Physical Heterogeneity Research Articles

Temporal and spatial heterogeneity of mineral dissolution rates in fractured media

Physical heterogeneity in the subsurface creates preferential flowpaths that have the potential to impact mineral dissolution rates. Previous studies using numerical simulations have found that physical heterogeneity can reduce the mineral dissolution rate by an order of magnitude relative to homogeneous simulations. These findings indicate that the long-studied difference between laboratory dissolution rates, and field dissolution rates could be the result of processes caused by heterogeneity in the subsurface, specifically variable fluid flowpaths controlling the approach to fluid saturation. In this study, we investigate the behavior of mineral dissolution rates in heterogeneous fractured rock domains through time. Domains containing albite and non-reactive quartz evolve through 1 million years as rainwater percolates through the system and allows for albite dissolution and secondary mineral precipitation. Fracture density and orientation vary in the domains to determine the importance of fracture topology on mineral dissolution rates. In addition, the volumetric flow rate through each domain is systematically varied to determine the impact of changing flow conditions relative to reaction rates.Temporal analysis of the simulation results indicates that domain-averaged dissolution rates decrease with time, similarly to what has been observed in field systems and long-term laboratory experiments. Spatial analysis of the mineral dissolution rates throughout the simulations, indicates that fractures remain reaction limited through most of the simulation, while the matrix is transport limited. Since most of the domain consists of matrix, the domain is transport limited as a whole. However, speciation of the flux-weighted fluid leaving the domain indicates that the fluid is undersaturated with respect to albite, potentially leading to an interpretation that dissolution within the domain is not transport limited. The direct comparison of the spatial distribution of rates and the integrated flux signal appears contradictory, however, this approach reveals that the transport-limited signal that persists through most of the domain is diluted by the higher volume of water that leaves the system through fast-flowing fracture pathways compared to the mass of solutes diffusing out of disconnected portions of the domain. This parsing of the domain into transport-limited regions and kinetic-limited regions, induced by physical heterogeneity, has the potential to further explain the differences between laboratory dissolution rates and field dissolution rates. It is possible that mineral weathering is dominated by transport-limited conditions in many field systems with disconnected fluid pathways where reaction rates are slow due to a buildup of solutes, despite integrated signals in streams indicating far-from equilibrium conditions for dissolution reactions of primary minerals.

Depth–Sequential Investigation of Major Ions, δ18O, δ2H and δ13C in Fractured Aquifers of the St. Lawrence Lowlands (Quebec, Canada) Using Passive Samplers

General and isotopic geochemistry of groundwater is an essential tool to decipher hydrogeological contexts and flow paths. Different hydrogeochemical patterns may result from the inherent physical aquifer heterogeneity, which may go unnoticed without detailed investigations gathered from multilevel or multiple observation wells. An alternative to overcome the frequent unavailability of multiple wellbores at sites is to perform a detailed investigation on the single wellbore available. In this perspective, the aim of this study is to use passive samplers to sequentially collect groundwater at depths in long–screened wellbores. Such investigation is carried out for major ions and stable isotopes compositions (δ2H, δ18O, δ13C) at ten sites in the context of fractured carbonate aquifers of the St. Lawrence Lowlands (Quebec, Canada). The information gathered from the calco–carbonic system, major ions and stable isotopes report poorly stratified and evolved groundwater bodies. Contribution of water impacted by anthropogenic activities, such as road salts pollution and carbon sources from C4 vegetation, when they occur, are even observed at the greatest depths. Such observations suggest quick flow paths and efficient mixing conditions, which leads to significant contributions of contemporary groundwater bodies in the fractured aquifers investigated down to depths of about 100 m. Although physical aquifer investigation reported few and heterogeneously distributed fractures per wellbore, hydrogeochemical findings point to at overall well interconnected fracture networks in the aquifer and high vulnerability of groundwater, even at significant depths.

