Application Of Phosphogypsum Research Articles

Soil utilization of solid waste: Small-strain dynamic properties and microscopic mechanism of phosphogypsum-modified coastal cement soil

Phosphogypsum (PG), a solid waste from the wet process phosphoric acid industry, but the utilization rate is low at present. The effect of phosphogypsum and cement on small strain dynamic characteristics of coastal soft soil was studied by resonance column test, and characterize the micro-mechanisms of the specimens by SEM and EDS test. The results show that the dynamic shear modulu (G) and the damping ratio (D) firstly increase and then decrease with the PG level increasing. PG can motivate the formation of hydrated calcium silicate (C–S–H) gel and react with calcium aluminate to form calcium. The critical value for assessing the dynamic behavior of PCS under small strain is γ = 10−4. The Hardin-Drnevich model eigenmodel can well characterize the dynamics of the PCS. Based on this model, a modified dynamic model is established to describe the dynamic characteristics of PCS. The microscopic results showed that the addition of phosphogypsum promoted the production of hydration products and made the particles more closely arranged. The content of this study provides a new reference for the application of solid waste phosphogypsum in cement soil.

Advances in Phosphogypsum Calcination and Decomposition Processes in Circulating Fluidized Beds.

Phosphogypsum (PG) is an industrial hazardous waste product discharged during wet-process phosphoric acid production. Once crystallized, the byproduct PG is filtered and separated from the liquid-phase product and sluiced to the disposal area near the production site for storage, seriously threatening the harmonious symbiosis between humans and nature. Therefore, devising effective solid waste management and cleaner production programs to contain and eliminate PG is of interest to researchers. In this study, the utilization status of PG is comprehensively reviewed, and a feasibility pathway for resourceful recovery of PG is proposed. The key challenges and countermeasures for the high-temperature calcination and decomposition of PG are analyzed and discussed. The visualization analysis based on bibliometrics reveals that the maximum recovery of abundant calcium (as CaO) and sulfur (as SO2) in PG and their utilization for the copreparation of calcium-based materials and sulfuric acid are the most suitable solutions for the large-scale application of PG. Five challenges that restrict the commercial promotion of PG calcination and decomposition processes are perfecting the calcium-sulfur conversion mechanism, establishing a process strengthening strategy, developing value-added technology routes, mastering unit scale-up regularity, and conducting sustainable performance assessment. Industrial applications are expected within 10-15 years.

Development of high-quality and water-resistant PBG through H-PDMS modification: From experiments to molecular dynamics simulation

The effective treatment and high-value application of phosphogypsum (PG) are of critical importance for the sustainable development of this construction material. However, its poor water-resistance property has limited its application in the construction field. In order to expand the application potential of phosphorous-building gypsum (PBG) as a durable material, potassium hydroxide (KOH) and hydroxyl‑terminated polydimethylsiloxane (H-PDMS) were used as the activating agent, and the water-resistant modifying agent in this study, respectively, to develop a high-quality and water-resistant PBG product. In addition, molecular dynamics was used to reveal the modification mechanism of H-PDMS and the water-resistance mechanism of KOH activating PBG. The study results show that H-PDMS can significantly improve the water-resistance performance of PBG test blocks. KOH can increase the surface activity of PBG by introducing -OH radicals, promote the reaction between H-PDMS and PBG, and form a dense hydrophobic layer on PBG, thus effectively improving its water-resistance performance. The number of surface active -OH radicals in PBG, the clustering effect of H-PDMS, and impurities in PBG can all result in different experimental and simulation outcomes. Meanwhile, the electrostatic force is an important factor influencing the adsorption of water droplets on the surface of PBG, and the reaction of H-PDMS with PBG normally occurs between Si-O and S-O. This study has systematically interpreted the working mechanism of water-resistant PBG, presenting an important significance in the utilization of PG resources.

Application of Phosphogypsum as Soil Amendment in Karst Farmlands and Its Environmental Impact Assessment

Application of Phosphogypsum as Soil Amendment in Karst Farmlands and Its Environmental Impact Assessment

High-Efficiency Purification and Morphology Regulation of CaSO4·2H2O Crystals from Phosphogypsum.

