Phosphorus Content Research Articles

Assessment of the Influence of zaï, Stone Rows, and Organo-mineral Fertiliser on Soil Properties and Groundnut Yields Performances in Sudan Sahelian Zone of Burkina Faso

Groundnut occupies a vital position in oilseed crop production in Burkina Faso, with current production at 630,526 tonnes. However, its production faces threats from drought and low soil fertility. This study aims to determine the influence of zaï, stone rows, ridge tillage, and mineral fertilisation on soil health and on groundnut yields performances in Sudan Sahelian zone of Burkina Faso. Experimental treatments were distributed randomly following a Fisher block design, comprising four treatments and five replications, in the village of Sandogo. Data on soil properties, plant growth, and yields were analysed using variance analysis in R software. The results indicate significant influences of the treatments on carbon content, nitrogen content, phosphorus content, pH values, soil moisture content, soil carbon dioxide release, and soil macrofauna. Moreover, notable effects were observed on the number of nodules, drier nodule weight, number of leaves and branches, pod load, pod and straw yields, and the weight of 100-pods. The highest carbon content (0.857; 0.861%), nitrogen content (0.081%; 0.087%), phosphorus content (7.488; 7.735 mg.kg-1), pH values (6.43; 6.54), and soil moisture content (24.80; 25.27%) were recorded in the homogeneous group of zaï and zaï associated to stone rows. The highest carbon dioxide release (2863.33 ppm) was recorded in plots treated with stone rows. Ants were the most widely encountered macrofauna, whereas no earthworms were recorded. The highest performance in terms of the number of nodules (84.76; 87.88), dry nodule weight (0.0893; 0.0886 g/plant), number of leaves (40; 40), number of branches (6; 6), pod load (25; 25), weight of 100-pods (112.90; 111.98 g), straw yields (1673.28; 1664.87 kg.ha-1), and pod yields (2122.32; 2161.96 kg.ha-1) were achieved with zaï and zaï combined with stone rows. Zaï and zaï combined with stone rows can therefore be used as effective alternatives to improve groundnut production in the Sudan Sahelian zone of Burkina Faso in a context of climate change, while protecting the environment.

Effect of Zinc and Silica Solubilizing Microbial Consortia on Soil and Plant Nutrient Status in Paddy

Effect of zinc and silica solubilizing bacteria and their consortia on paddy was studied under pot culture conditions at Agricultural Research Station, Janagamaheswarapuram, Andhra Pradesh, India. Thirteen treatments were assessed for availability of nutrients viz., Nitrogen, Phosphorus, Potassium, Zinc and Silica in soil and concentration of Nitrogen, Phosphorus and Potassium in plant at 45, 90 and 120 days after sowing (DAS). Significantly highest nitrogen (189.3, 249.4 and 239.7 kg ha-1), available phosphorus (34.6, 61.8 and 38.5 kg ha-1), potassium (214.2, 347.9 and 232.1 kg ha-1), zinc (0.78, 0.99 and 0.86 ppm) and silica (60.1, 90.8 and 78.4 ppm) were recorded in T13 (RDF + ZnKJJ-4 & ZnPGG-1 + SiKPP-1 & SiPYY-3) at 45, 90 and 120DAS. In plant, nitrogen (0.79, 0.99 and 0.89 %), phosphorus (0.37, 0.58 and 0.49 %) and potassium (1.78, 2.18 and 1.89 %) were significantly highest in T13. There was increase in available nutrient content upto 90 DAS which then decreased at 120DAS. It is inferred that consortia of two zinc solubilizing and two silica solubilizing microorganisms (T13) is useful for increased availability of Nitrogen, Phosphorus, Potassium, Zinc and Silica in soil and increased uptake of NPK by rice plant.

