Pillar-like Structures Research Articles

Irradiated interfaces in the Ara OB1, Carina, Eagle Nebula, and Cyg OB2 massive star formation regions

Regions of massive star formation offer some of the best and most easily-observed examples of radiation hydrodynamics. Boundaries where fully-ionized H II regions transition to neutral/molecular photodissociation regions (PDRs) are of particular interest because marked temperature and density contrasts across the boundaries lead to evaporative flows and fluid dynamical instabilities that can evolve into spectacular pillar-like structures. When detached from their parent clouds, pillars become ionized globules that often harbor one or more young stars. H2 molecules at the interface between a PDR and an H II region absorb ultraviolet light from massive stars, and the resulting fluoresced infrared emission lines are an ideal way to trace this boundary independent of obscuring dust. This paper presents H2 images of four regions of massive star formation that illustrate different types of PDR boundaries. The Ara OB1 star formation region contains a striking long wall that has several wavy structures which are present in H2, but the emission is not particularly bright because the ambient UV fluxes are relatively low. In contrast, the Carina star formation region shows strong H2 fluorescence both along curved walls and at the edges of spectacular pillars that in some cases have become detached from their parent clouds. The less-spectacular but more well-known Eagle Nebula has two regions that have strong fluorescence in addition to its pillars. While somewhat older than the other regions, Cyg OB2 has the highest number of massive stars of the regions surveyed and contains many isolated, fluoresced globules that have head–tail morphologies which point towards the sources of ionizing radiation. These images provide a collection of potential astrophysical analogs that may relate to ablated interfaces observed in laser experiments of radiation hydrodynamics.

Light harvesting analysis of a nano‐cylinder structure on crystalline silicon using the Mie scattering model

In this study, nano spheres of different diameters (d=200nm, 300nm, and 400nm) were applied in nano-sphere lithography with dry etching to construct nano-cylinder structures on the surface of crystalline silicon wafers. The structure was then bombarded by a Kaufman-type directive ion source to shape and modify the surface topography as pillar-like or cone-like structures. Finally, an AR-coating layer was deposited on the surface of the nano-cylinder structure. When the size of the nano-cylinder structure approached the wavelength of light, Mie scattering analysis was utilized to describe the optical properties formed by the structures. The results showed that the haze parameters could reach 87.8% in the visible region and 91.1% in the infra-red region.

DNA Pillars Constructed from an i‐Motif Stem and Duplex Branches

At an acidic pH, cytosine-rich DNA strands can form i-motif tetramers. Pillar-like DNA structures are self-assembled with such i-motifs as the central stems. The central stem has some overhanging structures that can enable hybridization with complementary units by Watson-Crick pairing and, thus, multiple i-motifs can join to form the pillar.

3D simulations of pillar formation around HII regions: the importance of shock curvature

Radiative feedback from massive stars is a key process to understand how HII regions may enhance or inhibit star formation in pillars and globules at the interface with molecular clouds. We aim to contribute to model the interactions between ionization and gas clouds to better understand the processes at work. We study in detail the impact of modulations on the cloud-HII region interface and density modulations inside the cloud. We run three-dimensional hydrodynamical simulations based on Euler equations coupled with gravity using the HERACLES code. We implement a method to solve ionization/recombination equations and we take into account typical heating and cooling processes at work in the interstellar medium and due to ionization/recombination physics. UV radiation creates a dense shell compressed between an ionization front and a shock ahead. Interface modulations produce a curved shock that collapses on itself leading to stable growing pillar-like structures. The narrower the initial interface modulation, the longer the resulting pillar. We interpret pillars resulting from density modulations in terms of the ability of these density modula- tions to curve the shock ahead the ionization front. The shock curvature is a key process to understand the formation of structures at the edge of HII regions. Interface and density modulations at the edge of the cloud have a direct impact on the morphology of the dense shell during its formation. Deeper in the cloud, structures have less influence due to the high densities reached by the shell during its expansion.