Phosphogypsum is a solid waste with great environmental stockpile pressure produced by the wet production of phosphoric acid. Although there are various methods to purify and utilize phosphogypsum, the means for environmentally friendly, low energy consumption, and high value-added utilization still need to be further explored. Here, CaSO4·2H2O crystal was directly purified and regulated from phosphogypsum by using the anti-solvent method. The antisolvent can be adsorbed in the c-axis direction of the crystal and further inhibit the growth rate in this direction, resulting in a change in the morphology of the crystal. By adjusting the polarity and chain length of the anti-solvent, the morphology of CaSO4·2H2O crystal can change from butterfly-like flake crystals to hexagonal prism-like crystals. When n-propanol with long chain was used as the anti-solvent, the morphology of the CaSO4·2H2O crystal showed a hexagonal prism with a specific surface area of 19.98 m2/g and a Cu2+ loading efficiency of 52.67%. The encouraging results open up new possibilities for the application of phosphogypsum.

The Concurrent Application of Phosphogypsum and Modified Biochar as Soil Amendments Influence Sandy Soil Quality and Wheat Productivity.

Sandy soil covers a significant portion of Egypt's total land area, representing a crucial agricultural resource for future food security and economic growth. This research adopts the hypothesis of maximizing the utilization of secondary products for soil improvement to reduce ecosystem pollution. The study focuses on assessing the impact of combining phosphogypsum and modified biochar as environmentally friendly soil amendments on loamy sand soil quality parameters such as soil organic carbon, cation exchange capacity, nutrient levels, and wheat yield. The treatments were T1: the recommended NPK fertilizer (control); T2: 2.5 kg phosphogypsum m-2 soil; T3: 2.5 kg rice straw biochar m-2 soil; T4: 2.5 kg cotton stalk biochar m-2 soil; T5: 2.5 kg rice-straw-modified biochar m-2 soil; T6: 2.5 kg cotton-stalk-modified biochar m-2 soil; and T7 to T10: mixed phosphogypsum and biochar treatments. The results revealed that the combined use of phosphogypsum and modified cotton stalk biochar (T10) significantly enhanced soil organic carbon (SOC) by 73.66% and 99.46% in both seasons, the soil available N both seasons by 130.12 and 161.45%, the available P by 89.49% and 102.02%, and the available K by 39.84 and 70.45% when compared to the control treatment. Additionally, this treatment led to the highest grain yield of wheat (2.72 and 2.92 Mg ha-1), along with a significant increase in straw yield (52.69% and 59.32%) compared to the control treatment. Overall, the findings suggest that the combined use of phosphogypsum and modified biochar, particularly cotton-stalk biochar, holds promise for improving loamy sand-soil quality and wheat productivity.

Effective strategies for reclaiming soda-saline soils: Field experimentation and practical applications in Southeast Kazakhstan

Soda-saline soils pose significant challenges to agricultural productivity, particularly in regions like the foothill plain of the Ili Alatau in southeast Kazakhstan. In this study, we examined the effectiveness of different ameliorants, including phosphogypsum, elemental sulfur, and sulfuric acid, in reclaiming soda-saline soils and enhancing crop yields. The study was conducted under real climatic and production conditions at the "Amiran" LLP farm. Using a randomized complete block design, we assessed the impact of these ameliorants on soil composition and alfalfa yield over two cutting cycles. The experiment involved the application of phosphogypsum, elemental sulfur, and sulfuric acid to designated plots within the farm, each covering an area of 15m2. Soil samples were collected before and after treatment to assess changes in soil composition and salinity. Alfalfa, a resilient perennial crop, was selected for cultivation due to its tolerance to adverse soil conditions. Our findings reveal that all tested ameliorants successfully neutralized the toxic environment of soda-saline soils, resulting in improved soil conditions and increased crop productivity. Phosphogypsum treatment led to a reduction in bicarbonate and carbonate ions, an increase in sulfate ion concentration, and improved soil structure. Elemental sulfur incubation decreased bicarbonate and carbonate ions, further reducing absorbed sodium levels and enhancing soil fertility. Sulfuric acid treatment provided rapid results in reducing alkalinity and increasing sulfate ion concentration, leading to significant improvements in soil quality and crop yield. However, the reclamation of soda-saline solonetzes presented challenges related to soil heterogeneity and poor water permeability. To address these challenges, we recommend the implementation of mechanical destruction of the solonetz soil horizon and deep soil loosening, accompanied by the addition of ameliorants. In conclusion, our study demonstrates the potential of phosphogypsum, elemental sulfur, and sulfuric acid as effective ameliorants for reclaiming soda-saline soils and improving agricultural productivity in challenging environments. By adopting recommended reclamation strategies, farmers can overcome soil limitations and achieve sustainable crop production in regions affected by soda-saline soil degradation.