Systematic Review of the Agro-Ecological, Nutritional, and Medicinal Properties of the Neglected and Underutilized Plant Species Tylosema fassoglense

Neglected and Under-utilized plant Species (NUS) can contribute to food system transformation in Sub-Saharan Africa, but many are understudied. Here, we conducted a systematic review of 37 empirical studies to synthesize the evidence from Sub-Saharan Africa about the agro-ecological characteristics, nutritional properties, and medicinal properties of the NUS Tylosema fassoglense. Overall, the evidence is highly fragmented and lacks a comprehensive description of the species characteristics, properties, and benefits. Most reviewed studies focus on the eastern part of Africa and a few on the southern part, suggesting its limited geographic distribution. Studies on agro-ecological properties, and especially on morphological characteristics, indicate that the species’ long tuberous roots and large vegetative systems help it adapt to harsh climatic conditions. The species is also utilized for medicinal and nutrition purposes by different communities across its range due to its phytochemical, macro-, and micronutrient content, along with its favorable physico-chemical properties. In particular, the seeds contain many different amino acids, while their calcium, magnesium, phosphorus, zinc, and carbohydrate content is comparable to Tylosema esculuntum, the better studied species in the Tylosema genus. These demonstrate the species’ potential to contribute to nutrition and food security. Furthermore, parts of the plant contain many phytochemicals, such as phenolics, alkaloids, flavonoid, terpenoids, and tannins (mainly in the roots), and for this reason local communities use it to treat various conditions. Overall, our systematic review suggests that although Tylosema fassoglense has some potential to contribute towards food security, nutrition, health, and livelihoods, there are many remaining knowledge gaps that constrain its effective integration into agricultural production systems and possible contribution to food system transformation in the region.

Benefits of Canavalia ensiformis, arbuscular mycorrhizal fungi, and mineral fertilizer management in tobacco production

Tobacco (Nicotiana tabacum L.) has long been vital to Cuban agriculture, with its products renowned for their quality. Cuban tobacco is grown in soils with a long history of continuous farming using traditional fertilization methods characterized by recommended doses of mineral fertilizers. This study aims to improve the nutrition resource strategy in tobacco cultivation to ensure high yields of superior-grade tobacco leaves with adequate quality and increase fertilization efficiency. With this goal, a field experiment evaluated the traditional method of fallow with alternatives of nutrient supply systems for the production of black tobacco in Ultic Paleustalf soils. The experiment utilized Canavalia ensiformis (Can) treated with a mycorrhizal inoculum (AMF) based on the Glomus cubense strain (INCAM-4) as a preceding green manure, combined with successive mineral fertilizations for tobacco during four growing seasons in a randomized block design with factorial arrangement. Canavalia presented a positive response to mycorrhizal inoculation, significantly increasing dry biomass production (87.34%, 129.96%), mycorrhizal colonization (26.90%, 103.66%), and spore production (26.79%, 52.52%) for Can and Can+AMF treatments respectively. A biplot analysis established a strong relationship between the biomass and mycorrhizal performance of Canavalia and the growth, yield, and mycorrhizal colonization of tobacco. The results indicate that inoculated Canavalia enhances mycorrhizal performance in successional tobacco, with Can+AMF significantly increasing mycorrhization of tobacco roots by (110.06%). Moreover, the combination of Can inoculate with AMF and 75% of the recommended mineral fertilization dose consistently produced the highest tobacco yields (42.06%), growth, and mycorrhizal activity across the four years while maintaining satisfactory combustibility. In this nutrition supply system, variations of the recommended fertilizer dose significantly decreased the percentage of mycorrhizal colonization. After four growing seasons using Can + AMF and Canavalia without inoculations, soil organic matter, and availability of exchangeable calcium, magnesium, and pH increased slightly without decreasing available phosphorus and potassium contents. Consequently, we conclude that Canavalia ensiformis, with an inoculum based on the Glomus cubense strain and 75% of the recommended dose of mineral fertilizers, provides an enhanced nutrition alternative system for black tobacco production.

Recovery and Characterization of Calcium-Rich Mineral Powers Obtained from Fish and Shrimp Waste: A Smart Valorization of Waste to Treasure

