Phosphor Layer Research Articles

Acquiring higher lumen efficacy and color rendering index with green NaYF4:Er3+Yb3+ and red α-SrO·3B2O3:Sm2+ layers for designing remote phosphor LED

Lighting devices that apply diodes to create white light-emitting diodes (WLEDs) can achieve remarkable results in color quality, especially those containing quantum dots (QDs) and phosphor. The technique to create an appropriate package is providing spaces between the QDs and phosphor components which helps decrease the ratio of the reabsorption losses and keeps the QDs surface ligands constant. The research aims to perfect the constructing method of remote phosphor configuration containing quantum dots and phosphor materials that based on lighting properties and temperature feature of WLEDs. The infrared thermography is the tool to measure and analyze total emitted light and emission ranges of the device. This device is also used in temperature simulation and experimental verification. At the given mA of 60, the WLEDs structure with green QDs layer above the phosphor layer results in 996 lm luminous flux (LF), and Ra = 57 in color rendering ability. Meanwhile, luminous flux of WLEDs with red QDs-on-phosphor structure is 632, and Ra = 70. Furthermore, comparing with the green QDs-on-phosphor type, the red QDs-on-phosphor type emitted less LF. However, the red QDs-on-phosphor type can be the most effective package design to achieve color rendering ability.

The application of green YPO4:Ce3+,Tb3+ and red LiLaO2:Eu3+ layers to remote phosphor LED

Remote phosphor structure is commonly limited in color quality, but has greater luminous flux when comparing to structures with in-cup or conformal coating. From this dilemma, various researches with advance modifications have been proposed to perfect the chromatic performance of remote structure. In this research, we reach higher color quality by obtaining better values in quality indcators such as color rendering index (CRI) and color quality scale (CQS) with the dual-layer phosphor in our remote white light-emitting diodes (WLEDs). The idea is to ultize WLEDs with 7000 K correlated color temperature (CCT) and create dual-layer configuration with yellow phosphor YAG:Ce3+ under green phosphor YPO4:Ce3+,Tb3+ or red phosphor LiLaO2:Eu3+. After that, we search for suitable concentration of LiLaO2:Eu3+ for addition in order to acquire the finest color quality. The result shows that WLED with LiLaO2:Eu3+ has better CRI and CQS as the higher the concentration of LiLaO2:Eu3+, the larger CRI and CQS due to increased light scattered in WLEDs. Meanwhile, the green phosphor layer YPO4:Ce3+,Tb3+ give advantages to luminous flux. However, the reduction in luminous flux and color quality occurs when the concentration of LiLaO2:Eu3+ and YPO4:Ce3+,Tb3+ over increase. Results are verified by Mie theory and Beer’s Law and can be applied to practical manufacturing of high quality WLEDs.

Thermally stable laser-driven phosphor converted white light source using multilayer structured diffuser system

We report the development of a thermally stable laser-driven phosphor-converted white light source using a multilayer structured diffuser system for general illumination. The developed extended diffuser system comprises an acrylic sheet, two glass plates, and a phosphor layer with the arrangement in a glass-acrylic-phosphor-glass combination. The high-power laser beam was gradually distributed inside the diffuser system for exciting the phosphor layer optimally without burning the resin and thermal quenching. The method is simple and efficient in which both the directionality and scattering properties of laser source are exploited using the transmission properties of diffusers. The high specular transmission of diffusers resulted in the optimum transfer of laser directional photons for exciting the middle section of phosphor layer, and the remaining laser photons were scattered from diffuser surfaces. The glass-acrylic combination results the refractive index inhomogeneity inside the system and helped to expand the scattered photons throughout the phosphor layer. The radiant power distribution of blue laser source inside the system resulted in synchronization between optimal absorption quantum efficiency and fluorescent conversion quantum efficiency of the phosphor layer. As a result, the thermal quenching effect on phosphor inside the white light system was minimized for efficient illumination. With this geometry, a bright and thermally stable white light source was realized due to the proper distribution of high-power laser throughout the system. The luminescence properties of the proposed laser-based white light system were examined and found thermally stable in terms of spectral changes, luminance, and correlated color temperature.

