We investigate the characteristics of temporal phase locking states observed in the route to phase synchronization. It is found that before phase synchronization there is a periodic phase synchronization state characterized by periodic appearance of temporal phase-locking state and that the state leads to local negativeness in one of the vanishing Lyapunov exponents. By taking a statistical measure, we present the evidences of the phenomenon in unidirectionally and mutually coupled chaotic oscillators, respectively. And it is qualitatively discussed that the phenomenon is described by a nonuniform oscillator model in the presence of noise.