With the increase in global aquaculture production, managing waste from aquatic biomass has become a significant concern. This research aimed to develop a sustainable valorization approach for recovering calcium-rich fish, including mackerel tuna and pangas bone and shrimp shell powders. The powders were characterized by various physicochemical and nutritional parameters, including proximate composition, amino acids, protein solubility, water holding capacity (WHC), oil holding capacity (OHC), and heavy metal contents. Color analysis and structural examination were carried out using field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), and Fourier-transform infrared spectroscopy (FT-IR), and in vitro radical scavenging activity was assessed. Significant protein content was observed in the powders, which was highest in shrimp shell powder (SSP) at 37.78%, followed by 32.29% in pangas bone powder (PBP) and 30.28% in tuna bone powder (TBP). The ash content was consistent in PBP and TBP at around 62.80%, while SSP had a lower ash content of 36.58%. Amino acid analysis detected 14 different amino acids in the recovered powders. Notably, SSP demonstrated the highest WHC and OHC values (2.90 and 2.81, respectively), whereas TBP exhibited the lowest values (1.11 for WHC and 1.21 for OHC). FE-SEM revealed the compact structure of TBP and PBP, contrasting with the porous surface of SSP. EDX analysis indicated higher calcium (24.52%) and phosphorus (13.85%) contents in TBP, while SSP was enriched in carbon (54.54%). All detected heavy metal concentrations were within acceptable limits. The recovered powders demonstrated significant ABTS free radical scavenging activity. The findings of this study suggest the suitability of the recovered powders for various food and pharmaceutical applications.

Groundwater inputs could be a significant but often overlooked source of phosphorus in lake ecosystems

Freshwater lakes are severely threatened, due largely to excess inputs of nutrients and other contaminants. Phosphorus (P) is receiving renewed attention due to recent increases in toxic cyanobacteria blooms in lakes worldwide. We investigated groundwater seepage for its role in P loading dynamics at Oneida Lake, New York, USA—one of the most well-studied lakes globally. P loading was measured at representative sites along the 88 km shoreline over three summers by directly measuring groundwater flow using seepage meters and porewater samplers. Groundwater seepage was a continuous and significant source of dissolved P over the summer months, comparable to tributary sources to the lake during that time. This constant input has enriched the concentrations of P in the nearshore surface waters, significantly above levels in the pelagic zone. Pore Total Phosphorus (TP) concentrations and loads reached extremely high values (up to 100 mg/L), with inorganic P representing only ~ 10% of TP per site. Groundwater seepage flows and P loadings were highly variable across space and time, partially explained by adjacent land uses and precipitation. Our research concludes that groundwater seepage is a significant, but overlooked, source of dissolved P and a crucial factor driving summer primary production at Oneida Lake, and likely other temperate lakes.

A Preliminary Evaluation of Faba Bean as a Green Shell Bean in Virginia, USA

Even though faba bean (Vicia faba L.) is an important food crop on worldwide basis, its use as a vegetable i.e. use of green seeds as food is limited. We were interested in characterizing production and food quality traits of faba bean grown in eastern USA. Our main objective is to develop faba bean as a winter alternative crop for this region to diversify cropping system that currently mainly depends upon cereal grain crops. This necessitates existence of winter-hardy faba bean varieties. We conducted a preliminary experiment with two winter-hardy faba bean breeding lines to record production and seed composition traits. Two faba bean lines (VSX-BL and VSX-BH) were planted in the field in November 2022 and green pods were harvested in June 2023 at physiological maturity. Values of most of the traits under study were statistically similar between the two lines except for concentration of phosphorus. Results demonstrated that faba bean green pod and green seeds yields could be approximately 5700 and 2100 kg ha-1. The shelling percent in green faba bean pods was approximately 37 whereas seed number per pod was approximately 2.6. Concentrations (g 100 g-1) of fructose, glucose, and sucrose were 0.245, 0.668, 2.9021, respectively whereas concentrations of Fe and Zn (mg kg-1) were 103.7 and 69.7, respectively. Green faba bean seeds contained small amounts of RFO carbohydrates. Seed composition traits of green faba bean seeds compare well with green seeds of pea, soybean, and white lupin. Our results provide a positive proof of concept that production of green faba bean as an alternate winter food legume crop in eastern USA is possible.

Burosumab Efficacy and Safety in Patients with X-Linked Hypophosphatemia: Systematic Review and Meta-analysis of Real-World Data.

