Pickering Emulsions Research Articles

Dynamic Assembly of Microgels and Polymers at Non-Aqueous Liquid/Liquid Interfaces.

Particle assembly at liquid-liquid interfaces presents a promising bottom-up strategy for creating supramolecular materials with advanced functionalities. However, the significantly lower interfacial tension observed in immiscible organic phases compared to traditional oil-water systems has hindered the effective adsorption and assembly of particles at oil-oil interfaces. In this work, a versatile and effective strategy is presented that utilizes the assembly and jamming of microgels and polymer ligands at non-aqueous liquid-liquid interfaces to create non-aqueous Pickering emulsions and reconfigurable droplet networks. The resulting microgel-polymer complexes form an asymmetric interfacial bilayer with high surface coverage, which effectively minimizes interfacial energy and improves interfacial elasticity. Through a combination of systematic interfacial measurements and molecular dynamics simulations, the underlying mechanisms governing interfacial self-assembly are elucidated. Notably, the stimuli-responsive nature of the microgel-polymer complexes allows for precise control over the interfacial assembly and disassembly by introducing competitive molecules. Furthermore, it is demonstrated that these non-aqueous Pickering emulsions serve as excellent templates for the fabrication of heterogeneous organogels and microgel-based colloidosomes through both covalent and non-covalent crosslinking strategies. This work underscores the potential of non-aqueous interfaces in advancing materials science and opens new avenues for developing multifunctional materials.

Oil-in-water Pickering emulsions with Buriti vegetable oil stabilized with cellulose nanofibrils: Preparation, stability and antimicrobial properties.

Mauritia flexuosa (Buriti) vegetable oil (OV) has attracted technological interest in various sectors, including pharmaceuticals, food, and beverages, because of its excellent antioxidant activity. The active OV components are fatty compounds, and stability is required for proper application. In this work, we investigated Pickering emulsions based on v in water stabilized by cellulose nanofibrils (CNF). CNF is sustainable, economically viable, and environmentally friendly, and it is suitable for developing products in an eco-friendly way. The factorial design of experiments (DoE) indicates that the amount of CNF and the homogenization time significantly affect the emulsion, preventing coalescence over 30 days. Fourier-transform Raman spectroscopy (FT-Raman) and Fourier-transform infrared spectroscopy (FTIR) show that CNF stabilizes the OV droplets through induced dipole-dipole interactions and hydrogen bonds. Rheological analysis was relevant to the relationship between internal microstructure strength and viscous flow behavior of the emulsions. A novel approach enabled the identification of the CNF stabilization mechanism in the emulsion system via fluorescence microscopy. Diameter distribution measurements and steady-state rheological tests indicate that the emulsions have good stability at room temperature and suitable steady-state viscosity for food applications and beverage products as they show pronounced shear thinning behavior for cream and lotion skin care products.

Small Ligand-Involved Pickering Droplet Interface Controls Reaction Selectivity of Metal Catalysts.

Developing efficient methods to improve catalytic selectivity, particularly without sacrificing catalytic activity, is of paramount significance for chemical synthesis. In this work, we report a small ligand-involved Pickering droplet interface as a brand-new strategy to effectively regulate reaction selectivity of metal catalysts. It was found that small ligands such as polar arenes could engineer the surface structure of Pt catalysts that were assembled at Pickering droplet interfaces. Due to the strong hydrogen-bonding interactions with water, the polar arenes preferentially adsorbed with the water adlayer that covered Pt surfaces, forming water-mediated metal-organic interfaces on the Pickering emulsion droplets. Such an interface system displayed a significantly enhanced p-vinylaniline selectivity from 8.7 to 94.2% with an unreduced conversion in p-nitrostyrene hydrogenation. The selectivity was found to follow a negatively linear correlation with the bond length of the interfacial hydrogen bonds. Theoretical calculations revealed that the small arene ligands could closely array at the interface, which modulated the adsorption patterns of reactant/product molecules to prevent the C═C group from approaching Pt surfaces without suppressing their accessibility toward reactant molecules. Such a remarkable interfacial steric effect contributed to the efficient control of the hydrogenation selectivity. Our work provides an innovative strategy to modulate the surface structure of metal catalysts, opening a new venue to tune catalytic selectivity.

