Physical Modification Of Starch Research Articles

Enhanced gelling property and freeze-thaw stability of potato, tapioca and corn starches modified by mild heating in aqueous ethanol solution.

Physically modified starches can be classified as natural ingredients on food labels and clean label products. Thus, the market demand for physically modified starch is increasing. Potato, tapioca and corn starches were physically modified by mild heat treatment in an alcoholic solution to enhance their gelling property and freeze-thaw stability. During mild heating of starch suspension (40% w/w) in 10% ethanol solution at the onset gelatinization temperature, granular swelling of starch occurred, followed by amylose leaching with medication of the surface structure of the starch granules. All treated starches exhibited increased gelatinization and pasting temperatures and decreased breakdown for pasting as a result of improved stability against shear and heat. The treated starches had higher hardness, cohesiveness and springiness of gel than the respective native starches, and these gel properties were more pronounced in potato starch than in tapioca and corn starches. The treated starches showed substantially reduced gel syneresis during freeze-thawing. Physical modification of starch by mild heat treatment in an alcoholic solution substantially improved its gelation ability and freeze-thaw stability. © 2024 Society of Chemical Industry.

Modulasi Kadar Pati Resisten Berbagai Pangan Karbohidrat melalui Pemanasan Microwave: Meta-Analisis

Starch is extensively utilized in food processing for various purposes. However, the use of native starch is limited due to its unsuitability with processing conditions or products characteristics. Physical modification of starch is commonly employed to enhance the properties of native starch. The physical starch modification using microwave heating is presently developed due to its more efficient energy consumption than that of traditional heating methods. The process of microwave heating followed by cooling has been found to induce the formation of type 3 resistant starch (RS3). However, the effects of microwaving heating towards the the increase of resistant starch contents varies among researchers. For this reason, a meta-analysis was conducted to evaluate the effect of microwave heating on the levels of resistant starch in carbohydrate sources such as cereals, pulses, and tubers. The objective of this study was to analyze the carbohydrate food groups that demonstrated the most significant increase in resistant starch levels due to microwave heating, and to determine the optimal microwave treatment parameters within these food groups using meta-analysis. The findings indicate that microwave heating treatment is particularly effective for cereals, with rice being the most responsive. The most favorable treatment parameters include a power range of 401-600 W, heating time of 60-99 s, and starch moisture content of 40-60%.

The effect of the electromagnetic field on the physicochemical properties of isolated corn starch obtained of plants from irradiate seeds

Maize grains are composed of the pericarp, endosperm, and germ. Consequently, any treatment, such as electromagnetic fields (EMF) must alter these components, which in turn alters the physicochemical properties of the grain. Since starch is a major component of corn grain, and given the great industrial importance of starch, this study investigates how EMF affects the physicochemical properties of starch. Mother seed were exposed to three different intensities 23, 70, and 118 μT for 15 days. Except for a slight porosity on the surface of the starch of the grains of plants exposed to higher EMF, the starch showed no morphological differences between the different treatments and the control (according to scanning electron microscopy). The X-ray patterns showed that the orthorhombic structure was kept constant, unaffected by the intensity of EMF. However, the pasting profile of starch was affected, and a decrease in the peak viscosity was obtained when the intensity of EMF increased. In contrast to the control plants, FTIR shows characteristic bands which can be attributed to the stretching of the CO bonds at wave number 1.711 cm−1. EMF can be considered a physical modification of starch.

Impact of Various Modification Methods on Physicochemical and Functional Properties of Starch: A Review

AbstractStarch is extensively used in food applications for process convenience and to improve the quality of food products at industrial levels. The contemporary research on starch has created lots of scientific information that provides a base for interventions in food formulations using starch as an active ingredient. The native starch has some limitations, i.e., low swelling and solubility, low thermal resistance, low shear rates, etc. Modification of starch results in altered properties of starch. To modify starch, various modification methods such as physical, chemical, enzymatic, and genetic methods are used which enhances the starch applications at the commercial level. In the physical modification of starch, the chemical structure of starch is not affected while in the case of chemical modification there is an introduction of a functional group in starch granules. The modified starches are used in various industries such as food, pharmaceutical, paper, and textile industries. The purpose of this manuscript is to provide a detailed overview of the physicochemical, morphological, and rheological properties of native and modified starch.