To assess the efficacy and safety of burosumab in children and adults with X-linked hypophosphatemia based on real-world evidence. MEDLINE (via PubMed) and Cochrane Library were searched until 18 October 2023 for single-arm (before-after) studies. Registries including Clinicaltrials.gov, EU Clinical Trials, WHO International Clinical Trials Registry Platform, and conference abstracts. The outcomes were a change in serum phosphorus concentrations and change in RSS, a change in serum ALP, bone-specific ALP, a change in the ratio of Tubular maximum reabsorption of Phosphate to Glomerular Filtrate rate, a change in serum 1,25(OH)2D and 25(OH)2D concentrations, change in height Z-score, McMaster Universities Osteoarthritis Index (WOMAC) and safety outcomes. An inverse variance random-effects meta-analysis was applied for data synthesis. Fifteen studies (289 participants) were included. Burosumab treatment improved serum phosphate concentrations [mean difference 0.88mg/dl, 95% confidence interval 0.70 to 1.07, I2 = 92%), Rickets Severity score (mean difference -1.86, 95% confidence interval -2.5 to -1.21, I2 = 71%), serum alkaline phosphate concentrations (mean difference -1.86, 95% confidence interval -2.5 to -1.21, I2 = 71%), serum 1,25(OH)2D concentrations (mean difference 18.91pg/ml, 95% confidence interval 6.39 to 31.43, I2 = 96%) and renal phosphate reabsorption (mean difference 1.22 mg/dl, 95% confidence interval 0.70 to 1.74, I2 93%). Burosumab treatment improved overall clinical and laboratory findings in patients with X-linked hypophosphatemia.

Effects of Biochar Pyrolysis Temperature and Application Rate on Saline Soil Quality and Maize Yield

The application of biochar to improve the quality of saline soils has attracted widespread attention. However, the impact of saline soil amendments with biochar prepared at different pyrolysis temperatures remains unclear. Therefore, we conducted a two-year (2022–2023) field experiment in the Hetao Irrigation District, China, to evaluate the effects of the biochar pyrolysis temperature (C1: 300 °C, C2: 500 °C, and C3: 700 °C) and application rate (T1: 10 t/ha and T2: 20 t/ha) on the soil quality and maize yield. The results indicated that (1) all biochar treatments significantly decreased the soil bulk density and increased the soil porosity; (2) treatment C3T1 significantly increased the soil moisture content and decreased soil salinity. The C3T2 treatment significantly increased the soil’s organic carbon content, and the soil’s available phosphorus content was greatest in the C1T2 treatment. (3) The maize yield increased linearly with the soil quality index (SQI), which was attributed mainly to improvements in the soil water–salt conditions and increases in the soil organic carbon content. In summary, biochar produced at high pyrolysis temperatures, when applied at a low application rate (C3T1), can result in high corn yields and improve saline soil quality.

Effects of different afforestation years on soil moisture and nutrient content in Maxian Mountain of the Loess Plateau

In the area of “returning farmland to forest” on the Loess Plateau in China, it is difficult to cultivate artificially planted trees into forests. In the current study, abandoned cultivated land after 10 years of natural restoration served as controls (CK), while the treatments included afforestation periods of 2, 4, 6, 8, and 10 years. Soil samples were collected from various depths: 0–20, 20–40, 40–60, 60–80, to 80–100 cm. The findings revealed that with increasing years of artificial afforestation, soil pH gradually increased, and soil moisture content rose in the 0–20 cm layer while declining in deeper layers (20–100 cm) in the Maxian Mountain region of the Loess Plateau. Moreover, the total carbon, nitrogen, phosphorus, and potassium content initially increased and then decreased with the duration of artificial afforestation, reaching peak values after 8 years. Contents of organic matter, ammonium nitrogen, nitrate nitrogen, available phosphorus, and available potassium in the same soil layer increased with each year of afforestation. However, upon reaching 10 years of artificial afforestation, the effective nutrient content in the 60–80 and 80–100 cm soil layers exhibited a decrease. The values of Integrated Fertility Index (IFI) in different afforestation years were ranked as follows: 8 years > 6 years > 10 years > 4 years > 2 year, but all of them were significantly smaller than those of natural restoration plot CK (P < 0.05). Overall, soil fertility in the Maxian Mountain area of the Loess Plateau increases with each additional year of artificial afforestation. However, when the artificial afforestation period is 10 years, soil fertility decreases and marking a shift from enhancement to decline beyond this duration.

