Detailed studies of flame-vortex interactions are extremely valuable to improve our understanding of turbulent combustion regimes. Combined experimental and numerical studies have already been performed in the premixed case during previous investigations. Therefore, we decided to carry out a detailed experimental investigation on the regimes observed during in teraction of a vortex ring and a non-premixed, diluted, hydrogen/air, laminar counterflow flame. To obtain the needed information, several optical diagnostic techniques have been used, in particular, planar laser-induced fluorescence (PLIF) of acetone to quantify vortex structure and speed, simultaneous OH PLIF and Rayleigh measurements, and simultaneous OH PLIF and particle-imaging velocimetry (PIV) measurements. A post-processing of the results combined with direct simulations using detailed chemistry and transport models to check the quality of the postprocessing procedures has led to the construction of a spectral interaction diagram. Eight interaction types were found, emphasizing the relative importance of competing physical phenomena such as straining, curvature, wrinkling, roll-up, and extinction. In particular, we observe two different types of extinction, one due to the combined action of curvature and straining, and the other purely due to straining effects. It was also observed that many vortices are too small or dissipate too rapidly to influence the flame. In other cases, the vortex ring can lead to the formation of pockets of oxidizer burning in the fuel part of the domain. These regimes and the limits between them have important implications for the modeling of turbulent non-premixed combustion.