Piper Trilinear Diagram Research Articles

Assessment of seawater intrusion based on geochemical and isotopic data in Makassar coastal area, South Sulawesi, Indonesia

Makassar coastal area has experienced rapid development and has shown various negative impacts from groundwater overexploitation, such as seawater intrusion. This study aimed to assess seawater intrusion based on geochemical and isotopic data in the Makassar coastal area. The research was carried out by field measurement and taking the groundwater samples to the laboratory for geochemical and isotope tests. Geochemical analysis of seawater intrusion was based on TDS, EC, Cl-, Simpson ratio, Ca enrichment, BEX, Na/Cl ratio, and the piper trilinear diagram typer of water. Isotope analysis of seawater intrusion is based on comparing oxygen and deuterium isotopic data from groundwater samples with seawater, river, and rainwater. The results showed that some areas near the sea indicated seawater intrusion in both the semi-unconfined and unconfined aquifers. The indicated seawater intrusion spread in the north Tallo, Mamajang, and Tamalate subdistricts.

Hydrogeochemical evolution and heavy metal characterization of groundwater from southwestern, Nigeria: An integrated assessment using spatial, indexical, irrigation, chemometric, and health risk models

This study examines the hydrogeochemical and heavy metal parameters of groundwater in Ojo District to determine its suitability for use, potential sources, and human health implications. Ten groundwater samples were assessed, and hydrogeochemical modelling was performed via the Aquachem software. The chemical ions were in the following order: EC > (107.78–448.65 μS/cm) > TDS (182.02–320.77 mg/l) > TH (46.22–182.45 mg/l) > pH (5.55–6.35); HCO3− (64.13–125.82 mg/l) > Na+ (36.87–96.49 mg/l) > Ca2+ (47.65–58.88 mg/l) > SO42− (19.94–53.67) > NO3− (15.55–44.25 mg/l) > Cl− (20.43–27.16 mg/l) > Mg2+ (11.09–16.87 mg/l) and K+ (2.55–7.86 mg/l). The concentrations of heavy metals in groundwater were in the range of: Fe (0.11–0.27 mg/l) > Mn (0.003–0.16 mg/l) > Ni (0.05–0.12 mg/l) > Zn (0.003–0.05 mg/l) > Pb (0.001–0.03 mg/l) > As (0.001–0.005 mg/l) > Cr (0.002–0.005 mg/l) > Cd (0.001–0.003 mg/l) and Cu (0.001–0.0002 mg/l), with Pb, Mn, and Ni exceeding their allowable limits. The Schoeller and Gibbs plots revealed that the major mechanisms controlling the aquifer groundwater in Ojo region are geological rock weathering and mineralization, with a minimal influence of saltwater intrusion. The piper trilinear diagram also revealed that none of the cation was dominant while the anions were strongly dominated by HCO3− (weak acids). The hydrogeochemical facies which describes the geochemical characteristics of the groundwater were classified into 3 types; “Ca2+–Mg+–HCO3– (65 %)”, “mixing zones (30 %)”, and “Na+–K+–Cl––HCO3– (5 %)”. The hydrogeochemical modelling revealed that the groundwater is characterized by forward cation exchange, while rock–water interactions (silicate dissolution) were heavily involved in the geochemical processes. The single pollution index showed that Pb, Ni, and Mn contributed significantly to contamination, and the multi–pollution indices showed that the groundwater was slightly-moderately polluted. The integrated groundwater quality index revealed that only 10 % were clean, 50 % were poor or moderately unclean, 30 % were highly unclean, and only 10 % were extremely unclean (unfit for utilization). The water pollution index showed that 70 % of the groundwater was good. The irrigation indices suggest that the groundwater would enhance soil quality and support plant growth. Multivariate analysis revealed that the groundwater is being influenced by geogenic factors and anthropogenic activities. The health risk assessment (Hazard Quotient and Hazard Index) showed that exposure of adults to the investigated groundwaters could result in noncarcinogenic adverse effects. The cancer risk values also exceeded the minimum limit (1.0 x 10−6) and thresholds (1.0 x 10−4) for adults, indicating the carcinogenic potential of the groundwater.