Pickering Emulsion for Enhanced Viability of Plant Growth Promoting Bacteria and Combined Delivery of Agrochemicals and Biologics

AbstractNon‐sporulating plant growth‐promoting bacteria (PGPB) are widely underutilized in the bio‐based agroindustry due to difficulties in maintaining viability without spores. A unique approach is presented to prepare PGPB‐based green formulations by integrating Gram‐negative, nonsporulating PGPBs: Pseudomonas simiae (Psi) and Azospirillum brasilense (Abr) into cellulose acetate stabilized Pickering emulsions. The bacteria show enhanced survivability within the emulsions without any nutrient supply after 4 weeks of storage with Psi and Abr showing 200% and 500% increases respectively relative to non‐nutritive saline (1X PBS) control. Transcriptomics suggest that lysed bacteria from the emulsification process act as crucial nutrient sources, thereby boosting bacterial survival rates. Moreover, these PGPBs maintain survival even in the presence of the model pesticide fluopyram, with Pseudomonas simiae concentration showing a twofold increase after 1 month of storage while still preserving the efficacy of fluopyram against target pests. This robust survival trait among nonsporulating PGPB marks a notable advancement in developing formulations tailored specifically for these organisms. It underscores their untapped potential for practical applications in agricultural and environmental contexts. Furthermore, the emulsions enable simultaneous loading of biologicals (PGPBs) and agrochemical pesticides without compromising performance, thus offering the promise of a single loading platform to deliver multiple actives.

A Bio-Redox Dynamic Pickering Emulsion from Nature to Nature.

The biosafety issue of Pickering emulsions has gradually become public. It is shown that the particles that make up Pickering emulsions, previously thought to be non-physiologically toxic, may also pose a potential threat to human life and health, as well as to ecosystems, due to their inherent emulsifying capacity. Hence, the principle of "from nature to nature" is proposed, which refers to emulsifiers that are of natural origin and can be metabolized by natural biological processes to eliminate their emulsifying ability. A feasible pathway by which the natural small molecule, thioctic acid, is exploited for the preparation of Pickering emulsions is also presented. The strategy of calcium ion-induced aggregation and ring-opening polymerization of sodium thioctate is utilized for the preparation of particulate emulsifiers, thus forming stable O/W-type Pickering emulsions. Benefiting from the antioxidant property of the thioctic acid moiety and the transdermal capacity of the emulsion itself, it combines protection of the bioactive substance with transdermal delivery. Furthermore, the particulate emulsifiers that are prepared, abundantly enriched with dynamic disulfide bonds, can be integrated into the natural metabolic pathway, specifically by being reduced through the involved glutathione, thereby facilitating their natural degradation and effectively mitigating any potential biological hazards.

Rheology and printability of biopolymeric oil-in-water high internal phase Pickering emulsions: a review.

Biopolymeric oil-in-water (O/W) high internal phase Pickering emulsions (HIPPEs) due to their unique rheological behaviors of HIPPEs such as shear-thinning property, viscoelasticity, and thixotropic recovery have emerged as highly promising printing inks in the 3D printing process. O/W biopolymer-based HIPPEs are categorized as complex fluids, where rheological parameters are crucial for optimizing printability. However, existing reviews have not fully elucidated the interrelationship between rheology and printability for HIPPEs in enhancing the quality and performance of printed parts. This review delved into the influence factors of the continuous phase (e.g., biopolymer type, concentration, pH, and ionic strength) and the oil phase (e.g., oil type, volume fraction, and encapsulated components) on their rheology, to adjust their rheological behaviors in order to prepare more eligible HIPPEs as printing inks. Moreover, a spectrum of rheology-printability relationships, derived from empirical trends and rigorous analytical models, is examined to provide generalized rheological guidelines for achieving successful printability in O/W biopolymer-based HIPPEs. Furthermore, unique challenges and future perspectives on preparing their complex rheological behaviors suitable for additive manufacturing in O/W biopolymer-based HIPPEs were presented. Leveraging these insights significantly reduces reliance on trial-and-error methods in printing, thereby fostering the robust development of novel O/W biopolymer-based HIPPEs and enhancing the overall quality of printed products.

Pickering emulsion stabilized by hollow Zein/SSPS nanoparticles loaded with Thymol: Formation, characterization, and application in fruit preservation.

