Photonic Metasurfaces Research Articles

Metalens Topology Optimization

Photonic metasurfaces are thin optical elements comprised of structures arranged strategically upon a surface to manipulate electromagnetic waves. To produce metasurfaces at a large scale, it is beneficial to obtain not just an optimal design, but also an understanding of which areas of the metasurface are most influential on the overall performance of the device and require greater manufacturing accuracy. My work consisted of implementing and testing a new physics-based method for identifying the relative importance of different regions of a proposed metasurface design. This method built on an existing topology optimization code, where the designable region of the metasurface was discretized, and the material density of each point in the design was optimized such that incoming light was maximally focussed to a target location. The existing optimization algorithm was then coupled to a molecular dynamics model called a Nosé-Hoover thermostat, by modelling the discrete locations on the design region as particles and their corresponding material densities as their positions. By numerically integrating the equations of motion of the thermostat model, I was able to generate metasurface designs at different thermostat temperatures, and observe how the designs changed with increasing temperature. To determine the most important areas of the metasurface design, I calculated the entropy of each of the "particles" for all temperature samples, and looked for design regions that had low entropy even at high temperatures, indicating strong convergence on an optimal material density value amidst high thermal noise. Once I implemented this design analysis framework, I tested it on both a metalens and a reflector design at multiple wavelengths of incoming light. My results demonstrated that this physics-based method provides easily interpretable information about the relative importance of different elements of a metasurface design.

Polycrystalline methylammonium-lead bromide perovskite films for photonic metasurfaces

Polycrystalline films of organo-inorganic perovskite semiconductors are promising as a foundation for creating functional optical metasurfaces. The requirements for film structural perfection, thickness uniformity, and defect-free characteristics are much more stringent compared to perovskite films for photovoltaics. This work presents the results of searching for optimal conditions for one-step synthesis of lead methylammonium bromide films using centrifugation, and describes the successful fabrication of subwavelength optical gratings from these films through focused ion beam processing. The measured spectra of light transmission through the gratings demonstrated their excellent optical quality and confirmed the possibility of creating semiconductor photon metasurfaces with submicrometer periodicity and high-Q dielectric resonances.

Revealing Mode Formation in Quasi-Bound States in the Continuum Metasurfaces via Near-Field Optical Microscopy.

Photonic metasurfaces offer exceptional control over light at the nanoscale, facilitating applications spanning from biosensing, and nonlinear optics to photocatalysis. Many metasurfaces, especially resonant ones, rely on periodicity for the collective mode to form, which makes them subject to the influences of finite size effects, defects, and edge effects, which have considerable negative impact at the application level. These aspects are especially important for quasi-bound state in the continuum (BIC) metasurfaces, for which the collective mode is highly sensitive to perturbations due to high-quality factors and strong near-field enhancement. Here, the mode formation in quasi-BIC metasurfaces on the individual resonator level using scattering scanning near-field optical microscopy (s-SNOM) in combination with a new image processing technique, is quantitatively investigated. It is found that the quasi-BIC mode is formed at a minimum size of 10×10-unit cells much smaller than expected from far-field measurements. Furthermore, it is shown that the coupling direction of the resonators, defects and edge states have pronounced influence on the quasi-BIC mode. This study serves as a link between the far-field and near-field responses of metasurfaces, offering crucial insights for optimizing spatial footprint and active area, holding promise for augmenting applications such as catalysis and biospectroscopy.

Uncovering Maximum Chirality in Resonant Nanostructures.

Chiral nanostructures allow engineering of chiroptical responses; however, their design usually relies on empirical approaches and extensive numerical simulations. It remains unclear if a general strategy exists to enhance and maximize the intrinsic chirality of subwavelength photonic structures. Here, we suggest a microscopic theory and uncover the origin of strong chiral responses of resonant nanostructures. We reveal that the reactive helicity density is critically important for achieving maximum chirality at resonances. We demonstrate our general concept on the examples of planar photonic crystal slabs and metasurfaces, where out-of-plane mirror symmetry is broken by a bilayer design. Our findings provide a general recipe for designing photonic structures with maximum chirality, paving the way toward many applications, including chiral sensing, chiral emitters and detectors, and chiral quantum optics.