Evolution Mechanism of Differential Diagenesis Combination and Its Effect on the Reservoir Quality in the Tight Sandstone: A Case from the Lower Shihezi Formation in the Hangjinqi Area of Ordos Basin, China

Abstract The physical property heterogeneity of tight sandstones was mainly caused by complex alteration of various diagenesis combinations during burial process. However, diagenetic evolution of different diagenesis combinations which generally result in the strong difference and heterogeneity of physical property and pore structure is rarely well understood. The Middle Permian lower Shihezi Formation is one of the most important tight gas sandstone reservoirs in the Hangjinqi area of Ordos Basin, China. The reservoir heterogeneity of lower Shihezi Formation, which was caused by the differential diagenesis combination, is crucial to efficient exploration and development. Evolution mechanism of differential diagenesis combination and its effect on the reservoir quality in the tight lower Shihezi Formation sandstone in the Hangjinqi area of Ordos Basin was investigated by means of thin-section description, cathodoluminescence (CL) imaging, X-ray diffraction (XRD), scanning electron microscopy (SEM), and homogenization temperature of fluid inclusions. The lower Shihezi Formation sandstones can be divided into four diagenesis combination types according to the reservoir characteristics and diagenetic relationship. The main diagenetic sequence was mechanical compaction-chlorite rim-early pore-filling calcite cementation-dissolution-authigenic kaolinite-quartz cementation-late calcite cementation. Differential diagenesis combination was mainly controlled by the petrological characteristics, microfacies, and fault. Low content of rock fragment and high content of detrital quartz were beneficial to the compaction resistance and cementation. The moderate content of pore-filling calcite was conducive to pore space protection and feldspar dissolution. The faults control dissolution and differential diagenesis combination by influencing the migration of acid fluids. Moderate compaction-moderate cementation-moderate dissolution type (BBB type) and weak compaction-moderate cementation-strong dissolution type (CBA type) were in favour of high-quality reservoir development.

Innovative Material Can Mimic Coral and Boulder Reefs Properties

Low-Voltage Mineral Deposition technology (LVMD), widely known as Biorock, has previously been suggested as support for coral reef restoration, as hypothesized high porosity, wide pore-size distribution and connectivity, and good strength properties may facilitate biological functions (for example larvae settlement) and durability. In this technology, very low voltage induces an electrical current that initiates precipitation and accretion of hard minerals (aragonite and calcite) on a metal in seawater. This technology has been discussed mainly for its biological value, while this paper wants to highlight also its engineering value as artificial reef material. Indeed, some of the properties that makes it valuable in one domain are also supporting its use in the other. Because the metal on which the precipitation takes place can be of any shape and size, so can the artificial reef and its mechanical strength characteristics are above the ones of corals and similar to concrete, indicating adequate durability. Coral and boulder reefs suffering from degradation have severe implications on biodiversity, protection from flooding, and cultural value and therefore understanding how to persevere and re-establish these ecosystems is central for sustainable intervention in the marine environment. By comparing chemical-physical characteristics of Coral Porites Exoskeleton (CPE), one typical reef building coral type, LVMD and High-Voltage Mineral Deposition (HVMD), we show that they possess highly similar properties including chemical composition, density, total porosity, pore-size distribution, physical and chemical heterogeneity, total and external surface areas, and comparable mechanical strength.

Devising manufacturing techniques to control the process of zonal segregation in large steel ingots

