Rb, sedimentation rates, and planktonic foraminifera δ18O records shows a control of short-term (0.1–0.4 Myr) and long-term (around 1 Myr) sedimentary cycles. During short-term fluctuations, the recurrence of fluid seeping structures is controlled by the lithology (coarse-grained versus fine-grained sediments) linked to glacial-interglacial fluctuations and a monsoon regime. Conditions favorable for fluid flow are related to the deposition of coarse-grained layers, glacial periods, sea-level lowstands, and low sedimentation rates. We hypothesize that cyclic gravity-driven sediment deformations controlled by glacial-interglacial and long-term variations in accommodation and sedimentation, have led to the cyclic evolution of the plumbing systems and associated seeping structures since the Plio-Pleistocene.

Disentangling environmental and diagenetic δ18O and δ13C signals from marine carbonates deposited under warm climate conditions during the early Danian

Paleoceanographic reconstructions are usually based on the chemical composition of foraminiferal tests, and pristine calcite preservation is crucial to support reliable interpretations. Therefore, prior knowledge about the structure and chemical composition of microfossils calcite is important to assess whether geochemical results reflect environmental and/or post-burial signals. Here, we present the first microstructural study of early Danian benthic foraminiferal calcite, and evaluate environmental signals and post depositional biases in benthic and planktonic foraminiferal and bulk carbon (δ13C) and oxygen (δ18O) isotope records at Ocean Drilling Program (ODP) Site 1262 (South Atlantic Ocean). We focused our study on the first ∼350 kyr that followed the Cretaceous-Paleogene (K-Pg) boundary, encompassing the Dan-C2 carbon cycle perturbation. Benthic and planktonic δ13C records show the expected surface-to-bottom gradient, suggesting the preservation of original environmental signals. However, benthic and planktonic δ18O records show strongly overlapping and scattered values, suggesting diagenetic alteration of isotopic signals. We identified the occurrence of authigenic carbonates, such as girvasite and siderite, in benthic foraminiferal tests, which increased Mg, Mn, Ba and Fe contents of tests calcite. Our results support that thermodynamic changes occurred in tandem with the decrease of bottom and pore water oxygenation to favor precipitation of authigenic carbonate phases, which altered isotopic fractionation of δ18O. Nevertheless, bulk sediments clearly depict the negative δ13C and δ18O excursions characteristic of the DanC2, with remarkably low values, characterizing the record of a surface ocean environmental signal. This low δ13C and δ18O were mostly recorded by highly-abundant calcispheres (calcareous dinocysts), suggesting that this group of microfossils has a high potential for surface ocean paleoceanographic reconstructions.

Late Pleistocene chronostratigraphy and biostratigraphy of Mentelle Basin and its implications for global correlation

An accurate and high-resolution age model in marine sediments is essential for reconstructing past oceanographic and climate changes. The southeastern Indian Ocean is an important component of oceanographic circulation and global climate. However, the integrated biostratigraphy for the Late Pleistocene interval is not well known in the region. To address this issue, we constructed a new chronology for International Ocean Discovery Program (IODP) Hole U1516B in the Mentelle Basin, offshore southwestern Australia. We employ planktonic foraminifera δ18O to construct an astronomically tuned age model for Hole U1516B. Biostratigraphic analysis was performed for Hole U1516B using planktonic foraminifera, nannofossils, radiolarian taxa and diatoms. Seven planktonic foraminifera events are recorded, including the PT1a and PT1b boundaries. Eight nannofossil events were recorded including the boundaries between CN14a, CN14b and CN15. The planktonic foraminifera datums marked in Hole U1516B are mostly synchronous with datums reported in the southern hemisphere but are diachronous with datums in the northern hemisphere. The nannofossil datums marked in Hole U1516B have a close affinity with globally reported datums but small inconsistencies are probably due to strong ecological control. The diatom events are inconsistent and only recorded in short intervals during interglacials and several key radiolarians taxa are absent.

