Structural Phase Change Research Articles

Failure Mechanism Analysis of Thermal Barrier Coatings Under a Service Simulation Environment

In this paper, the ceramic coating of thermal barrier coatings (TBCs) was prepared on the surface of the tube specimens by Electron Beam Physical Vapor Deposition (EB-PVD) process. Subsequently, a service simulation was conducted using a simulation device to analyze the failure behavior of the TBCs. The effects of high-temperature sintering and CaO-MgO-Al2O3-SiO2 (CMAS) corrosion on the microstructural evolution, phase structural changes, and insulation performance of the thermal barrier coatings were investigated. The results indicated that with increasing high-temperature sintering time, the “feather” structures at the boundaries of the columnar grains evolve into the “tentacle” structure that facilitates the fusion of adjacent columnar grains, resulting in increased grain diameter and wider gaps. No transformation from t’-ZrO2 to the monoclinic phase m-ZrO2 occurred during the high-temperature sintering process. Over time, CMAS wets the coating surface and infiltrates the interior of the coating, causing corrosion to the Yttria-stabilised zirconia (YSZ) and accelerating sintering. A new phase, ZrSiO4, was formed after corrosion without inducing the transition.

The Effect of Phase Changes on Optoelectronic Properties of Lead-Free CsSnI3 Perovskites

Abstract First-principles calculations were carried out within the framework of density functional theory to investigate the influence of phase changes on the electronic and optical properties of CsSnI3. The lattice parameter and band gap of four different phases, i.e., α-, β-, γ-, and δ-phases, of CsSnI3 are estimated by employing different exchange–correlation functionals in order to explore their ability to reproduce geometric and electronic structures adequately. Comparison of the calculated total energies shows the non-perovskite orthorhombic (δ-phase) modification of CsSnI3 is the most stable, followed by the orthorhombic (γ-CsSnI3) perovskite phase. Thermal stability calculations in the form of temperature dependence of entropy as well as the absence of imaginary frequencies in the phonon dispersion diagrams also confirmed the dynamical stability of the δ-CsSnI3. The influence of the structural phase changes on the band gap and Fermi level shifts of CsSnI3 were assessed. Contribution of the electronic states on the formation of the valence and conduction band of four phases of CsSnI3 were determined, which were calculated using various exchange–correlation functionals, including the high-precision hybrid functional HSE06, and compared with available experimental ones. The calculated energy band distribution diagrams showed that all three perovskite modifications of CsSnI3 have direct transitions, while δ-CsSnI3 has an indirect transition. It was found that during the transition from δ- to α-phase, the Fermi level descends to the low energy region (towards the valence band), and the band gap decreases from 2.99 eV to 1.33 eV. During the transition from α- to β-phase, the band gap width again decreases to 1.23 eV and the Fermi level mixes by 1.65 eV towards the conduction band (CB). On the contrary, the band gap increases from β- to γ-phase and the Fermi level shifts by 0.41 eV towards the conduction band. The values of the complex dielectric constant and the refractive index of four phases of CsSnI3 were also calculated.

Anionic modulation induces molecular polarity in a three-component crown ether system.

Three-component crown ether phase change materials are characterized by a structural phase change in response to external stimuli such as temperature and electric or magnetic fields, resulting in significant changes in physical properties. In this work, we designed and synthesized two novel host-guest crown ether molecules [(PTFMA)(15-crown-5)ClO4] (1) and [(PTFMA)(15-crown-5)PF6] (2), through the reaction of p-trifluoromethylaniline (PTFMA) with 15-crown-5 in perchloric acid or hexafluorophosphoric acid aqueous solution. Compound 1 undergoes a structural change from the non-centrosymmetric space group (P21) to the centrosymmetric space group (P21/c) with increasing temperature. This transformation is accompanied by a switchable second harmonic generation (SHG) signal, a noticeable dielectric response, and a reversible phase transition in differential scanning calorimetry (DSC). For compound 2, there are reversible phase transitions accompanied by a dielectric response, but it does not exhibit a switchable SHG signal. The difference in properties between the two compounds may be due to the polarity modulation of the anion, providing new ideas for obtaining crown ether complexes with SHG response properties.