A method of physical modeling was applied to study the effect of external actions on the processes of crystallization and the formation of the structure of ingots. A brief review of existing hypotheses about the evolution of physical, structural, and chemical heterogeneities in large steel ingots is given. The parameters of the structure and the two-phase zone have been determined, as well as the nature of the distribution of segregated materials along the cross-section of ingots, depending on the conditions of their curing. The decisive importance of convective and capillary mass transfer in the interdendritic channels of hardening ingots on the formation of a zonal heterogeneity at their cross-section has been proven. Experimentally, when crystallizing a model environment (camphene), it has been visually confirmed that the flow of segregated materials in interdendritic channels occurs when a certain amount of impurities accumulates in them. A clear dependence of the speed of this flow on the rate of melt crystallization has been established. With an increase of the hardened part of the melt, the rate of segregated material movement (Vl) increases while the rate of crystallization (R) decreases due to worsening heat release conditions. At a certain distance from the ingot’s surface, these rates become equal, and impurities are carried to the curing border, which is the main cause of the formation of zonal segregation. The results reported here show that the evolution of zonal segregation in ingots can be controlled using various techniques involving external influence on the hardening melt. This study has demonstrated that the adjustable intensity of heat removal from an ingot, as well as the addition of external excess pressure on the hardening melt, could be used as such tools. In the study, to obtain ingots with a minimum level of chemical heterogeneity, it would suffice to provide the following conditions for the curing of the alloy: a value of the alloy crystallization speeds at the level of Rcr ≥ 9·10–2 mm/s, or external pressure on the free surface of ingots Рext. ≥ 135 kPa. The industrial implementation of the reported results could make it possible to improve the technology of obtaining large blacksmith ingots, provide savings in materials and energy resources, increase the yield of a suitable metal, and improve its quality

Physicochemical Gas-Solid Sorption Properties of Geologic Materials Using Inverse Gas Chromatography.

The goal of this study was to determine the physicochemical properties of a variety of geologic materials using inverse gas chromatography (IGC) by varying probe gas selection, temperature, carrier gas flow rate, and humidity. This is accomplished by measuring the level of interaction between the materials of interest and known probe gases. Identifying a material's physicochemical characteristics can help provide a better understanding of the transport of gaseous compounds in different geologic materials or between different geological layers under various conditions. Our research focused on measuring the enthalpy (heat) of adsorption, Henry's constant, and diffusion coefficients of a suite of geologic materials, including two soil types (sandy clay-loam and loam), quartz sand, salt, and bentonite clay, with various particle sizes. The reproducibility of IGC measurements for geologic materials, which are inherently heterogeneous, was also assessed in comparison to the reproducibility for more homogeneous synthetic materials. This involved determining the variability of physicochemical measurements obtained from different IGC approaches, instruments, and researchers. For the investigated IGC-determined parameters, the need for standardization became apparent, including the need for application-relevant reference materials. The inherent physical and chemical heterogeneities of soil and many geologic materials can make the prediction of sorption properties difficult. Characterizing the properties of individual organic and inorganic components can help elucidate the primary factors influencing sorption interactions in more complex mixtures. This research examined the capabilities and potential challenges of characterizing the gas sorption properties of geologic materials using IGC.

Prediction of interwell connectivity and interference degree between production wells in a tight gas reservoir

Sulige gas field has poor reservoir physical properties and strong heterogeneity. The existing development well pattern is difficult to realize the overall effective production of reserves, especially in block SuX. Therefore, this paper takes SuX block in the east of Sulige as an example to describe an effective method suitable for the development of well pattern in this area. Combined with logging and production data, the connectivity of gas wells in X infill area in the east of Sulige is determined from the aspects of pressure, sand body, logging, performance and well test. By using the method of dynamic and static analysis, the connectivity between wells of main gas reservoir is judged. Through the analysis of flow unit, the discharge area and the stable value of well-controlled reserves are determined. The degree of interference determined by curve fitting and the distribution characteristics of sand bodies are comprehensively analyzed. A new oil well interference degree model defined by mathematical expression of production is established. The interference degree is quantified by gas production through numerical simulation. Based on the comprehensive analysis of the connectivity, interference degree and other factors in the area, it is determined that 500 * 600 well pattern is a reasonable well pattern in SuX block, and the interference degree is about 20%. Based on the analysis of the connectivity between wells and the interference degree between production wells in SuX block, the distribution and connectivity of sand bodies in tight sandstone gas field under complex geological conditions are determined. It provides a reasonable basis for the network encryption development of tight sandstone gas in this block. It provides a powerful technical support for the efficient development of different tight gas reservoirs in Sulige area.