Application of phosphogypsum and phosphate-solubilizing fungi to Pb remediation: From simulation to in vivo incubation

Phosphogypsum (PG) is the produced solid waste during phosphorus (P) extraction from phosphate rocks. PG is featured by its abundant PO43− and SO42−. This study investigated the utilization of PG as a material for lead (Pb) remediation, with the assistance of functional fungus. Aspergillus niger (A. niger) is a typical phosphate-solubilizing fungi (PSF), which has high ability to secret organic acids. Oxalic acid is its major secreted organic acid, which is often applied to enhance the P release from phosphate minerals. In this study, synthetic oxalic acid increased the immobilization rate of Pb2+ up to >99 % with the addition of PG. Then, it was observed that biogenic oxalic acid from A. niger can achieve comparable remediation effects. This was due to that PG could provide sufficient P for fungal growth, which allowed sustainable remediation. Subsequently, oxalic acid secreted by A. niger significantly increased the release of active P from PG, and then induced the formation of PPb minerals. In addition, other metabolites of A. niger (such as tyrosine-like substance) can also be complexed with Pb2+. Simultaneously, A. niger did not induce evidently elevation water-soluble fluorine (F) as PG contained abundant Ca2+. Moreover, this study elucidated that oversupply of PG promoted the formation of anglesite (Ksp = 1.6 × 10−8, relatively unstable), whereas the formation of lead oxalate (Ksp = 4.8 × 10−10, relatively stable) was reduced. This study hence shed a bright light on the sustainable utilization of PG for fungus-assisted remediation of heavy metals.

Research on the application of phosphogypsum in magnesium oxysulfate cement: A comparison with sand

Phosphogypsum (PG), as an industrial by-product, has historically suffered from challenges in achieving efficient utilization, resulting in enormous accumulation and environmental contamination. In this study, a certain proportion of PG was employed as a substitute for sand in magnesium oxysulfate cement (MOSC). The effects of PG on the properties, pores distribution, phase composition and microstructure of MOSC were investigated. The results showed that the introduction of PG yielded several beneficial effects, including enhanced volume stability and water resistance, alongside reduced apparent density. However, it also entailed several drawbacks, such as decreased paste flowability, prolonged setting time and increased water absorption rate of the specimens. PG incorporation induced no new crystalline phase, but moderate PG could promote nucleation and development of 5Mg(OH)2∙MgSO4∙7H2O (5∙1∙7 phase) and the group at 10% PG substitution has the highest compressive strength of 68.2 MPa. PG demonstrated the capability to hinder precipitation of Mg(OH)2, thereby enhancing the mechanical properties of MOSC. Due to the affordability and favorable environmental sustainability, PG-MOSC displayed considerable potential for various applications. This study elucidates the mechanism by which PG influences MOSC, providing reference and approach for the recycling of PG.

Amelioration of the physicochemical properties enhanced the resilience of bacteria in bauxite residues

Bacteria-driven strategies have gained attention because of their effectiveness, viability, and cost-efficiency in the soil formation process of bauxite residues. However, further investigation is needed to enhance the extreme environment of bauxite residues and facilitate long-term sustainable development of bacteria. Here, soil, phosphogypsum, and leaf litter were selected as amendments, and soil and leaf litter were also used as bacterial inoculants in a 12-month microcosm experiment with bauxite residues. The results showed significant improvements in physicochemical properties, including alkalinity, organic carbon content, nutrient availability, and physical structure, when bauxite residue was mixed with amendments, particularly when different amendments were combined. The diversity, structure, and function of the bacterial community were significantly enhanced with the amelioration of the physicochemical properties. In the treated samples, especially those treated with a combination of different amendments, the relative abundance (RA) of alkali-resistant bacterial taxa decreased, whereas the RA of some common taxa found in normal soil increased, and the structure of the bacterial community gradually changed towards that of normal soil. A strong correlation between physicochemical and biological properties was found. These findings suggest that rational application of soil, phosphogypsum, and leaf litter effectively improves the environmental conditions of bauxite residues and facilitate long-term sustainable bacterial communities.