In‐Depth Analysis of the Internal Energy Conversion of Nuclear Batteries and Radiation Degradation of Key Materials

Low conversion efficiency and energy output are the main factors hindering the application of the radioluminescent nuclear battery in space. This study analyzes the energy conversion process and proposes a solution of performance promotion. It is found that the energy conversion efficiency of the photovoltaic units is enhanced with increasing incident light intensity. The efficiency of the AlGaInP unit is stable at 22% when the incident energy is at least 3 μW. As for the GaAs unit, the incident threshold value of the photovoltaic response sensitivity is greater than 120 μW. The overall efficiency of the radioluminescent nuclear battery is only 0.37%, consisting of an AlGaInP unit loaded with a low activity 63Ni and the ZnS:Cu phosphor layer. The efficiency increases to 0.87% when an electron radiation source with 270.27 mCi cm−2 is adopted. Moreover, the intense intensity source constitutes an extremely electromagnetic pulse radiation environment, which cause the batteries to fail. The radiation damage is introduced to the phosphor layer by radiation sources, producing agglomerations and cracks on the surface and resulting in the transmittance reduction. This study provides guidance for improving the electrical property and optimization solutions of radioluminescent nuclear battery.

Enhancing light sources color homogeneity in high-power phosphor-based white LED using ZnO particles

Color uniformity is one of the essentials for the on-going development of WLED. To achieve a high color uniformity index, increasing the scattering events within the phosphor layers was reported to be the most efficient method and in this article, ZnO is the chosen material to apply in this method. After analyzing the scattering properties through the scattering cross-section , scattering coefficient and scattering phase function , the which outcomes comfirm that ZnO can enhance the scattered light in the phosphor layers. Moreover, the findings from the study of ZnO concentration from 2% to 26% suggest that color uniformity also depends on the fluctuation of ZnO concentration, therefore, to control color uniformity the focus should be implied on both size and concentration of ZnO. The experimental results from this research show that the luminous flux of WLED is at the peak if the concentration of ZnO is at 6%, and when the concentration of ZnO is at 18% and has 100 nm particles size, the ΔCCT reaches the lowest level. The final choice should be based on the desired characteristic of WLEDs, however, if the WLED need to excel in both luminous flux and ΔCCT then 6% ZnO concentration with particles size from 100 nm-300 nm is the optimal choice.

Improving color quality and luminous flux of white LED utilizing triple-layer remote phosphor structure

In this manuscript, we presented a research that enhance the performance of WLED using the multi-phosphor configuration. The phosphor layers in the research are separated from each other to achieved better luminous efficiency, however, it makes controlling color light quality more complex. Another issue is finding out the whether two layers of phosphor or three layers of phosphor is better in improving color quality. The research addressed this issue by analyzing the optical aspects of the respective WLEDs that employ these structure. The studied aspects are quality indicators such as luminous efficacy (LE), and color uniformity, color rendering index (CRI), color quality scale (CQS). The results of the experiments in this research, which come from the employment of WLEDs with 2 color temperatures 5600 K and 8500, suggest that WLED with three phosphor layers is better in CRI, CQS, LE. This type of phosphor structure also limits the color deviation significantly, thus, improves the color uniformity. This results is verifies with Mie theory, therefore, can be applied as reference or guideline for production of better WLEDs

The Effects of ZnO particles on the color homogeneity of phosphor-converted high-power white LED light sources

Color homogeneity is one of the goals to continuously improve WLED. Among the methods for enhancing the color uniformity of WLEDs, improving scattering in phosphor layer is considered to be the most effective. In this paper, ZnO is used for that purpose. The results show that ZnO particle size significantly affects scattering in the phosphor layer, which is a vital factor to analyze scattering, scattering sand surface, scattering coefficient and scattered phase function C_sca (D,λ), μ_sca (λ) and ρ(θ,λ). In addition, the concentration of ZnO was also analyzed with values from 2% to 22%. Color homogeneity depends not only on size but also on the concentration of added ZnO. Therefore, color homogeneity control is the control of ZnO size and concentration. The proposed result is 10% ZnO for the highest lumen of LED. With 14% and 500 nm of ZnO particles, ΔCCT reaches the lowest. Depending on the production needs, manufacturers can choose the most appropriate way. However, with both required lumen and ΔCCT, 14% ZnO is suitable for ZnO sizes.