Roadmap on photonic metasurfaces

Here we present a roadmap on Photonic metasurfaces. This document consists of a number of perspective articles on different applications, challenge areas or technologies underlying photonic metasurfaces. Each perspective will introduce the topic, present a state of the art as well as give an insight into the future direction of the subfield.

Probing the Polarization of Low-Energy Excitations in 2D Materials from Atomic Crystals to Nanophotonic Arrays Using Momentum-Resolved Electron Energy Loss Spectroscopy.

Spectroscopies utilizing free electron beams as probes offer detailed information on the reciprocal-space excitations of 2D materials such as graphene and transition metal dichalcogenide monolayers. Yet, despite the attention paid to such quantum materials, less consideration has been given to the electron-beam characterization of 2D periodic nanostructures such as photonic crystals, metasurfaces, and plasmon arrays, which can exhibit the same lattice and excitation symmetries as their atomic analogues albeit at drastically different length, momentum, and energy scales. Because of their lack of covalent bonding and influence of retarded electromagnetic interactions, important physical distinctions arise that complicate interpretation of scattering signals. Here we present a fully-retarded theoretical framework for describing the inelastic scattering of wide-field electron beams from 2D materials and apply it to investigate the complementarity in sample excitation information gained in the measurement of a honeycomb plasmon array versus angle-resolved optical spectroscopy in comparison to single monolayer graphene.

Twist-Induced Hyperbolic Shear Metasurfaces

Following the discovery of moiré-driven superconductivity and density waves in twisted-graphene multilayers, twistronics has spurred a surge of interest in tailored broken symmetries through angular rotations enabling new properties, from electronics to photonics and phononics. Analogously, in monoclinic polar crystals a nontrivial angle between nondegenerate dipolar phonon resonances can naturally emerge due to asymmetries in their crystal lattice, and its variations are associated with intriguing polaritonic phenomena, including axial dispersion, i.e., the rotation of the optical axis with frequency, and microscopic shear effects that result in an asymmetric distribution of material loss. So far, these phenomena have been restricted to specific midinfrared frequencies difficult to access with conventional laser sources and fundamentally limited by the degree of asymmetry and by the strength of light-matter interactions available in natural crystals. Here, we leverage the twistronics concept to demonstrate maximal axial dispersion and loss redistribution of hyperbolic waves in elastic metasurfaces, achieved by tailoring the angle between coupled metasurface pairs featuring tailored anisotropy. We show extreme control over elastic wave dispersion and absorption via the twist angle and leverage the resulting phenomena to demonstrate enhanced propagation distance, in-plane reflection-free negative refraction and diffraction-free defect detection. Our work welds the concepts of twistronics, non-Hermiticity, and extreme anisotropy, demonstrating the powerful opportunities enabled by metasurfaces for tunable, highly directional surface-acoustic-wave propagation of great interest for a wide range of applications spanning from seismic mitigation to on-chip phononics and wireless communication systems, hence paving the way toward their translation into emerging photonic and polaritonic metasurface technologies. Published by the American Physical Society 2024

2D‐Material‐Fused High‐Emittance Plasmo–Photonic Metasurfaces

AbstractTransition metal dichalcogenides (TMDC) are a family of atomic‐layer 2D materials (2dMs). Many researches have attempted to reinforce the unique properties by incorporating artificially designed nanostructures. Here, a highly photoluminescence (PL) enhancing platform is reported that is formed by combining high‐emittance plasmo–photonic metasurfaces with a large‐area 2dM, which is a continuous monolayer of TMDC of cm2 dimension. It is experimentally demonstrated that the 2dM‐PL intensity at room temperature is enhanced by more than 1030‐fold in comparison with that observed on the flat gold film regions. The enhancement is associated with spectral transformation indicating a resonant effect of the metasurfaces. It is moreover revealed that the confocal PL image originates from a coherent single‐mode emission that forms a photon number distribution obeying the Poisson probability distribution. Thus, the 2dM‐fused metasurfaces function as efficient coherent quantum light sources. PL decay‐time analysis also reveals the coexistence of two components in the enhanced PL. The fast component exhibits a lifetime of 18 ps whereas the slow component decays at 4.4 ns. Both components are most likely to undergo radiative processes, which indicates that metal‐induced PL quenching is suppressed on these 2dM‐fused metasurfaces. The long lifetime component is ascribed to an excitonic intervalley transition.