Enhanced Reduction of Carbon-Iron Ore Composite Briquettes under Varying Pressing Forces via Direct Microwave Heating

This study uses direct microwave heating to investigate the direct reduction process in carbon-iron ore composite briquettes under varying pressing forces. The composite briquettes, made from magnetite iron ore concentrate, anthracite coal, and bentonite as binder, were pressed at 1-ton, 2-ton, and 3-ton loads and then subjected to microwave irradiation. X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were employed to analyze the phase composition and structural changes. The results show that the 1-ton briquettes exhibited predominantly metallic Fe with minor fayalite and FeO phases, whereas the 2-ton and 3-ton samples displayed increased fayalite formation. Notably, re-oxidation occurred in the 2-ton and 3-ton samples, as indicated by the presence of Fe₃O₄. The higher pressing forces caused reduced air permeability and lower CO diffusion efficiency, hindering the reduction process. These findings highlight the influence of compaction pressure on the reduction process and the potential of microwave heating as an energy-efficient alternative in ironmaking.

In Situ Transmission Electron Microscopy of Electrocatalyst Materials: Proposed Workflows, Technical Advances, Challenges, and Lessons Learned.

In situ electrochemical liquid phase transmission electron microscopy (LP-TEM) measurements utilize micro-chip three-electrode cells with electron transparent silicon nitride windows that confine the liquid electrolyte. By imaging electrocatalysts deposited on micro-patterned electrodes, LP-TEM provides insight into morphological, phase structure, and compositional changes within electrocatalyst materials under electrochemical reaction conditions, which have practical implications on activity, selectivity, and durability. Despite LP-TEM capabilities becoming more accessible, in situ measurements under electrochemical reaction conditions remain non-trivial, with challenges including electron beam interactions with the electrolyte and electrode, the lack of well-defined experimental workflows, and difficulty interpreting particle behavior within a liquid. Herein a summary of the current state of LP-TEM technique capabilities alongside a discussion of the relevant experimental challenges researchers typically face, with a focus on in situ studies of electrochemical CO2 conversion catalysts is provided. A methodological approach for in situ LP-TEM measurements on CO2R catalysts prepared by electro-deposition, sputtering, or drop-casting is presented and include case studies where challenges and proposed workflows for each are highlighted. By providing a summary of LP-TEM technique capabilities and guidance for the measurements, the goal is for this paper to reduce barriers for researchers who are interested in utilizing LP-TEM characterization to answer their scientific questions.

Exploring the Intrinsic Effects of Lattice Strain on the Hydrogen Evolution Reaction via Electric-Field-Induced Strain in FePt Films.

Strain engineering has the potential to modify the adsorption process and enhance the electrocatalytic activity, especially in the hydrogen evolution reaction (HER). However, the introduction of lattice strain in electrocatalysts is often accompanied by a change in chemical composition, surface morphology, or phase structure to a certain extent, impeding the investigation of the intrinsic strain effect on HER. In this work, the FePt film was deposited on a Pb(Mg1/3Nb2/3)0.7Ti0.3O3 (PMN-PT) substrate to construct the FePt/PMN-PT heterojunction, and the continuously adjustable nonvolatile lattice strain is induced by the asymmetric electric field manipulation avoiding the aforementioned disturbance factors. HER experimental results demonstrate a drastic improvement in the overpotential of FePt with the largest tensile strain of 3000 ppm, and the observed variation of HER performance indicates an upward trend as the tensile strain increases. Density functional theory calculations reveal that the Gibbs free energy of FePt with the appropriate tensile strain is closer to zero, attributed to the downward shift of the d-band center. Our study provides an approach to continuously regulate the lattice strain with less interference factors, facilitating the exploration of the intrinsic strain effect on a wide range of catalysts.

Enhancing performance in heat storage unit and packed-bed system: Novel capsule designs inspired by drop structure

Packed-bed system offers a promising solution to the uneven spatiotemporal variability of solar energy. However, challenges persist in its development, including excessive disparity in localized temperature, sluggish heat storage rate, and suboptimal efficiency. In this context, the drop structure phase change material capsule concept was proposed to enhance thermal energy storage performance, drawing inspiration from the streamlined structure such as tuna or submarine. This research delves into the comprehensive performance of drop, sphere, and shuttle structure capsules, encompassing experimental investigation and simulation analysis of the external convection, internal melting, and charging processes. Additionally, an experimental visualization setup was devised to monitor the melting process. The results indicated that replacing conventional sphere structure capsule with the drop structure capsule reduces the drag of external flow by 10.12%. The complete melting time of the individual capsule and the packed-bed system was shortened by 5.53% and 10.94%, respectively. Furthermore, the standard deviations of the longitudinal and radial average temperatures decreased by 24.12% and 29.97%, respectively.