SrBaSiO4:Eu2+ phosphor: a novel application for improving the luminous flux and color quality of multi-chip white LED lamps

This paper described in detail the chromatic homogeneity and luminous flux influences in producing better quality white LED devices with various phosphor layers (MCW-LEDs). The method is to let Eu2+-activated strontium–barium silicate (SrBaSiO4:Eu2+) mixed with their phosphor compounding, which results in notable impact on lighting performance. The increase in concentration of yellow-green-emitting SrBaSiO4:Eu2+ phosphor also promotes the color performance and lumen output of WLED devices at high correlated color temperature around 8500K. This is the first time this approach is applied and it results can be utilized for better understanding of optical properties interaction with phosphor materials. Although SrBaSiO4:Eu2+ receives many positive responses, we still need to limit it concentration for high SrBaSiO4:Eu2+ concentration is detrimental to CQS. The appropriate choice of concentration and size of SrBaSiO4:Eu2+ is the principal factor to decide the performance of MCW-LEDs.

The application of double-layer remote phosphor structures in increasing WLEDs color rendering index and lumen output

The remote phosphor structure often has inferior color quality but better luminous flux in than conformal or in-cup configurations. Therefore, numerous researches study remote phosphor structure for methods to enhance it chromatic quality. This study introduces the use of dual-layer remote phosphor structure in WLEDs with identical structure but at different color temperature, 6600K and 7700K, to demonstrate their effect on quality indicators. The concept is placing a green phosphor layer (Ce,Tb)MgAl11O19:Ce:Tb or a red phosphor layer MgSr3Si2O8:Eu2+,Mn2+ on the layer of yellow-emitting phosphor YAG:Ce3+ and find the suitable concentration of the additional phosphor to create the best color quality. The results showed that the increase of CRI and CQS are affected by MgSr3Si2O8:Eu2+,Mn2+, in particular, the higher the concentration of red phosphor gets the better CRI and CQS because the emitted red light in enhanced. The green phosphor layer (Ce,Tb)MgAl11O19:Ce:Tb, on the other hand, is beneficial for the luminous flux. The concentration of MgSr3Si2O8:Eu2+,Mn2+ and (Ce,Tb)MgAl11O19:Ce:Tb, however, need to be adjusted properly to avoid decreasing the luminous flux due to overgrowth. The Mie scattering theory and Beer’s law are the verification tools for these conclusions, which gives them the credibility to be applied in producing better quality WLEDs.

The options in remote phosphor structure for better white LEDs color quality

The WLEDs configuration with remote phosphor layers has higher luminescent performance than WLEDs with dispense coating or conformal coating and is applied for many modern devices. However, managing the chromatic performance of lighting structure with remote phosphor materials is a challenging objective that demands more research. This has inspired the usage of multi phosphor configurations with distance in between the layers to improve color quality. The results of this manuscript can support the manufacturers in choosing the optimal configuration for optical performance in LEDs devices with more than one phosphor material. The simulated model used in the experments is 6500 K CCT WLEDs, which results show the triple-layers structure is more favorable in terms of color quality and light output. Besides, a notable reduction occurs in color deviation means that chromatic stability is also enhanced in WLEDs with three phosphor layers. Through experimental results, which were confirmed by the Mie-scattering theory, this research offers valuable approach and details to produce better WLEDs.