Interplay between gain and loss in arrays of nonlinear plasmonic nanoparticles: toward parametric downconversion and amplification.

With the help of a theoretical model and finite-difference time-domain (FDTD) simulations based on the hydrodynamic-Maxwell model, we examine the effect of difference-frequency generation (DFG) in an array of L-shaped metal nanoparticles (MNPs) characterized by intrinsic plasmonic nonlinearity. The outcomes of the calculations reveal the spectral interplay between gain and loss in the vicinity of the fundamental frequency of the localized surface plasmon resonances. Subsequently, we identify different array thicknesses and pumping regimes facilitating parametric amplification and spontaneous parametric downconversion. Our results suggest that the parametric amplification regime becomes feasible on a scale of hundreds of nanometers and spontaneous parametric downconversion on the scale of tens of nanometers, opening up new exciting opportunities for developing building blocks of photonic metasurfaces.

Pixelated non-volatile programmable photonic integrated circuits with 20-level intermediate states

Multi-level programmable photonic integrated circuits (PICs) and optical metasurfaces have gained widespread attention in many fields, such as neuromorphic photonics, optical communications, and quantum information. In this paper, we propose pixelated programmable Si3N4 PICs with record-high 20-level intermediate states at 785 nm wavelength. Such flexibility in phase or amplitude modulation is achieved by a programmable Sb2S3 matrix, the footprint of whose elements can be as small as 1.2 μm, limited only by the optical diffraction limit of an in-house developed pulsed laser writing system. We believe our work lays the foundation for laser-writing ultra-high-level (20 levels and even more) programmable photonic systems and metasurfaces based on phase change materials, which could catalyze diverse applications such as programmable neuromorphic photonics, biosensing, optical computing, photonic quantum computing, and reconfigurable metasurfaces.

Thin-film polymeric metasurfaces for visible wavelengths

Photonic metasurfaces are typically realized by the periodic distribution of meta-atoms, which incorporate two or more different materials. This requirement introduces constraints in the design and fabrication that are particularly significant for flexible and conformable metasurfaces. Here, we report on the design and fabrication of efficient, polarization-independent, all-polymeric metasurface membranes for holographic applications in the visible range. These results will facilitate the large-scale production of holographic metasurfaces, advancing their adoption in practical, real-life scenarios.

Sensitive detection and evaluation of ultrafine dust particles with a resonant terahertz metasurface [Invited

We demonstrate efficient and highly sensitive detection methods for ultrafine dust and introduce a controllable evaluation way. Using the nanogaps of terahertz resonant metasurfaces where the terahertz field is greatly enhanced by the squeezed mode volume, the ultrafine dust particles were efficiently detected. The measured signal changes of the resonance can be modified in their spectral shape by the deposited particle concentrations with their effectively changed optical properties. Various resonant metasurfaces were compared and evaluated in terms of their geometrical design, relative gap size to the particle size, and particle concentration. Positioning ultrafine particles into the small nano gaps via the Polydimethylsiloxane film sweeping technique results in further significant changes in measured terahertz optical signal. The proposed method for ultrafine dust detection by photonic metasurface is promising as it guides advanced stages of ultrasensitive terahertz molecule sensors even at the real-world environmentally hazardous particulates both in qualitative and quantitative manners.