Single-Step Direct Fabrication of Pillar-on-Pore Hybrid Nanostructures in Anodizing Aluminum for Superior Superhydrophobic Efficiency

Conventional electrochemical anodizing processes of metals such as aluminum typically produce planar and homogeneous nanopore structures. If hydrophobically treated, such 2D planar and interconnected pore structures typically result in lower contact angle and larger contact angle hysteresis than 3D disconnected pillar structures and, hence, exhibit inferior superhydrophobic efficiency. In this study, we demonstrate for the first time that the anodizing parameters can be engineered to design novel pillar-on-pore (POP) hybrid nanostructures directly in a simple one-step fabrication process so that superior surface superhydrophobicity can also be realized effectively from the electrochemical anodization process. On the basis of the characteristic of forming a self-ordered porous morphology in a hexagonal array, the modulation of anodizing voltage and duration enabled the formulation of the hybrid-type nanostructures having controlled pillar morphology on top of a porous layer in both mild and hard anodization modes. The hybrid nanostructures of the anodized metal oxide layer initially enhanced the surface hydrophilicity significantly (i.e., superhydrophilic). However, after a hydrophobic monolayer coating, such hybrid nanostructures then showed superior superhydrophobic nonwetting properties not attainable by the plain nanoporous surfaces produced by conventional anodization conditions. The well-regulated anodization process suggests that electrochemical anodizing can expand its usefulness and efficacy to render various metallic substrates with great superhydrophilicity or -hydrophobicity by directly realizing pillar-like structures on top of a self-ordered nanoporous array through a simple one-step fabrication procedure.

Plasma modified flexible bucky paper as an efficient counter electrode in dye sensitized solar cells

Platinum (Pt) -free counter electrodes (CEs) for dye sensitized solar cells (DSSCs) were developed using freestanding flexible single wall carbon nanotube (SWNT) films called bucky papers (BPs). BP was irradiated with microwave plasma, created using a mixture of Ar (1%) and H2 (99%) gases, for 2 h. Raman scattering measurements revealed that no significant defects were created in the SWNTs as a result of the treatment. Plasma-treated BP (P-BP) developed vertically oriented, micron sized, pillar-like structures on its surface, while its base was still a dense random mesh of SWNTs. This unique flexible film had a larger accessible surface area and better catalytic properties. The plasma treatment improved the efficiency of BP-based DSSCs from 2.44% to 4.02%, which is comparable to Pt thin film (4.08%). The P-BP based solar cell operated with an open circuit voltage of 0.73 V and a fill factor of 0.70. It also had much higher efficiencies than films of randomly oriented plasma treated SWNTs. Using electrochemical impedance spectroscopy, the charge transfer resistances of P-BP and Pt were found to be 1.46 and 1.73 Ω cm2, respectively.

Synthetic observations of simulated Pillars of Creation

We present synthetic observations of star-forming interstellar medium structures obtained by hydrodynamic calculations of a turbulent box under the influence of an ionising radiation field. The morphological appearance of the pillar-like structures in optical emission lines is found to be very similar to observations of nearby star forming regions. We calculate line profiles as a function of position along the pillars for collisionally excited [OIII]5007, [NII]6584 and [SII]6717, which show typical FWHM of 2--4 km/s. Spatially resolved emission line diagnostic diagrams are also presented which show values in general agreement with observations of similar regions. The diagrams, however, also highlight significant spatial variations in the line ratios, including values that would be classically interpreted as shocked regions based on one-dimensional photoionisation calculations. These values tend to be instead the result of lines of sight intersecting which intersect for large portions of their lenghts the ionised-to-neutral transition regions in the gas. We caution therefore against a straightforward application of classical diagnostic diagrams and one--dimensional photoionisation calculations to spatially resolved observations of complex three-dimensional star forming regions.

Protein LidA from Legionella is a Rab GTPase supereffector

The causative agent of Legionnaires disease, Legionella pneumophila, injects several hundred proteins into the cell it infects, many of which interfere with or exploit vesicular transport processes. One of these proteins, LidA, has been described as a Rab effector (i.e., a molecule that interacts preferentially with the GTP-bound form of Rab). We describe here the structure and biochemistry of a complex between the Rab-binding domain of LidA and active Rab8a. LidA displays structural peculiarities in binding to Rab8a, forming a considerably extended interface in comparison to known mammalian Rab effectors, and involving regions of the GTPase that are not seen in other Rab:effector complexes. In keeping with this extended binding interface, which involves four α-helices and two pillar-like structures of LidA, the stability of LidA-Rab interactions is dramatically greater than for other such complexes. For Rab1b and Rab8a, these affinities are extraordinarily high, but for the more weakly bound Rab6a, K(d) values of 4 nM for the inactive and 30 pM for the active form were found. Rab1b and Rab8a appear to bind LidA with K(d) values in the low picomolar range, making LidA a Rab supereffector.