ZnO Nanoparticles in Bettering The Color Uniformity of Phosphor-Converted White Led Lights

To make further improvements in future WLED generation, bettering color uniformity is an important goal manufacturers desire to accomplish. One of the most common and effective methods to enhance the color homogeneity is the one focusing on improving scattering in phosphor layer which can be achieved by adding ZnO into the phosphor layer. Based on theoretical application of Mie-scattering, we compute and analyze the scattering characteristics of the diffusor particles. From the results, the ZnO particles are proven to have positive influences on the development of lighting quality. Additionally, the article analyzed and presented the effects of ZnO concentration which fluctuates from 2% to 22% on the color homogeneity. Thus, the color uniformity is influenced not only by the particle size but also by the concentration of the added ZnO. Hence, managing the color uniformity of WLEDs means controlling the size and concentration of ZnO. With the concentration of 10% ZnO, the lumen output of LEDs reaches the highest values. Meanwhile, when the concentration and size of ZnO are 14% and 500 nm respectively, ∆CCT is reduced to the lowest value. Based on the manufacturers' requirements, the most appropriate ZnO concentration and particle size can be determined. However, if requirements include both lumen and color uniformity, the right choice is 14% concentration with 500 nm particle size of ZnO. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium provided the original work is properly cited.

Solid-State Thin-Film Broadband Short-Wave Infrared Light Emitters.

Solid-state broadband light emitters in the visible have revolutionized today's lighting technology achieving compact footprints, flexible form factors, long lifetimes, and high energy saving, although their counterparts in the infrared are still in the development phase. To date, broadband emitters in the infrared have relied on phosphor-downconverted light emitters based on atomic optical transitions in transition metal or rare earth elements in the phosphor layer resulting in limited spectral bandwidths in the near-infrared and preventing their integration into electrically driven light-emitting diodes (LEDs). Herein, phosphor-converted LEDs based on engineered stacks of multi-bandgap colloidal quantum dots (CQDs) are reported as a novel class of broadband emitters covering a broad short-wave infrared (SWIR) spectrum from 1050-1650 nm with a full-width-half-maximum of 400 nm, delivering 14 mW of optical power with a quantum efficiency of 5.4% and power conversion efficiency of 13%. Leveraging the electrical conductivity of the CQD stacks, further, the first broadband SWIR-active LED is demonstrated, paving the way toward complementary metal-oxide-semiconductor integrated broadband emitters for on-chip spectrometers and low-cost volume manufacturing. SWIR spectroscopy is employed to illustrate the practical relevance of the emitters in food and material identification case studies.

Phosphor thermometry at the surface of single reacting large-diameter spherical coke particles to characterise combustion for packed bed furnaces

Packed-bed furnaces fired with large-diameter coke are important in high-temperature material processing industries such as lime and iron production. The combustion conditions are complicated by the presence of an ash layer surrounding the coke particle that remains intact during passage through the furnace and alters oxygen diffusion and heat transfer to the reacting particle core. The objective of this study is to determine the surface temperature of this ash layer using lifetime-based phosphor thermometry during combustion of single spherical 38 mm diameter coke particles in a high temperature tube furnace. Time traces of the coke particle core temperature and mass conversion rate do not significantly differ between experiments performed with and without the phosphor layer, indicating that the presence of the phosphor particles does not alter the overall combustion behaviour. Surface temperatures of up to 950 °C are measured and correlated with the fuel mass conversion rate. When the coke particle starts to react the surface temperature is up to 100 °C higher than that of the core. As the reaction front progresses toward the centre, the core temperature exceeds the surface temperature by 200 °C due to the insulating effect of the ash layer. The surface temperature of the ash layer decreases with time due to the steadily decreasing fuel mass conversion rate. The method and results can be used to provide key validation data for shrinking-core combustion models, for example by constraining the unknown transport properties of the ash layer, thereby assisting the development of complete packed-bed furnace simulations for process optimisation.