Reflective Spin–Orbit Geometric Phase from Planar Isotropic Interface

AbstractManipulating angular momentum of light relies on the change of geometric phase in anisotropic nanostructures or optical interface phenomena. Spin–orbit interactions demonstrated in normal incidence at a planar isotropic interface are conditioned by Brewster reflection, limited to the light beam with a single radial frequency in the k‐space. This study demonstrates a geometric (Pancharatnam–Berry) phase that overcomes Brewster angle limitations providing high variability in the modulation of light reflected from a planar isotropic interface. The examined geometric phase stems from the reflection anisotropy imitating the structural anisotropy of photoaligned liquid crystals and photonic metasurfaces. Using a geometric‐phase modulation of tightly focused light reflected from a glass slab, three modes of spin to orbital angular momentum conversion are demonstrated. The discovered reflective spin–orbit interaction allows for design of a double‐helix focusing sensor to be used in microscopy imaging for precise depth measurements (accuracy 109 nm and precision 7 nm in the range of 8 µm). Experiments with a focused astigmatic beam prove that a glass plate can perform very complex modulation of the geometric phase using illumination structuring. The results thus provide the foundation for the design of low‐cost geometric‐phase systems relying on the space‐variant reflection anisotropy.

Compact structured light generation based on meta-hologram PCSEL integration

Metasurfaces, a catalog of optical components, offer numerous novel functions on demand. They have been integrated with vertical cavity surface-emitting lasers (VCSELs) in previous studies. However, the performance has been limited by the features of the VCSELs such as low output power and large divergence angle. Although the solution of the module of VCSEL array could solve these issues, the practical application is limited by extra lens and large size. In this study, we experimentally demonstrate reconstruction of a holographic images using a compact integration of a photonic crystal surface-emitting laser and metasurface holograms designed for structured light generation. This research showcases the flexible design capabilities of metasurfaces, high output power (on the order of milliwatts), and the ability to produce well-uniformed images with a wide field of view without the need for a collection lens, making it suitable for 3D imaging and sensing.

Spin-dependent properties of optical modes guided by adiabatic trapping potentials in photonic Dirac metasurfaces.

The Dirac-like dispersion in photonic systems makes it possible to mimic the dispersion of relativistic spin-1/2 particles, which led to the development of the concept of photonic topological insulators. Despite recent demonstrations of various topological photonic phases, the full potential offered by Dirac photonic systems, specifically their ability to emulate the spin degree of freedom-referred to as pseudo-spin-beyond topological boundary modes has remained underexplored. Here we demonstrate that photonic Dirac metasurfaces with smooth one-dimensional trapping gauge potentials serve as effective waveguides with modes carrying pseudo-spin. We show that spatially varying gauge potentials act unevenly on the two pseudo-spins due to their different field distributions, which enables control of guided modes by their spin, a property that is unattainable with conventional optical waveguides. Silicon nanophotonic metasurfaces are used to experimentally confirm the properties of these guided modes and reveal their distinct spin-dependent radiative character; modes of opposite pseudo-spin exhibit disparate radiative lifetimes and couple differently to incident light. The spin-dependent field distributions and radiative lifetimes of their guided modes indicate that photonic Dirac metasurfaces could be used for spin-multiplexing, controlling the characteristics of optical guided modes, and tuning light-matter interactions with photonic pseudo-spins.

On-Chip Optical Trapping with High NA Metasurfaces.

Optical trapping of small particles typically requires the use of high NA microscope objectives. Photonic metasurfaces are an attractive alternative to create strongly focused beams for optical trapping applications in an integrated platform. Here, we report on the design, fabrication, and characterization of optical metasurfaces with a numerical aperture up to 1.2 and trapping stiffness greater than 400 pN/μm/W. We demonstrate that these metasurfaces perform as well as microscope objectives with the same numerical aperture. We systematically analyze the impact of the metasurface dimension on the trapping performance and show efficient trapping with metasurfaces with an area as small as 0.001 mm2. Finally, we demonstrate the versatility of the platform by designing metasurfaces able to create multisite optical tweezers for the trapping of extended objects.

