Phase Transformation Behavior Research Articles

Effects of Calcination Conditions on the Structural and Electrochemical Behaviors of High‐Nickel, Cobalt‐Free LiNi0.9Mn0.1O2 Cathode

AbstractEliminating cobalt from high‐nickel layered oxide cathodes lowers the cost of lithium‐ion batteries for electric vehicles. However, cobalt‐free cathodes with high Mn4+ and Ni2+ contents are prone to Li/Ni mixing after synthesis, potentially compromising battery energy density, rate capability, and cycling stability. Without cobalt facilitating cation ordering in the layered structure, the degree of Li/Ni mixing in cobalt‐free cathodes depends heavily on the calcination conditions. In this study, a systematic exploration of calcination temperatures and LiOH ratio for LiNi0.9Mn0.1O2 (NM‐90) provides detailed insights into the optimal synthesis conditions for high‐capacity cobalt‐free cathodes with extended cycle life. Surprisingly, high Li/Ni mixing does not necessarily lead to poor cycling stability whereas low Li/Ni mixing does not guarantee a long cycle life. More importantly, although excessive calcination temperature can further decrease Li/Ni mixing, it does not necessarily enhance capacity. Instead, the pernicious effects from the H2 → H3 phase transition are amplified due to a pronounced two‐phase reaction. An extensive suite of chemical and structural characterization methods uncovers a correlation between elevated calcination temperature, phase transformation, cation ordering, and capacity fading behavior: “overcooking” high‐nickel, cobalt‐free cathodes induce structural arrangement toward that of LiNiO2, with exacerbated lattice distortion and surface instability accelerating capacity fade.

Interaction between phase transformation and static recrystallization during annealing of rolled TC18 titanium alloy

TC18 titanium alloy was subjected to hot rolling at 840 °C, followed by annealing experiments at 830, 860, and 890 °C for different time lengths. The effects of annealing temperature and time on phase transformation and static recrystallization (SRX) behavior, as well as the interaction between phase transformation and SRX, were studied. The results showed that at the low annealing temperature of 830 °C, the microstructure underwent β → α phase transformation and α grain growth with the increase of annealing time, and the SRX of β phase proceeded through subgrain nucleation mechanism induced by α particles. At the middle annealing temperature (860 °C), the α → β phase transformation occurred before the SRX of β phase, and the SRX of β phase was dominated by the grain boundary (GB) bulge mechanism. Meanwhile, the reduction of α phase content accelerated the SRX rate and grain growth. As the annealing temperature (890 °C) exceeded the β transus temperature, the α phase completely transformed to the β phase, and the SRX of the β phase proceeded with a very fast grain growth rate. In addition, the interaction between phase transformation and SRX affected the distribution of α particles. The large-sized α particles (830 °C) were located at the triple GB junction and hindered the SRX β grain growth, while smaller α particles (860 °C) were bypassed by β GB and dispersed within the SRX β grains.

Atomistic investigation of phase transformations in NiTiCu shape memory alloys

NiTiCu shape memory alloys have attracted much attention for their ability to reduce hysteresis, which is required fast responses in actuator and sensor applications, but the correlation between the properties and specific process of phase transformation is unclear. In this work, an atomic-level understanding of the detailed phase transformation behavior of NiTiCu shape-memory alloys is achieved based on a newly developed interatomic potential for the Ni–Ti–Cu ternary system. Free energy calculations based on the thermodynamic integration method faithfully reproduce reported experimental trends, such as the compositional dependency of different phase transformation paths. Further, large-scale molecular dynamics simulations performed on nanocrystalline alloys provide visual evidence of the detailed phase transformation process involving different martensitic transformation paths. Our results suggest that although both the composition and grain size can be adjusted to realize slim hysteresis, the effect of increasing the Cu amount is only significant if changes in the phase transformation modes are involved at relatively low Cu contents. When the material exhibits only a single phase transformation mode at relatively high Cu contents, the additional Cu is not highly effective in reducing the hysteresis.