Boron and Phosphorous Doping of GeSn for Photodetectors and Light Emitting Diodes

With an electrically pumped group IV laser operating at room temperature as a long term goal, we would like to replace the boron and phosphorous doped Ge layers used in previous pin structures with GeSn:B and GeSn:P. We have thus investigated the in-situ doping of GeSn with Ge2H6, SnCl4, B2H6 (p-type) or PH3 (n-type) at 349°C, 100 Torr on Ge Strain-relaxed Buffers, themselves on Si(001) substrates. The Sn content from Wavelength Dispersive X-Ray Fluorescence (WDXRF) was constant around 6.5% for low F(B2H6)/F(Ge2H6) and F(PH3)/2*F(Ge2H6) Mass-Flow Ratios (MFRs). It fell down to 4.6% (GeSn:B) and 5.6% (GeSn:P) for higher MFRs. This drop was likely due to the dopant precursors that catalyzed the Ge Growth Rate component. Substitutional B and P contents were extracted from the differences between real Sn contents from WDXRF and “apparent” Sn contents from X-Ray Diffraction (compressive strain compensation by small B and P atoms). The B substitutional concentrations increased sub linearly with the MFR, reaching values of at most 5.2x1019 cm-3. Meanwhile, the P substitutional concentration increased linearly with the MFR, up to 2.2x1020 cm-3. WDXRF gave us also access to the atomic P concentrations, with values as high as 2.2x1020 cm-3 A cross-hatch along <110> was otherwise present on the surface of the various GeSn:B and GeSn:P layers, which were rather smooth. Only the GeSn:B layers grown at the three highest MFRs exhibited some B and/or Sn surface segregation.

Building superior lighting properties for WLEDs utilizing two-layered remote phosphor configurations

Abstract The remote phosphor structure produces higher luminous flux but delivers poorer color quality than the conformal or in-cup phosphor structure. To eliminate this weakness, researchers have attempted to improve the chromatic properties of remote phosphor package. This study tends to enhance lighting features for WLEDs including color quality and luminous flux in general or color rendering index (CRI) and color quality scale (CQS) in particular by applying dual-layer remote phosphor structure. In the simulation section, we utilize two identical LEDs that only differ in correlated color temperature values which are 6600 K and 7700 K. The study offers an idea of placing a yellow-green phosphor layer SrBaSiO4:Eu2+ or a red phosphor layer SrwFxByOz:Eu2+,Sm2+ on the yellow phosphor layer YAG:Ce3+ and then modifying the concentrations of SrwFxByOz:Eu2+,Sm2+ and SrBaSiO4:Eu2+ to the suitable values to improve the color quality and lumen output of WLEDs. The results show that red phosphor layer SrwFxByOz:Eu2+,Sm2+ has a significant influence on CRI and CQS improvement. Particularly, the increase of SrwFxByOz:Eu2+,Sm2+ concentration leads to increased CRI and CQS because the red light component increases in WLEDs. On the other hand, the green phosphor layer SrBaSiO4:Eu2+ only brings benefit to the luminous flux. However, the WLEDs’ luminous flux and color quality drop sharply, when SrwFxByOz:Eu2+,Sm2+ and SrBaSiO4:Eu2+ concentrations rise extremely, which is verified based on the Mie-scattering theory and the Lambert-Beer law. In short, the article provides general knowledge and primary information for the production of higher-quality WLEDs.

Evidence for electron-tunneling-limited Knudsen diffusion of mercury in phosphor layers and coatings of fluorescent lamps

Recent experimental studies and modelling of the mercury loss (i.e. the mercury consumption) in fluorescent lamps yield diffusion coefficients of mobile mercury in phosphor layers and coatings, which are several orders of magnitude smaller than expected for a gas diffusion in a situation in which the mean free path of the diffusing particles is restricted by the pore radius in those materials (Knudsen diffusion). In the present work it is shown that the transition of mercury ions from the plasma to the Knudsen diffusion regime may be one reason for this observation. Another possibility is that only discharged ions from the plasma form the mercury oxide as which mercury is deposited in the phosphor layer and coating, from the investigation of which the diffusion coefficient of mobile mercury is concluded by fitting the model to the experiment.