Hydrochemical Characteristics and Variation in Karst Groundwater in the Baiquan Spring Area of Xingtai Over the Last 30 Years

To elucidate the variation patterns in the hydrochemical characteristics of karst groundwater in the Baiquan Spring area of Xingtai over the past 30 years, an integrated approach utilizing mathematical statistics, Piper trilinear diagrams, Gibbs diagrams, and ion ratio analyses was employed. Comparative analysis was conducted on 62 sets of karst water samples collected during the dry seasons of 1991 and 2020. The findings indicated that the groundwater in the spring area was generally weakly alkaline with a low salinization degree, predominantly characterized by Ca2+ and HCO3- as the dominant ions. Compared to that in 1991, the alkalinity of groundwater in 2020 had intensified, with a general increase in the concentration of various indicators. The hydrochemical types had shifted from the relatively concentrated HCO3-Ca and HCO3-Ca·Mg types to a broader spectrum of types, gradually exhibiting a salinization trend. The distribution characteristics of exceeding components such as TDS, Na++K+, SO42-, and F- showed significant spatial differences. Rock weathering played a pivotal role in the changes observed in the hydrochemical components of groundwater, with enhanced cation exchange and evaporation processes further influencing the hydrochemical characteristics and their spatial distribution.

Hydrogeochemical Characteristics and Formation Processes of Ordovician Limestone Groundwater in Zhuozishan Coalfield, Northwest China

A comprehensive understanding of the characteristics and formation mechanisms of groundwater in mining areas is essential for the effective prevention of coal mine water and the rational management of groundwater resources. The objective of this study was to examine the hydrogeochemical characteristics and evolution of Ordovician groundwater in the Zhuozishan coal mine, located in the northwest region of China. A total of 34 groundwater samples were collected for hydrogeochemical analyses and the investigation of their evolution processes, with the aid of a piper trilinear diagram, a Gibbs diagram, and an ion ratio diagram. The results indicate that the concentration of sodium (Na+), potassium (K+), bicarbonate (HCO3−), chloride (Cl−), sulphate (SO42−), total dissolved solids (TDS), and pH increases from the recharge area to the discharge area, whereas the concentration of calcium (Ca2+) and magnesium (Mg2+) decreases. The hydrogeochemical characteristics of the runoff from Zhuozishan to Gongdeer coalfield and further southward display a notable north–south directional change. The groundwater process is primarily controlled by rock weathering action and cation exchange, with Na+ and K+ deriving primarily from cation exchange and only to a minor extent from halite dissolution. In conclusion, the northern part of the coalfield is characterised by a geological structure that creates a retention area with groundwater, resulting in an unordered runoff process with a complex formation mechanism. The middle region is devoid of geological constraints that would alter the flow direction, thus simplifying the process of groundwater formation. In contrast, the southern area experiences an increase in strata depth and fault blocking, which creates a retention zone, thereby rendering the groundwater formation process more complex. This research contributes to the effective management of groundwater resources in this coalfield and other mining sites.

Irrigation Water Quality Assessment in Egyptian Arid Lands, Utilizing Irrigation Water Quality Index and Geo-Spatial Techniques

This study focused on assessing surface water quality in the northwest part of the Egyptian Nile Delta (El-Menoufia Governorate) and evaluated water suitability for irrigation purposes using the Irrigation Water Quality Index (IWQI), Permeability Index (PI), Wilcox, United State Salinity (USSL) diagram, and Piper trilinear diagrams categories, taking into consideration various water quality parameters. The results showed that, based on the IWQI, most of the water samples (61.8%) in the investigated area fell under the no restriction water (NR) category. Furthermore, the Wilcox diagram demonstrated that most of the investigated water samples (93.6%) are categorized as doubtful water; this shows that those samples have a higher sodium content material. According to the USSL diagram, most of the water samples (70.9%) fell into the high salinity (C) and moderate sodium (S) content (C3S2) class. According to the PI index, 8.2% of the tested water samples fell into class II (suitable for irrigation) and 91.8% fell into class III (unsuitable for irrigation). Based on the Piper trilinear, the water type is Na-Cl-HCO3. According to these results, most of the water samples require more water regulations, are categorized as doubtful water that causes plants’ augmentation sensitivity if used for irrigation, and fell into the high salinity (EC) and sodium absorption ratio (SAR) magnitude, which might have negative outcomes on soil and plant health if used for irrigation, have extensive obstacles, and are improper for irrigation. Therefore, proper management practices and treatments may be vital to mitigate the adverse effects of salinity and SAR on soil and plant health in this study area. Therefore, addressing water deficiency and quality in Egypt’s northwest Nile delta is crucial for suitable irrigation purposes.