Evaluation of mine waste characterization to identify opportunities for optimizing project economics using fragmentation analysis

ABSTRACT As metal mineral resources get depleted over time, there is a need to recover metals from ores of lower grades and waste. Mining wastes are largely characterized using physical and mineralogical heterogeneity properties. There is variation in the geochemical properties with different grain sizes, thus, different metal recovery potential. The research evaluated mine waste characterization and identified opportunities for optimizing project economics using fragmentation analysis. This study linked petrographic, compositional and quantitative mineralogical analyses with fragmentation data resulting from conventional mechanical communition of mined-out waste rock. The results improve the understanding of what grain sizes are optimal for metal recovery from the waste rock and established that environmental threats can be mitigated by removing fines from waste. The economic metals including Ni and Cu sulphides are predominantly held in pentlandite and chalcopyrite within the rocks. Maximum liberation and metal recovery are in the finer grains.

Investigating the Influence of Structure and Heterogeneity in Waste Rock Piles on Mass Loading Rates—A Reactive Transport Modeling Study

Placement methods and material availability during waste rock pile (WRP) construction may create significant heterogeneities in physical and geochemical parameters (such as grain size, permeability, mineralogy, and reactivity) and influence the internal pile structure. Due to the enormous scale of WRPs, it is difficult to capture the influence of heterogeneities on mine drainage composition and evolution. Although laboratory- or field-scale experimental studies have provided much insight, it is often challenging to translate these results to full scale WRPs. This study uses a numerical modeling approach to investigate the influence of physical and chemical heterogeneities, structure, and scale on the release of acid rock drainage (ARD) through 2D reactive transport simulations. Specifically, the sensitivity of drainage quality to parameters including grain size distribution, sulfide mineral weathering rates, abundance and distribution of primary minerals, and pile structure as a function of construction methods are investigated. The geochemical model includes sulfide oxidation, pH buffering by calcite dissolution, and ferrihydrite and gypsum as secondary phases. Simulation results indicate that the implications of heterogeneity and construction method are scale-dependent; when grain size distribution trends observed in a pile's core are applied to the entirety of a pile, results between push- and end-dumping methods vary substantially—however, predicted drainage for different construction methods become more similar when features such as traffic surfaces, structural variation, and multiple benches are also considered. For all scales and construction methods investigated, simulated results demonstrate that pile heterogeneity and structure decrease peak mass loading rates 2 to 3-fold, but cause prolonged ARD release compared to the homogeneous case. These findings have implications for the economics of planning water treatment facilities for life of mine and closure operations.

Identification of radiative and advective populations in Canadian temperature time series using the Linear Pattern Discrimination algorithm

AbstractLong‐term high‐frequency air temperature time series, typically considered the most authoritative observed records for the detection of climate changes, appear physically heterogeneous by nature. We examine multiple Canadian air temperature records for the presence of physical heterogeneities, using the analysis of their diurnal temperature patterns as the main criterion for the separation of temperature series into ‘homogeneous’ populations. Based on the key differences observed in their diurnal air temperature patterns, two distinct populations of the air temperature sample are identified and assumed to be the result of different heat exchange mechanisms. The Linear Pattern Discrimination (LPD) algorithm, implemented in the R‐code, is introduced in this work and applied to 66‐year long hourly temperature records of 25 Canadian stations for the separation of the radiative temperature population from the advective temperature population and examination of incidences of specific, advective cases in air temperature data. The LPD analysis reveals a predominance of a remarkably warmer, radiatively driven air temperature regime. In contrast, the significantly colder and geographically controlled advective temperature regime plays a counterbalancing role on the overall magnitude of the midlatitude air temperature signal. Our findings suggest that a substantial temperature increase in annual averages of advective minima amplifies the effect of a positively shifted radiative temperature range, intensifying the overall heating observed in the Canadian North and northwestern regions.

