Photodissociation Regions Research Articles

Triggered and dispersed under feedback of super H ii region W4

The W3/4 Giant Molecular Cloud (GMC) was an ideal target to study the impact of H ii regions onto the surrounding molecular gas and star formation. We utilized PMO CO (1--0) data from the Milky Way Imaging Scroll Painting (MWISP) survey to analyze the cloud structure and the feedback effect from the W4 H ii region. Our observations showed that cold gas, traced by CO, mainly resided in the W3 GMC, with C18O concentrated in dense regions, while gas around W4 was dispersed. The 13CO position-position-velocity (PPV) distributions revealed a "C" shaped structure in the W3 cloud with more redshifted gas at higher galactic longitudes. A high density layer (HDL) region on the eastern side of the W3 region exhibited a flattened structure facing W4. Subdividing the area into sixteen subregions, we found that regions 6--9 on the HDL layer exhibited the strongest radiation, while clouds at the W4 bubble boundary not facing W3 exhibited weak signals, possibly due to star formation triggering and subsequent molecular gas dispersal by the H ii region. Analysis along four paths from the W4 H ii region to the far side showed a consistent trend of sharply increasing intensity followed by a slow decrease, indicating the gas was effectively eroded and heated by the photon dominated region (PDR) near the boundary of the H ii region. Clump identification based on 13CO emission revealed 288 structures categorized as "bubble," "HDL," and "quiescent" clumps. Analysis of mass-radius and Virial-mass relationships showed a potential for high-mass star formation in 29.5$<!PCT!>$ (85/288) of the clumps, with 39.2$<!PCT!>$ (113/288) being gravitationally bound. HDL clumps exhibited distinct $L/M$ and velocity dispersion, suggesting an earlier evolutionary stage and gravitational instability compared to quiescent and bubble clumps. Clump parameter differences provided evidence for triggered and dispersed effects of the W4 H ii region on the HDL and bubble regions, respectively.

Magnetic Field Alignment Relative to Multiple Tracers in the High-mass Star-forming Region RCW 36

We use polarization data from SOFIA HAWC+ to investigate the interplay between magnetic fields and stellar feedback in altering gas dynamics within the high-mass star-forming region RCW 36, located in Vela C. This region is of particular interest as it has a bipolar H ii region powered by a massive star cluster, which may be impacting the surrounding magnetic field. To determine if this is the case, we apply the histogram of relative orientations (HRO) method to quantify the relative alignment between the inferred magnetic field and elongated structures observed in several data sets such as dust emission, column density, temperature, and spectral line intensity maps. The HRO results indicate a bimodal alignment trend, where structures observed with dense gas tracers show a statistically significant preference for perpendicular alignment relative to the magnetic field, while structures probed by the photodissociation region (PDR) tracers tend to align preferentially parallel relative to the magnetic field. Moreover, the dense gas and PDR associated structures are found to be kinematically distinct such that a bimodal alignment trend is also observed as a function of line-of-sight velocity. This suggests that the magnetic field may have been dynamically important and set a preferred direction of gas flow at the time that RCW 36 formed, resulting in a dense ridge developing perpendicular to the magnetic field. However, on filament scales near the PDR region, feedback may be energetically dominating the magnetic field, warping its geometry and the associated flux-frozen gas structures, causing the observed preference for parallel relative alignment.

SOFIA/upGREAT far-infrared spectroscopy of bright rimmed pillars in IC 1848

Using the upGREAT instrument on SOFIA, we imaged the [C II] 158 µm fine structure line emission in bright-rimmed pillars located at the southern edge of the IC 1848 H II region, and carried out pointed observations of the [O I] 63 and 145 µm fine structure lines toward selected positions. The observations are used to characterize the morphology, velocity field, and the physical conditions in the G1–G3 filaments. The velocity-resolved [C II] spectra show evidence of a velocity shift at the head of the brightest G1 filament, possibly caused by radiation pressure from the impinging UV photons or the rocket effect of the evaporating gas. Archival Herschel PACS and SPIRE observations imply H2 column densities in the range 1021 –1022 cm−2 , corresponding to maximum visual extinction AV ≃ 10 mag, and average H2 volume density of ≃4500 cm−3 in the filaments. The [C II] emission traces ∼17% of the total H2 column density, as derived from dust SED fits. Photon-dominated region models are unable to explain the observed line intensities of the two [O I] fine structure lines in IC 1848, with the observed [O I] 145 µm line being too strong compared to the model predictions. The [O I] lines in IC 1848 are overall weak and the signal-to-noise ratio is limited. However, our observations suggest that the [O I] 63/145 µm intensity ratio is a sensitive probe of the physical conditions in photon-dominated regions such as IC 1848. These lines are thus excellent targets for future high-altitude balloon instruments, less affected by telluric absorption.