Simultaneous Solid Electrolyte Deposition and Cathode Lithiation for Thin Film Batteries

Interest in thin film solid state lithium-ion batteries (TFSSLIBs) continues to grow because of their increased safety over flammable liquid electrolytes and their compatibility with well-established thin-film fabrication methods and characterization techniques. TFSSLIBs are also attractive for addressing fundamental questions because they generally comprise fewer components (no binders or conductive additives), and are commonly used to investigate the formation and evolution of solid electrode/electrolyte interfaces. TFSSLIBs are well suited to study the inherent capacity retention and rate performance of cathode materials in a symmetric battery structure, e.g., cathode/SSE/cathode. V2O5 is a candidate with a high theoretical capacity and insertion chemistry of up to 3 Li ions per V2O5, but which practically is unable to achieve highly reversible cycling of even Li2V2O5 due to the structural phase change upon lithiation. By designing a TFSSLIB model system with a solid electrolyte that forms a stable electrode/electrolyte interface, e.g. lithium phosphorous oxynitride (LiPON), in a symmetric configuration, we are able to study the performance of LixV2O5 thin film cathodes without the additional deleterious effects related to anode performance.We will discuss the fabrication and cycling performance of two different symmetric V2O5 TFSSLIB configurations. The first is a V2O5/LiPON/LixV2O5 TFSSLIB, where the cyclable lithium in this system is included via simultaneous electrolyte deposition and lithiation of one V2O5 cathode during the RF sputtering process, as discussed in our recent publication.1 The second configuration is an LixV2O5/LiPON/LixV2O5 TFSSLIB where lithium is included during the auto-lithiation step of the first V2O5 electrode as well as during the co-sputtered deposition of the second V2O5 electrode. A comparison of the two TFSSLIB symmetric cell performances will be discussed, as well as a comparison to similar symmetric cells cycled in liquid electrolyte. We show that the deposition of the solid-state electrolyte LiPON onto thin film V2O5 leads to a uniform lithiation of up to 2.2 Li per V2O5, without affecting the Li concentration in the LiPON and its ionic conductivity. In the LixV2O5/LiPON/LixV2O5 system, we demonstrate cycling of >270 mAh/g at a rate of 20C, for 1600 cycles with only 8.4% loss in capacity.1. Warecki, Z. et. al., Simultaneous Solid Electrolyte Deposition and Cathode Lithiation for Thin Film Batteries and Lithium Iontronic Devices, ACS Energy Lett, 2024, 9, 2065-2074

The Effect of the Surrounding Matrix on Spin Transition Nanoparticles: How Shell Characteristics Alter Core Elastic Properties in Core‐Shell Particles

AbstractA surrounding matrix is known to alter nanoparticle spin transitions, the solid state structural phase changes associated with transitions between high spin (HS) and low spin(LS) states. To better quantify how the spin transition solid and surrounding matrix interact, several series of core‐shell particles were prepared based on RbxCo[Fe(CN)6]z ⋅ nH2O, RbCoFe‐PBA, as spin transition core with isostructural shells of different compositions and thicknesses. Synchrotron PXRD through the thermal high HS to LS, the LS to photoexcited high spin (PXHS), and thermal PXHS to LS transitions, show the activation energy is lowered as shells become thicker and stiffer. Calorimetry data coupled with transition state theory analysis indicate the core stiffens in the core‐shell particles relative to the uncoated particles. The conclusion is supported by microstrain analysis that shows stiffer shells limit the extent to which the core distorts as individual sites transition, leading to the lower activation energy. Finally, differences in lattice mismatch with different shell materials are shown to alter the mechanism by which the transition progresses.