It is the ambience, not the menu. Prey availability does not drive habitat selection by the endangered Pyrenean desman

Abstract The Pyrenean desman (Galemys pyrenaicus) is an endangered stream‐dwelling insectivore endemic to the Iberian Peninsula and the north of the Pyrenees. It favours riffles over slow habitats such as runs or pools, yet it is still unclear whether habitat preference is based on prey availability or on other factors, such as mechanical constraints on its hunting habits. Desman diet and prey selection were analysed along the pristine Elama Stream and the slightly modified Leitzaran Stream in the Basque Country, Spain. In each stream the prey consumed were identified by metabarcoding 94 desman faeces, and prey availability characterized from 10 Surber samples taken in each habitat type (riffles, runs and pools). Invertebrates were sorted and identified, the biomass of each taxon was calculated, and their DNA was also extracted, amplified using PCR, and sequenced to build a reference database. Prey availability and diet varied between streams. Desmans positively selected shredders and invertebrates that live on the substrate, and selected against taxa that live in fine sediment, taxa with hard shells or those that are highly mobile. The diet of desmans was more selective in the Elama, the stream with better ecological status. Food availability did not differ among habitats, and therefore does not explain the preference of desmans for riffles; rather, mechanical constraints to deal with buoyancy and physical habitat heterogeneity were hypothesized to be the reason behind the habitat preference. The results suggest that promoting the formation of riffles in streams can improve the situation of some desman populations living in degraded habitats.

The Relationship between Diagenetic Evolution and Hydrocarbon Charge in Deep Tight Reservoirs: A Case Study from Kepingtage Formation of S9 Well Block in Tarim Basin

The Silurian Kepingtage Formation of Tarim Basin is an important deep clastic reservoir. Exploration practice shows that the reservoirs are generally characterized by extremely low porosity and permeability, exhibiting strong mineral composition and physical property heterogeneities. The study of heterogeneity and its effect on oil charge is of great significance to the understanding of oil migration and accumulation in such reservoirs and thus is crucial to oil exploration. Therefore, based on identification and quantitative statistics of thin sections, SEM, and homogenization temperature measurements, this study was designed to examine the relationship between diagenetic evolution and oil emplacement in the Silurian Kepingtage Formation in S9 Block in Tarim Basin. The control of differential diagenesis and physical property evolution on oil charge process are discussed. It is found that the sandstones with fine grain size and high content of ductile grains (>20%) have experienced strong mechanical compaction, the porosity decreases rapidly in the early stage of burial. The densification process has been completed before the first period of oil charge so that no oil was found in the reservoir. In contrast, sandstones with relatively coarse grain size and low ductile grain content have better porosity and permeability properties, which are generally oil-bearing. This kind of sandstone generally experienced two periods of oil charge. Apart from moderate compaction, multiple diagenesis events were also observed, including quartz cementation, calcite cementation, and dissolution. Before the early period of oil charge, the diagenesis events are dominated by moderate compaction, chlorite cementation, and dissolution, and the reservoir property is still high. It seems that the time of late period oil charge is relatively long. With the growth of multiple types of authigenic minerals such as quartz, calcite, and illite after or sometimes synchronously occurred with the late period oil charge, the porosity gradually decreases.

Investigation of Chemical Heterogeneity of Cast Metal Ingots of Different Geometries and Assessment of their Applicability for Producing Round Rolled Products