Effects of postbiotic products from Saccharomyces cerevisiae fermentation on lactation performance, antioxidant capacities, and blood immunity in transition dairy cows

This study aimed to evaluate the effects of dietary supplementation with different types of Saccharomyces cerevisiae fermentation products (SCFP) on lactational performance, metabolism, acute phase protein response, and antioxidant capacities in dairy cows from -21 to 56 d in milk (DIM). One hundred and 80 multiparous Holstein dairy cows were blocked by parity, expected calving date, pre-trial body condition score, and previous 305-d ME yield, and then randomly assigned to 1 of 3 dietary treatments: basal diet (CON; n = 60), basal diet supplemented with 40 g/d of SCFP1 (XPC; n = 60; XPC, Diamond V, Cedar Rapids, IA), and basal diet supplemented with 19 g/d of SCFP2 (NTK; n = 60, NutriTek®, Diamond V, Cedar Rapids, IA). Blood (n = 15, 13 and 12 in the CON, XPC and NTK groups, respectively) was sampled at -7 ± 3, + 3, + 7, + 21, and + 28 d, and milk samples (n = 19, 18 and 15 in the CON, XPC and NTK groups, respectively) was sampled during 1-8 wk from a subset of cows from -21 to 56 d relative to calving. Data were analyzed using the MIXED procedure in SAS (SAS Institute Inc.). All data were subjected to repeated measures ANOVA. Dietary treatment (TRT), time, and their interaction (TRT × time) were considered as fixed effects and cow as the random effect. Cows fed XPC and NTK had greater energy-corrected milk (ECM). Supplementing NTK increased milk fat content and yield, and 3.5% fat-corrected milk (FCM) yield compared with CON. Milk urea nitrogen (MUN) was lower in XPC cows than CON. SCFP supplementation decreased plasma β-hydroxybutyrate (BHB), ceruloplasmin (CER), haptoglobin (HPT), and interleukin-1β (IL-1β) concentrations, whereas increased plasma phosphorus (P) concentrations. In addition, cows fed NTK showed lower creatinine (CR) and cortisol (COR) concentrations but increased plasma calcium (Ca) and myeloperoxidase (MPO) concentrations than those in the CON cows. In addition, cows fed NTK and XPC both had reduced plasma concentrations of serum amyloid-A (SAA) at 3 DIM of lactation compared with CON fed cows. Furthermore, SCFP cows had greater concentrations of plasma glucose (GLU) and calcium (Ca) than CON cows at 7 DIM, and greater concentrations of plasma phosphorus (P) at 21 DIM. Between different SCFP type fed groups, plasma concentrations of nonesterified fatty acids (NEFA), MDA, creatinine (CR), SAA, and HPT were lower in cows fed NTK compared with cows fed XPC at 7 DIM. Overall, our results indicate the potential benefits of supplementing SCFP in transition dairy cows by modulating immunity, liver metabolic function and supporting ECM yield. The results also suggest that NutriTek at 19 g/d appears to support the performance and health of dairy cows better compared with XPC at 40 g/d, based on improved metabolic and inflammatory status during the transition period.

Noodle Production for Diabetics from Modified Green Banana Starch by Phosphate Cross‐Linking

AbstractThe development of Green banana (GB) starch in prebiotic foods to address health problems such as diabetes. It is modified by phosphate cross‐linking to increase the resistant starch content, improve functional properties, and reduce digestible starch consumption. The starch is modified using a mixture of sodium trimetaphosphate (STMP) and sodium tripolyphosphate (STPP) with 6 to 12 wt%ratios in the presence of sodium sulfate. The results showed an increase in phosphorus content from 0.18% to 0.45% corresponding to the increase in sodium trimetaphosphate/sodium tripolyphosphate ratios. Resistant starch reached 60 wt% after increasing the concentration of phosphate agent above 10 wt% and rapidly digestible starch decreased significantly. Accordingly, the physicochemical properties of starch changed significantly. Phosphate cross‐linking led to disruption of the crystalline structure of starch granules and fragmentation, reducing enthalpy and increasing gelatinization temperature. The oil and water absorption and freeze‐thaw stability of treated starch increased. While water absorption and solubility index of starch decreased significantly as the result of phosphate cross‐linking. Modified starch is used for the production of rice noodles. From 10 to 30 wt% of 10P modified starch mixed, cooking fracture rate is not more than 10% and resistant starch content is over 41 wt%.