Thermal and Mechanical Properties Enhancement of Cement Mortar using Phosphogypsum Waste: Experimental and Modeling Study

This research presents an in-depth investigation into the application of phosphogypsum (PG), a by-product of phosphate fertilizer plants and chemical industries, as a replacement material for cement in mortar, with a focus on enhancing its thermal and mechanical properties. The influence of PG as a partial replacement for cement on the compressive strength of mortar after 3, 7, and 28 days is investigated. Utilizing the Box-Behnken design within Response Surface Methodology, this study analyzed factors, such as sulfuric acid concentration, washing time, calcination temperature, and PG to cement ratio. Results indicate that optimal PG levels enhance mortar strength, particularly at 28 days, through sustained ettringite formation and microstructure optimization. Sulfuric acid concentration and calcination temperature were identified as the most significant elements influencing compressive strength, with the latter improving PG quality and reactivity. A PG to cement ratio up to 10% was found beneficial, while washing time had a negligible effect. The research highlights a critical synergy between the sulfuric acid concentration applied during the purification of PG and the calcination temperature. A significant improvement of 21% in compressive strength was achieved, underscoring the combined effect of chemical and thermal treatment on PG's efficacy in mortar. The increased sulfuric acid concentration is presumed to purify the PG by removing impurities, thus improving its reactivity. Concurrently, calcination alters the PG's crystalline structure and diminishes its organic composition. This interdependent optimization is instrumental in enhancing the structural integrity of PG-modified mortar. The potential for raw PG to be used as an insulating material is more pronounced at higher replacement rates (10%), while sulphuric acid treated PG (SCPG) and heat treated PG (HTPG) seem to be unable to provide a clear insulative advantage.

Utilization of phosphogypsum and red mud in alfalfa cultivation

In this work, the utilization of phosphogypsum (PG), a waste coming from the manufacture of phosphate fertilizers, as fertilizer for alfalfa (Medicago sativa L.) crops was investigated using pot experiments. The objective of this study was to evaluate the effects of both phosphogypsum and red mud (RM) in two soils representative of the pasture production area in Southern Spain. The morpho-physiological parameters of biomass, plant height, number of stems and number of leaves, as well as the chemical parameters of soil content, were measured. High doses of PG inhibited seed germination in some treatments. In addition, the treatment substrate (2550 g soil + 50 g kg−1 PG + 100 g kg−1 RM) also affected seed germination, possibly due to the large amount of RM. The application of PG and RM to the soil increased the availability of important nutrients for alfalfa, such as phosphorus (P), calcium (Ca2+) and magnesium (Mg2+). The results demonstrate that the treatment with PG significantly improved the uptake of P in alfalfa.

Soil Contamination by Heavy Metals and Radionuclides and Related Bioremediation Techniques: A Review

The migration of heavy metals and radionuclides is interrelated, and this study focusses on the interaction and complex influence of various toxicants. The rehabilitation of radioactively contaminated territories has a complex character and is based on scientifically supported measures to restore industrial, economic, and sociopsychological relations. We aim for the achievement of pre-emergency levels of hygienic norms of radioactive contamination of output products. This, in its sum, allows for further economic activity in these territories without restrictions on the basis of natural actions of autoremediation. Biosorption technologies based on bacterial biomass remain a promising direction for the remediation of soils contaminated with radionuclides and heavy metals that help immobilise and consolidate contaminants. A comprehensive understanding of the biosorption capacity of various preparations allows for the selection of more effective techniques for the elimination of contaminants, as well as the overcoming of differences between laboratory results and industrial use. Observation and monitoring make it possible to evaluate the migration process of heavy metals and radionuclides and identify regions with a disturbed balance of harmful substances. The promising direction of the soil application of phosphogypsum, a by-product of the chemical industry, in bioremediation processes is considered.

The combined application of salt-alkali tolerant phosphate solubilizing microorganisms and phosphogypsum is an excellent measure for the future improvement of saline-alkali soils.

The combined application of salt-alkali tolerant phosphate solubilizing microorganisms and phosphogypsum is an excellent measure for the future improvement of saline-alkali soils.

