Polarization of electromagnetic waves carries a large amount of information about their astrophysical emitters and the media they passed through, and hence is crucial in various aspects of astronomy. Here we demonstrate an important but long-overlooked depolarization mechanism in astrophysics: when the polarization vector of light travels along a nonplanar curve, it experiences an additional rotation, in particular for radio waves. The process leads to depolarization, which we call “geometric” depolarization (GDP). We give a concise theoretical analysis of the GDP effect on the transport of radio waves in a randomly inhomogeneous plasma under the geometrical optics approximation. In the case of isotropic scattering in the coronal plasma, we show that the GDP of the angle of arrival of the linearly polarized radio waves propagating through the turbulent plasma cannot be ignored. The GDP effect of linearly polarized radio waves can be generalized to astrophysical phenomena, such as fast radio bursts and stellar radio bursts, etc. Our findings may have a profound impact on the analysis of astrophysical depolarization phenomena.