Starch source, modification and food application

The starch chemistry aspect of amylose and amylopectin fractions along with their contributory roles in defining starch food behavior; such as in gels formation, pasting quality, swellability, dextrinization and viscosity from various sources such as legumes, root, tubers and cereals were reviewed. Chemical and physical modifications of starch like cationation, esterification, acetylation, alkalization and annealing, which somehow weakens glucose linked bond and releasing fractional starch moieties have shown to modify characteristic behavior of starch in food systems and for non-food systems. The application of starch in food and non-food systems were envisaged from resistant to non-resistance starches in legumes, roots and tubers and these were observed to be better in functional characteristic than cereal starches.

Embedded Target Filler and Natural Fibres as Interface Agents in Controlling the Stretchability of New Starch and PVOH-Based Materials for Rethinked Sustainable Packaging.

A structuring solution converting starch into a multiphase polymeric material was obtained through a melt compounding sequence, which can be irreversibly shaped by thermoforming into rethinked, sustainable packaging, based on the physical modification of starch with polyvinyl alcohol (PVOH), target fillers, (CaCO3 and wood flour), and a good plasticizer compatible with the polar components. Polymeric material can be thermoformed if it can be stretched without breaking in the positive temperature range, have functional properties required by the application, and keep its shape and properties after stretching for more than six months. The properties of the selected quaternary starch-based compound, fulfil the requirements for a thermoformable polymeric material due to the chemical compatibility between the components and the compounding in a selected procedure and optimal conditions wich ensure a comfortable miscibility. Most likely, the obtained miscibility can be explained only by the arrangement of the wood flour at the interface, where it acts as compatibilizer with a main role in structuring the new starch-based materials. The compatibilizer role of the wood flour was proved for the quaternary selected blend by the changing of the thermal degradation mechanism, from one with two stages for binary and tertiary blends, to one consisting of a single stage: decreasing till elimination of morphological defects, the reproducibility of the mechanical properties, stretching without breaking, and dimensional stability after stretching. Future studies will aim to achieve rethinked packaging for applications that require higher strength properties.

Investigation of physico-chemical properties of native and gamma irradiated starches

Starch is one of the most abundantly found carbohydrates in cereals, roots, legumes and fruits located in amyloplasts of plants. Native starch comprises of amylose, a linear α-glucan with α-1,4-linkage and amylopectin, a branched polysaccharide with both α-1,4-linkage and α-1,6-linkage. In food industries, the native starch is modified to manufacture the desired quality of starchy foods by means of physical, chemical, and enzymatic modification techniques. Gamma irradiation technique is one among the physical modifications of starch which is extensively used for the modification of native starch as it is rapid, less toxic and cost-effective technique. When starch is radiated with gamma rays, it is observed to produce free radicals owing to cleavage of amylopectin branches and exhibit variation in their physicochemical properties. In this study, commercially available corn, rice, and potato starch were irradiated with 10 kGy dose of gamma radiation and changes in their physicochemical properties were investigated. Native and irradiated starch was subjected to enzymatic hydrolysis with bacterial α-amylase (150 U/mL). The highest starch hydrolysis was observed for irradiated rice starch (17.03%). Amylose content of irradiated starch decreased by 3–4 %. The optical microscopic images showed the surface erosions of the irradiated starch and differential scanning calorimeter (DSC) revealed the thermal transition temperatures. Overall, starch hydrolysis and amylose content showed inverse correlation between them. Further studies regarding the effect of storage on gamma irradiated starch can help to gain new insights into the usage of modified starches in the manufacture of processed foods.

Pressure moisture treatment and hydro-thermal treatment of starch.

Starch is often subjected to denaturation treatment to improve its useful properties and eliminate its shortcomings. Various methods have been developed to produce modified starches with different properties and for a variety of uses. Because physically modified starch can be produced without chemical substances or biological agents, the modification method is very simple and inexpensive, and the resulting material can be used as clean label starch. Among these physical modification technologies, heat moisture treatment (HMT) is a universally valid technology, but little is known about pressure moisture treatment (PMT)-related technology. Physical modification of starch using PMT results in new functions and value-added characteristics required by industry, and PMT has the potential to produce starch with new functions. In this paper, PMT-related technologies for physically modified starch, the difference between PMT and the hydro-thermal treatment, and clean label starch manufacturing using HMT and PMT were investigated.