Study on the Effect of Magnesium Chloride-Modified Straw Waste Biochar on Acidic Soil Properties

Soil biochar is a kind of organic matter rich in carbon, which is of great significance in soil fertility improvement, fertilizer type innovation and greenhouse gas emission reduction. In this paper, Mg-modified biochar was prepared by thermal cracking using rice straw and corn straw as raw materials. The Mg-modified biochar and unmodified biochar were fully mixed with prepared soil samples at the addition amounts of 0.5% (w/w), 1% (w/w) and 2% (w/w), respectively, and then simulated indoor soil cultivation experiments were carried out. The effects of magnesium ion-modified biochar and non-modified biochar on soil chemical properties and the effects of different amounts of biochar on soil properties were studied. The results showed that the yield of Mg-modified biochar from rice straw and corn straw, prepared by pyrolysis, was 65%, and the ash content was large. The pH of MG-modified corn stalk biochar (MCBC) is weakly basic (8.55), while the pH of MG-modified rice stalk biochar (MRBC) is basic (10.1), and their internal structures are slightly different. After the application of biochar prepared from rice straw and maize stover, soil indicators were determined. Compared to the control, the chemical properties of the treated soil samples were significantly improved, with an increase in soil pH, an increase in the content of effective nutrients, such as fast-acting potassium, fast-acting phosphorus and alkaline dissolved nitrogen, and an increase in the content of the total phosphorus and total nitrogen, as well as an increase in the content of organic matter. The Mg-modified biochar was generally superior to the unmodified biochar in improving soil fertility, at the same addition level. It was also found that the rice-straw biochar performed better than the corn-stover biochar and had a more obvious effect on soil improvement in terms of fast-acting potassium, ammonium nitrogen, nitrate nitrogen, total phosphorus and total nitrogen contents.

Study on Soil Fertility Characteristics of Walnut Orchards with Different Parent Materials and Soil Types in Gyaca County, Tibet

Walnut trees on the Tibetan Plateau have sustainable and nutritious characteristics. They grow naturally without the use of any chemical fertilizers and pesticides. Therefore, the soil fertility of walnut orchards is a key factor influencing walnut yield and quality. This experiment measured and analyzed the basic soil nutrient content, microbial biomass carbon (MBC), nitrogen (MBN), phosphorus (MBP), and leaf nutrient indicators in five types of representative walnut orchard soil parent materials in Gyaca County to clarify the fertility characteristics of different soil types and their correlations with walnut nutrients, providing a basis for the sustainable development of the plateau walnut industry. The results showed that there were significant differences in soil organic matter (SOM), total nitrogen (TN), available nutrient contents, and microbial activity among soil types with different parent materials. The comprehensive representation of available nutrient levels in the soils is as follows: gray-cinnamon soil and calcareous alluvial soil &gt; mountain meadow soil &gt; plateau prairie soil and brush prairie soil. The average MBC, MBN, and MBP contents in the five soils were 368.8 mg/kg, 28.4 mg/kg, and 23.6 mg/kg, respectively, and the content in the topsoil (0–20 cm) was higher than that of the subsoil (20–40 cm). The total nitrogen (PN), total phosphorus (PP), and total potassium (PK) contents in walnut leaves were found to be closely related to the soil physicochemical properties and microbial activity, among which five indicators, including soil TN, available nitrogen (AN), SOM, MBC, and slowly available potassium (SAK), had the greatest impact on leaf nutrient levels. These findings are valuable for the future management and development of walnut orchards. Therefore, for different soil parent materials and soil types, improving the soil fertility and actively applying nitrogen-rich organic fertilizers should be prioritized to improve the yield and quality of Tibetan Plateau walnuts.

Phosphorylating Tannin in Urea System: A Simple Approach for Enhanced Methylene Blue Removal from Aqueous Media.

Tannin, after lignin, is one of the most abundant sources of natural aromatic biomolecules. It has been used and chemically modified during the past few decades to create novel biobased materials. This work intended to functionalize for the first time quebracho Tannin (T) through a simple phosphorylation process in a urea system. The phosphorylation of tannin was studied by Fourier transform infrared spectroscopy (FTIR), NMR, inductively coupled plasma optical emission spectroscopy (ICP-OES), and X-ray fluorescence spectrometry (XRF), while further characterization was performed by scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDX) and thermogravimetric analysis (TGA) to investigate the morphology, composition, structure, and thermal degradation of the phosphorylated material. Results indicated the occurrence of phosphorylation, suggesting the insertion of phosphate-containing groups into the tannin structure, revealing a high content of phosphate for modified tannin (PT). This elevated phosphorus content serves as evidence for the successful incorporation of phosphate groups through the functionalization process. The corresponding PT and T were employed as adsorbents for methylene blue (MB) removal from aqueous solutions. The results revealed that the Langmuir isotherm model effectively represents the adsorption isotherms. Additionally, the pseudo-second-order model indicates that chemisorption predominantly controls the adsorption mechanism. This finding also supports the fact that the introduced phosphate groups via the phosphorylation process significantly contributed to the improved adsorption capacity. Under neutral pH conditions and at room temperature, the material achieved an impressive adsorption capacity of 339.26 mg·g-1 in about 2 h.

