We prove the uniqueness of Riemann solutions in the class of entropy solutions in L ∞ ∩ B V l o c L^\infty \cap BV_{loc} for the 3 × 3 3\times 3 system of compressible Euler equations, under usual assumptions on the equation of state for the pressure which imply strict hyperbolicity of the system and genuine nonlinearity of the first and third characteristic families. In particular, if the Riemann solutions consist of at most rarefaction waves and contact discontinuities, we show the global L 2 L^2 -stability of the Riemann solutions even in the class of entropy solutions in L ∞ L^\infty with arbitrarily large oscillation for the 3 × 3 3\times 3 system. We apply our framework established earlier to show that the uniqueness of Riemann solutions implies their inviscid asymptotic stability under L 1 L^1 perturbation of the Riemann initial data, as long as the corresponding solutions are in L ∞ L^\infty and have local bounded total variation satisfying a natural condition on its growth with time. No specific reference to any particular method for constructing the entropy solutions is made. Our uniqueness result for Riemann solutions can easily be extended to entropy solutions U ( x , t ) U(x,t) , piecewise Lipschitz in x x , for any t > 0 t>0 .