Optimizing ageing conditions for commercial NiTi archwires: Insights from thermal phase transformation and tensile deformation analysis

Superelastic nickel-titanium (NiTi) archwires are now commonly used as the standard archwire during the orthodontic alignment and levelling stage. They are preferred due to their ability to apply minimal force on teeth while allowing for a wide range of tooth movements. During orthodontic treatment, the orthodontist assesses the dimension and shape of the NiTi archwire to determine the amount and direction of force required to align misaligned teeth. The main contribution of this study is the parametric analysis and establishment of a set of optimal ageing temperatures and duration for the investigation of functionally graded nickel-titanium archwire using differential scanning calorimetry (DSC) and tensile deformation testing. The mechanical and thermal phase transformation behavior after ageing at six temperatures for duration of 15 minutes have been investigated using tensile deformation test and differential scanning calorimetry (DSC) test in this paper. Experimental results reveal that in thermal analysis as the ageing temperatures increase from 400 °C to 490 °C, the austenite finish temperature rises to a value between 9.53 °C and 35.48 °C, and subsequently decreases to 520 °C. The archwire specimen aged for temperature of 490 °C exhibited the austenite finish temperature of around 35.48 °C, and it is highest among the aged wire specimens closest to oral temperature. In tensile deformation, the ideal ageing temperature for orthodontic applications was determined to be 490 °C for 15 minutes, resulting in relatively low plateau slope 13.73 GPa with high superelatic ratio 12.04, and maximum plateau strain of 7 %.

Synthesis and high-temperature phase transformation behavior of Dy2O3–Sc2O3 co-stabilized ZrO2 powders prepared by cocurrent chemical coprecipitation

In this study, Dy2O3–Sc2O3 co-stabilized ZrO2 (DyScSZ) powders with various stabilizer ratios were synthesized by cocurrent chemical coprecipitation method. The difference analysis of phase composition and microstructure was conducted on the synthesized powders in detail. The phase evolution and phase transformation behaviors of the synthesized powders were also investigated. Results show that all of the powders were synthesized with nanoscale and exhibit subglobose morphology. The excessive elevation of Sc2O3 fraction in total stabilizers was adverse to the formation of the synthesized powders with pure tetragonal phase, which also exhibit a significant effect both on the phase transformation behaviors and the final volume fractions of transform products. The 2.5Dy1.0ScSZ powders exhibit favorable phase stability resulting from the nano-size effect and the synergies of Dy2O3 and Sc2O3 stabilizers during the phase transformation process. Moreover, a phase transformation mechanism of DyScSZ was proposed based on the new phase nucleation and growth theory.

Microstructure and Phase Transformation Behavior of NiTiCu Shape Memory Alloys Produced Using Twin-Wire Arc Additive Manufacturing

NiTiCu thin walls were produced by twin-wire arc additive manufacturing (T-WAAM) using commercial NiTi and Cu wires as the feedstock materials. This approach aims to solve the problems typically associated with large phase transformation hysteresis in NiTi shape memory alloys. The microstructure, mechanical properties, and phase transformation behavior of the as-deposited NiTiCu alloy were comprehensively examined. The results revealed that the as-deposited NiTiCu alloy was well-formed, with its microstructure showed columnar, equiaxed, and needle-like grains, depending on the location within the deposited walls. The microhardness gradually increased from the first to the third layer. The Cu content was 20.80 at%, and Cu-based precipitates were formed in the as-deposited NiTiCu. The volume fractions and lattice parameters of the matrix and precipitates in the as-deposited NiTiCu material were analyzed using high-energy synchrotron X-ray diffraction. The martensitic phase was identified as a B19 crystal structure, and the as-deposited NiTiCu underwent a one-step B2-B19 phase transformation. The tensile strength and fracture strain were approximately 232 MPa and 3.72%, respectively. In particular, the addition of Cu narrowed the phase transformation hysteresis of the as-deposited NiTiCu alloy from 24.4 to 7.1 ℃ compared with conventional binary NiTi alloys. This study expands the potential of T-WAAM in modifying the phase transformation behavior of NiTi-based ternary alloys.

Effect of heat treatment on the microstructure and superelasticity of NiTi alloy via selective laser melting