Based on the study results, it is shown that the selected ingot geometry makes it possible to obtain a solidified metal structure with a favorable distribution of physical and chemical heterogeneities of the cast metal. The temperature profile calculations have shown that 1 h 45 min after the onset of solidification of a big-end-down ingot, the advancing crystallization front closes, and an extended “closed” zone of liquid metal is formed, the height of which reaches 37% of the height of the ingot body. The provided data correlated well with the actual shrinkage defects, the length of which constituted 36% of the height of the ingot body. The comparison of the temperature distribution profiles with the assessment of steel contamination with non-metallic inclusions and specifics of segregating impurity distribution has revealed a more uniform distribution of impurities and nonmetallic inclusions due to intensive advancement of the solid phase under the hot-top part of the ingot. In this case, the optimized thermal performance of the hot top helps move segregating impurities and tertiary inclusions to the ingot head. The assessment of applicability of the big-end-up and big-end-down ingots has demonstrated the feasibility of using the former to produce round rolled products with a diameter in excess of 250 mm. The big-end-down ingot weighing 5.9 ton is feasible to use for the production of rolled products having a diameter not exceeding 200 mm due to the formation of a closed secondary pipe cavity. The use of a low hot-top height big-end-down ingot allows increasing the yield of the usable metal, while improving the quality of the rolled products.

3D Cell Culture for the Study of Microenvironment-Mediated Mechanostimuli to the Cell Nucleus: An Important Step for Cancer Research.

The discovery that the stiffness of the tumor microenvironment (TME) changes during cancer progression motivated the development of cell culture involving extracellular mechanostimuli, with the intent of identifying mechanotransduction mechanisms that influence cell phenotypes. Collagen I is a main extracellular matrix (ECM) component used to study mechanotransduction in three-dimensional (3D) cell culture. There are also models with interstitial fluid stress that have been mostly focusing on the migration of invasive cells. We argue that a major step for the culture of tumors is to integrate increased ECM stiffness and fluid movement characteristic of the TME. Mechanotransduction is based on the principles of tensegrity and dynamic reciprocity, which requires measuring not only biochemical changes, but also physical changes in cytoplasmic and nuclear compartments. Most techniques available for cellular rheology were developed for a 2D, flat cell culture world, hence hampering studies requiring proper cellular architecture that, itself, depends on 3D tissue organization. New and adapted measuring techniques for 3D cell culture will be worthwhile to study the apparent increase in physical plasticity of cancer cells with disease progression. Finally, evidence of the physical heterogeneity of the TME, in terms of ECM composition and stiffness and of fluid flow, calls for the investigation of its impact on the cellular heterogeneity proposed to control tumor phenotypes. Reproducing, measuring and controlling TME heterogeneity should stimulate collaborative efforts between biologists and engineers. Studying cancers in well-tuned 3D cell culture platforms is paramount to bring mechanomedicine into the realm of oncology.

Could spatial heterogeneity in flow disturbance drive temporal stability of native–invasive species co‐occurrence in riverscapes?

Abstract Spatial heterogeneity of abiotic influences like disturbance in riverscapes could play an important role in dispersal‐aided community stability. We tested if higher spatial variability in conditions around river confluences caused by different flood disturbance regimes in branches could possibly influence the stability of a fish assemblage dominated by strong negative interactions between non‐native trout and native galaxiid fishes. We used field surveys to evaluate the effects of disturbance‐driven differences between river branches on fish densities and temporal variation in the relative abundance of galaxiids. Three repeated electrofishing surveys were conducted in two reaches of all branches of eight confluences in Canterbury, New Zealand. We found the differences in flood disturbance regimes between the two stream branches joining at a confluence were associated with higher mean fish abundance and more temporal stability in the relative abundance of native fish. Conversely, when flood disturbance conditions in the two streams joining were similar, resulting in a homogeneous confluence, fish abundance was lower and temporal variability was higher. For homogeneous confluences, strong interactions between native galaxiids and invasive trout probably produced lower fish densities where rivers with low flow disturbance met, whereas when two highly flow‐disturbed rivers met, environmental harshness probably lowered fish densities. By comparison, enhanced galaxiid temporal stability at confluences containing both disturbed and stable river branches probably reflected the combined effects of refugia from trout predation in disturbed branches and refugia from flooding in stable branches. Overall, these results are likely to reflect the combined effects of population‐specific responses to physical heterogeneity and spatially variable interspecific interactions. They may mean that river network configuration, and confluences especially, could influence community stability through a habitat portfolio effect. Furthermore, it will be worth investigating further whether preservation or restoration of differences in flow disturbance conditions in riverscapes encourages higher ecosystem resilience in the face of global change.