Agroecological assessment of the efficiency of utilization of quail manure in the restoration of disturbed sod-podzolic soils with the formation of a stable herbage

The most acute environmental problems of our time include large volumes of bird droppings produced annually at large livestock complexes. At the same time, the sod-podzolic soils dominating in the Non-Chernozem zone of the European part of Russia are characterized by low reserves of humus, which quickly fall with intensive agricultural use and soil anthropogenic degradation. To restore degraded sod-podzolic soils, a peat-sand substrate enriched with compost from quail manure without and with the application of phosphogypsum to stabilize organic compounds of compost was used with the support of project No. 075-15-2021-1030 of the Ministry of Science and Higher Education of Russia. The vegetation experiment showed the maximum increase in plant biomass of the herbage in the variant with the combined use of compost and phosphogypsum: respectively, 30% higher than the control one. In the summer, there is an increased intensity of soil CO2 emissions in the variants with compost, but with a multiple more active increase in grass biomass growing, so one can talk about the atmosphere carbon sequestering nature of the technology of utilization of quail droppings during the restoration of disturbed sod-podzolic soils with the formation of a stable herbage.

Impact of Phosphogypsum Application on Fungal Community Structure and Soil Health in Saline–Alkali-Affected Paddy Fields

Modifying saline–alkali soil is crucial for ensuring food security and expanding arable land. Microorganisms play a key role in driving various biochemical processes in agricultural ecosystems. However, limited information exists on the changes in the microbial community and soil structure in soda saline-alkali soil under modified conditions. In this study, we examined the changes in soil physicochemical properties of saline–alkali soil altered by rice planting alone and by combined application of phosphogypsum in the Songnen Plain. The results demonstrated that phosphogypsum significantly improved the soil’s physicochemical properties; it notably reduced salinity and alkalinity while enhancing nutrient structure. Additionally, the utilization efficiency of carbon (C), nitrogen (N), and phosphorus (P) increased. Fungal community diversity also significantly improved, influenced mainly by soil water content (SWC), total organic carbon (TOC), soil organic matter (SOM), total nitrogen (TN) and sodium ion (Na+). TOC, SOM, TN, ESP, and Na+ served as the primary drivers affecting the fungal community. Our findings indicate that combining rice planting with phosphogypsum application effectively modifies saline–alkali soil, regulates fungal community structure, and enhances long-term soil health. Furthermore, the beneficial effects of phosphogypsum on saline–alkali soil persist for persists for several years, largely owing to its role in promoting microbial community growth.

Utilization of phosphogypsum in phenol removal from coking wastewater

The paper presents the results of the application of raw phosphogypsum as an adsorbent for the preliminary treatment of coke-chemical wastewater with an initial concentration of phenol 395 mg/L. Studies in batch mode have proved that phenol removal is promoted by increasing the adsorbent dose and effluent temperature, the optimal phosphogypsum dose was found to be 5 g/L. The adsorption kinetics follows a pseudo-first-order model, the maximum adsorption capacity of phosphogypsum reaches 85 mg/g, which provides purification from phenol at the level of 85–90%. The process is spontaneous and endothermic. In column mode, at an effluent flow rate of 3 mL/min and the height of the fixed bed of 15 mm adsorbent dynamic capacity reached 124 mg/g. The obtained data indicate that raw phosphogypsum, available in huge quantities in the dumps of phosphoric acid plants, can be effectively used for the pretreatment of phenolic wastewater before biological treatment.

Long term co-application of lime and phosphogypsum increases 15 N recovery and reduces 15 N losses by modulating soil nutrient availability, crop growth and N cycle genes

In no-tillage rotation systems, the recovery of nitrogen (N) fertilizer in the soil–plant system is affected by soil fertility and biological changes caused by the surface application of lime (L) and phosphogypsum (PG). Here we assessed the effect of surface-applied L and/or PG on the fate of 15N-labeled fertilizer, soil chemical properties, microbial gene copy number (16 S rRNA of prokaryotes and genes of N cycle) and grain yield of maize (Zea mays L. intercropped with ruzigrass) in rotation with soybean [Glycine max (L.) Merrill] during two growing seasons. We found that applying L improved soil fertility, particularly when combined with PG (LPG treatment), resulting in higher grain yield. Moreover, compared with the control, the recovery of 15N-labeled ammonium sulfate [(15NH4)2SO4] increased in maize and ruzigrass dry matter but decreased in soybean grown on the residue of the first growing season in two treatments (L and LPG). The losses of 15N-labeled fertilizer were highest in the control and PG treatments. A large amount of 15N-labeled fertilizer was found in the deep layers of PG-amended soil, indicating leaching of fertilizer-derived 15N. Conversely, the analysis of soil microbial N cycle genes revealed that the abundances of denitrifiers were highest in the control (no correctives applied), suggesting that the N fertilizer remaining in the soil increased denitrification rates. Surface application of a combination of L and PG is clearly a feasible strategy for increasing soil fertility, 15N recovery from fertilizer, and grain yield while reducing environmental pollution associated with nitrification and denitrification.