In this study, a Ni50.4Ti49.6 shape memory alloy (SMA) was fabricated by selective laser melting (SLM), and it is found that heat treatments were effective to change the phase transformation behavior, microstructure, and superelasticity under compression for SLM Ni50.4Ti49.6. Detailed results based on EBSD demonstrated that, for SLM Ni50.4Ti49.6 during solid solution and aging (450 °C) treatment, the ultrafine cellular and columnar grains (∼16.5 μm) in as-fabricated Ni50.4Ti49.6 became equiaxed grains (∼70.2 μm), and the frequency of low-angle grain boundaries (26.7%→13.5%) and kernel average misorientation (0.37 → 0.21) decreased. The SEM and TEM analyses show that Ti-rich Ti2Ni/Ti4Ni2Ox and Ni-rich Ni4Ti3 precipitate phases were formed in the matrix simultaneously. After solid solution treatment, the size and distribution of Ti2Ni/Ti4Ni2Ox almost unchanged with aging temperature increasing from 350 °C to 550 °C, however, the size of Ni4Ti3 in aging-treated NiTi samples increased with aging temperature obviously, and it is interesting to find that the distribution of Ni4Ti3 became uneven and dislocation networks were formed in the matrix when the aging treatment reached up to 550 °C, which originated from the internal stress generated by supersaturated Ni atoms. Furthermore, the results of superelasticity for aging-treated NiTi demonstrated that the characteristics of Ni4Ti3 precipitate phase were powerful to influence the process of superelasticity decay/fatigue instead of determining the ultimately recovery strain after 10 compressive cycles. The aging-treated NiTi with evenly-distributed, high-density, and relatively-small Ni4Ti3 precipitate phase shows minimum recovery strain at 1st cycle compression and best superelasticity stability among three aging-treated NiTi, which was attributed to strong obstruction effect of these Ni4Ti3 precipitate for the occurrence of stress-induced martensitic transformation process and formation of dislocations. In contrast, the aging-treated NiTi with unevenly-distributed and low-density Ni4Ti3 precipitate shows maximum recovery strain at 1st cycle compression and worst superelasticity stability. These results in this work can bring some meaningful insights into tailoring the microstructure and superelasticity of SLM NiTi SMAs.

Understanding the role of laser processing parameters and position-dependent heterogeneous elastocaloric effect in laser powder bed fused NiTi thin-walled structures

To reduce the driving load and enhance the heat exchange capacity and elastocaloric refrigeration efficiency, increasing interests in porous structure design and laser-based additive manufacturing (LAM) of NiTi materials with a large specific surface area have been emerging. As a type of characteristic unit of porous components, we mainly focused on the LAM process optimization and elastocaloric effect of NiTi-based thin-walled structures (TWSs) in this work. Firstly, we systemically studied the influence of laser processing parameter on the forming quality and phase transformation behavior of NiTi-based TWS samples. Results showed that high relative density (>99.0%) was inclined to be obtained in a range of 67–133 J mm−3 (laser energy density). Besides, the transformation temperatures (TTs) and enthalpy change roughly showed a positive linear relationship with the applied laser energy density. At an optimized parameter (P = 100 W and v = 1000 mm s−1), the sample exhibited a high relative density (99.88%), good dimensional accuracy, and the lowest TTs. Then, this work emphatically unveiled the position-dependence of phase transformation behavior and elastocaloric effect (eCE) in a NiTi-based TWS sample. It was found that both the TTs and enthalpy change monotonously decreased along the building direction, while the transformation strain kept an increase trend. As a result, the middle portion of the sample exhibited the largest adiabatic temperature change which reached 6.5 K at the applied stain of 4%. The variation in TTs and eCE could be attributed to the heterogeneous solidification microstructure induced by the thermal cycle nature of LAM process.

Heat treatment protocol for additively manufactured nitinol shape memory alloys in biomedical applications

Additive manufacturing (AM) is getting significant attention in realizing customizable nitinol (NiTi) devices for biomedical applications. However, due to the change in composition and constituent phases occurring during printing and the microstructural inhomogeneity in the printed parts, obtaining a desired set of phase transformation behaviors and superelastic properties is a major challenge. In this work, laser powder bed fusion (LPBF) was used to fabricate NiTi at a very low laser energy density (35 J/mm3) on a titanium base plate while keeping these behaviors and properties within desirable ranges without any structural defects such as crack and delamination. Our measurements showed that the as-printed NiTi exhibited distinct one-step phase transformation with the austenite finish (Af) temperature of 2.1 °C. To increase the Af temperature to 30.2 °C (within the recommended range of Af temperature for biomedical applications), a heat treatment protocol was developed, which includes a solution cycle (at 900 °C for 1 h) followed by an aging cycle (at 450 °C for 30 min). The heat treatment protocol enabled us to attain the homogenized microstructure while creating ultrafine metastable Ni-rich precipitate, Ni4Ti3, which facilitated the desirable phase transformation behavior with the increased Af temperature. The heat-treated sample showed narrower and sharper two-step martensitic phase transformation with the formation of intermediate R-phase. The presence of both Ni4Ti3 and the R-phase was confirmed by the transmission electron microscopic (TEM) analysis. In the superelasticity test at the body temperature, these samples, starting from the 2nd cycle, demonstrated a recovery ratio of more than 90% and a recoverable strain of more than 6.5%. After 10th cycles, the stable recoverable strain was 6.52% with a recovery ratio of 96%, which is the highest superelasticity reported for the LPBF processed NiTi to the best of our knowledge. After the initial deformation process, we expect these NiTi samples to attain near full superelasticity during service. The micro-hardness study also showed that the hardness of the heat-treated samples is less affected by the cyclic loading. Therefore, this paper presents a viable heat treatment protocol, which provides an important processing roadmap in making NiTi implants by AM while maintaining excellent functional properties of NiTi for biomedical applications.