Chemical and physical heterogeneity within native gold: implications for the design of gold particle studies

Studies of populations of gold particles are becoming increasingly common; however, interpretation of compositional data may not be straightforward. Natural gold is rarely homogenous. Alloy heterogeneity is present as microfabrics formed either during primary mineralization or by modification of pre-existing alloys by chemical and physical drivers during subsequent residence in either hypogene or surficial environments. In electron-probe-microanalysis (EPMA)-based studies, the combination of Cu, Hg, and Pd values and mineral inclusion suites may be diagnostic for source style of mineralization, but Ag alone is rarely sufficient. Gold characterization studies by laser-ablation-ICP mass spectrometry linked to both quadrupole and Time-of-Flight (ToF-MS) systems show that only Ag, Cu, and Hg form homogenous alloys with Au sufficiently often to act as generic discriminants. Where present, other elements are commonly distributed highly heterogeneously at the micron or submicron scale, either as mineral inclusions or in highly localized, but low concentrations. Drawing upon our own data derived from individual inspection and analyses of approximately 40,000 gold particles from 526 placer and in situ localities worldwide, we show that adequate characterization of gold from a specific locality normally requires study of a minimum of 150 particles via a two-stage approach comprising spatial characterization of compositional heterogeneity, plus crystallographic orientation mapping, that informs subsequent targeted acquisition of quantitative compositional data by EPMA and/or laser-ablation ICP-MS methods. Such data provide the platform to review current understanding of the genesis of gold particle characteristics, elevating future compositional studies from empirical descriptions to process-focused interpretations.

Mechanism and Effect of Nanoparticles on Controlling Fines Migration in Unconsolidated Sandstone Formations

Summary Pore throat blockage due to fines migration during drilling and completion is one of the leading causes of damage to unconsolidated sandstone reservoirs. Therefore, it is necessary to explore an effective control method for fines migration. Five types of nanoparticles in suspension with aqueous NaCl solutions of six different ionic strengths were chosen. Their ability to control the migration of quartz and kaolinite fines in quartz sand as the porous medium is discussed in this work. Results show that nanoparticles can effectively adsorb and fix fines, thus successfully suppressing their migration. Among these nanoparticles, Al2O3 showed the best performance, and nanoparticle suspensions with higher ionic strengths were preferable. A surface element integration method was used to establish a mathematical model for calculating the interaction energy between the formation fines and the rock pore surface with adsorbed nanoparticles. Through atomic force microscopy and zeta potential measurements, the effect of nanoparticle adsorption on the heterogeneity of the pore surface was analyzed in terms of roughness and electrical properties. The interaction energy between the formation fines and the heterogeneous pore surface was calculated; it revealed the microscopic mechanism of how nanoparticles control fines migration. The results indicated that the nanoparticles form an adsorption layer, which enhances the physical and chemical heterogeneities of the pore surface and provides favorable conditions for the adsorption and fixation of fines. As a result, the interaction energy curves of the fines and the pore surface shift downward, and their repulsive barriers decrease or even disappear, exhibiting higher attractive potential energy. These variations promote adsorption and fixation of fines at the pore surface, as confirmed by the experimental results reported in this work, thus successfully preventing formation damage.

