A novel photoelectron spectrometer based on pulsed laser radiation is developed. The spectrometer realizes two features: the first is the photoelectron spectromicroscopy by focused vacuum ultraviolet (VUV) coherent radiation, the second is the two-photon photoelectron spectroscopy to probe excited states of adsorbed species. The characteristic feature of the photoelectron spectromicroscope is that it records photoelectron spectrum at every two-dimensional mesh point of the specimen. The feature allows detailed inspection of the electronic states of a spatially inhomogeneous surface. The two-photon photoelectron spectroscopy allows observation of the occupied and normally unoccupied states of adsorbed species. The method is applied to molecularly adsorbed NO on Cu(111). Preliminary result of two-photon photoelectron microscopy is also reported.