Planktonic foraminifera document palaeoceanographic changes across the middle Cenomanian carbon-isotope excursion MCE 1: new evidence from the UK chalk

AbstractPlanktonic foraminifera were studied at Lydden Spout, near Folkestone (southeast England, UK), the reference section of the middle Cenomanian Event 1 (MCE 1) characterized by a prominent double-peak δ13C excursion of 1 ‰ identified in different ocean basins and considered a global event. Biostratigraphic and quantitative analysis of planktonic foraminifera are correlated to the δ13C perturbation, to the positive δ18O shifts identified within MCE 1 and to the occurrence of Boreal macrofossils (the bivalvesChlamys arlesiensisandOxytoma seminudum, and the belemnitePraectinocamax primus). Variations in abundance and species richness of planktonic foraminifera and the inferred palaeoecological preferences of taxa permit the identification of distinct palaeoenvironmental settings across MCE 1. The stratigraphic interval corresponding to MCE 1 is characterized by the absence of oligotrophic rotaliporids, and by the evolutionary appearance of meso-eutrophic dicarinellids and ofMuricohedbergella portsdownensis, a cold-water species that occurs at the same level as the Boreal macrofossils. These observations indicate a palaeoceanographic scenario characterized by reduced stratification of surface waters and absence/disruption of the thermocline in a dominantly eutrophic regime during MCE 1. Evidence provided by planktonic foraminifera, Boreal macrofossils and δ18O records documented for the late Cenomanian Plenus Cold Event (PCE) at Eastbourne (UK) reveal similarities that confirm the periodic inflow of cold Boreal seawater originating in the Norwegian Sea as previously postulated to explain the occurrence of Boreal fauna in the Anglo-Paris Basin. The southerly extension of this water mass may be related to the reorganization of circulation driven by the long eccentricity cycle.

Comparing age model techniques for the last glacial cycle: A case study of ten Iberian Margin sediment cores

Because interpretations of paleoclimate records from ocean sediment cores rely on age models to estimate age as a function of core depth, age model uncertainty can affect the conclusions drawn from paleoclimate data. To assess the age model uncertainty associated with three methods, we compare the age models they generate over the last glacial cycle for high-resolution data from ten western and southern Iberian Margin cores. The first method uses radiocarbon data and the Bayesian statistical software Bacon [Blaauw and Christen, 2011]. The second method aligns benthic δ18O to a target core using the probabilistic alignment algorithm HMM-Match [Lin et al., 2014]. The third method is alignment of planktonic δ18O or sea surface temperature (SST) using the deterministic alignment software Match [Lisiecki and Lisiecki, 2002]. Where three or more age model types overlap in a core, the average range of age estimates is 1.7 kyr, and 90% of age ranges are less than 3 kyr. For the two probabilistic methods, HMM-Match and Bacon, age estimates agree to within uncertainty, and the highest resolution records yield 95% confidence interval widths of 1–2 kyr. However, HMM-Match appears to underestimate alignment uncertainty near gaps in benthic δ18O data in one core, as indicated by disagreement with the core's planktonic δ18O and SST alignments. Planktonic δ18O appears to provide the most precise age models for Iberian Margin cores due to strong millennial-scale variability and good correlation between aligned cores. Probabilistic alignment algorithms should be developed for planktonic δ18O and SST proxies to improve estimates of the age uncertainty for these alignments.

Post–glacial tephrochronology record off the Chilean continental margin (∼41° S)