Using Pickering emulsion (PE) as the carrier of active compounds in bio-based coatings constitutes a highly promising research domain. This study focused on creating a food-grade, biocompatible, and antibacterial PE to coat fresh fruits and vegetables, extending their shelf life. Hollow zein/soluble soybean polysaccharide nanoparticles loaded with thymol (H-ZSH/T) were produced using NaHCO3 as a sacrificial template to stabilize PE. The results revealed that the prepared hollow zein-based nanoparticles had superior dispersibility and structure compared to solid nanoparticles, with an average particle size of 92.24-95.18nm and polydispersity index (PDI) of 0.151-0.179. Thymol was successfully encapsulated through hydrogen bonding, electrostatic attraction, and hydrophobic interactions. The zein-based nanoparticles loaded with thymol showed notable antibacterial properties against E. coli and S. aureus, with a more substantial effect on E. coli. H-ZHS/T demonstrated the highest antibacterial efficacy by disrupting bacterial cell membranes. The prepared PE was an oil-in-water type; increasing the oil fraction improved stability and droplet size while reducing the creaming index. Rheological assessments indicated elastic gel-like characteristics, ensuring both stability and uniformity. The PE coating significantly slowed the loss of fruit hardness, inhibited microbial growth, and extended the shelf life of blueberries and fresh-cut cantaloupe. These findings demonstrated that H-ZHS/T-stabilized PE is an effective and eco-friendly food coating.

Surface modification of particles/nanoparticles to improve the stability of Pickering emulsions; a critical review.

Pickering emulsions (PEs) are dispersions stabilized by solid particles, which are derived from various materials, both organic (proteins, polysaccharides, lipids) and inorganic (metals, silica, metal oxides). These colloidal particles play a critical role in ensuring the stability and functionality of PEs, making them highly valued across multiple industries due to their enhanced stability and lower toxicity compared to conventional emulsions. The stabilization mechanisms in PEs differ from those in emulsions stabilized by surfactants or biopolymers. The stability of PEs is influenced by intrinsic particle properties, such as wettability, size, shape, deformability, and charge, as well as external conditions like pH, salinity, and temperature. Some particles, especially organic ones, alone may not be effective stabilizers. For instance, many polysaccharides inherently lack surface activity, while most proteins have significant surface activity but often become unstable under environmental stresses, potentially leading to emulsion instability. The chemical composition and morphology of the particles can lead to varying properties, particularly wettability, which plays a vital role in their ability to adsorb at interfaces. As a result, surface modification emerges as an essential approach for improving the effectiveness of particles as stabilizers in PEs. This review presents the mechanisms that stabilize PEs, identifies factors influencing the stability of PEs, and discusses physical and chemical techniques for modifying particle surfaces. There has been a significant advance in understanding surface modification, employing both physical (non-covalent bonds) and chemical (covalent bonds) approaches. These insights are invaluable for optimizing PE formulations, broadening their application potential across various fields.

Strong self-association of chitosan microgels at interface mediated high stabilities in Pickering emulsion.

The spontaneous self-organization of naturally-occurring polysaccharide particles into a thick and robust gel network at interface in Pickering emulsion is challenging. Inspired by the phenomenon that chitosan microgels (CSMs) with a certain size could self-associate into a solidified gel phase upon freezing, here we tentatively used CSMs to construct a highly-stable Pickering emulsion. CSMs can form a stable Langmuir's layer at the water/oil interface through the network deformation and re-arrangement of dangling chains, while the subsequent negative polymer coating can avoid the bridging resulting from the cross-association for CSMs on different emulsion droplets upon freezing. The experimental results indicated that the emulsion showed excellent features, including the wide pH range stability (3-12), long-term storage stability (> 3months), thermal stability (121°C, 30min). Moreover, CSMs could self-associate into a reliable gel layer around the oil droplet in freezing, leading to the better freeze-thaw stability (1-3cycles). The negative coating not only facilitates the formation of interfacial gel network around each emulsion droplet, but also produces huge steric hindrance and electrostatic repulsion to suppress the coalescence. This work provides a different way to modulate the interfacial structure, thus developing a more stable polysaccharide-based Pickering emulsion.

Hydrophobic modification of cellulose nanofibers/bionic flower-like ZnO synergistically stabilized Pickering emulsion to enhance pesticide deposition.

