Chromium molybdenum alloy steels are employed in high temperature services. Welded components in both fossil–fuel fired and nuclear power plants are some examples of critical applications. This study shows the characterization of the mechanical properties and microstructure of 9Cr–1Mo–V steel, revealing the presence of cracks and pores in the weld metal of a circumferential joint made by GMAW with metal cored wire process. Analyses by Scanning Electron Microscopy (SEM) were performed in samples obtained before and after the post weld heat treatment (PWHT). Supplementary analyses by Energy Dispersive X ray Spectroscopy (EDS) were made at diverse regions where discontinuities occurred. The cracks presented an intergranular propagation. The greater crack was localized in the root neighborhood with approximately 1.8mm of extension in a sample with post weld heat treatment (PWHT). The fractured surfaces of Charpy specimens were also analysed by EDS–SEM. The results obtained show the cleaning process of the joint and the chemical composition of the wire and base metal can play an important role in the behavior of the weld joint in pipe service; despite the acceptable mechanical tests results, in accordance with the specifications.