The Southern Volcanic Zone of the Andes (∼33–46° S) is a very active volcanic zone with several volcanic centers recording recurrent historical activity (e.g. Llaima, Villarrica, Puyehue-Cordón Caulle, Osorno, Calbuco and Hudson). Tephrochronology is a valuable tool to help better understand the eruptive history of volcanic centers, essential for producing volcanic hazard maps. Additionally, tephrochronology can also be very useful to synchronize stratigraphic records of different nature such as paleoclimatological, paleoceanographical and archaeological records on land, lakes, ice and the ocean. Here we present a (crypto) tephrochronological record from two marine sediment cores retrieved in the Chilean continental margin at ∼41° S and ∼41.6° S. The records display continuous sedimentation since the late glacial, as robustly constrained by planktonic foraminifera δ18O and 14C dates. During this period, twenty three cryptotephras were identified as glass shard peaks together with two ∼25–30 cm–thick visible tephras (one in each core). The source of the (crypto) tephras was mainly constrained by major and trace element geochemistry of individual glass shards together with their stratigraphic position, since it is not possible to observe physical characteristics, such as color and grain size, when analyzing cryptotephras. From these, one cryptotephra was robustly correlated with the HW7 eruption from the Hudson volcano occurring in the Late Holocene at ∼1.5 cal ka BP; and the two visible tephra layers were identified as distant correlatives of the Lepué tephra originating from Michinmahuida volcano and occurring in the Deglaciation/Holocene transition at around 11 cal ka BP. Additionally, eight cryptotephra occurring at ∼3.6, 6.2, 7.0, 8.5, 9.6, 14.2, 15.9 and 18.2 cal ka BP were robustly identified as sourced from Michinmahuida volcano but where otherwise not correlated, providing novel evidence of pre Holocene activity of this volcanic center.

Multiproxy record of suborbital-scale climate changes in the Algero-Balearic Basin during late MIS 20 - Termination IX

High-resolution quantitative analyses have been carried out in samples from the Ocean Drilling Program (ODP) Site 975 in the Algero-Balearic basin through late Marine Isotope Stage (MIS 20)-Termination IX (800–784 ka). The multi-proxy study combines data of planktonic δ18O, δ13C, calcareous plankton (coccolithophores, foraminifera), palynomorphs, alkenone-based sea surface temperature (SST), % alkenone tetraunsatured (% C37:4), and terrigenous biomarkers (C23–C31n-alkanes, C22–C30n-alkanols) with the aim to reconstruct climate-induced paleoenvironmental changes at orbital-submillennial scale, in a crucial time interval of the Early-Midde Pleistocene transition. The surface water δ18Osw has been reconstructed from δ18OG.bulloides and alkenone-based SST as a proxy for salinity changes. The late MIS 20 has been subdivided in several phases based on evidence of (i) meltwater events of polar origin or from surrounding mountain glaciers, (ii) changes in the production rate of Western Mediterranean Deep Water (WMDW) and in deep water ventilation, (iii) variation in terrestrial input and river discharge, and iv) variations in the strength of the north westerlies, and polar front shift. Following a glacial stadial (lasting ca 3 kyr) marked by the strongest WMDW production, coeval with a boreal summer insolation minimum and a marked low sea level, the latest MIS 20 is characterized by a terminal stadial event (lasting ca 3.5 kyr), which is traced by the occurrence of cold-low salinity water, pointing to meltwater advection at the site location. Short-term warm and cool events occurred through Termination IX during sea level rise and insolation increase, preceding the onset of full MIS 19c, characterized by an organic rich layer (ORL) associated with insolation cycle 74. The succession of these climate and oceanographic events has been compared to evidences from other Mediterranean sites, highlighting similar basin-wide patterns, which recall the climate evolution of Termination I. The comparison of our results with the climate proxies from the Integrated Ocean Drilling Program (IODP) Site U1385 located west of Iberian margin made it possible to point at the connection between Mediterranean oceanographic and atmospheric dynamics and the northern hemisphere ice-sheet instability, providing insight on the relationship with the Atlantic meridional overturning circulation and thermal front migration.