An optimization method of horizontal well completion control water and sand

With the development and maturity of horizontal well drilling and completion technology, horizontal wells are widely used in various reservoirs and have achieved good development results. Due to horizontal wells in the reservoir through a long distance, horizontal section of the reservoir physical property heterogeneity, water avoidance height difference and horizontal wellbore flow with toe effect, leading to production pressure difference and water breakthrough time in all parts of the shaft is different, the level of sand and bottom water cresting is strong heterogeneity, oil well early water breakthrough and local a large amount of sand production, the serious influence of horizontal well production and development of comprehensive benefits. In this paper, based on the prediction model of critical production pressure difference of sand production in horizontal wells and the prediction model of water appearance time of horizontal Wells in bottom water reservoir, the critical production pressure difference and water appearance time of sand production in each micro-element section are quantitatively determined along the horizontal well section, so as to form a design method of horizontal well completion that takes water and sand control into account. And ICD horizontal well completion method as the research object, water breakthrough time, yield as the optimization goal, control sand as constraint conditions, with each section down into the number of ICD string and nozzle sizes as design variables, the ICD horizontal well completion parameters established multi-objective optimization model, obtained the comprehensive consideration of water control sand control effect of the optimal ICD completion program.

Laterally varying scattering properties in the North Anatolian Fault Zone from ambient noise cross-correlations

SUMMARY Intrinsic absorption and scattering properties provide us with information about the physical state and heterogeneity of the Earth’s crust. These properties are usually obtained by observing the energy decay of naturally occurring earthquakes, leading to sparse spatial sampling and therefore average scattering values over a large region. This study uses ambient noise cross-correlations to analyse the energy decay and scattering properties over a part of the North Anatolian Fault (NAF; Turkey) from the continuous records of the 73 stations of the DANA temporary array in the frequency band 0.1–0.5 Hz. The region covered by the stations has rapidly varying geological characteristics and is highly faulted around the northern strand of the NAF. We measured in the noise correlations the space–time evolution of the energy of the coda waves. We first perform measurements in separate subregions. The local scattering and attenuation properties are obtained by global optimization of a 2-D solution of the radiative transfer equation for surface waves. We found that the mean free path and attenuation coefficient are considerably varying laterally with strong scattering observed in the region lying along the northern strand of NAF. The optimization provides well-constrained values for the scattering mean free path on the order of 10 km in the fault region. The mean free path is much larger (>100 km) in the neighbouring regions. We compare our global observations with a phonon based Monte Carlo simulation of scattered energy in a laterally variable scattering model. These simulations confirm the large contrast of heterogeneity between NAF and the surrounding crust and provide further constraints on the lateral extent of NAF. When sources are located inside the fault zone, we find a signature of the actual non-uniform scattering properties, observed as a concentration of energy in the fault zone for a limited amount of time. This in turn suggests that lateral variations of scattering properties should be taken into account in future monitoring studies.

Complex to simple: Fish growth along the Illinois River network

Fish growth in river ecosystems is influenced by a multitude of environmental drivers, including the heterogeneity of these drivers. Globally, river ecosystems are subject to anthropogenic stressors that can simplify riverine landscapes, homogenize riverine communities, and favor nonnative fishes. Yet, how anthropogenically driven simplification of riverine landscapes affects fish life-history traits remains largely unknown. The aim of this study was to examine the character of fish growth along the entire main channel of an Anthropocene River. We collected four species of potamodromous fish from different functional feeding guilds, from each of six functional process zones (FPZs) – unique large-scale hydrogeomorphic patches – along the entire length of the Illinois River (Illinois, USA), and calculated three growth metrics: growth rate (k), maximum size (L∞), and a relative growth index. The majority (7 of 12) of species-growth metric combinations did not differ among FPZs. Of the five species-growth metric combinations that were different, none exhibited more than three distinct groups of values. The limited difference in growth along the main channel of the Illinois River reflects a homogenization of ecosystem function, and is associated with the systemic simplification of physical heterogeneity of the river channel. The fishes studied from the Illinois River also tended to have faster growth rates (k) and smaller maximum sizes (L∞) relative to other North American freshwater ecosystems. Our results reveal spatial constraints to life-history traits and changes to ecosystem interactions, which are evidence of being in a new regime or state. This has implications for the reproductive output and resilience of native fishes in Anthropocene Rivers.