Phosphorylating Tannin in Urea System: A Simple Approach for Enhanced Methylene Blue Removal from Aqueous Media.

Tannin, after lignin, is one of the most abundant sources of natural aromatic biomolecules. It has been used and chemically modified during the past few decades to create novel biobased materials. This work intended to functionalize for the first time quebracho Tannin (T) through a simple phosphorylation process in a urea system. The phosphorylation of tannin was studied by Fourier transform infrared spectroscopy (FTIR), NMR, inductively coupled plasma optical emission spectroscopy (ICP-OES), and X-ray fluorescence spectrometry (XRF), while further characterization was performed by scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDX) and thermogravimetric analysis (TGA) to investigate the morphology, composition, structure, and thermal degradation of the phosphorylated material. Results indicated the occurrence of phosphorylation, suggesting the insertion of phosphate-containing groups into the tannin structure, revealing a high content of phosphate for modified tannin (PT). This elevated phosphorus content serves as evidence for the successful incorporation of phosphate groups through the functionalization process. The corresponding PT and T were employed as adsorbents for methylene blue (MB) removal from aqueous solutions. The results revealed that the Langmuir isotherm model effectively represents the adsorption isotherms. Additionally, the pseudo-second-order model indicates that chemisorption predominantly controls the adsorption mechanism. This finding also supports the fact that the introduced phosphate groups via the phosphorylation process significantly contributed to the improved adsorption capacity. Under neutral pH conditions and at room temperature, the material achieved an impressive adsorption capacity of 339.26 mg·g-1 in about 2 h.

Multimedia Nitrogen and Phosphorus Migration and Source Control Using Multivariate Analysis and XGBoost: The Case Study in a Typical Agricultural Basin, Danjiangkou Reservoir

Preventing eutrophication requires a deep understanding of nutrient sources and migration processes. The Guanshan River in the Danjiangkou Reservoir was selected as a typical agricultural basin. River water, sediment, and soil samples were collected to determine nitrogen (N) and phosphorus (P) contents and forms. Multivariate statistical analysis, buffer analysis, and extreme gradient boosting regression (XGBoost) were used to investigate the nutrient sources, the sources’ scale effects, and migration. The results showed that the exogenous sources of river nutrients were fertilizer (provided phosphate (PO4-P) and ammonium (NH4-N)), domestic wastewater (provided nitrate (NO3-N) and organic nitrogen), and natural soil and rock leaching (provided PO4-P and organic phosphorus). Fertilization within 300–1200 m and domestic wastewater discharge within 150 m of the river affected the contents of the river nutrients significantly (with R ranging between 0.40 and 0.73, p ≤ 0.01). The sediment was the N source and P sink of the overlying water. With NH4-N/PO4-P compound fertilization, the NO3-N and calcium-bound phosphorus (Ca-P) exhibited co-enrichment. Appropriately increasing NH4-N application could stimulate P biological uptake, thus inhibiting P emigration from agricultural soil under N-limited states. In conclusion, this study effectively recognized river nutrient sources and their scale impacts and also explored more effective fertilization strategies, which are beneficial for the optimized management of agricultural activities.