Decreasing Atmospheric CO2 During the Late Miocene Cooling

AbstractA pronounced late Miocene cooling (LMC) from ~7 to 5.7 Ma has been documented in extratropical and tropical sea surface temperature records, but to date, available proxy evidence has not revealed a significant pCO2 decline over this event. Here, we provide a new, high‐resolution pCO2 proxy record over the LMC based on alkenone carbon isotopic fractionation (εp) measured in sediments from the South Atlantic at Ocean Drilling Program (ODP) Site 1088. We apply a recent proxy calibration derived from a compilation of laboratory cultures, which more accurately reflects the proxy sensitivity to pCO2 changes during late Quaternary glacial‐interglacial cycles, together with new micropaleontological proxies to reconstruct past variations in algal growth rate, an important secondary influence on the εp. Our resulting pCO2 record suggests an approximately twofold to threefold decline over the LMC and confirms a strong coupling between climate and pCO2 through the late Miocene. Within this long‐term trend are pCO2 variations on sub‐myr timescales that may reflect 400‐kyr long‐eccentricity cycles, in which pCO2 minima coincide with several orbital‐scale maxima in published high‐resolution benthic δ18O records. These may correspond to ephemeral glaciations, potentially in the Northern Hemisphere. Our temperature and planktonic δ18O records from Site 1088 are consistent with substantial equatorward movement of Southern Ocean frontal systems during the LMC. This suggests that potential feedbacks between cooling, ocean circulation and deep ocean CO2 storage may warrant further investigation during the LMC.

Muted cooling and drying of NW Mediterranean in response to the strongest last glacial North American ice surges

Abstract The massive North Atlantic iceberg discharges of the last glacial period, the so-called Heinrich events (HE), resulted in atmospheric and oceanic responses of the Mediterranean region that remain poorly documented and understood. This paper focuses on the climatic phases termed Heinrich stadials (HS) 4 and 5 generated by the HE 4 and 5 that occurred during a period of similar intermediate global ice volume and greenhouse gas concentrations but with different iceberg discharges and orbital boundary conditions. Our comparison of sea surface temperature and salinity changes with deep water conditions in the Gulf of Lions (planktonic and benthic foraminifera δ18O and δ13C records) and regional pollen-based temperature and precipitation reconstructions in NW Mediterranean for these Heinrich stadials reveal a paradoxical situation. A lower North American iceberg discharge during HS 5 compared to HS 4 is associated with colder and drier conditions in the NW Mediterranean borderlands. During the moderate iceberg discharge of HS 5 a relatively high salinity in the Gulf of Lions lead to stronger Western Mediterranean Deep Water formation and mixing of the surface with the deeper layers. By contrast during HS 4, we suggest that the massive North Atlantic iceberg break-up decreased the salinity of the Gulf of Lions and reduced the wind stress in the Mediterranean, leading to the stratification of the Mediterranean water column and inducing limited upward mixing of cold water, resulting in regional atmospheric warming and wetting compared to HS 5. This work highlights the potential crucial role of local processes in modulating the regional response to a global climate change related with ice-sheet instabilities.

Retraction Note to: Late Quaternary stable isotope record and meltwater discharge anomaly events to the south of the Antarctic Polar Front, Drake Passage

Marine isotope stages (MISs) 1 to 5 were identified in the planktonic δ18O record in sediment core DP00-02 just south of the Antarctic Polar Front in the Drake Passage, Antarctica. The oxygen isotope record, based on Neogloboquadrina pachyderma sinistral, is correlated with the contemporaneous global δ18O stratigraphy. Marked deviations from the global climate curve suggest a local/regional overprint, particularly during MIS 3 which is considered a colder time period in the ocean record than MIS 1 and MIS 5 during the last interglacial. The comparison shows that negative δ18O shifts in core DP00-02 during MIS 3 are larger than mean global changes which show a shift equal to or smaller than 0.5‰. The isotope shift, exceeding the glacial-interglacial ice volume effect, probably resulted from changes in the isotope composition of seawater, which is linearly related to decreases in salinity rather than to increases in sea-surface temperature. Increased ice-rafted debris (IRD) content during this interval indicates a strong influx of IRD from melting ice shelves and icebergs, which may be related to upwelling of warmer circumpolar deep water.