Microstructure and Wear Behavior of AlxCoCuNiTi (x = 0, 0.4, and 1) High-Entropy Alloy Coatings

AlxCoCuNiTi (x = 0, 0.4, and 1) high-entropy alloy coatings on 45 steel substrates were prepared by laser cladding, and their phase structure, microstructure, element partition, and wear behavior were investigated. The results show that the AlxCoCuNiTi (x = 0, 0.4, and 1) coatings have a dual-phase structure of FCC and BCC. With the increase of x from 0 to 1, the content of the FCC phase decreases from 66.9 wt.% to 14.3 wt.%, while the content of the BCC phase increases from 33.1 wt.% to 85.7 wt.%. When x = 0.4, the lattice constants of the two phases are the largest, and their densities are the smallest. The microstructure of the AlxCoCuNiTi (x = 0, 0.4, and 1) coatings is composed of BCC-phase dendrites and FCC-phase interdendrite regions. Ti is mainly enriched in the primary phase or BCC dendrites, Cu is enriched in the interdendrite regions, and Al is enriched in the dendrites. The friction coefficients of AlxCoCuNiTi (x = 0, 0.4, and 1) coatings during wear tests are 0.691, 0.691, and 0.627, respectively. The lowering of the wear friction coefficient when increasing the Al content is mainly related to the change in phase structure, microstructure, and wear mechanism.

Comprehensive investigation into thermal stability of AB-type bio- carbonate hydroxyapatite synthesized via heat-treated bovine bone

This study investigates the thermal stability and structural changes of AB-type carbonate-hydroxyapatite (AB-type CHA) prepared from heat-treated bovine bone occurring during calcination at 1000, 1100, 1200, and 1300 °C. The structural phase changes and morphological properties of the calcined AB-type CHA samples were assessed by SEM/EDX, XRD, FTIR, and Raman spectroscopy. The findings highlighted that the decomposition of AB-type CHA undergoes three stages: Dehydroxylation, formation of A-type carbonate-hydroxyapatite (A-type CHA), and decomposition. Pure AB-type CHA was stable in a vacuum atmosphere, and no decomposition occurred at temperatures up to 1000 °C. Dehydroxylation and formation of A-type CHA occurred at 1100 °C. The AB-type CHA partially decomposed at a temperature of 1200 °C. A-type CHA, tricalcium phosphate (α-TCP), and tetracalcium phosphate (TTCP) were the main products of the decomposition reactions, and tricalcium phosphate (β-TCP) was also detected in the system. After sintering at 1300 °C, the AB-type CHA was completely decomposed and converted into α-TCP, β-TCP, and TTCP.

Cl− skeleton modification and K+ charge compensation construct Eu2+ subcrystalline luminescent structure in NaAlSiO4

In this work, the highly homogeneous NaAlSiO4 structure was constructed by glass relaxation crystallization method. The evolution of the subcrystalline luminescence structure was examined by using Eu2+ as a structural probe. The optimization of luminescent properties and phase structure changes of Cl− substitution, Eu2+ occupancy and K+ charge compensation were studied by XRD, EDS, PL spectra, PLE spectra and luminescence thermal stability analysis. The research revealed the AB layer spacing of the crystal stretched and the hexatomix ring opened by Cl− directionally replace O2−(O5), inducing more Eu2+ to selectively occupy the Na+(I) site, resulting in local charge defects in the lattice. The transition emission efficiency of Eu2+ was increased by 50 % with introducing K+ for directional charge compensation. In comparison with NaAlSiO4:2%Eu2+, the NaAlSiO3.96Cl0.04:2%Eu2+-8K+ phosphor showed a 20.82 % increase in ΔE, indicating improved thermal sensitivity in this phosphor series, which holds promising potential for application in LED devices.

Enhanced energy storage properties of BaTiO3 ceramics: Effect of doping Bi(Mg0.25Zn0.25Ti0.5)O3 on microstructure, dielectric and ferroelectric properties