Quantifying the informativity of emission lines to infer physical conditions in giant molecular clouds

Context. Observations of ionic, atomic, or molecular lines are performed to improve our understanding of the interstellar medium (ISM). However, the potential of a line to constrain the physical conditions of the ISM is difficult to assess quantitatively, because of the complexity of the ISM physics. The situation is even more complex when trying to assess which combinations of lines are the most useful. Therefore, observation campaigns usually try to observe as many lines as possible for as much time as possible. Aims. We have searched for a quantitative statistical criterion to evaluate the full constraining power of a (combination of) tracer(s) with respect to physical conditions. Our goal with such a criterion is twofold. First, we want to improve our understanding of the statistical relationships between ISM tracers and physical conditions. Secondly, by exploiting this criterion, we aim to propose a method that helps observers to make their observation proposals; for example, by choosing to observe the lines with the highest constraining power given limited resources and time. Methods. We propose an approach based on information theory, in particular the concepts of conditional differential entropy and mutual information. The best (combination of) tracer(s) is obtained by comparing the mutual information between a physical parameter and different sets of lines. The presented analysis is independent of the choice of the estimation algorithm (e.g., neural network or χ2 minimization). We applied this method to simulations of radio molecular lines emitted by a photodissociation region similar to the Horsehead Nebula. In this simulated data, we considered the noise properties of a state-of-the-art single dish telescope such as the IRAM 30m telescope. We searched for the best lines to constrain the visual extinction, AVtot, or the ultraviolet illumination field, G0. We ran this search for different gas regimes, namely translucent gas, filamentary gas, and dense cores. Results. The most informative lines change with the physical regime (e.g., cloud extinction). However, the determination of the optimal (combination of) line(s) to constrain a physical parameter such as the visual extinction depends not only on the radiative transfer of the lines and chemistry of the associated species, but also on the achieved mean signal-to-noise ratio. The short integration time of the CO isotopologue J = 1 − 0 lines already yields much information on the total column density for a large range of (AVtot, G0) space. The best set of lines to constrain the visual extinction does not necessarily combine the most informative individual lines. Precise constraints on the radiation field are more difficult to achieve with molecular lines. They require spectral lines emitted at the cloud surface (e.g., [CII] and [CI] lines). Conclusions. This approach allows one to better explore the knowledge provided by ISM codes, and to guide future observation campaigns.

Bright-rimmed clouds in IC 1396

Aims. We investigate the dynamical and physical structures of bright-rimmed clouds (BRCs) in a nearby H II region. We focused on carbon- and oxygen-bearing species that trace photon-dominated regions (PDRs) and warm molecular cloud surfaces in order to understand the effect of UV radiation from the exciting stars on the cloud structure. Methods. We mapped four regions around the most prominent BRCs at scales of 4–10 arcmin in the H II region IC 1396 (IC 1396A, B, D, and E) in [C II] 158 µm with (up)GREAT on board SOFIA. IC 1396 is predominantly excited by an O6.5V star. Toward IC 1396A, we also observed [O I] 63 µm and 145 µm. We combined these observations with JCMT archive data, which provide the low-J transitions of CO, 13CO, and C18O. All spectra are velocity-resolved. Results. The line profiles in the four mapped regions show a variety of velocity structures, which we investigated in detail for all observed emission lines. IC 1396B and D show clearly distinct velocity components that overlap along the line of sight. We find no clear sign of photoevaporating flows in the [C II] spectra, although the uncertainty in the location of the BRCs along the line of sight makes this interpretation inconclusive. Our analysis of the [13C II] emission in IC1396 A, which has the best signal-to-noise ratio, suggests that the [C II] is likely mostly optically thin. The heating efficiency, measured by the ([C II]+[O I] 63 µm)/far-infrared intensity ratio, is higher in the northern part of IC 1396A than in the southern part, which may indicate a difference in the dust properties of the two areas. Conclusions. The complex velocity structures identified in the BRCs of IC 1396, which is apparently a relatively simple H II region, highlight the importance of velocity-resolved data for disentangling different components along the line of sight and thus facilitating a detailed study of the dynamics of the cloud. We also demonstrate that the optically thin [13C II] and [O I] 145 µm emission lines are essential for a conclusive interpretation of the [C II] 158 µm and [O I] 63 µm line profiles.

