The 0.55Pb(Ni1/3Nb2/3)O3–0.45Pb(Zr0.3Ti0.7)O3 (0.55PNN-0.45PZT) ceramics were prepared by conventional solid state reactions. The effects of calcining temperature on the particle size and piezoelectric properties of 0.55PNN-0.45PZT piezoelectric ceramics were investigated. The particle size and crystallinity of 0.55PNN-0.45PZT ceramic powders are influenced by calcining temperature, and therefore the microstructure and final piezoelectric properties of 0.55PNN-0.45PZT are different. The highest piezoelectric properties (d 33 = 720pC/N, k p = 0.55. ϵ r = 6255) were observed at the sample fabricated from the powder calcined at 1100°C, which was attributed to the improved crystallinity and the homogeneous distribution of the particles.