Unraveling effect of Nb addition on the microstructure, phase transformation behaviour and shape memory effect of CuAlMn alloy fabricated by laser powder bed fusion

In this work, the various amount of Nb powder was mechanically mixed into the Cu–Al–Mn shape memory alloys (SMAs) to prepare quaternary SMAs by laser powder bed fusion (LPBF). Altered microstructure, transformation behaviour of alloys and its underlying mechanisms were analyzed. Corresponding shape memory effect (SME) was also studied. Result shows that Nb content has significant effect on the microstructure, phase transition temperatures (TTs) and SME. The microstructure of the alloy was refined by addition of appropriate Nb content. The formation of precipitates and massive grain boundaries after the addition of Nb caused a reduction of TTs and wide thermal hysteresis. Sample with 1 at%Nb containing fine and small volume fraction precipitate shows the best available strain.

Defect-Free Prussian Blue Analogue as Zero-Strain Cathode Material for High-Energy-Density Potassium-Ion Batteries.

Prussian blue analogues (PBAs) have been widely studied as cathodes for potassium-ion batteries (PIBs) due to their three-dimensional framework structure and easily adjustable composition. However, the phase transition behavior and [Fe(CN)6]4- anionic defects severely deteriorate electrochemical performances. Herein, we propose a defect-free potassium iron manganese hexacyanoferrate (K1.47Fe0.5Mn0.5[Fe(CN)6]·1.26H2O, KFMHCF-1/2) as the cathode material for PIBs. The Fe-Mn binary synergistic and defect-free effects can inhibit the cell volume change and octahedral slip during the K-ion insertion/extraction process, so that the phase transformation behavior (monoclinic ↔ cubic) is effectively inhibited, achieving a zero-strain solid solution mechanism employing Fe and Mn as dual active-sites. Thus, KFMHCF-1/2 contributes the highest initial capacity of 155.3 mAh·g-1 with an energy density of 599.5 Wh·kg-1 at 10 mA·g-1 among the reported PBA cathodes, superior rate capability, and cyclic stability over 450 cycles. The assembled K-ion full battery using K deposited on graphite (K@G) as anode also delivers high reversible specific capacity of 131.1 mAh·g-1 at 20 mA·g-1 and ultralong lifespans over 1000 cycles at 50 mA·g-1 with the lowest capacity decay rate of 0.044% per cycle. This work will promote the rapid application of high-energy-density PIBs.

Effects of laser welding on the martensitic transformation of a shape-memory Ti-Ni alloy

The objective of this study is to investigate the martensitic transformation behavior of a Ti-Ni alloy subjected to a laser welding process. Materials characterization techniques were used to analyze the influences of this welding procedure on the phase transformation behavior. This study can provide valuable insights for the improvement of Ti-Ni alloy welding processes used for technological applications, such as in the aerospace industry. In this study, samples were prepared under three conditions: thermal treatment at 400°C, thermal treatment at 500°C, and as-received. The characterization techniques used were: Optical Microscopy (OM), Differential Scanning Calorimetry (DSC), Electron Dispersion Spectroscopy (EDS), X-Ray Diffraction (XRD), and Vickers Microhardness (HV). The results allow for analysis of thermoelastic martensitic transformation and variations in the compositions of the alloy elements. The research, in general, aims to repurpose welding waste in Ti-Ni alloys for the production of mini sensors. The enthalpy was higher for the alloy treated at 500°C and welded. The research findings led to the observation of martensitic phase transformation in the laser-welded Ti-Ni alloy, which suggests that it can be used as a sensor/actuator.