An ALCHEMI inspection of sulphur-bearing species towards the central molecular zone of NGC 253

Context. Sulphur-bearing species are detected in various environments within Galactic star-forming regions and are particularly abundant in the gas phase of outflow and shocked regions in addition to photo-dissociation regions. Thanks to the powerful capabilities of millimetre interferometers, studying sulphur-bearing species and their region of emission in various extreme extra-galactic environments (e.g. starburst and active galactic nuclei) and at a high-angular resolution and sensitivity is now possible. Aims. In this work, we aim to investigate the nature of the emission from the most common sulphur-bearing species observable at millimetre wavelengths towards the nuclear starburst of the nearby galaxy NGC 253. We intend to understand which type of regions are probed by sulphur-bearing species and which process(es) dominate(s) the release of sulphur into the gas phase. Methods. We used the high-angular resolution (1.6″ or ∼27 pc) observations from the ALCHEMI ALMA Large Program to image several sulphur-bearing species towards the central molecular zone (CMZ) of NGC 253. We performed local thermodynamic equilibrium (LTE) and non-LTE large velocity gradient (LVG) analyses to derive the physical conditions of the gas where the sulphur-bearing species are emitted, and their abundance ratios across the CMZ. Finally, we compared our results with previous ALCHEMI studies and a few selected Galactic environments. Results. To reproduce the observations, we modelled two gas components for most of the sulphur-bearing species investigated in this work. We found that not all sulphur-bearing species trace the same type of gas: strong evidence indicates that H2S and part of the emission of OCS, H2CS, and SO are tracing shocks, whilst part of SO and CS emission rather traces the dense molecular gas. For some species, such as CCS and SO2, we could not firmly conclude on their origin of emission. Conclusions. The present analysis indicates that the emission from most sulphur-bearing species throughout the CMZ is likely dominated by shocks associated with ongoing star formation. In the inner part of the CMZ where the presence of super star clusters was previously indicated, we could not distinguish between shocks or thermal evaporation as the main process releasing the S-bearing species.

Ongoing and Fossil Large-scale Outflows Detected in a High-redshift Radio Galaxy: [C ii] Observations of TN J0924-2201 at z = 5.174

We present Atacama Large Millimeter/submillimeter Array observations of the [C ii] 158 μm line and the underlying continuum emission of TN J0924−2201, which is one of the most distant known radio galaxies at z > 5. The [C ii] line and 1 mm continuum emission are detected at the host galaxy. The systemic redshift derived from the [C ii] line is z [C II] = 5.1736 ± 0.0002, indicating that the Lyα line is redshifted by a velocity of 1035 ± 10 km s−1, marking the largest velocity offset between the [C ii] and Lyα lines recorded at z > 5 to date. In the central region of the host galaxy, we identify a redshifted substructure of [C ii] with a velocity of 702 ± 17 km s−1, which is close to the C iv line with a velocity of 500 ± 10 km s−1. The position and the velocity offsets align with a model of an outflowing shell structure, consistent with the large velocity offset of Lyα. The nondetection of [C ii] and dust emission from the three CO(1–0)-detected companions indicates their different nature compared to dwarf galaxies, based on the photodissociation region model. Given their large velocity of ∼1500 km s−1, outflowing molecular clouds induced by the active galactic nucleus are the most plausible interpretation, and they may exceed the escape velocity of a 1013 M ⊙ halo. These results suggest that TN J0924−2201, with ongoing and fossil large-scale outflows, is in a distinctive phase of removing molecular gas from a central massive galaxy in an overdense region in the early Universe. A dusty H i absorber at the host galaxy is an alternative interpretation.

Radiative and mechanical energies in galaxies

Context. Atomic and molecular lines emitted from galaxies are fundamental tracers of the medium responsible for the emission and contain valuable information regarding the energy budget and the strength of the different feedback mechanisms. Aims. The goal of this work is to provide a new framework for the interpretation of atomic and molecular lines originating from extragalactic sources and a robust method to deduce the mechanical and radiative energy budget from a set of observations. Methods. Atomic and molecular lines detected in a given object are assumed to result from the combination of distributions of shocks and photo-dissociation regions (PDRs) within the observational beam. The emission of individual structures is computed using the Paris-Durham shock code and the Meudon PDR code over a wide range of parameters. The total emission is then calculated assuming probability distribution functions for shocks and PDRs. A distance between the observational dataset and the model is finally defined based on the ratios of the observed to the predicted intensities. Results. As a test case scenario, we consider the radio galaxy 3C 326 N. The dataset is composed of 12 rotational and ro-vibrational lines of H2 and the fine structure lines of C+ and O. Our interpretative framework shows that both shocks and PDRs are required to explain the line fluxes. Surprisingly, viable solutions are obtained at low density only (nH < 100 cm−3), indicating that most of the emission originates from diffuse interstellar matter. The optimal solution, obtained for nH = 10 cm−3, corresponds to a distribution of low-velocity shocks (between 5 and 20 km s−1) propagating in PDR environments illuminated by a UV radiation field ten times larger than that in the solar neighborhood. This solution implies that at least 4% of the total mass carried by the PDRs is shocked. The H2 0-0 S(0) 28 μm, [CII] 158 μm, and [OI] 63 μm lines originate from the PDR components, while all the other H2 lines are mostly emitted by shocks. The total solid angles sustained by PDRs and shocks imply that the radiative and mechanical energies reprocessed by these structures are LUV = 6.3 × 109 L⊙ and LK = 3.9 × 108 L⊙, respectively, in remarkable agreement with the values of the IR luminosity deduced from the fit of the spectral energy distribution (SED) of 3C 326 N, and consistent with a small fraction of the active galactic nuclei (AGN) jet kinetic power dissipated in the interstellar medium (≈1%). Conclusions. This work shows that the radiative and mechanical energy budget of galaxies can be derived from the sole observations of atomic and molecular lines. It reveals the unexpected importance of the diffuse medium for 3C 326 N, in contrast to previous studies. A last-minute comparison of the model to new JWST data obtained in 3C 326 N shows a striking agreement and demonstrates the ability of the model to make accurate predictions. This framework opens new prospects for the prediction and interpretation of extragalactic observations, in particular in the context of JWST observations.