(1-x) BaTiO3 – x Bi(Mg0.25Zn0.25Ti0.5)O3 (x = 0.00, 0.06, 0.12, 0.20,molar ratio) ceramics were prepared by solid sintering method. The effects of Bi(Mg0.25Zn0.25Ti0.5)O3 (BMZT) doping on microstructure, dielectric, ferroelectric and energy storage properties of BaTiO3 (BTO) were studied. With BMZT addition, the sintering temperature gradually decreases, the grain size reaches a minimum at x = 0.12 and the phase structure changes from tetragonal to cubic. And dielectric properties changed from temperature-dependent to temperature-insensitive. Additionally, higher cubic phase content induced slim polarization and electric field (P-E) loop and low remnant polarization (Pr). Therefore, 0.88 BaTiO3 - 0.12 Bi(Mg0.25Zn0.25Ti0.5)O3 ceramics achieved recoverable energy storage density (Wrec) of 702.7 mJ/cm3 and high energy efficiency of 87.3 % under electric field of 93 kV/cm. It exhibited optimum properties, including a minimum grain size (0.620 μm), superior dielectric properties (εr = 1811.3, tanδ = 0.0552 at 1150 °C), a high maximum polarization strength (14.3 μC/cm2), and the maximum dielectric breakdown strength (93 kV/cm), as identified in the present study. It simultaneously maintains high energy storage density and efficiency over a wide electric field range and large temperature range (room temperature - 90 °C). Thus (1-x) BaTiO3 – x Bi(Mg0.25Zn0.25Ti0.5)O3 ceramics are a promising material for energy storage applications.

Stimuli-responsive hydrogel actuators for skin therapeutics and beyond

Stimuli-responsive hydrogels are innovative soft materials that have garnered significant attention in recent years. These hydrogels can undergo phase transitions or structural changes in response to external stimuli, offering considerable potential for use as actuators. They can effectively be used for drug delivery and disease treatment by responding flexibly to a variety of stimuli. This paper first categorizes the types of external stimuli that hydrogel actuators respond to and outlines their applications in skin therapeutics. It then reviews therapeutic potentials of hydrogel actuators beyond the skin, and discusses the challenges and future prospects for the development of stimuli-responsive hydrogel actuators.

Giant Thermosalient Effect in a Molecular Single Crystal: Dynamic Transformations and Mechanistic Insights.

The exploration of mechanical motion in molecular crystals under external stimuli is of great interest because of its potential applications in diverse fields, such as electronics, actuation, or sensing. Understanding the underlying processes, including phase transitions and structural changes, is crucial for exploiting the dynamic nature of these crystals. Here, we present a novel organic compound, PT-BTD, consisting of five interconnected aromatic units and two peripheral alkyl chains, which forms crystals that undergo a drastic anisotropic expansion (33% in the length of one of its dimensions) upon thermal stimulation, resulting in a pronounced deformation of their crystal shape. Remarkably, the transformation occurs while maintaining the single-crystal nature, which has allowed us to follow the crystal-to-crystal transformation by single-crystal analysis of the initial and expanded polymorphs, providing valuable insights into the underlying mechanisms of this unique thermosalient behavior. At the molecular level, this transformation is associated with subtle, coordinated conformational changes, including slight rotations of the five interconnected aromatic units in its structure and increased dynamism in one of its peripheral alkyl chains as the temperature rises, leading to the displacement of the molecules. In situ polarized optical microscopy reveals that this transformation occurs as a rapidly advancing front, indicative of a martensitic phase transition. The results of this study highlight the crucial role of a soft and flexible structural configuration combined with a highly compact but loosely bound supramolecular structure in the design of thermoelastic materials.

Lead-free semiconductor materials with high phase transition temperature: [1-Methylimidazole][SbBr4]

Semiconductor with structure phase change is a special multi-functional material, which plays an important role in the field of Solar Energy, information computing, sensor technology, artificial intelligence, etc. In this paper, the organic–inorganic lead-free semiconductor phase change material [1-Methylimidazole][SbBr4] (1) was successfully constructed. The IR, TGA, DSC, VT-PXRD, solid-state UV–vis spectroscopy and temperature dependence of dielectric constant were characterized and analysed. Single crystal X-ray diffraction shows that at 298 K, the space group is P21/c, the point group 2/m; an endothermic and exothermic peak appeared near 386 K and 367 K in the DSC heating–cooling cycles. Near the corresponding phase transition temperature point, compound 1 exhibits a significant reversible change in the dielectric platform. Interestingly, the band gap of compound 1 is about 2.53 eV. The existence of such interesting physical properties is closely related to the interaction between cations and anions in the molecule and the connection of internal hydrogen bonds. By constructing organic–inorganic hybrid semiconductor materials, we hope to obtain semiconductor materials with phase transition properties and actively explore and provide some ideas and support for the application of new high-tech materials.

