The investigation of graphene quantum dots (GQDs) at very small nano- and atomic sizes is a novel approach in the fields of structural cement, concrete, and ceramic materials, which have not been thoroughly explored. This study investigates the comparative effects of two variations of GQDs, Qdl and Qdp, against a control mixture to assess the potential of graphene derivatives in enhancing thermal and mechanical properties of cement composites. The research presents their influences across a wide range of attributes, including flowability, bulk density, permeable voids, water absorption, compressive strength, flexural strength, surface temperature, thermal conductivity, thermal diffusivity, specific heat capacity, Brunauer-Emmett-Teller (BET) isotherm, thermogravimetric analysis (TGA), and microstructural characteristics. The empirical data underscore the superior freshness, physical, mechanical, and thermal attributes of GQDs-infused cement composites. Notably, the composites with 0.3 % Qdl show 20.8 % and 50 % increases in compressive and flexural strengths, respectively. On the other hand, the composites with 1.2 % Qdp show significant improvements in both compressive and flexural strengths, being 40 % and 108 % stronger than the control, respectively. Additionally, the thermal properties of the composites exhibit a proportional enhancement with increasing GQDs content. Microstructural analyses reveal a nano-bridging mechanism well-uniformly facilitated by the secondary nucleation and crystallization of calcium silicate hydrate (CSH) gel. This investigation offers innovative insights into the incorporation of GQDs in cement composites, highlighting their potential to create highly conductive structural cement and ceramic.