FEAST: Feedback in Emerging extragAlactic Star ClusTers: JWST Spots Polycyclic Aromatic Hydrocarbon Destruction in NGC 628 during the Emerging Phase of Star Formation

We investigate the emergence phase of young star clusters in the nearby spiral galaxy NGC 628. We use JWST NIRCam and MIRI observations to create spatially resolved maps of the Paα 1.87 μm and Brα 4.05 μm hydrogen recombination lines, as well as 3.3 and 7.7 μm emission from polycyclic aromatic hydrocarbons (PAHs). We extract 953 compact H ii regions and analyze the PAH emission and morphology at ∼10 pc scales in the associated photodissociation regions. While H ii regions remain compact, radial profiles help us to define three PAH morphological classes: compact (∼42%), extended (∼34%), and open (∼24%). The majority of compact and extended PAH morphologies are associated with very young star clusters (<5 Myr), while open PAH morphologies are mainly associated with star clusters older than 3 Myr. We observe a general decrease in the 3.3 and 7.7 μm PAH band emission as a function of cluster age, while their ratio remains constant with age out to 10 Myr and morphological class. The recovered PAH3.3μm/PAH7.7μm ratio is lower than values reported in the literature for reference models that consider neutral and ionized PAH populations and analyses conducted at galactic physical scales. The 3.3 and 7.7 μm bands are typically associated with neutral and ionized PAHs, respectively. While we expected neutral PAHs to be suppressed in proximity to an ionizing source, the constant PAH3.3μm/PAH7.7μm ratio would indicate that both families of molecules disrupt at similar rates in proximity to H ii regions.

Multiline observations of hydrogen, helium, and carbon radio-recombination lines toward Orion A: A detailed dynamical study and direct determination of physical conditions

We present a study of hydrogen, helium, and carbon millimeter-wave radio-recombination lines (RRLs) toward 10 representative positions throughout the Orion Nebula complex, using the Yebes 40 m telescope in the Q band (31.3 GHz to 50.6 GHz) at an angular resolution of about 45″ (~0.09 pc). The observed positions include the Orion Nebula (M42) with the Orion Molecular Core 1, M43, and the Orion Molecular Core 3 bordering on NGC 1973, 1975, and 1977. While hydrogen and helium RRLs arise in the ionized gas surrounding the massive stars in the Orion Nebula complex, carbon RRLs stem from the neutral gas of the adjacent photo-dissociation regions (PDRs). The high velocity resolution (0.3 km s−1) enables us to discern the detailed dynamics of the RRL emitting neutral and ionized gas. We compare the carbon RRLs with SOFIA/upGREAT observations of the [C II] 158 µm line and IRAM 30 m observations of the 13CO (J = 2−1) line (the complete map is presented here for the first time). We observe small differences in peak velocities between the different tracers, which cannot always be attributed to geometry but potentially to shear motions. Using the far-infrared [C II] and [13C II] intensities with the carbon RRL intensities, we can infer physical conditions (electron temperature Te and electron density ne, converted to hydrogen nuclei density nH by dividing by the carbon gas-phase abundance 𝒜c ≃ 1.4 × 10−4) in the PDR gas using nonlocal thermal equilibrium excitation models. For positions in OMC1, we infer ne ≃ 20–40 cm−3 and Te ≃ 210–240 K. On the border between OMC1 and M43, we observe two gas components with ne ≃ 2 cm−3 and ne ≃ 8 cm−3, and Te ≃ 100 K and Te ≃ 150 K. In M43, we infer ne ≃ 2–3 cm−3 and Te ≃ 140 K. The Extended Orion Nebula southeast of OMC1 is characterized by ne ≃ 2 cm−3 and Te ≃ 180 K, while OMC3 has ne ≃ 1 cm−3 and Te ≃ 130 K. Our observations are sensitive enough to detect faint lines toward two positions in OMC1, in the BN/KL PDR and the PDR close to the Trapezium stars, that may be attributed to RRLs of C+ or O+. In general, the RRL line widths of both the ionized and neutral gas, as well as the [C II] and 13CO line widths, are broader than thermal, indicating significant turbulence in the interstellar medium, which transitions from super-Alfvénic and subsonic in the ionized gas to sub-Alfvénic and supersonic in the molecular gas. At the scales probed by our observations, the turbulent pressure dominates the pressure balance in the neutral and molecular gas, while in the ionized gas the turbulent pressure is much smaller than the thermal pressure.