Phase transformation behavior and superelasticity of nanocrystalline Ti50Ni50-xCox shape memory alloys

The phase transformation behavior and superelasticity of nanocrystalline Ti50Ni50-xCox (x = 3, 5, 9) alloy wires were investigated. The results showed that the starting temperature of the B2→R phase transformation gradually decreased with the Co content, while the superelastic temperature range of the alloy wires shifted toward cryogenic temperatures as the Co content increased. The superelastic temperature range appeared from 100 to - 45 °C for the Ti50Ni47Co3 alloy wire and from 80 to - 90 °C for the Ti50Ni45Co5 alloy wire. The Ti50Ni41Co9 alloy wire exhibited excellent superelasticity over a temperature range from -40 to -196 °C and ultra-high superelastic stresses from 1200 to 960MPa.

Phase Transformation Behavior of NiTi Triply Periodic Minimal Surface Lattices Fabricated by Laser Powder Bed Fusion

Phase Transformation Behavior of NiTi Triply Periodic Minimal Surface Lattices Fabricated by Laser Powder Bed Fusion

Effect of Temperature on the Cyclic Fatigue Resistance and Phase Transformation Behavior of Three Different NiTi Endodontic Instruments.

Background This study aims to analyze the phase transformation behavior and evaluate the effect of different temperatures on the fracture strength of files. Methodology A total of 108 files were used, and cyclic fatigue tests were performed on HyFlex EDM, VDW.ROTATE, and TruNatomy at three different temperatures (+4°C, +35°C, and +60°C) The time to fracture of files was measured, and the number of cycles was calculated. In addition, the fractured fragment lengths were measured. The Kruskal-Wallis test was used to compare the data that were not normally distributed according to groups. The Mann-Whitney U test was performed for comparisons. P-values <0.05 were considered statistically significant. Results As the temperature increased for all files, the number of cycles to fracture (NCF) decreased. NCF was significantly higher for ROTATE at 4°C and 60°C and HyFlex EDM at 35°C. Conclusions The resistance to cyclic fatigue in all files decreased significantly as the temperature increased.

Effect of phase transformation on the densification of LaYO3 pellet

Fabrication process of LaYO3 pellets was studied to develop a reaction-preventing material for casting metallic nuclear fuel. LaYO3 pellets were fabricated by sintering La2O3 and Y2O3 powders. Phase transformation and densification behavior of the LaYO3 were investigated at various temperatures to find optimal conditions of LaYO3 sintering process. Two different LaYO3 structures were formed depending on sintering temperature; an orthorhombic perovskite LaYO3 structure was formed at the sintering temperatures of 1633, 1703, 1743, 1763, 1773, and 1793 K, while a monoclinic LaYO3 structure was formed at a sintering temperature of 1843 K. The Bulk density of sintered LaYO3 pellets increased up to 1763 K, and decreased at the temperatures ranging from 1763 to 1843 K. This study demonstrated that the formation of the LaYO3 phases and the density of the LaYO3 sintered pellets were regulated by varying the sintering temperature. Thus, the fabrication temperature of the high-density LaYO3 sintered pellets was optimized, and the mechanism of the change in density was elucidated.

Finite Element Method of Functionally Graded Shape Memory Alloy Based on UMAT

Functionally graded shape memory alloy (FG-SMA) is widely used in practical engineering regions due to it possessing the excellent properties of both FG material and SMA material. In this paper, the incremental constitutive equation of SMA was established by using the concept of a shape memory factor. On this basis, the secondary development function of the ABAQUS software 2023 was used to write the user-defined material subroutine (UMAT). The phase transformation and mechanical behavior of transverse and axial FG NiTi SMA cantilever beams under concentrated load at free ends were numerically simulated by discrete modeling. Numerical results show that the stress and shape memory factor were distributed asymmetrically along the thickness direction of the transverse FG-SMA cantilever beam, while the stress and the shape memory factor distributed symmetrically along the thickness direction of the cross section of the axial FG-SMA cantilever beam. The bearing capacity of the axial FG-SMA cantilever beam is stronger than the SMA homogeneous cantilever beam, but weaker than the transverse FG-SMA cantilever beam. The load-bearing capacity of the transverse FG-SMA cantilever beam is twice that of the axial FG-SMA cantilever beam under the same functionally graded parameters and deflection conditions. The discrete modeling method of FG-SMA beams proposed in this paper can simulate the phase transformation and mechanical behavior of an FG-SMA beam well, which provides a reference for the practical application and numerical calculation of FG-SMA structures.

