To establish a secure and high-bandwidth communication link between the gateway node and the central node in the internet of underwater things (IoUwT), it is meaningful to introduce quantum key distribution (QKD) protocols into underwater wireless optical communication (UWOC) systems. However, the line-of-sight (LOS) requirement for photon transmission will pose an inevitable challenge to the QKD-based UWOC system. In this work, an optical intelligent reflecting surface (OIRS) array mounted on an autonomous underwater vehicle (AUV) is utilized for the first time to alleviate the LOS blockage and enable more reliable underwater wireless optical quantum link for both discrete-variable quantum key distribution (DV-QKD) and continuous-variable quantum key distribution (CV-QKD). To begin with, a novel statistical model of the aggregated channel transmissivity experienced by the OIRS-based quantum states in underwater link is derived by combing the effects of oceanic absorption, scattering, turbulence and OIRS misalignment, where the oceanic turbulence-induced irradiance fluctuation is modeled by exponential and generalized gamma (EGG) distribution, and the jitter angle associated with AUV-carried OIRS misalignment is characterized by a Rayleigh distribution. Then, on the basis of this statistical model and the Gauss-Chebyshev quadrature, the quantum bit error rate and the lower bound secret key rate (SKR) for the AUV-carried OIRS-assisted DV-QKD link are obtained with weak coherent optical source and decoy state idea by utilizing Gottesman-Lo-Lütkenhaus-Preskill. In terms of univariate Fox-H function, the average Pirandola-Laurenza-Ottaviani-Banchi (PLOB) bound over the bosonic pure-loss channel, as well as the thermal upper and lower bounds over the thermal-loss channel are both derived for the AUV-carried OIRS-assisted CV-QKD link. Additionally, the achievable SKR for a practical GG02 CV-QKD protocol in underwater channels is also presented through the worst-case analysis. Furthermore, the impacts of the number of OIRS elements, OIRS positioning, jitter variances, the probability of erroneous detection and link distance on the security performance of the proposed links are studied with different water types, thereby offering valuable insights for the QKD-based UWOC system in IoUwT.
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