PDRs4All

Context. Mid-infrared emission features are important probes of the properties of ionized gas and hot or warm molecular gas, which are difficult to probe at other wavelengths. The Orion Bar photodissociation region (PDR) is a bright, nearby, and frequently studied target containing large amounts of gas under these conditions. Under the “PDRs4All” Early Release Science Program for JWST, a part of the Orion Bar was observed with MIRI integral field unit (IFU) spectroscopy, and these high-sensitivity IR spectroscopic images of very high angular resolution (0.2″) provide a rich observational inventory of the mid-infrared (MIR) emission lines, while resolving the H II region, the ionization front, and multiple dissociation fronts. Aims. We list, identify, and measure the most prominent gas emission lines in the Orion Bar using the new MIRI IFU data. An initial analysis summarizes the physical conditions of the gas and demonstrates the potential of these new data and future IFU observations with JWST. Methods. The MIRI IFU mosaic spatially resolves the substructure of the PDR, its footprint cutting perpendicularly across the ionization front and three dissociation fronts. We performed an up-to-date data reduction, and extracted five spectra that represent the ionized, atomic, and molecular gas layers. We identified the observed lines through a comparison with theoretical line lists derived from atomic data and simulated PDR models. The identified species and transitions are summarized in the main table of this work, with measurements of the line intensities and central wavelengths. Results. We identified around 100 lines and report an additional 18 lines that remain unidentified. The majority consists of H I recombination lines arising from the ionized gas layer bordering the PDR. The H I line ratios are well matched by emissivity coefficients from H recombination theory, but deviate by up to 10% because of contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni. We show how the Ne III/Ne II, S IV/S III, and Ar III/Ar II ratios trace the conditions in the ionized layer bordering the PDR, while Fe III/Fe II and Ni III/Ni II exhibit a different behavior, as there are significant contributions to Fe II and Ni II from the neutral PDR gas. We observe the pure-rotational H2 lines in the vibrational ground state from 0–0 S(1) to 0–0 S (8), and in the first vibrationally excited state from 1–1 S (5) to 1–1 S(9). We derive H2 excitation diagrams, and for the three observed dissociation fronts, the rotational excitation can be approximated with one thermal (~700 K) component representative of an average gas temperature, and one nonthermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model of the Orion Bar PDR, and find that the predicted excitation matches the data qualitatively, while adjustments to the parameters of the PDR model are required to reproduce the intensity of the 0–0 S (6) to S (8) lines.

PDRs4All

Context. One of the main problems in astrochemistry is determining the amount of sulfur in volatiles and refractories in the interstellar medium. The detection of the main sulfur reservoirs (icy H2S and atomic gas) has been challenging, and estimates are based on the reliability of models to account for the abundances of species containing less than 1% of the total sulfur. The high sensitivity of the James Webb Space Telescope provides an unprecedented opportunity to estimate the sulfur abundance through the observation of the [S I] 25.249 µm line. Aims. Our aim is to determine the amount of sulfur in the ionized and warm molecular phases toward the Orion Bar as a template to investigate sulfur depletion in the transition between the ionized gas and the molecular cloud in HII regions. Methods. We used the [S III] 18.7 µm, [S IV] 10.5 µm, and [S l] 25.249 µm lines to estimate the amount of sulfur in the ionized and molecular gas along the Orion Bar. For the theoretical part, we used an upgraded version of the Meudon photodissociation region (PDR) code to model the observations. New inelastic collision rates of neutral atomic sulfur with ortho-and para- molecular hydrogen were calculated to predict the line intensities. Results. The [S III] 18.7 µm and [S IV] 10.5 µm lines are detected over the imaged region with a shallow increase (by a factor of 4) toward the HII region. This suggests that their emissions are partially coming from the Orion Veil. We estimate a moderate sulfur depletion, by a factor of ~2, in the ionized gas. The corrugated interface between the molecular and atomic phases gives rise to several edge-on dissociation fronts we refer to as DF1, DF2, and DF3. The [S l] 25.249 µm line is only detected toward DF2 and DF3, the dissociation fronts located farthest from the HII region. This is the first ever detection of the [S l] 25.249 µm line in a PDR. The detailed modeling of DF3 using the Meudon PDR code shows that the emission of the [S l] 25.249 µm line is coming from warm (&gt;40 K) molecular gas located at AV ~1–5 mag from the ionization front. Moreover, the intensity of the [S l] 25.249 µm line is only accounted for if we assume the presence of undepleted sulfur. Conclusions. Our data show that sulfur remains undepleted along the ionic, atomic, and molecular gas in the Orion Bar. This is consistent with recent findings that suggest that sulfur depletion is low in massive star-forming regions because of the interaction of the UV photons coming from the newly formed stars with the interstellar matter.