Chemical characteristics, formation mechanisms, and geological evolution processes of high-salinity coal reservoir water in the Binchang area of the southern Ordos Basin, China

The chemical characteristics of coal reservoir water are important for studying the formation and enrichment of biogenic coalbed methane (BCM). Based on geological and sampling test data, this paper studied the geochemical characteristics and formation mechanisms of high-salinity coal reservoir water (CRW) in the Jurassic Yan'an Formation of the Binchang area in the southern Ordos Basin. The results show that the TDS contents of the CRW in the Binchang area are between 7577.38 and 15,138.61 mg/L (av. 13,268.95 mg/L), which is high-salinity brackish water. The ion types of CRW are mainly Na+, Cl− and HCO3−, and the correlations between TDS and Na+ and Cl− are close to 1. The Piper trilinear diagram indicates that the evolution direction of the CRW is deep concentrated brine, and the hydrochemical type is the NaCl type. The 127I concentrations of CRW are between 285 and 484 μg/L, which are much higher than the values of 55.88 μg/L for seawater. The results of 129I dating show that the minimum age of the CRW in the study area is between 6.7 Ma and 39.97 Ma, which is much younger than the actual geological age of the Yan'an Formation. The hydrogen and oxygen isotope results show that the CRW in the study area experiences an apparent oxygen drift, indicating that the coal reservoir of the Yan'an Formation has good sealing and a long retention time for the CRW. The hydrodynamic factors show that the hydrodynamic conditions of the coal reservoir are weak, and the primary ions in the CRW originated from the dissolution of salt rocks. The main ion differentiation indices show that high-salinity coal seam water is mainly formed by evaporation, and the ion exchange between CRW and the surrounding rock and the alternating adsorption of cations in water are very weak. Evaporation and diagenesis lead to an increase in the contents of Na+, Cl− and I+ in coalbed water, which in turn leads to an increase in the total dissolved solids contents of CRW and its evolution toward concentrated brine. The genesis and evolution of the CRW in the study area are affected by the combination of the relationships among the paleoclimate, aquifers and aquifuges, and tectonic evolution processes. The CRW in the study area has experienced five evolution stages, i.e., sedimentary water and diagenetic water, high-salinity infiltration water, primary mixed water, paleoatmospheric precipitation recharge water, and secondary mixed water. The above understanding can provide a basis for studying the formation period and accumulation mechanism of BCM and provide a hydrogeological basis for water resource utilisation and pollution prevention and the control of high-salinity water.

Mechanism of Rock-Water Interaction in Kuzhithuraiyar Sub-Basin, Kanniyakumari District, Tamilnadu, India

The chemical composition of groundwater is changed by a number of hydro-geochemical processes. Rock-water interaction is the primary process that controls the ionic concentration of water, even though vaporization, concentration and dilution due to precipitation alter the chemical composition of groundwater. The chemical reactions differ depending on the preliminary composition of water, the geological formations it passes through and even how long it has been there. The 48 groundwater samples used in this study were collected, and the pH, Electrical Conductivity, Total Dissolved Solids, major cations and anions concentrations were measured. Gibb's Plot, Bivariate diagrams, Piper's Trilinear diagrams along with Saturation Indices were used to examine the mechanism of rock-water interaction in Kuzhithuraiyar Sub-Basin. Keywords: Rockwater Interaction, Bivariate Diagrams, Gibbs Plot, Pipers Trilinear Diagram, Saturation Indices

Distribution of inorganic compositions of Japanese tap water: a nationwide survey in 2019–2024

A nationwide survey of inorganic components of tap water all over Japan was conducted from 2019 to 2024. In this survey, 1564 tap water samples were collected, and an additional 194 tap water samples were collected from 33 other countries. The water samples were analyzed for 27 dissolved inorganic components, with a primary focus on the distribution of major and trace components, including Ca, Mg, K, Na, Cl−, NO3−, SO42−, total-hardness, Al, Fe, Cu, Mn, and Zn. The Japanese tap water hardness was 50.5 ± 30.2 (± 1σ SD) mg/L, classified as soft water according to the World Health Organization (WHO) classification. The average content of each major component in Japanese tap water tended to be lower than those in other countries. Furthermore, Piper trilinear diagrams were used to categorize Japanese tap water types. The dominating water types were the Ca–HCO3 and mixed types, which had a nationwide distribution. Japanese tap water generally complied with Japanese and WHO drinking water criteria, with only 1% (17/1564 sites) of the samples exceeding water quality standards. Observations of water quality changes for 2 years at three household faucets revealed that fluctuations in major components and trace metals (Al, Fe, Cu, Mn, and Zn) varied in different patterns. This suggests that the behavior of trace metal elements is influenced by local infrastructure, such as supply pipes, distinct from the variability in source water quality.