Environmental issues arising from the low pesticide utilization rate make the development of environmentally friendly and low-cost pesticide carrier systems an urgent problem to be solved. Pickering emulsion systems have shown broad application prospects in pesticide delivery. In this study, dodecenyl succinic anhydride (DDSA) was used to hydrophobically modify cellulose nanofiber (D-CNF), and biomimetic flower-like zinc oxide (ZnO) particles were prepared by precipitation method at room temperature. Then the two functioned synergistically as stabilizers for the Pickering emulsion, which significantly diminished the reliance on conventional surfactants. Turpentine, an essential oil, was used as a solvent for the broad-spectrum herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) and as a part of the oil phase in an emulsion, replacing traditional toxic solvents for pesticide dissolution in the construction of a Pickering emulsion system. ZnO/D-CNF formed a dense layer at the oil-water interface to prevent droplet aggregation. After the Pickering emulsion contacted the leaves, ZnO could be embedded and adhere to leaves due to its morphology, which effectively reduced the splash of the droplets. No matter what the inclination angle was, the droplets could adhere and diffuse on the leaves. This study presents a new idea for creating a simple, eco-friendly, and practical pesticide carrier system.

Gliadin/Konjac glucomannan particle-stabilized Pickering emulsion for honokiol encapsulation with enhanced digestion benefits.

Owing to the limited availability of biocompatible, edible and natural emulsifiers, the development of Pickering emulsions applicable to the food industry still confronts challenges. Moreover, Honokiol (HNK), due to its poor stability and susceptibility to oxidation, most of the existing delivery systems are centered on injection administration routes and relatively complex in preparation, posing significant challenges for industrialization. In this research, a Pickering emulsion system stabilized by gliadin and konjac glucomannan composite particles (GKPs) was constructed using the pH cycling method and was employed for the delivery of HNK. Under the conditions of a 1:2 mass ratio of the composite particles at pH4 and an oil phase fraction of 50%, the storage stability of HNK was effectively enhanced, attaining a retention rate of 84.88%±0.78% at 4°C for 14days. In simulated in vitro digestion, this emulsion system effectively mitigated the degradation of HNK, achieving a bioavailability of 66.94%±4.05% and increasing the release of free fatty acids. Pickering emulsions stabilized by GKPs may provide a useful means of delivery of bisphenol lignans.

Stable Pickering emulsions of cinnamaldehyde were formulated using tannic acid-assisted cellulose nanofibers and applied for mango preservation.

Recent explorations into cinnamaldehyde (CIN) have identified its potential as a natural preservative, particularly when incorporated into active packaging to enhance the shelf-life of fruits and vegetables. This study explores the use of cellulose nanofiber (CNF)-stabilized Pickering emulsions as a novel delivery system for essential oils, demonstrating broad applicability in food preservation strategies. We employ CNF as Pickering stabilizers to effectively emulsify and encapsulate CIN, investigating the influence of tannic acid (TA) concentrations on the stability of these emulsions. Results reveal that a TA concentration of 0.05 % significantly improves emulsion stability against centrifugation, freeze-thaw cycles, and thermal stresses. This enhanced stability is attributed to hydrogen bonding between TA and CNF, which fosters a uniform and robust network structure. Moreover, the incorporation of TA markedly boosts both the antioxidant properties and the bacteriostatic effectiveness of the CIN Pickering emulsion. Notably, DPPH radical scavenging efficacy escalated from 31.96 % to 93.82 %, and ABTS radical scavenging increased from 22.0 % to 86.31 %. We developed a functional coating by integrating carboxymethyl chitosan (CMCS) with the CIN Pickering emulsions. Application of this coating on mangoes under ambient conditions proved effective in minimizing weight loss, retarding senescence, inhibiting enzymatic activities, and consequently extending the fruit's shelf life.

Topical delivery performance of Pickering emulsions stabilized by differently charged spirulina protein isolate/Chitosan composite particles.

Pickering emulsions, stabilized by particulate particles, have emerged as a promising vehicle for topical delivery. Herein, Pickering emulsions stabilized by differently charged spirulina protein isolate - chitosan (SC) composite particles were studied for effective topical delivery of α-Bisabolol (ABS). The composite particles were synthesized via electrostatic assembly of spirulina protein isolate (SPI) and chitosan (CS), and their surface charge was assessed using zeta potential measurements. The Pickering emulsions stabilized by SC composite particles with different charges were all stable over 30 days and had a high encapsulation efficiency for ABS. In vitro skin permeation study revealed that positively charged emulsions significantly increased ABS retention within the skin, predominantly in the stratum corneum layer. The underlying delivery mechanism was further explored using attenuated total reflection Fourier transform infrared spectroscopy. Lastly, the influence of particle concentration and oil phase volume fraction on the topical delivery efficiency was conducted to optimize the Pickering formulations. This study provides insight into the role of particle charge in enhancing topical delivery of Pickering emulsions.