Multimedia Nitrogen and Phosphorus Migration and Source Control Using Multivariate Analysis and XGBoost: The Case Study in a Typical Agricultural Basin, Danjiangkou Reservoir

Preventing eutrophication requires a deep understanding of nutrient sources and migration processes. The Guanshan River in the Danjiangkou Reservoir was selected as a typical agricultural basin. River water, sediment, and soil samples were collected to determine nitrogen (N) and phosphorus (P) contents and forms. Multivariate statistical analysis, buffer analysis, and extreme gradient boosting regression (XGBoost) were used to investigate the nutrient sources, the sources’ scale effects, and migration. The results showed that the exogenous sources of river nutrients were fertilizer (provided phosphate (PO4-P) and ammonium (NH4-N)), domestic wastewater (provided nitrate (NO3-N) and organic nitrogen), and natural soil and rock leaching (provided PO4-P and organic phosphorus). Fertilization within 300–1200 m and domestic wastewater discharge within 150 m of the river affected the contents of the river nutrients significantly (with R ranging between 0.40 and 0.73, p ≤ 0.01). The sediment was the N source and P sink of the overlying water. With NH4-N/PO4-P compound fertilization, the NO3-N and calcium-bound phosphorus (Ca-P) exhibited co-enrichment. Appropriately increasing NH4-N application could stimulate P biological uptake, thus inhibiting P emigration from agricultural soil under N-limited states. In conclusion, this study effectively recognized river nutrient sources and their scale impacts and also explored more effective fertilization strategies, which are beneficial for the optimized management of agricultural activities.

Temporal Variations in Aboveground Biomass, Nutrient Content, and Ecological Stoichiometry in Young and Middle-Aged Stands of Chinese Fir Forests.

Understanding the ecological dynamics of forest ecosystems, particularly the influence of forest age structure on soil carbon (C), nitrogen (N), and phosphorus (P) content, is crucial for effective forest management and conservation. This study aimed to investigate the nutrient storage and ecological stoichiometry across different-aged stands of Chinese fir forests. Soil samples were collected from various depths (0-15 cm, 15-30 cm, and 30-45 cm) across four age groups of Chinese fir forests (8-year-old, 12-year-old, 20-year-old, and 25-year-old) in the Forest Farm, Pingjiang County, China. Soil organic carbon (SOC), total nitrogen (TN), and total phosphorus (TP) were measured, and their stoichiometries were calculated. The results showed that both individual tree biomass and stand biomass, along with SOC, TN, and TP content, increased with stand age, highlighting the significant importance of stand age on biomass production and nutrient accumulation in forests. Specifically, soil C and P contents significantly increased as the forest aged, while variation in N content was relatively minor. Soil C/N and C/P ratios exhibited variation corresponding to forest age, suggesting alterations in the ecological stoichiometry characteristics of the forests over time. These findings are crucial for understanding the dynamics of ecosystem functioning and nutrient cycling within Chinese fir forests and provide a solid scientific basis for the effective management and conservation of these vital forest ecosystems.

Unlocking the potential of biofilm-forming plant growth-promoting rhizobacteria for growth and yield enhancement in wheat (Triticum aestivum L.)

Plant growth-promoting rhizobacteria (PGPR) boost crop yields and reduce environmental pressures through biofilm formation in natural climates. Recently, biofilm-based root colonization by these microorganisms has emerged as a promising strategy for agricultural enhancement. The current work aims to characterize biofilm-forming rhizobacteria for wheat growth and yield enhancement. For this, native rhizobacteria were isolated from the wheat rhizosphere and ten isolates were characterized for plant growth promoting traits and biofilm production under axenic conditions. Among these ten isolates, five were identified as potential biofilm-producing PGPR based on in vitro assays for plant growth-promoting traits. These were further evaluated under controlled and field conditions for their impact on wheat growth and yield attributes. Surface-enhanced Raman spectroscopy analysis further indicated that the biochemical composition of the biofilm produced by the selected bacterial strains includes proteins, carbohydrates, lipids, amino acids, and nucleic acids (DNA/RNA). Inoculated plants in growth chamber resulted in larger roots, shoots, and increase in fresh biomass than controls. Similarly, significant increases in plant height (13.3, 16.7%), grain yield (29.6, 17.5%), number of tillers (18.7, 34.8%), nitrogen content (58.8, 48.1%), and phosphorus content (63.0, 51.0%) in grains were observed in both pot and field trials, respectively. The two most promising biofilm-producing isolates were identified through 16 s rRNA partial gene sequencing as Brucella sp. (BF10), Lysinibacillus macroides (BF15). Moreover, leaf pigmentation and relative water contents were significantly increased in all treated plants. Taken together, our results revealed that biofilm forming PGPR can boost crop productivity by enhancing growth and physiological responses and thus aid in sustainable agriculture.