The effects of stellar feedback on molecular clumps in the Lagoon Nebula (M8)

Context. The Lagoon Nebula (M8) is host to multiple regions with recent and ongoing massive star formation, due to which it appears as one of the brightest H II regions in the sky. M8-Main and M8 East, two prominent regions of massive star formation, have been studied in detail over the past few years, while large parts of the nebula and its surroundings have received little attention. These largely unexplored regions comprise a large sample of molecular clumps that are affected by the presence of massive O- and B-type stars. Thus, exploring the dynamics and chemical composition of these clumps will improve our understanding of the feedback from massive stars on star-forming regions in their vicinity. Aims. We established an inventory of species observed towards 37 known molecular clumps in M8 and investigated their physical structure. We compared our findings for these clumps with the galaxy-wide sample of massive dense clumps observed as part of the APEX Telescope Large Area Survey of the Galaxy (ATLASGAL). Furthermore, we investigated the region for signs of star formation and stellar feedback. Methods. To obtain an overview of the kinematics and chemical abundances across the sample of molecular clumps in the M8 region, we conducted an unbiased line survey for each clump. We used the Atacama Pathfinder EXperiment (APEX) 12m submillimetre telescope and the 30 m telescope of the Institut de Radioastronomie Millimétrique (IRAM) to conduct pointed on-off observations of 37 clumps in M8. These observations cover bandwidths of 53 GHz and 40 GHz in frequency ranges from 210 GHz to 280 GHz and from 70 GHz to 117 GHz, respectively. Temperatures were derived from rotational transitions of acetonitrile, methyl acetylene, and para-formaldehyde. Additional archival data from the Spitzer, Herschel, MSX, APEX, WISE, JCMT, and AKARI telescopes were used to investigate the morphology of the region and to derive the physical parameters of the dust emission by fitting spectral energy distributions to the observed flux densities. Results. Across the observed M8 region, we identify 346 transitions from 70 different molecular species, including isotopologues. While many species and fainter transitions are detected exclusively towards M8 East, we also observe a large chemical variety in many other molecular clumps. We detect tracers of photo-dissociation regions (PDRs) across all the clumps, and 38% of these clumps show signs of star formation. In our sample of clumps with extinctions between 1 and 60 mag, we find that PDR tracers are most abundant in clumps with relatively low H2 column densities. When comparing M8 clumps to ATLASGAL sources at similar distances, we find them to be slightly less massive (median 10 M⊙) and have compatible luminosities (median 200 L⊙) and radii (median 0.16 pc). In contrast, dust temperatures of the clumps in M8 are found to be increased by approximately 5 K (25%), indicating substantial external heating of the clumps by radiation of the present O- and B-type stars. Conclusions. This work finds clear and widespread effects of stellar feedback on the molecular clumps in the Lagoon Nebula. While the radiation from the O- and B-type stars possibly causes fragmentation of the remnant gas and heats the molecular clumps externally, it also gives rise to extended PDRs on the clump surfaces. Despite this fragmentation, the dense cores within 38% of the observed clumps in M8 are forming a new generation of stars.

A Radial Decrease in Kinetic Temperature Measured with H2CO in 30 Doradus

Feedback from star formation is a critical component of the evolution of galaxies and their interstellar medium. At parsec scales internal to molecular clouds, however, the observed signatures of that feedback on the physical properties of CO-emitting gas have often been weak or inconclusive. We present subparsec observations of H2CO in the 30 Doradus region, which contains the massive star cluster R136 that is clearly exerting feedback on its neighboring gas. H2CO provides a direct measure of gas kinetic temperature, and we find a trend of decreasing temperature with projected distance from R136 that may be indicative of gas heating by the stars. While it has been suggested that mechanical heating affects H2CO-measured temperature, we do not observe any correlation between T K and line width. The lack of an enhancement in mechanical feedback close to R136 is consistent with the absence of a radial trend in gravitational boundedness seen the Atacama Large Millimeter/submillimeter Array CO observations. Estimates of cosmic-ray flux in the region are quite uncertain, but can plausibly explain the observed temperatures if R136 itself is the dominant local source of energetic protons. The observations presented here are also consistent with the H2CO-emitting gas near R136 being dominated by direct radiation from R136 and photoelectric heating in the photodissociation regions.