A novel Pickering emulsion stabilized solely by agar-glycine Maillard conjugates.

A novel Pickering emulsifier was developed through the Maillard reaction between acidolyzed agar and glycine. The resulting agar-glycine (Agar-Gly) Maillard product particles effectively stabilized a long-term Pickering emulsion at low pH (as low as 3) and medium oil content (40 %-50 %) with a particle concentration of 1 %. Microstructural analysis revealed that Agar-Gly particles adsorbed around the droplets, forming a typical O/W Pickering emulsion. The formation of a dense and regular three-dimensional gel network around the droplets was crucial in restricting droplet movement and ensuring emulsion stability. This stability was significantly superior to emulsions stabilized solely with agar or a mixture of agar and glycine (Agar+Gly), owing to synergistic effects between particle interfacial layers and spatial site resistance. Incorporating the Agar-Gly Maillard product into low-fat mayonnaise not only markedly reduces its greasiness but also provides consumers with a low-fat, healthy alternative. Furthermore, Agar-Gly used as a Pickering stabilizer, it offers an easy mode of application for agar that does not require dissolution at elevated temperatures. This provides a straightforward and promising avenue for the use of agar in the high-value food industry.

Water-in-water Pickering emulsions as a fascinating culture and embedding medium for Saccharomyces cerevisiae

Water-in-water Pickering emulsions as a fascinating culture and embedding medium for Saccharomyces cerevisiae

Sodium caseinate/cellulose nanofiber-stabilized Pickering emulsions: A study on lipid absorption regulation.

This study aimed to develop a sustainable and bio-based nano-additive (sodium caseinate/cellulose nanofibers (SC/CNF) complex) to modulate liquid-based oil-in-water (O/W) colloid interfaces, which function as a fat control agent to slow lipid digestion. Edible protein (SC) was grafted onto CNF through facile electrostatic attraction, which reduces solvent and chemical usage for greener process. The physicochemical properties of SC/CNF showed that adding SC increased the interfacial bonding between CNF particles, resulting in higher interfacial pressure by forming dense and compact layers of SC/CNF. This characteristic improves the mechanical strength and colloidal stability of SC/CNF during water-oil stabilization. Further preparation of O/W Pickering emulsions stabilized by SC/CNF complexes was conducted using different parameters (such as SC concentration, dosage of SC/CNF, and O/W ratio) to investigate profile of free fatty acid (FFA) released during lipid digestion via simulated in vitro gastrointestinal tract (GIT) model. The results showed that the optimized emulsion stabilized by the SC/CNF complex rendered a lower value of free fatty acids (FFA) after undergoing in vitro simulated digestion. The lowest FFA release (31.18%) was achieved under the following conditions: 1%w/v (SC concentration), 1% w/w (dosage of SC/CNF), and 20/80 (O/W) ratio. Low FFA release within the digestive system indicated that the nano-emulsions effectively regulated lipid digestion. The changes in physicochemical characteristics in terms of colloidal stability (particle size, microstructure, and surface charge) of the stabilized emulsions corresponding to the FFA released were studied during each digestion phase (including mouth, stomach, and small intestine). This study revealed that the SC/CNF complex is a promising nano-biomaterial that can function as a bio-functional food additive, particle stabilizer, and fat digestion controller. The unique characteristics of SC/CNF complexes in stabilizing oil-water emulsions present a potential interfacial mechanism for modulating lipid bioavailability. The innovation approach allows for the demand for green-label products, promote development of healthier food options, and the pursuit of sustainable food solutions.

Stability and in vitro digestion behavior of astaxanthin-loaded Pickering emulsions stabilized by OSA-modified starch: Influence of oil phase content.