Photoinduced Self-Structured Surface Pattern on a Molecular Azo Glass Film: Structure–Property Relationship and Wavelength Correlation

In this study, three series of star-shaped molecular azo glasses were synthesized, and self-structured surface pattern formation on the azo compound films was studied by laser irradiation at different wavelengths. The molecular azo glasses were synthesized from three core precursors (Tr-AN, Tr-35AN, Tr-H35AN), which were prepared by ring-opening reactions between 1,3,5-triglycidyl isocyanurate and corresponding aniline derivatives. The star-shaped azo compounds were obtained through azo-coupling reactions between the core precursors and diazonium salts of 4-chloroaniline, 4-aminobenzonitrile, and 4-nitroaniline, respectively. By using the two-step reaction scheme, three series of azo compounds with different structures were obtained. The core precursors and azo compounds were characterized by using (1)H NMR, FT-IR, UV-vis, mass spectrometry, and thermal analyses. The self-structured surface pattern formation on films of the azo compounds was studied by irradiating the azo compound films with a normal-incident laser beam at different wavelengths (488, 532, and 589 nm). The results show that the photoinduced surface pattern formation behavior is closely related to the structure of the azo compounds, excitation wavelength, and light polarization conditions. The absorption band position of the π-π* transition is mainly determined by the electron-withdrawing groups on the azo chromophores. When the excitation wavelength is between λ(max) and the band tail at the longer wavelength side, the self-structured surface patterns can be more efficiently induced to form on the films. The 3,5-dimethyl substitution on azo chromophores inhibits the surface pattern formation for certain excitation wavelengths. Increasing molecular interaction also shows an effect of restraining the surface pattern formation. The irradiations with linearly and circularly polarized light cause significant differences in the alignment manner of the pillarlike structures and their saturated height.

Porous Biphasic Calcium Phosphate Scaffolds from Cuttlefish Bone

Cuttlefish bone is an inexpensive, readily available, morphologically complex natural material. It has an open structure, consisting of layers separated by pillar-like structures made of calcium carbonate. In this study natural bones from cuttlefish were successfully converted into porous biphasic calcium phosphate (BCP) scaffolds with a range of hydroxyapatite and β-tricalcium phosphate compositions. The process involved reaction with solutions of phosphoric acid (H3PO4) and 2-propanol, followed by heat treatment at high temperatures (up to 1300°C) in air. The crystalline composition of the BCP scaffolds could be controlled by varying the concentration of the H3PO4 in solution, and the duration of reaction time at room temperature. The original microstructure of the cuttlefish bone was preserved in the BCP scaffolds which featured >90% interconnected porosity. The structure consisted of continuous macroporous channels with smallest measured cross-sectional openings of 400 μm × 100 μm size. The BCP scaffolds prepared with 16 wt% H3PO4 solution had a measured compressive strength of 2.38 ± 0.24 MPa, with a characteristic noncatastrophic failure behavior. The ability to tailor the composition of these BCP scaffolds allows development of implants with controlled biodegradation, while their superior mechanical and microstructural properties stand to benefit efficient osteointegration and osteoinduction.

Propane combustion in non-adiabatic microreactors: 2. Flow configuration in posted microreactors

The aim of this paper is to analyze cross-flow operation in a microreactor with posted catalytic inserts for Pt-catalyzed propane combustion under fuel-lean conditions. The insert consists of 150 posts arranged in-line in six rows. The posts are static pillar-like structures in the flow channel, which act as static mixers and provide higher catalytic surface area. Computational Fluid Dynamics (CFD) simulations are used to compare the post microreactors for axial- and cross-flow configurations. In cross-flow case, where the bulk flow is in transverse direction across the six rows of posts, significant flow mal-distribution is observed. Tapering of the inner walls of the microreactor solid structure, at an angle of 5.766°, is proposed for obtaining more uniform flow distribution. For the cross-flow microreactors with tapered inner walls (referred to as “tapered-post”), the flow distribution becomes more uniform as the flow rate is decreased. The axial- and tapered-post microreactors show similar propane conversion for a wide range of operating conditions. Tapered-post microreactors have lower pressure drop and more uniform wall temperatures because the reaction zone is spread over the entire length of the catalytic insert. We also show that tapered-post microreactors have lower heat losses, and therefore are more stable towards device extinction. Consequently, the primary advantages of tapered-post microreactors are better thermal management and ability to operate at more fuel-lean conditions.