Origin and Geochemical Characterization of Groundwater from Coal Seam: A Case Study of Balasu Coalfield, Ordos Basin.

The hydrochemical characteristics of groundwater are of great significance for studying the source, development, and utilization of groundwater. This study investigated the characteristics of anions and cations, total dissolved solids (TDS), hydrochemical types, and hydrogen and oxygen isotopes of surface water and groundwater in the Balasu coalfield. By conducting experiments using inductively coupled plasma emission electron spectrometry, ion chromatography, acid-base titration, and gravimetric analysis, the characteristics of ion concentration and TDS in different aquifers were analyzed to determine the possible source of groundwater in C2 (number 2 coal seam in Yan'an Formation). The Piper trilinear diagram was used to determine the hydrochemical types of aquifers, and the source of groundwater was determined based on the stable isotope characteristics of hydrogen and oxygen. The changes in ion, TDS, hydrogen, and oxygen isotopes of surface water and groundwater were analyzed, and the groundwater differences between the two sets of coal seams were compared. The research results indicate that the groundwater in C2 (number 2 coal seam in Yan'an Formation) is caused by the original sedimentary water and the infiltration of Zhiluo Formation and A1 (strata at the top of the Yan'an Formation to number 2 coal seam). However, C4 (number 3 coal seam in Yan'an Formation) is hindered by the well-developed mudstone in A3 (bottom of number 2 coal seam to the top of number 3 coal seam), which hinders the infiltration of groundwater. The study emphasizes that the overlying strata can have a significant impact on the coal seam when the moisture content is high and there is a lack of overlap, thereby promoting changes in the moisture content of the coal seam. This study provides some insights into the safety of coal mines, especially in mining areas with a high coal seam moisture content.

Hydrogeochemical analysis of groundwater quality during the pre- monsoon season of Manipur, India

ABSTRACT The water quality index (WQI) and irrigational index for groundwater were studied in the northeastern section of the Manipur Valley in northeast India. Water samples were collected in 2022 during the pre-monsoon season. To compute the water quality index for drinking water, the basic chemical parameters of total hardness, pH, electrical conductivity, total dissolved solids, Calcium, Sodium, Iron, Magnesium, Manganese, Chlorine, and Hydrogen Carbonate were used. The assessment of bacteriological quality is also done, which is crucial for overall water quality evaluation, alongside physical and chemical analyze. For determining irrigation suitability, irrigational indices such as sodium absorption ratio, sodium percentage, and magnesium hazard were calculated. WQI, %Na+, Sodium Adsorption Ratio (SAR), magnesium hazard, permeability Index and total hardness indicate that most water samples are harmless for irrigation and drinking purpose. They have affirmative relationships indicating that these characteristics are interdependent. Approximately 25% of the Piedmont zone groundwater is found to be unfit for agricultural and drinking usage. The encrustation of gypsum, halite, and evaporation into the Disang shares accelerate the dissolution of ions in Piedmont water, resulting in quality degradation. According to Gibbs plots, Durov Scatter Plot, and Hill Piper Trilinear Diagram of water dominated the rock-weathering process, while hydrochemical facies progressed from the beginning to the intermediate stage of Chadha’s graphical representation illustrates the progression of hydrochemical processes in surface water. Therefore, proper integrated water resource management and development are required for effective water resource utilization, particularly around the Piedmont zone. In recent years, the quality of groundwater has caused a significant deal of alarm, and an increasing number of studies relating to it have been published. The geological, structural, and geomorphological features in the intermontane Imphal Valley in Manipur, India, were identified using SRTM DEM data by QGIS Software. This area has simple geology and structural elements, making it an appropriate site to evaluate the use of remote sensing and GIS tools in geological studies. To prevent a water crisis, groundwater resources must be managed sustainably. The current study also concentrated on a bibliometric examination of groundwater management and access to gauge the state of the field. A bibliometric examination of these papers may offer insight into current research and trends. We are the first to join Groundwater Quality Assessment with bibliometric analysis. This prediction, if taken into consideration strategically during the planning of preventive measures for groundwater quality can help to analyze future evaluation to a great extent.