First Constraints on the Interstellar Medium Conditions of a Low-mass, Highly Obscured z = 4.27 Main-sequence Galaxy

We present the molecular gas content and interstellar medium conditions of MACS J0717_Az9, a strong gravitationally lensed z = 4.273, M * ≃ 2 × 109 M ⊙ star-forming galaxy with an unusually high (∼80%) obscured star formation fraction. We detect CO (4–3) in two independent lensed images, as well as [N ii] 205 μm, with the Atacama Large Millimeter Array. We derive a molecular gas mass of log 10[MH2(M⊙)]=9.77 , making it moderately deficient in molecular gas compared to the lower-redshift gas fraction scaling relation. Leveraging photodissociation region (PDR) models, we combine our CO (4–3) measurements with existing measurements of the [C ii] 158 μm line and total infrared luminosity to model the PDR conditions. We find PDR conditions similar to those in local star-forming galaxies, with a mean hydrogen density log10[n H cm−3] = 4.80 ± 0.39 and a mean radiation field strength log10[G 0 Habing] = 2.83 ± 0.26. Based on Band 3 continuum data, we derive an upper limit on the intrinsic dust mass of log10[M dust(M ⊙)] < 7.73, consistent with existing estimates. We use the 3D tilted-ring model fitting code 3D-Barolo to determine the kinematic properties of the CO (4–3) emitting gas. We find that it is rotationally dominated, with a V/σ = 4.6 ± 1.7, consistent with the kinematics of the [C ii]. With PDR conditions remarkably similar to those in normal dusty star-forming galaxies at z < 0.2 and a stable molecular disk, our observations of Az9 suggest that the dust-obscured phase for a low-mass galaxy at z ∼ 4 is relatively long. Thus, Az9 may be representative of a more widespread population that has been missed owing to insufficiently deep existing millimeter surveys.

Constraining the physical properties of gas in high-z galaxies with far-infrared and submillimetre line ratios

Optical emission line diagnostics, which are a common tool for constraining the properties of the interstellar medium (ISM) of galaxies, become progressively inaccessible at higher redshifts for ground-based facilities. Far-infrared (FIR) emission lines, which are redshifted into atmospheric windows that are accessible for ground-based submillimetre facilities, could provide ISM diagnostics alternative to optical emission lines. We investigated FIR line ratios involving CII OIII OIII NII and NIII using synthetic emission lines applied to a high-resolution gas $= 883.4 M$_ odot $) cosmological zoom-in simulation, including radiative transfer post-processing with the code at z = 6.5. We find that the CII NII 122 ratio is sensitive to the temperature and density of photodissociation regions. It might therefore be a useful tool for tracing the properties of this gas phase in galaxies. We also find that NII NIII is a good tracer of the temperature and that OIII OIII 88 is a good tracer of the gas density of HII regions. Emission line ratios containing the OIII line are sensitive to high-velocity outflowing gas.

First detection of CF+ in the Large Magellanic Cloud

Context. CF+ has been established as a valuable diagnostic tool for investigating photodissociation regions (PDRs) and fluorine abundances in the Milky Way. However, its role in extragalactic environments remains largely uncharted. Aims. Our objective is to explore the significance of CF+ in the Large Magellanic Cloud (LMC) and assess its utility as a probe for examining C+ and fluorine abundances in external galaxies. Methods. We performed pointed CF+ observations toward an active star-forming region, N113 in the LMC, using the Atacama Pathfinder EXperiment 12 m submillimeter telescope. Results. We report the first discovery of CF+ in the LMC through the successful detection of the CF+ (2→1) and (3→2) lines. The excitation models indicate that CF+ emission originates from dense PDRs characterized by an H2 number density of (0.5–7.9) × 104 cm−3 in N113. Our observations provide the first constraint on the fluorine abundance in molecular clouds in the LMC, ≲1.7 × 10−9. This value is about an order of magnitude lower than those previously measured toward red giants in the LMC, indicative of fluorine deficiency in the molecular gas. The estimated column density ratio between C+ and CF+ appears to be lower than the anticipated equilibrium ratio derived from the fluorine abundance in red giants. Both phenomena can be explained by the deficiency of CF+ caused by the freeze-out of its primary chemical precursor, HF, onto dust grains. Conclusions. The deficiency of CF+ within molecular clouds suggests that the measurements presented in this work serve exclusively as conservative estimates, establishing lower bounds for both the fluorine abundance and C+ column densities in external galaxies.