Propane combustion in non-adiabatic microreactors: 1. Comparison of channel and posted catalytic inserts

The reduction in size of catalytic microreactors results in high heat and mass transfer rates and a significant increase in the surface area to volume ratio. A further increase in the catalytic surface area can be achieved in a scaled-down version of fixed bed reactors. Since micro-fixed bed reactors are often deemed impractical due to their large pressure drops, one could use precisely structured inserts to increase the surface area, enhance mixing and manipulate the flow distribution. Catalytic propane combustion in microreactors with multi-channel and posted inserts, which consist of multiple static structures (walls separating various channels and pillar-like structures, respectively) in the flow channel of a microreactor, is considered in this series of two papers. In this first paper, we present numerical comparison of multi-channel and posted catalytic inserts for non-adiabatic self-sustained propane combustion. The inserts are oriented axially along the flow direction. We show that channel and post microreactors have similar performance for low thermal conductivity of the inserts. The in-line arrangement of the posted structures is preferred over a staggered arrangement because the former provides higher propane conversion and more stable combustion. The role of thermal conductivity of the microreactor wall structure and the catalytic inserts is investigated. The thermal conductivity of the microreactor structure affects the performance of the posts but not the channels; this is contrary to the effect of catalyst insert thermal conductivity where it is vice-versa. The channel microreactor is more stable towards high flow-rate blowout limit, whereas the post microreactor is significantly more stable at the lower flow-rate extinction limit. This results in stable operation of the post microreactor under more fuel-lean mixtures than the channel microreactor.

DETAILED NUMERICAL SIMULATIONS ON THE FORMATION OF PILLARS AROUND H II REGIONS

We study the structural evolution of turbulent molecular clouds under the influence of ionizing radiation emitted from a nearby massive star by performing a high resolution parameter study with the iVINE code. The temperature is taken to be 10K or 100K, the mean number density is either 100cm^3 or 300cm^3. Besides, the turbulence is varied between Mach 1.5 and Mach 12.5 and the main driving scale between 1pc and 8pc. We vary the ionizing flux by an order of magnitude. In our simulations the ionizing radiation enhances the initial turbulent density distribution and thus leads to the formation of pillar-like structures observed adjacent to HII regions in a natural way. Gravitational collapse occurs regularly at the tips of the structures. We find a clear correlation between the initial state of the turbulent cold cloud and the final morphology and physical properties of the structures formed. The most favorable regime for the formation of pillars is Mach 4-10. Structures and therefore stars only form if the initial density contrast between the high density unionized gas and the gas that is going to be ionized is lower than the temperature contrast between the hot and the cold gas. The density of the resulting pillars is determined by a pressure equilibrium between the hot and the cold gas. A thorough analysis of the simulations shows that the complex kinematical and geometrical structure of the formed elongated filaments reflects that of observed pillars to an impressive level of detail. In addition, we find that the observed line-of sight velocities allow for a distinct determination of different formation mechanisms. Comparing the current simulations to previous results and recent observations we conclude that e.g. the pillars of creation in M16 formed by the mechanism proposed here and not by the radiation driven implosion of pre-existing clumps.

Effects of Surface Properties of Different Substrates on Fine Structure of Plasma-Polymerized SiOCH Films Prepared from Hexamethyldisiloxane (HMDSO)

In this study, Doppler broadening energy spectroscopy (DBES) combined with slow positron beam was used to discuss the effect of substrate types on the fine structure of a plasma-polymerized SiOCH layer as a function of depth. From the SEM pictures, the SiOCH films formed on different substrates showed hemispherical macrostructures, and the deposition rate was dependent on the mean pore size. It appears that the morphology of the plasma-polymerized SiOCH films was associated with the porosity-related characteristics of the substrate such as the size/shape of pores. As deposited on the MCE-022 substrate (mixed cellulose esters membrane with a mean pore size of 0.22 μm) with a nodular structure, the SiOCH films had pillar-like structures and high gas permeabilities. DBES results showed that the SiOCH films deposited on different substrates were composed of three layers: the SiOCH bulk layer, the transition layer, and the substrate. It was observed that the microstructure of the SiOCH films was affected layer by layer; a higher surface pore size in the substrates induced thicker transition layers with higher microporosities and led to thinner bulk layers having higher S parameter values during the plasma polymerization. It was also observed that the change in O(2)/N(2) selectivity was consistent with the DBES analysis results. The gas separation performance and DBES analysis results agreed with each other.

Impact of water drops onto the junction of a hydrophobic texture and a hydrophilic smooth surface

Wettability gradient surfaces play a significant role in control and manipulation of liquid drops. The present work deals with the analysis of water drops impacting onto the junction line between hydrophobic texture and hydrophilic smooth portions of a dual-textured substrate made using stainless steel material. The hydrophobic textured portion of the substrate comprised of unidirectional parallel groove-like and pillar-like structures of uniform dimensions. A high-speed video camera recorded the spreading and receding dynamics of impacting drops. The drop impact dynamics during the early inertia driven impact regime remains unaffected by the dual-texture feature of the substrate. A larger retraction speed of drop liquid observed on the hydrophobic portion of the substrate during the impact of low velocity drops makes the drop liquid on the higher wettability portion to advance further (secondary drop spreading). The net horizontal drop velocity towards the hydrophilic portion of the dual-textured substrate decreases with increasing drop impact velocity. The available experimental results suggest that the movement of bulk drop liquid away from the impact point during drop impact on the dual-textured substrate is larger for the impact of low inertia drops.