Groundwater quality assessment in the La Mojana region of northern Colombia: implications for consumption, irrigation, and human health risks

Water quality is one of the most relevant issues related to water management, with water pollution and access to clean water for drinking and irrigation being common issues in developing countries. Groundwater is an available water source, especially where surface sources are scarce or unsuitable. In this sense, studies to improve knowledge of aquifers should be undertaken where information on groundwater resources is not available. In the current study, 50 groundwater samples were collected from rural and urban wells used by local communities for human consumption and to irrigate local crops. Several indices for drinking water and irrigation use have been used for the assessment of water quality. Conversely, the carcinogenic and noncarcinogenic human health risks due to exposure to heavy metals in the groundwater were estimated, as were the predominant hydrochemical characteristics. The groundwater water quality index (GWQI) shows values < 100 for all the samples; groundwater is recommended for drinking after disinfection. By contrast, the irrigation water quality index (IWQI) shows that 80% of groundwater samples pose a potential threat to irrigation, with restriction categories ranging from high to severe. The individual hazard quotients were < 1. However, the multielement and multipathway hazard index (HI) for children and adults were > 1, whereas As and Mn had a higher contribution to the HI. The Piper trilinear diagram shows that hydrochemical facies of Ca2+ and HCO3− are significantly dominant. By contrast, weathering of rocks and atmospheric precipitation is the dominant factors regulating the chemistry of groundwater in the aquifer system of La Mojana. Our findings indicate that there are significant potential noncarcinogenic health risks for local populations exposed to groundwater.

Evaluating arsenic contamination in northwestern Bangladesh: A GIS-Based assessment of groundwater vulnerability and human health impacts

One of the biggest environmental worries in the world today is the risk of arsenic (As) contamination in groundwater. The Atomic Absorption Spectrometer (AAS) was used in this work to assess the As content in groundwater samples from 38 shallow (27 m) tubewells in northwest Bangladesh to determine the existing situation, potential source(s), and likely health risk of As and other important water quality parameters. The range of arsenic concentrations (μgL−1) was troublesome and greater than the WHO recommended level for drinking water, ranging from 0.50 to 164 (mean ± SD: 20.22 ± 36.46). In groundwater, the concentrations of Fe, and Mn vary from 0.04 to 52.75 mgL−1 (mean ± SD: 4.23 ± 9.68), and 0.23 to 3.27 mgL−1 (mean ± SD: 1.10 ± 0.67). The obtained groundwater samples have pH values ranging from 5.9 to 7.1, which indicates a somewhat acidic to neutral character. Major cations have an average abundance that is as follows: Ca2+ > Mg2+ > Na+ > K+, while major anions have an average abundance that is as follows: HCO3− > Cl− > SO42− > NO3−; Ca2+ and HCO3− are the main cation and anion, respectively. The groundwater in the Rajarampur village was deemed unfit for drinking or irrigation based on analyses of water quality performed using the entropy water quality index. The Ca–HCO3 type of water, in which Ca2+ and HCO3− are the main positive ions and negative ions, is suggested by the Piper tri-linear diagram. It was discovered that silicate weathering regulates the hydro-geochemical activities in groundwater using a bi-variate examination of several hydro-chemical variables. Four major clusters were observed for the water sample. According to reductive dissolution processes and principal component analysis, the arsenic in groundwater is geogenic in origin. Arsenic is discharged from sediment to groundwater by reductive dissolution of FeOOH and MnOOH, as shown by the modest connection between As, Fe, and Mn. The United Nations Environmental Protection Agency's (USEPA) suggested value for probable cancer risk assessment was 10−6, however the probable cancer risk assessment found a higher value, indicating that the population in the study region was at high risk for cancer. Remedial measures for arsenic mitigation include removing arsenic from groundwater after it is extracted, searching for alternative aquifers, and implementing various water-supply technologies such as dugwells, deep tubewells, pond-sand filters, and rainwater harvesting systems.

Study on inverse geochemical modeling of hydrochemical characteristics and genesis of groundwater system in coal mine area - a case study of Longwanggou Coal Mine in Ordos Basin.