Integrating palaeoclimate time series with rich metadata for uncertainty modelling: strategy and documentation of the PalMod 130k marine palaeoclimate data synthesis

Abstract. Palaeoclimate data hold the unique promise of providing a long-term perspective on climate change and as such can serve as an important benchmark for climate models. However, palaeoclimate data have generally been archived with insufficient standardisation and metadata to allow for transparent and consistent uncertainty assessment in an automated way. Thanks to improved computation capacity, transient palaeoclimate simulations are now possible, calling for data products containing multi-parameter time series rather than information on a single parameter for a single time slice. Efforts are underway to simulate a complete glacial–interglacial cycle using general circulation models (https://www.palmod.de/, last access: 6 May 2020), and to confront these simulations with palaeoclimate data, we have compiled a multi-parameter marine palaeoclimate data synthesis that contains time series spanning 0 to 130 000 years ago. We present the first version of the data product that focuses exclusively on time series for which a robust chronology based on benthic foraminifera δ18O and radiocarbon dating is available. The product contains 896 time series of eight palaeoclimate parameters from 143 individual sites, each associated with rich metadata, age–depth model ensembles, and information to refine and update the chronologies. This version contains 205 time series of benthic foraminifera δ18O; 169 of benthic foraminifera δ13C; 131 of seawater temperature; 174 and 119 of planktonic foraminifera δ18O and δ13C; and 44, 38 and 16 of carbonate, organic carbon and biogenic silica content, respectively. The data product is available in three formats (R, LiPD and netCDF) facilitating use across different software and operating systems and can be downloaded at https://doi.org/10.1594/PANGAEA.908831 (Jonkers et al., 2019). This data descriptor presents our data synthesis strategy and describes the contents and format of the data product in detail. It ends with a set of recommendations for data archiving.

Magnetofossil Abundance and Diversity as Paleoenvironmental Proxies: A Case Study From Southwest Iberian Margin Sediments

AbstractIt is still contentious how the abundance and diversity of magnetofossils reflect varying paleoenvironmental conditions. Here, we apply rock magnetic methods and transmission electron microscopy to identify magnetofossils in the core MD01‐2444 from the southwestern Iberian margin during the period 49.6–18.5 ka and 193.8–171.7 ka. Results show a correlation between the biogenic magnetite component and contrasting paleoenvironmental conditions. Specifically, remanence ratio (Mrs/Ms), the ratio of anhysteretic susceptibility (χARM) to saturation isothermal remanant magnetization (SIRM), fractions of biogenic soft and biogenic hard components (BS + BH), and delta–delta ratio (δFC/δZFC) have a negative relationship with planktonic δ18O, suggesting that more magnetofossils existed in sediments during warmer periods. Combining transmission electron microscopy images with paleoenvironmental proxies, we found that the proportions of bullet‐shaped magnetofossils increased in a warmer and less oxic environment, while isotropic shapes dominated in cooler and oxic environments.

δ18O and Mg/Ca Thermometry in Planktonic Foraminifera: A Multiproxy Approach Toward Tracing Coastal Upwelling Dynamics

AbstractPlanktonic foraminifera δ18O and Mg/Ca ratios are widely considered as a powerful proxy to reconstruct past seawater‐column temperature. Due to the complex interpretation of planktonic foraminifera δ18O data in regard to past seawater temperatures, temperature determination based on the foraminifera shell Mg/Ca ratio is believed to be more accurate. Scarce Mg/Ca calibration data exists for coastal upwelling regions, resulting in incoherent results of past seawater reconstructions. The current study along the NW Iberia coastal upwelling system intends to define the best Mg/Ca temperature equation for the most representative species of this region (Neogloboquadrina incompta, Globigerina bulloides, and Globorotalia inflata). Seawater temperature from δ18O and Mg/Ca of these three planktonic foraminifera species was compared with the surface sediments alkenone derived SST and with the in situ temperatures measured at the depths where these foraminifera species currently live and calcify. The equations that better reflect each species calcification depth were selected as our regional equations for δ18O and Mg/Ca temperature reconstructions. The δ18O‐estimated temperatures for surface sediment specimens were comparable with in situ seawater‐column temperature measurements, whereas the Mg/Ca derived temperatures seem to underestimate in situ values, in special for G. bulloides from samples affected by stronger coastal upwelling. The G. bulloides δ18O and Mg/Ca estimated temperatures from samples located offshore, further from coastal upwelling influence, are comparable to surface sediment alkenone derived temperatures. Our study shows that in upwelling areas, regional calibration of planktonic foraminifera Mg/Ca temperature equations is necessary for reliable interpretations of high‐resolution past temperature variability in these important environments.

