Dielectric structures containing ferroelectret layers are commonly investigated because of their high piezoelectric activity. The mechanical properties of electret–gas-only ferroelectrets are limited; therefore, new layered structures containing nonelectret materials are explored. Separation of requirements related to the mechanical and electrical properties of particular layers is the latest concept to achieve structures with a higher piezoelectric response. This article presents an exemplary dielectric-layered structure exhibiting piezoelectric activity, where 3-D printed polylactic acid (PLA) mesh layer, polypropylene (PP) electret foil, and elastomer top layer are applied. The piezoelectric coefficient <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${d}_{33}$ </tex-math></inline-formula> , measured under static conditions, is found to be at the level of 300 pC <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\cdot \text{N}$ </tex-math></inline-formula> <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">−1</sup> . The simplified model of the structure is proposed to allow for the determination of the piezoelectric coefficient <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${d}_{33}$ </tex-math></inline-formula> . Due to the presented model, an improvement of the piezoelectric response is possible by optimizing the electrical properties and geometry of the particular layers. A comparison of calculated and measured values of the <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${d}_{33}$ </tex-math></inline-formula> coefficient confirms the validity of the proposed model. The influence of the poling voltage and the static pressure on the structure piezoelectric properties is experimentally examined.