The exploitation of coal resources has disturbed the equilibrium of the original groundwater system, resulting in a perturbation of the deep groundwater dynamic conditions and hydrochemical properties. Exploring the formation of mine water chemistry under the conditions of deep coal seam mining in the Ordos Basin provides a theoretical basis for the identification of sources of mine water intrusion and the development and utilization of water resources. This paper takes Longwanggou Coal Mine as the research area, collects a total of 106 groups of water samples from the main water-filled aquifers, comprehensively uses Piper trilinear diagram, Gibbs diagram, ion correlation, ion ratio coefficient and mineral saturation index analysis, and carries out inverse geochemical modeling with PHREEQC software, so as to analyze the hydrochemical characteristics and causes of the main water-filled aquifers in deep-buried coal seams in the research area. The results show that the main hydrochemical processes in the study area are leaching and cation exchange, and the groundwater is affected by carbonate (calcite, dolomite), silicate (gypsum) and evaporite. Calculations of mineral saturation indices and PHREEQC simulations have led to the conclusion that the dissolution of rock salt and gypsum in groundwater accounts for most of the ionic action. Na+, Cl- and SO42- are mainly derived from the dissolution of rock salt and gypsum minerals, while Ca2+ and Mg2+ are mostly derived from the dissolution of dolomite and calcite. The results of the inverse geochemical modeling are consistent with the theoretical analysis.

A Comparative Analysis of Water Quality Parameters of Vembanad Lake, Kerala and Its Primary Inflows Based on the Seasonal Variations

The ecology of lakes is largely dependent on rivers. However, because research has frequently concentrated on rivers and lakes independently, the interconnectivity between them is poorly defined. During the present study, hydrochemical investigation of surface water from the Vembanad Lake and its primary inflows, Periyar, Muvattupuzha, Manimala, Meenachil, Pamba and Achenkovil were carried out. This study describes the quality and suitability of lake and river water for consumption and irrigation purposes. It also aids in determining the influence of six rivers over the Vembanad lake water quality. Total 80 samples were collected during pre-monsoon and post monsoon seasons. Various physico-chemical parameters such as Temperature, Turbidity, Total Dissolved Solids (TDS), Conductivity, pH, Alkalinity, Total Hardness, Calcium, Magnesium, Sodium, Potassium, Chloride, Bicarbonate and Sulphate were analysed. The chemical classification using Piper trilinear diagram reveals that sodium is the predominant cation in both seasons. The Water Quality Index value of the Vembanad Lake is found to be higher in the pre-monsoon season compared to the postmonsoon. Sodium hazard (Sodium Adsorption Ratio- SAR), Residual Sodium Carbonates (RSC), Sodium Percentage (Na%), Magnesium Hazard (MH), Kelly's Ratio (KR) and Permeability Index (PI) are the parameters used to identify the irrigation water quality. Based on the irrigation water quality parameters it can be concluded that water from southern portion of the lake and six inflows are suitable for irrigation purpose. The U.S. Salinity diagram indicates that the northern portion of the lake occupies the high sodium hazard zone. The water quality of the southern portion of the Vembanad Lake is chiefly controlled by its primary freshwater in flows and the northern portion by the saline water from the Arabian Sea. Keywords: Hydrogeochemistry, Water Quality, Sodium Adsorption Ratio,Vembanad Lake Kerala

Hydrogeochemical Characterization of Groundwater of Field Y, Offshore Niger Delta

Hydrogeochemical analyses were carried out on groundwater samples in order to understand the hydrochemistry of the water. The results revealed that groundwater has a high electrical conductivity, which could be as a result of more chemicals dissolved in the water and total hardness observed in all samples shows that the water isn’t hard water. Major cations and anions were identified using Piper Trilinear diagram Durov diagrams and Stiff diagrams. The parameters studied include; Ph, Electrical conductivity, Temperature, Total Suspended Solid, Salinity as Chloride, Sulphate, Total Hardness, Total Hydrocarbon Content, Nitrate, Phosphate, Alkalinity, Calcium, Sodium, Magnesium, Potassium, Iron, Zinc. The major cations are: Sodium (Na+), Potassium(K+), Calcium (Ca2+), while the major anions are: Bicarbonate (HCO3–), Carbonate(C03–), Sulfate (SO4–), and Chloride (Cl–). TDS is the major physical parameter that is dominant in the Durov diagram, although the analysis in the Durov, Piper and Stiff diagram shows that Ca2+ and HCO3–, are the major cation and anion respectively which implies that the groundwater in the study area are Ca2+ and HCO3–. It was also observed that the quality of groundwater was suitable for domestic purpose and agricultural purpose.