A contactless single-step process for simultaneous nanoscale patterning and cleaning of large-area graphene

The capability to structure two-dimensional materials (2DMs) at the nanoscale with customizable patterns and over large areas is critical for a number of emerging applications, from nanoelectronics to 2D photonic metasurfaces. However, current technologies, such as photo- and electron-beam lithography, often employing masking layers, can significantly contaminate the materials. Large-area chemical vapour deposition-grown graphene is known to have non-ideal properties already due to surface contamination resulting from the transferring process. Additional contamination through the lithographic process might thus reduce the performance of any device based on the structured graphene. Here, we demonstrate a contactless chemical-free approach for simultaneous patterning and cleaning of self-supporting graphene membranes in a single step. Using energetic ions passing through a suspended mask with pre-defined nanopatterns, we deterministically structure graphene with demonstrated feature size of 15 nm, approaching the performance of small-area focused ion beam techniques and extreme ultraviolet lithography. Our approach, however, requires only a broad beam, no nanoscale beam positioning and enables large area patterning of 2DMs. Simultaneously, in regions surrounding the exposed areas, contaminations commonly observed on as-grown graphene targets, are effectively removed. This cleaning mechanism is attributed to coupling of surface diffusion and sputtering effects of adsorbed surface contaminants. For applications using 2DMs, this simultaneous patterning and cleaning mechanism may become essential for preparing the nanostructured materials with improved cleanliness and hence, quality.

Chiral metasurfaces in anisotropic thin film lithium niobate and its nonlinear effect

Different from conventional two-dimensional photonic metasurfaces, chiral photonic metasurfaces, which are composed of a chiral pattern with subwavelength dimensions, exhibit different chiroptical physical phenomena, such as spin-preserving, nonlinear chiroptical effects, and optical vortex generation. However, the effect of symmetry in the vertical direction on the linear and nonlinear response of the chiral quasi-two-dimensional metasurface has been seldom reported. In this study, we design and simulate a chiral metasurface using topological patterns in lithium niobate (LN) thin film to obtain the optimal circular dichroism and its corresponding nonlinear effect. Triangular holes with a certain rotation constitute a quasi-two-dimensional metasurface, which possesses outstanding chirality for the spin state of light, thus allowing it to control linear and nonlinear chiralities. The nonlinear conversion efficiency ηSHG reaches 2×10−4 and 4×10−3 on the LN structure with substrate and without substrate, respectively. Nonlinear circular dichroism CDSHG is 5.8 dB at 783 nm on a SiO2 substrate. This tunable chiral metasurface is expected to be applicable to nonlinear chiroptical responses and chiral light modulation.

Meshless optical mode solving using scalable deep deconvolutional neural network

Optical mode solving is of paramount importance in photonic design and discovery. In this paper we propose a deep deconvolutional neural network architecture for a meshless, and resolution scalable optical mode calculations. The solution is arbitrary in wavelengths and applicable for a wide range of photonic materials and dimensions. The deconvolutional model consists of two stages: the first stage projects the photonic geometrical parameters to a vector in a higher dimensional space, and the second stage deconvolves the vector into a mode image with the help of scaling blocks. Scaling block can be added or subtracted as per desired resolution in the final mode image, and it can be effectively trained using a transfer learning approach. Being a deep learning model, it is light, portable, and capable of rapidly disseminating edge computing ready solutions. Without the loss of generality, we illustrate the method for an optical channel waveguide, and readily generalizable for wide range photonic components including photonic crystals, optical cavities and metasurfaces.

Dual functional metasurface with broadband polarization conversion and perfect absorption

A dual-functional metasurface based on vanadium dioxide (VO2) and operating in the infrared region is proposed in this paper. The photonic metasurface consists of a double-split ring resonator and the gaps are loaded with VO2 to achieve dual-functionality. The proposed metasurface functions as a polarization converter at a temperature (T) of 358 K when VO2 is in insulating state. In this state, broadband linear to cross polarization is achieved with an excellent polarization conversion ratio (PCR) of > 98% in the 2702–4687 nm wavelength range. At a lower temperature (303 K), VO2 is in the metallic state and the metasurface functions as a wideband absorber with an absorptivity of > 90% in the wavelength range from 3896 − 4615 nm. There is a significant overlap in the frequency responses of the absorber and polarization converter leading to dual-functional behavior of the metasurface. Therefore, the structure is thermally tunable and suitable for optical and photonic applications.