Efficient energy storage and uvioresistant perovskite solar cells through insulating Y2O2S-based long-lasting phosphor layer

Perovskite solar cells (PSCs) attract widespread attention owing to its extremely high power conversion efficiency (PCE) and low-price fabrication processing. However, the high-power output is merely limited under sunlight illumination and nearly zero at a dark atmosphere, which may potentially hinder the commercial development and outdoor applications. In this work, we introduce an efficient and stable long-lasting phosphor layer, Y2O2S: Eu3+, Ti4+, Mg2+ enabling PSCs to achieve energy-storage function owing to its persistent photoelectric conversion. When sunlight illumination is turned off, the modified devices can still keep current output for 2 h. Besides, the modified devices demonstrate a considerable improvement of PCE, suppressed hysteretic effects, and highly prolonged light stability. The optimized PCE of 20.9% is obtained through elevated light-harvesting, optimized bandgap alignment, and depressed charge recombination provided by the YOS layer. The modified PSCs maintain 83% of their original PCE after aging in UV light for 100 h and retain 78% of their original PCE after 90 days in the oxygen and humid condition. This work represents a novel strategy on obtaining energy storage and uvioresistant PSCs.

Dual-layer remote phosphor structure: a novel technique to enhance the color quality scale and luminous flux of WLEDs

The effects of red light-emitting phosphor CaMgSi2O6:Eu2+,Mn2+ on the optical properties of single-layer remote phosphor structure (SRPS) and dual-layer remote phosphor structure (DRPS) are the focus of this study. The differences in color quality and luminous flux (LF) of white light-emitting diodes (WLEDs) between these two structures are also revealed and demonstrated based on the Mie theory. SRPS consists of one mixed phosphor layer betweenCaMgSi2O6:Eu2+,Mn2+ andYAG:Ce3+particles, while DRPS includes two separated layers: red phosphor layer and yellow phosphor layer. In this work, 5% SiO2 is added into the phosphor layers to increase scattering abilities. Discrepancies in structures greatly affect the optical characteristics of WLEDs. The results showed that the color rendering index (CRI) increased with the concentration in both structures with nearly equal values. Meanwhile, color quality scale (CQS) of DPRS is 74 at ACCTs ranging from 5600K to 8500K, higher than CQS of SRPS which is only 71 at 8500K. In addition, the luminous flux of DRPS is significantly higher than SRPS at 2% -14% of CaMgSi2O6:Eu2+,Mn2+. In summary, DRPS is better for color quality and lumen outputin comparison to SRPS and adding the right amount of red phosphor can enhance CQS and LF.

Na3Ce(PO4)2:Tb3+ and Na(Mg2–xMnX)LiSi4O10F2:Mn phosphors: a suitable selection for enhancing color quality and luminous flux of remote white light-emitting diodes

This study proposed the TRP, a remote phosphor structure that has 3 phosphor layers, to ehance the chromatic quality and lumen output for white light-emitting diodes devices (WLEDs). The arrangment of phosphor layers is yellow YAG:Ce3+ phosphor, green Na3Ce(PO4)2:Tb3+ phosphor, and red Na(Mg2–xMnX)LiSi4O10F2:Mn phosphor from bottom to top. Red Na(Mg2–xMnX)LiSi4O10F2:Mn phosphor is used for the red light component to boost color rendering index (CRI). The green layer Na3Ce(PO4)2:Tb3+ phosphor is utilized for the green light component to produce higher luminous flux (LF). With the addition of red and green phosphor, the yellow YAG:Ce3+ concentration must decrease to maintain the 6000 K color temperature. The research results show that red phosphor Na(Mg2–xMnX)LiSi4O10F2:Mn concentration is beneficial for CRI, while green phosphor Na3Ce(PO4)2:Tb3+ is detrimental to CRI. Morever, CQS reaction with red and green phosphor is also studied, which show notable improvement when Na(Mg2–xMnX)LiSi4O10F2:Mn concentration is from 10%-14%, regardless of Na3Ce(PO4)2:Tb3+. The luminous flux (LF) can also increase for more than 40% with the reduced light loss and added green phosphor. Research results are valuable references for producers to enhance the color quality and the light emission of WLEDs.

82‐3: Red‐Enhanced Laser‐Phosphor Light Source with Quantum Dot Conversion Layer

We developed a red‐enhanced laser‐phosphor light source with quantum dot conversion layer for projector applications. This device uses dual‐layer wheel structure, in which a quantum dot layer is underneath a Ce:YAG phosphor layer. We demonstrated a high brightness and wide color gamut QD‐based light source.