THE INFLUENCE OF PHOSPHOGYPSUM ON THE SALT COMPOSITION OF SALINATED SOIL

Global climate changes in many countries of the world lead to the need to use irrigation as a driving factor for obtaining guaranteed and stable harvests of agricultural crops. Irrigation with water of different quality leads not only to an increase in the yield, but also to a change in the salt composition of the soil. The change in the salt composition of soils occurs much faster during irrigation with mineralized water, which leads to the accumulation of soluble salts in the arable layer of the soil and the deterioration of the composition of the soil absorption complex. Accumulation of sodium ions leads to salinization of irrigated soils. It is possible to stop or suspend the salinization processes by introducing chemical melioration with calcium-containing meliorants. As an ameliorant in this work, the use of a by-product of the mineral fertilizers production – phosphogypsum, which contains a significant amount of calcium (up to 95%), replacing exchangeable sodium in the soil absorption complex is proposed. Our researches are related to the establishment of optimal calculation norms and terms of phosphogypsum application, their influence on the change in the components of the soil’s saline extract. The research was conducted on soils that had been irrigated with mineralized water from the Samara River (Ukraine) for a long time (over 50 years). According to the amount of exchangeable sodium, the soils of the experimental sites belonged to low-sodium soils with physical signs of salinization processes, and according to the content of toxic salts-moderately saline. For phosphogypsum in the soil-ameliorative conditions of the Northern Steppe of Ukraine, the ameliorative, agronomic, and ecologically safe rates of introduction in spring and autumn were calculated. The scheme of experiments provided options with sprinkler irrigation and without irrigation. The composition of the aqueous extract was determined by indicators of anion-cation content. During the research, a gradual decrease in the number of sulfates was observed: by 1.5% in the second year after exposure, and by 7.5% in the third year after exposure to phosphogypsum. The number of hydrocarbons decreased in irrigated areas where phosphogypsum was applied, and an increase in their content was observed in areas where irrigation was not carried out. Irrigation options were characterized by a significant increase in the content of chlorine ions, which is explained by the arrival of these ions exclusively with irrigation water. The degree of salinity was determined by pH and sodium adsorption ratio (SAR). Based on these indicators, it was established that the soils are slightly saline in all variants of the experiments. As a result of multi-year research, a positive effect of phosphogypsum melioration on the anion-cation composition of water extract and the degree of soils salinity irrigated with mineralized water for a long time was noted. According to the anionic composition, the chemistry of the soils in the experimental plots was sulfate in the variants where phosphogypsum was applied and vegetation irrigation was carried out and without irrigation, while in the control plots (without phosphogypsum and without irrigation) soda-sulfate chemistry was characterized. The chemistry of the soils in the experimental areas according to the cationic composition was sodium in all versions of the experiments. According to the sodium-adsorption ratio (SAR), the degree of soil salinization belonged to the slightly saline type, while the average type of salinity remained in the control plots without phosphogypsum.

Phosphogypsum and poultry manure enhance diversity of soil fauna, soil fertility, and barley (Hordeum aestivum L.) grown in calcareous soils

Enrichment of calcareous soils with phosphogypsum and poultry manure amendments could increase nutrient availability, improve calcareous chemical characteristics, and enhance barley plant growth. In the current study, phosphogypsum (PG) and poultry manure (PM) were used to determine the effects of PG and PM application on soil fauna diversity, soil fertility, and barley yield. The pot experiment treatments were: C: control; PG1: 4.20 g kg−1 soil; PG2: 6.30 g kg−1 soil; PM1: 4.20 g kg−1 soil; PM: 6.30 g kg−1 soil, and their combinations. The results indicated that the application of PM alone or combined with PG had significant effects on the microbial biomass carbon (MBC), organic matter (OM), soil NPK availability, and yield of barley. Collembola and Prostigmata accounted for 50.0 and 43.3%, respectively, of the total number of soil fauna. Shannon and evenness indices increased significantly in the soil amended with PM alone or combined with PG. Amended soil with PG and/or PM significantly increased the yield and yield components of plants compared to the control. The PM1PG2 treatment increased the yield by 76.2% above the control.