Groundwater Quality Assessment from a Hard Rock Terrain Kundalika River Basin, Beed District, Maharashtra, India

In the study area, the primary source of water is groundwater for the drinking and irrigation purpose. For the assessment of groundwater quality results of 48 groundwater samples in post&amp; pre monsoon season for the year 2021 &amp; 2022 were carried out from Kundalika River basin Beed District, Maharashtra. The pH values of groundwater reveal that slightly alkaline in nature. The electric conductivity varies from 290 to 2640 µS/cm; the total dissolved solids (TDS), alkalinity, total hardness, calcium, magnesium, sodium, potassium, chloride measured. Most of TDS values of groundwater samples less 1000 mg/l indicate suitable for drinking and irrigation purpose. In the piper trilinear diagram, it is observed that 80% groundwater samples in post monsoon season 2021 and pre monsoon season 2022 fall in the Ca-HCO3 region and remaining 20 % groundwater samples of both season falls in mixed type such as Ca-Na-HCO3 region. According to Wilcox’s diagram all groundwater samples are good for irrigation purpose except 2 % samples of post monsoon season 2021 and pre monsoon season 2022 are doubtful to unsuitable area for irrigation use. Various water quality indices like: EC, SAR, SSP, RSC, MAR and KR shows that most water samples are suitable for irrigation uses. U. S. Salinity Laboratory Diagram shows that all the groundwater samples belongs to C2-S1,C3-S1,C3-S1 and C3-S2 category suggesting a medium to high salinity and alkalinity; this can be good for irrigation purpose, with few exceptions under specific conditions.

Hydrogeochemical study of groundwater in arid and semi-arid regions of the Infracenomanian aquifers (Cretaceous Errachidia basin, Southeastern Morocco). Using hydrochemical modeling and multivariate statistical analysis

Groundwater in the Cretaceous Errachidia basin, located in the southern part of Morocco, is crucial in supporting the region's main economic activities, such as farming. This arid region faces multiple challenges, including an average annual rainfall of less than 80 mm/year, intense agricultural activities, high evaporation, and extremely high evapotranspiration rates up to 1580 mm/year. Therefore, the hydrogeochemical study focuses on the Infracenomanian aquifers in the Cretaceous Errachidia basin. The goal is to evaluate the sustainable use of saline lands and brackish water, particularly assessing water resources and sustainable socioeconomic development in southeastern Morocco. In June 2021, 20 samples were collected and analyzed for pH, electrical conductivity (EC), total dissolved solids (TDS) and major ions. The hydrogeochemical parameters were analyzed using multivariate statistical methods. Statistical techniques such as Piper's trilinear diagram analysis of hydrochemistry types, Gibbs diagram analysis, The HFE diagram and ion correlation analysis were used to examine the origins of the main ions in the groundwater and to determine the source of the salinization processes in the groundwater.The findings revealed a strong positive correlation between TDS and the spatial distribution of major ions (Na+, Ca2+, Mg2+, Cl−) and EC, revealing high mineralization in the study area. The main cations in groundwater are Na+ and Ca2+, while the main anions are Cl−. The elevated concentrations of Cl− and Na+ are due to the evapotranspiration of irrigation water. Furthermore, the hydrochemical facies types are predominantly sodium chloride (Na–Cl), followed by calcium chloride (Ca–Cl) and a mix of calcium and magnesium chloride facies (Ca–Mg–Cl). These analyses indicate that the hydrochemistry of groundwater in the study area is primarily influenced by water-rock interactions, such as the dissolution of sedimentary rocks, soil leaching through gravity irrigation, and evaporation in the region. Moreover, the analysis using the Gibbs diagram indicates that evaporation is the primary hydrogeochemical process that shapes the chemical composition of the groundwater in the area under study.

Hydrochemical Appraisal and Driving Forces of Groundwater Quality and Potential Health Risks of Nitrate in Typical Agricultural Area of Southwestern China