Astaxanthin, a lipid-soluble carotenoid, is widely recognized for its health-promoting properties. However, its use in functional foods is limited due to its low water solubility, chemical instability, and poor bioavailability. This study evaluated the potential of esterified starch-stabilized emulsions as astaxanthin carriers. The effects of the oil phase content on the emulsion properties, stability, and in vitro digestion behavior of the emulsions were investigated. All emulsions exhibited adequate encapsulation efficiency (>80%) for astaxanthin. Moreover, the particle size and viscosity of the emulsions increased with an increasing oil phase content. The emulsion with a 10% oil phase content (E-10%) showed high retention of astaxanthin (>40%) under the temperature, pH, and ionic strength conditions tested and long-term stability (42days). On the other hand, the release of free fatty acids and bioaccessibility of astaxanthin were negatively correlated with the oil phase content. And the bioaccessibility of astaxanthin was increased to 11.66% (for E-10%). Under a constant emulsifier concentration, E-10% and E-20% exhibited a thicker interfacial layer at the oil/water interface. Based on this, a smaller particle size may favor oil droplet dispersion and inhibit droplet floatation and aggregation, improving emulsion stability. Therefore, this study provides useful information on the effect of the oil phase content in esterified starch-stabilized Pickering emulsion delivery systems.

Corn Stover-derived nanocellulose and lignin-modified particles: Pickering emulsion stabilizers and potential quercetin sustained-release carriers.

Pickering emulsions (PEs) have wide applications in delivering nutraceuticals. However, the impact of extracting nanocellulose from corn stover on stabilizing PEs and delivering nutraceuticals remains unclear. In this study, four types of nanocellulose, cellulose nanocrystals (CNC), cellulose nanofibers (CNF), lignin-containing cellulose nanocrystals (LCNC), and lignin-containing cellulose nanofibers (LCNF) were successfully prepared from corn stover, an agricultural waste. Among them, LCNC and LCNF exhibited stable reticulated microstructures, lower crystallinity, and excellent thermal stability. Besides, lignin enhanced the nanoparticles' hydrophobicity, promoting the formation of more ideally amphiphilic particles, resulting in denser emulsions at the oil-water interface. Furthermore, emulsions stabilized by LCNC and LCNF demonstrated remarkable resistance to quercetin degradation under UV light exposure (with residual level exceeding 90%) and improved quercetin's bioaccessibility during the in vitro digestion tests, achieving the highest bioaccessibility of 48.3%. This study provided an innovative perspective on utilizing stover-derived materials for stabilizing PEs and delivering lipophilic nutrients.

Unfolding bovine serum albumin decorated selenium nanoparticles crosslinking with chitosan: Achieve stabilization of Pickering emulsions gel and enhance resveratrol bioaccessibility.

Resveratrol (Res) is a natural polyphenol exhibiting anti-oxidant and anti-inflammatory activity. However, the applications of Res have been limited due to its low stability and water solubility. To enhance the bioaccessibility of Res, unfolding bovine serum albumin-modified selenium nanoparticles (UBSA@SeNPs) encapsulated within chitosan (CS)-coated Pickering emulsions (CS-UBSA@SeNPs-PE) were used to load Res. The results showed that Res-loaded CS(0.06%)-UBSA@SeNPs-PE has small droplet size (16.13μm), high gel properties and excellent antioxidant properties. During the simulated digestion process, CS reduced the release rate of Res from Res-loaded CS(0.06%)-UBSA@SeNPs-PE (42.27%) to reach a slow release effect. Importantly, Res could quickly release from CS-UBSA@SeNPs-PE within intestinal fluid or in the presence of chitosanase. In simulated absorption experiments, the intestinal permeability of Res in Res-loaded CS(0.06%)-UBSA@SeNPs-PE were enhanced by 292.31% compare to Res-loaded CS(0%)-UBSA@SeNPs-PE. In pharmacokinetic studies, Res-loaded CS(0.06%)-UBSA@SeNPs-PE had an area under the curve (AUC) up to 3467.99±127.43ng*h/mL. Furthermore, CS also improved the mucoadhesive nature of UBSA@SeNPs-PE, resulting in a gut-retention time of Res-loaded CS(0.06%)-UBSA@SeNPs-PE that reached up to 60h. In conclusion, CS-UBSA@SeNPs-PE can serve as an effective oral delivery system for improving the bioaccessibility of Res.

Stabilization of oil-in-water high internal phase Pickering emulsion by using 7S globulin/konjac glucomannan complexes: Rheology properties, stability properties and 3D/4D printing performance

Stabilization of oil-in-water high internal phase Pickering emulsion by using 7S globulin/konjac glucomannan complexes: Rheology properties, stability properties and 3D/4D printing performance