Integrated stratigraphy of ODP Site 1115 (Solomon Sea, southwestern equatorial Pacific) over the past 3.2 Ma

Abstract We provide an integrated stratigraphy for the southern margin of the Indo-Pacific Warm Pool back to 3.2 million years ago (Ma) from ODP Site 1115, Hole B (9o11'S, 151o34'E, water depth 1149 m, 0–217 m below sea floor), the only hole with core recovery beyond 4.4 m. An initial age model based on 14 calcareous nannofossil datums, 5 planktonic foraminiferal biostratigraphic events and 12 magnetic polarity reversals is refined by planktonic foraminiferal Globigerinoides sacculifer (300–355 μm) δ18O stratigraphy. The planktonic δ18O record with an average 3–4 kyr resolution matches the global stack LR04 (Lisiecki and Raymo, 2005). The 41-kyr obliquity and 100-kyr eccentricity patterns show good correlation between the LR04 and the dataset presented herein. The precession amplitude matches eccentricity, supporting the established stratigraphy. Sedimentation rates at Hole 1115B have decreased from 9.3 to 4.5 cm/kyr during the past 3.2 Ma toward present, mainly due to the gradual deepening of the Woodlark Basin. The planktonic δ18O record from Site 1115 matches the global climate evolution well.

Calcareous plankton and the mid-Brunhes climate variability in the Alboran Sea (ODP Site 977)

Quantitative calcareous plankton analyses have been performed at the Ocean Drilling Program Site 977 in the Alboran Sea through the mid-Brunhes interval (300–540 ka). The results evidence orbital-suborbital and millennial scale climate variability which primary reflects temperature change. The patterns of increase/decrease of coccolithophore and planktonic foraminifera warm water taxa reproduce the stage and substage climate variability in the planktonic δ18O in good agreement with other planktonic isotope records from Mediterranean Sea and Atlantic Ocean. Variable conditions, characterized by alternating cool nutrient-rich or warm and stable sea-surface waters, occurred during interglacial Marine Isotope Stage (MIS) 13 in response to high amplitude oscillations of insolation during obliquity maximum and to North Africa monsoon strength, influencing distribution of taxa. MIS 13a resulted warmer than MIS 13c based on the higher abundances of warm water taxa; they increase just after insolation maxima, suggesting a primary response of calcareous plankton to precessional orbital control. Following short-term warm (MIS 11e) and more humid (MIS 11d) phases, a climate optimum lasting about 16 kyr is recognized during MIS 11c, when major tropical-subtropical water arrival into the Alboran Sea occurred as evidenced by the presence of Trilobatus sacculifer. MIS 11c records unstable climate condition that persisted up to the late MIS 11, indicating multiple pulses of southward migrations of subpolar front following the full interglacial MIS 11c. Warm and oligotrophic conditions occurred during MIS 9 as during MIS 11, especially in MIS 9e, although without a climate optimum. Reduced abundance of warm water taxa and decrease of Globorotalia inflata highlight colder surface water conditions and decreased Atlantic-Mediterranean water exchange during glacials, especially during the prominent sea-level low-stand of MIS 12. Short-term prominent peaks of the polar-subpolar Neogloboquadrina pachyderma and Coccolithus pelagicus ssp. pelagicus, and additional key taxa preferring fresher and turbid water, together with minima in total Nannofossil Accumulation Rate and enhanced coccolith reworking, sustain a correlation with the North Atlantic Heinrich-type (Ht) events Ht1, Ht1a, Ht3, Ht4-6, thus documenting the sensitiveness of the Alboran Sea in recording European and Laurentide ice-sheet dynamics. The comparable chronology of most of these cold spells in the available Balearic and Ionian calcareous plankton records highlights that Atlantic melt water entering Alboran basin through Gibraltar Strait may have reached the central Mediterranean preserving some of its original polar signature.