Observing the Biofilm Matrix ofStaphylococcus epidermidisATCC 35984 Grown Using the CDC Biofilm Reactor

Bacteria flourish in nearly every environment on earth. Contributing to their ability to grow in many esoteric locations is their development into a biofilm structure. In an effort to more accurately model the growth environment of biofilms in nature, a Center for Disease Control and Prevention (CDC) biofilm reactor has been developed that mimics nature-like shear forces and renewable nutrient sources. To date, there has been no confirmation by scanning electron microscopy (SEM) that mature biofilms develop on a surface when grown using the CDC biofilm reactor. Three different SEM methods were used to collect images of Staphylococcus epidermidis ATCC 35984 that was to be grown using the CDC biofilm reactor. In addition, two different fixative techniques were used in each of the imaging methods. Results indicated that after 48 hours of growth in the reactor, S. epidermidis ATCC 35984 does produce a significant network of matrix components and 3D mushroom- or pillar-like structures with signs of water channel development. In conclusion, S. epidermidis ATCC 35984 grown using the CDC biofilm reactor does appear to display signs of mature biofilm development. These results could be important for studies wherein mature biofilms are needed for in vitro and/or in vivo applications.

YOUNG STELLAR OBJECTS AND TRIGGERED STAR FORMATION IN THE VULPECULA OB ASSOCIATION

The Vulpecula OB association, VulOB1, is a region of active star formation located in the Galactic plane at 2.3 kpc from the Sun. Previous studies suggest that sequential star formation is propagating along this 100 pc long molecular complex. In this paper, we use Spitzer MIPSGAL and GLIMPSE data to reconstruct the star formation history of VulOB1, and search for signatures of past triggering events. We make a census of Young Stellar Objects (YSO) in VulOB1 based on IR color and magnitude criteria, and we rely on the properties and nature of these YSOs to trace recent episodes of massive star formation. We find 856 YSO candidates, and show that the evolutionary stage of the YSO population in VulOB1 is rather homogeneous - ruling out the scenario of propagating star formation. We estimate the current star formation efficiency to be ~8 %. We also report the discovery of a dozen pillar-like structures, which are confirmed to be sites of small scale triggered star formation.

Slip Sequences during Tensile Deformation of Palladium Nanocontacts

The thinning dynamics of palladium (Pd) nanocontacts (NCs) during tensile deformation was observed in situ at room temperature by transmission electron microscopy. Simultaneously, force acting on the NCs and conductance of them were measured. Slip sequences occurred in the most constriction region of the NCs, resulting in thinning through a series of the formation of, first, pillar-like structures of several nanometers width and then single-atom wires. The critical shear stress for the slip events was estimated.

From Hydrophilic to Superhydrophobic: Fabrication of Micrometer-Sized Nail-Head-Shaped Pillars in Diamond

The hydrophobicity of microtextured diamond surfaces was investigated. Pillarlike structures were fabricated in both nanocrystalline diamond and microcrystalline diamond. By changing the surface termination of the textured diamond surface, we could switch between superhydrophobic surfaces and hydrophilic surfaces. Examined terminations were hydrogen, fluorine, and oxygen. To evaluate the wetting properties, advancing and receding contact angles were measured. By designing pillars with a wide diamond top on a narrower silicon stem, superhydrophobicity was achieved even when the advancing contact angle on the unstructured diamond surface was below 70 degrees. The possibility to manipulate the hydrophobicity and the Fresnel reflection simultaneously at an infrared wavelength is also demonstrated.

Through-mask anodization of titania dot- and pillar-like nanostructures on bulk Tisubstrates using a nanoporous anodic alumina mask

Nanosized surface topography on an implant material has the capability of stimulating theacceptance of the material in its host surrounding. Fine-tuning of nanotopographyfeature size has been shown to trigger differentiation of mesenchymal stem cellsinto bone cells in vitro. For this purpose we have created well defined nanosizedtitania dot- and pillar-like structures on mechanically polished Ti substrates using athrough-mask anodization technique with an anodic porous alumina template. Theanodization technique allowed the titania structure dimensions to be precisely tunedin the range 15–140 nm in a single electrolyte system. The fabricated surfacesserve as good model surfaces for precise studies of in vitro cell behaviour. Thethrough-mask anodization technique was used directly on bulk Ti surfaces, thusdemonstrating a potential application for patterning of actual Ti implant surfaces.