JWST observations of the Horsehead photon-dominated region

Context. The James Webb Space Telescope (JWST) has captured the sharpest infrared images ever taken of the Horsehead nebula, a prototypical moderately irradiated photon-dominated region (PDR) that is fully representative of most of the UV-illuminated molecular gas in the Milky Way and star-forming galaxies. Aims. We investigate the impact of far-ultraviolet (FUV) radiation emitted by a massive star on the edge of a molecular cloud in terms of photoevaporation, ionization, dissociation, H2 excitation, and dust heating. We also aim to constrain the structure of the edge of the PDR and its illumination conditions. Methods. We used NIRCam and MIRI to obtain 17 broadband and 6 narrowband maps of the illuminated edge of the Horsehead across a wide spectral range from 0.7 to 28 µm. We mapped the dust emission, including the aromatic and aliphatic infrared (IR) bands, scattered light, and several gas phase lines (e.g., Paa, Brα, H2 1-0 S(1) at 2.12 µm). For our analysis, we also associated two HST-WFC3 maps at 1.1 and 1.6 µm, along with HST-STIS spectroscopic observations of the Ha line. Results. We probed the structure of the edge of the Horsehead and resolved its spatial complexity with an angular resolution of 0.1 to 1″ (equivalent to 2 × 10−4 to 2 × 10−3 pc or 40 to 400 au at the distance of 400 pc). We detected a network of faint striated features extending perpendicularly to the PDR front into the HII region in NIRCam and MIRI filters sensitive to nano-grain emission, as well as in the HST filter at 1.1 µm, which traces light scattered by larger grains. This may indeed figure as the first detection of the entrainment of dust particles in the evaporative flow. The filamentary structure of the 1-0 S(1) line of H2 at the illuminated edge of the PDR presents numerous sharp sub-structures on scales as small as 1.5″. An excess of H2 emission compared to dust emission is found all along the edge, in a narrow layer (width around 1″, corresponding to 2 × 10−3 pc or 400 au) directly illuminated by σ-Orionis. The ionization front and the dissociation front appear at distances 1–2″ behind the external edge of the PDR and seem to spatially coincide, indicating a very small thickness of the neutral atomic layer (below 100 au). All broadband maps present strong color variations between the illuminated edge and the internal regions. This can be explained by dust attenuation in a scenario where the illuminating star σ-Orionis is slightly inclined compared to the plane of the sky, so that the Horsehead is illuminated from behind at an oblique angle. The deviations from predictions of the measured emissions in the Hα, Paα, and Brα lines also indicate dust attenuation. With a very simple model, we used the data to derive the main spectral features of the extinction curve. A small excess of extinction at 3 µm may be attributed to icy H2O mantles onto grains formed in dense regions. We also derived attenuation profiles from 0.7 to 25 µm across the PDR. In all lines of sight crossing the inner regions of the Horsehead, especially around the IR peak position, it appears that dust attenuation is non-negligible over the entire spectral range of the JWST.

Vertical and radial distribution of atomic carbon in HD 163296

Context. In protoplanetary disks, atomic carbon is expected to originate from the photo dissociation region at the disk surface where CO is dissociated by ultraviolet (UV) photons coming from the stellar, or external interstellar, radiation field. Even though atomic carbon has been detected in several protoplanetary disks, there is a lack of spatially resolved observations of it. Aims. For the HD 163296 protoplanetary disk, we aim to obtain both the radial and vertical structure of [CI] = 3P1 − 3P0 line emission and perform the first direct comparison of this tracer with the optically thick line emission 12CO J = 2 − 1. Methods. We used archival ALMA data for [CI] = 3P1 − 3P0 and previously published12 CO J = 2 − 1 data in HD 163296. Through the disksurf software, we extracted the vertical structure; meanwhile, we obtained the radial profiles directly from imaging. Brand new DALI modeling was employed to perform a direct comparison with the data. Results. We find that these tracers are colocated radially but not vertically, where the 12CO J = 2 − 1 emission is, on average, located at higher altitudes, as is also the case for other tracers in the same disk. Conclusions. Due to this difference in the vertical height of the emission, the optically thick 12CO J = 2 − 1 emission line appears to trace the highest altitudes, despite the expected formation mechanism of [CI] in the disk. The latter phenomena may be due to efficient mixing of the upper layers of the disk, or UV photons penetrating deeper than we expected.

Role of Polycyclic Aromatic Hydrocarbons with Edge Defects in Explaining Astronomical Infrared Emission Observations

A systematic study was performed on the spectral properties of polycyclic aromatic hydrocarbons (PAHs) with edge defects using harmonic density functional theory calculations. Their potential astronomical relevance was assessed through direct comparison with NIRSpec and MIRI-MRS spectra of the atomic photodissociation region of the Orion Bar from the JWST Early Release Science PDRs4All program. It is found that the astronomical 6.2 μm PAH emission band, including its blue side, is well reproduced by PAHs with edge defects, when taking into account the effects of polarization in the computations, and without a need for PAHs that contain nitrogen. Small neutral PAHs with edge defects explain the blue wing of the 3.3 μm band. A low number of edge defects is required to reproduce the 8.6 and 11.2 μm band profiles, while the 11.0 + 11.2/12.7 μm band intensity ratio is a measure for the number of edge defects. A blind database fit to the Orion Bar spectrum reproduces the 6–15 μm region with an error of 9.9% and shows a clear delineation of charge, with the 6–10 μm PAH bands being carried by PAH cations and the 10–15 μm region by predominantly neutral PAHs. The contribution of anions is negligible. Armchair PAHs fit the 12.7 μm band, simultaneously producing a very weak broad emission feature centered at 3.225 μm. Zigzag PAHs fit the 11.2 μm band. It is concluded that PAHs with a low number of edge defects, in addition to armchair and zigzag PAHs, all contribute to the observed interstellar infrared emission.