Effect of Carburization on the Microstructure and Laser Weldability of 316L Stainless Steel

This study aims to investigate the influence of the carburizing layer on the microstructure of laser-welded joints in 316L stainless steel, aiming to enhance the properties of stainless steel components through the incorporation of carburization. Through a comprehensive experimental approach, including nanoindentation and Vickers hardness measurements, the microstructural analysis of the laser-welded specimens was conducted. The nanoindentation results reveal a significant increase in hardness, with the carburizing layer exhibiting a remarkable 215% improvement compared to the base material. In order to effectively harness the wear resistance for various applications, the examination of macroscopic characteristics in laser-welded joints reveals the necessity of regulating heat input and minimizing defects to attain welds of superior quality. Additionally, the phase transformation behavior of stainless steel during welding was found to be altered due to dilution in the fusion zone and the presence of high carbon content in the heat-affected zone of the carburizing layer. Overall, this research provides valuable insights into the microstructural changes induced by carburization and its implications for the welding performance and mechanical properties of stainless steel.

Influence of sodium hydroxide on phase transformation of gamma alumina to alpha alumina

AbstractCorundum and transition alumina powders are commonly produced through the Bayer process—that is, by digestion of bauxite in a sodium hydroxide solution, followed by gibbsite precipitation, which contains significant amounts of Na+ ions. During the de‐hydroxylation of gibbsite, Na+ is associated with retardation of the structural phase transformations between transition alumina and corundum (α‐Al2O3) phases, although the exact role of Na is unclear. The influence of Na+ ions on the phase transformation of γ‐Al2O3 to α‐alumina was investigated by varying the concentration of NaOH in aqueous γ‐Al2O3 suspensions. The phase transformation behavior of γ‐Al2O3 was monitored through thermal analysis, X‐ray diffraction, scanning electron microscope, X‐ray photoelectron spectrometer (XPS), and transmission electron microscope. As the Na concentration in γ‐alumina suspensions increased, the amount of α‐Al2O3 decreased in samples that were heat treated at 1200°C for 2 h. XPS analysis indicated that washing transition alumina powders with NH4OH solutions had decreased the surface concentration of Na+ and facilitated the phase transformation to α‐Al2O3.

(Best Presentation Award - 2nd Place) Investigating Low Temperature Reaction Mechanisms of Alloy Anodes for Lithium-Ion Batteries

Lithium-ion batteries (LIBs) are the battery of choice for most energy storage applications, including personal electronic devices and electric vehicles. However, poor low temperature performance, resulting from hindered solid state diffusion, slow desolvation kinetics, and dendrite formation, limits their use in nascent applications that require operation below -20 ºC, like electric aviation and space exploration. A small number of previous studies have shown that anode materials that electrochemically alloy with lithium ions can be cycled at temperatures as low as -40 ºC with significantly improved performance compared to graphite. Despite their improved low-temperature performance, reaction mechanisms and degradation behavior for these materials at low temperatures are poorly understood. This work aims to fill this gap in understanding by investigating the structural pathways during reactions of alloy anodes at low temperatures as well as characterizing their mechanical and electrochemical degradation. Electrode cross sectioning and scanning electron microscopy reveal that rapid capacity decay in antimony anodes at -40 ºC is a result of increased lithium trapping as well as particle fracture due to mechanical damage associated with volume change. We show that rapid capacity degradation of antimony at -40 ºC can be mitigated through the use of nanoscale particles. While nanoscale particles have been studied extensively at room temperature, little is known about they behave at low temperatures. Through SEM cross-sectioning and the galvanostatic intermittent titration technique (GITT), we show that the improvement in stability is likely due to faster kinetics related to the shorter diffusion length and increased mechanical stability resulting in less lithium trapping at low temperatures. Additionally, X-ray diffraction measurements were carried out as a function of temperature on micron- and nanosized antimony particles, as well as tin and graphite, to determine the composition and structure of lithiated phases formed at low temperatures. The results show that reduced temperatures alter phase transformation behavior in certain alloy materials. Overall, this work provides improved mechanistic understanding of alloy anodes at low temperatures, setting the stage for enhanced electrochemical performance.