Structure phase change induced by nonequilibrium effects in molecular-scale junctions

Structure phase change induced by nonequilibrium effects in molecular-scale junctions

Influence of electrophysical characteristics of plasma electrolytic treatment of 16MnCr5 structural alloy steel on structural and phase changes in the surface and its tribological properties

The possibility of using plasma electrolytic technologies for surface treatment of 16MnCr5 steel in order to increase its wear resistance is shown. The influence of electrophysical characteristics of plasma electrolytic treatment on structural-phase changes of the surface and its tribological properties is studied. A comparison of anodic and cathodic variants of diffusion saturation, as well as subsequent polishing on the results of surface modification is carried out. The complex effect of surface layers strengthened above 1100 HV, including iron carbide and nitride, martensite and retained austenite, to a depth of up to 250 μm with the preservation of a viscous core and the formation of a relatively homogeneous surface with reduced roughness on increasing wear resistance has been revealed. The features of tribological behavior of surfaces formed under different electrophysical parameters of processing, mainly related to the difference in surface microrelief, are shown. The correlation of the Kragelsky-Kambolov criterion as a complex assessment of surface roughness with its wear resistance is shown. The influence of changes in sliding speed and friction load on the occurrence and development of leading processes that determine the intensity and nature of destruction of friction surfaces is established.

Effect of x-ray irradiation on magnetocaloric materials, (MnNiSi)1-x(Fe2Ge)x and LaFe13-x-yMnxSiyHz

Abstract Understanding the behavior of magnetocaloric materials when exposed to high-energy x-ray irradiation is pivotal for advancing magnetic cooling technologies under extreme environments. This study investigates the magnetic and structural changes of two well-studied magnetocaloric materials, (MnNiSi)1−x(Fe2Ge)x composition (x = 0.34) and LaFe13-x-yMnxSiyHz composition (x = 0.30,y = 0.1.26 and z = 1.53) alloys upon irradiation. The alloys were exposed to x-ray radiation with a dosage of a continuous sweeping rate of ∼>120 Gy min−1 and an absorbed dose of 35 kGy . Both the samples didn’t show any observable crystal change after irradiation. There was a considerable change in magnetization at low applied magnetic fields in magnetization versus temperature measurements from 2.72 emu g−1 to 4.01 emu g−1 in the irradiated (MnNiSi)1−x(Fe2Ge)x sample and 4.41 emu g−1 to 5.49 emu/g for the LaFe13-x-yMnxSiyHz alloys. The Magnetization versus magnetic field isotherms near transition temperature exhibited irradiation-induced magnetic hysteresis for the (MnNiSi)1−x(Fe2Ge)x (x = 0.34) while the LaFe13-x-yMnxSiyHz samples did not result in any irradiation-induced magnetic hysteresis. In both the samples the magnitude of entropy change did not change due to irradiation however, the peak entropy change shifted to different temperatures in both the samples, (MnNiSi)1−x(Fe2Ge)x (x = 0.34), showed a maximum entropy change, ΔSmag of ∼ 11.139 J/kgK at 317.5 K compared to ΔSmag of ∼ 11.349 J/kgK at Tave peak of 312.5 K for the irradiated sample. LaFe13-x-yMnxSiyHz, pristine sample exhibited a maximum magnetic entropy change, ΔSmag ∼ 18.663 J/kgK, with the corresponding peak temperature, Tave peak, of 295 K compared to ΔSmag ∼ 18.736 J/kgK, at Tave peak of 300 K. It was determined that irradiation applied to the samples did not induce any structural or magnetic phase changes in the selected compositions but rather modified the magnetic properties marginally.

Ballistic impact behavior of shear thickening fluid impregnated sisal fabrics

The study explores the ballistic impact performance of shear thickening fluid (STF) impregnated sisal fabric panels with varying nano silica loadings (10 wt%, 20 wt%, and 30 wt%). Rheological analysis indicated improved shear thickening behavior with increased nano-silica. FESEM, XRD, and FTIR analyses were conducted to assess changes in morphology, phase structure, and functional groups. The yarn pull-out test showed a higher pull-out force for STF-impregnated fabrics, with 30 wt% STF demonstrating the highest pull-out speed. Ballistic impact tests revealed significant improvements in energy absorption for STF-impregnated fabrics compared to neat fabrics, with energy absorption enhancements of 4.40% for 10 wt%, 45.09% for 20 wt%, and 50.17% for 30 wt%. The increased nano-silica loading resulted in greater energy absorption, attributed to enhanced inter-yarn friction and improved fabric integrity.