Elucidating the hydrogeochemical processes and quality assessment of groundwater holds significant importance for its sustainable development. In this paper, 53 groundwater samples were collected from a typical agricultural area in the northeastern Chongqing municipality in SW China. The integration of multivariate statistical analysis, ion ratio analysis, geomodelling analysis, the entropy water quality index, health risks assessment, and sensitivity analysis was carried out to explore the hydrochemical processes and quality assessment of groundwater in this study. The statistical results reveal that the cationic concentrations followed the order of Ca2+ &gt; Mg2+ &gt; Na+ &gt; K+, while the anionic components were in the order of HCO3− &gt; SO42− &gt; NO3− &gt; Cl−. Based on the Piper trilinear diagram, the hydrochemical types were shown as Ca-HCO3 and Ca-Mg-HCO3 types. Hierarchical cluster analysis indicated that the groundwater samples could be categorized into three groups. The hydrochemical compositions were primarily influenced by water–rock interactions (e.g., carbonate dissolution and silicate weathering). In terms of irrigation suitability, the sodium adsorption ratios (SARs) ranged from 0.05 to 1.82, and the electrical conductivity (EC) varied from 116 to 1094 μs/cm, indicating that most groundwater samples were suitable for irrigation. The entropy-weighted water quality index ranged from 15 to 94, suggesting that the groundwater samples were suitable for drinking purposes. Non-carcinogenic human health risks followed the order of children &gt; adult females &gt; adult males, within the average values of 0.30, 0.21, and 0.18, respectively. Sensitivity analysis showed that the parameters had the weight order of NO3 &gt; body weight (BW) &gt; ingestion rate (IR) &gt; exposure frequency (EF). Hence, we recommend prioritizing the management of areas with high salinity levels, while avoiding the excessive use of nitrogen fertilizers, raising awareness among local residents about safe groundwater, and providing robust support for the sustainable development of groundwater in typical agricultural areas.

Hydrogeochemical Characteristics and Genetic Analysis of Karst Groundwater in the Fengfeng Mining Area

The karst water resources in the Fengfeng mining area are an important water supply source in the region. In recent years, due to the influence of external environment changes, the hydrochemical environment of karst groundwater has changed. In order to scientifically understand karst groundwater and rationally develop groundwater resources, it is necessary to study the hydrochemical characteristics and evolution laws of groundwater in this area. In this study, major elements in karst groundwater of different years and hydrogen and oxygen isotopes in 2022 were analyzed. The hydrochemical types of the study area were analyzed by using the Piper trilinear diagram drawn with Aquachem10.0 software. D and 18O were used to analyze the source and elevation of groundwater recharge. Origin software was used to draw Gibbs diagrams, three-terminal diagrams, ion ratio diagrams, etc., to analyze the influencing factors of groundwater chemical components. The research results show that: (1) The groundwater in the study area is mainly HCO3-Ca(Mg) type water; (2) The main supply source of karst water in the study area is atmospheric precipitation, and the supply elevation ranges from 1166.7 to 1533.3 m; (3) Most of the karst groundwater in the study area is affected by the dissolution of carbonate and silicate rocks; (4) With the influence of human activities, mainly agricultural activities, with the passage of time, the impact of industrial activities on groundwater has been weakening.

Interaction between Groundwater and Surface Water in the Qujiang River Basin in China: Evidence from Chemical Isotope Measurements

The Qujiang River Basin is a significant water system located in Zhejiang Province, China, that serves as a primary water source for Quzhou City. For this research, we collected and examined water samples from the Qujiang River Basin. In this study, we collected and analyzed water samples from the Qujiang River Basin and employed a combination of methods, including water balance analysis; Piper trilinear diagram; Gibbs diagram; and environmental tracer techniques, such as hydrochemical and isotopic analysis. These techniques helped us to analyze the spatial distribution patterns and evolutionary trends of surface water and groundwater hydrochemistry, along with the stable isotopes of hydrogen and oxygen, as well as to determine the sources of surface water and groundwater by calculating the conversion ratio between surface water and groundwater. (1) The findings of our study indicate that the primary hydrochemical types in the study area are Ca-HCO3 and Ca-HCO3·Cl, with the ion composition of water primarily influenced by rock weathering and precipitation. (2) Similar spatial variations in hydrochemical indicators were observed between surface water and groundwater in the study area, with frequent transitions between the two. (3) The hydrogen and oxygen isotope content increases downstream, signifying that both groundwater and surface water in the study area are replenished by atmospheric precipitation, as supported by the relationship between hydrogen and oxygen isotopes and the meteoric water line. (4) We determined that groundwater predominantly replenishes surface water in the upstream area. The average contribution rate of groundwater to surface water is 19.67%, with an annual average recharge volume of 1.23 × 106 m3. Midstream and downstream, surface water mainly recharges groundwater, with an average contribution rate of 22.77% and an annual average recharge volume of 1.59 × 106 m3.