Impact of physical modifications on starch nutritional fractions: Rapidly Digestible Starch, Slowly Digestible Starch and Resistant Starch

The industrial utilization of native starches is limited because of their poor qualities and different starch modifications are used to improve functionality of starch. Physical modification of starch is preferred since it is simple, inexpensive, and specially it does not involve any chemical reagents. Physical modifications can be divided into thermal and non-thermal treatments. These techniques alter physicochemical properties of starch including in vitro digestibility, which indicates the nutritional value of starch. Starch nutritional fractions are of three types; RDS (rapidly digestible starch), SDS (slowly digestible starch) and RS (resistant starch). It is important to understand how physical modifications affect starch nutritional fractions as both SDS and RS have beneficial health effects and specially RS has the potential to be used as a natural bioactive compound. This review aims to summarize the recent knowledge regarding the physical modifications and their impact on in vitro digestibility and nutritional fractions of starch.

Physical modification of starch: changes in glycemic index, starch fractions, physicochemical and functional properties of heat-moisture treated buckwheat starch.

Native buckwheat starch was extracted and modified by heat-moisture treatment (HMT) with different treatment time (15, 30 and 45min) to investigate its effect on physicochemical, morphological, functional properties, starch profile (rapidly digestible starch, RDS; slowly digestible starch, SDS and resistant starch, RS fractions) and expected glycemic index (eGI). Results revealed that with increasing time duration of HMT from 15 to 45min, amylose content, pasting temperature and thermostability increased substantially whereas swelling power, solubility and viscosity parameters decreased. The SEM micrographs showed that HMT caused fissures in the granule and surface indentation. HMT-45 (starch treated for 45 min) had the lowest RDS content (29.33%) and the highest SDS (51.30%) and RS (8.21%) levels. The decreased hydrolysis rate, high amylose and RS content of HMT-45 resulted in a significant decrease in estimated glycemic index (eGI) values from 51.49% (Native) to 44.16% (HMT-45) thus indicating its role in prevention of non-insulin- dependent diabetes.

Chemical and Physical modification of starch: modern trends

Chemical and Physical modification of starch: modern trends

Green isolation and physical modification of pineapple stem waste starch as pharmaceutical excipient

The waste of inedible parts of pineapple, particularly in tropical countries, contributes to environmental burden. This study aimed to utilize pineapple stem waste as a source of starch-based pharmaceutical excipient. The starch was isolated from pineapple stem waste using a simple process without applying harsh chemicals. The isolated starch (PSS) was then physically modified through gelatinization and spray drying to improve its physical properties. Starch characteristics were identified by FTIR, TGA, and XRD analysis. The SEM imaging showed morphological change with reduced surface roughness due to physical modification of the starch. Decreased crystallinity of modified starch (MPS) was confirmed by our XRD results: the peaks of A-type crystalline at 2θ of 13°, 15°, 18°, and 23° were present in PSS, yet mostly absent in MPS. Thermogravimetric analysis showed that MPS behaved differently from PSS and the degradation events occurred at lower temperature. When the starch was spray-dried without prior gelatinization process, the physicochemical characteristics of spray-dried starch resembled untreated starch. Moisture content in PSS (10.66%) decreased after gelatinization to 7.3%. Potential use of MPS was demonstrated by its powder flowability (Student’s t test, p < 0.05), swelling capacity (Student’s t test, p < 0.05), and compaction profile. In summary, our findings demonstrated that modified pineapple starch showed better physical characteristics and quite promising as a tablet binder and disintegrant.

Physical modification of starch by high-pressure homogenization for improving functional properties of κ-carrageenan/starch blend film

Cornstarch granules were physically modified by high-pressure homogenizer at a pressure of 14 MPa (two and five passes) and 20 MPa (two passes). Then, the modified starches were blended with κ-carrageenan and functional properties of κ-carrageenan/starch films were investigated. Upon homogenization, X-ray diffraction pattern of native starch changed and relative crystallinity reduced. Differential scanning calorimetry showed that melting-point peaks of native starch were shifted to lower temperature after homogenization process. The modified starch granules preserved their integrity, while several micro-pores appeared on their surfaces. In order to study the impact of modified starches on κ-carrageenan film, morphological properties, mechanical parameters, contact angle, water solubility and water vapor permeability of blend films were evaluated. Scanning electron microscopy micrographs of cross-sectional view revealed a good level of miscibility between κ-carrageenan and modified starches. Κ-carrageenan films containing pressured starches showed the highest surface hydrophobicity and tensile strength. Water barrier property and water resistance of κ-carrageenan film were found to improve after addition of modified starches. These changes were more marked when the starch was modified with high level of homogenization pressure.