Matrix Phase Research Articles

Application of Product of Vitrification of Asbestos-Cement Waste and CRT Glass Cullet as Reinforcing Phase in Surface Composites Produced by FSP Method

In this study, the vitrification of asbestos-cement waste (ACW) and glass cullet from cathode-ray tubes (CRTs) was performed. The resulting product of vitrification from the abovementioned waste was used as the reinforcing phase in a composite with the AA7075 alloy matrix. The composite was made by means of the FSP (friction stir processing) method. The main aim of this work was to determine whether the product of the vitrification can be utilized as the reinforcing phase in the composite. The tests show that introducing the vitrification product into the composite matrix increases both the hardness of the material and its wear resistance. The composite was characterized by a 39% higher hardness and 30.4% higher wear resistance compared to the initial AA7075 alloy. The changes in the properties were caused by strong refinement of the grains, but primarily by the presence of the hard particles of the reinforcing phase in the composite matrix. This research demonstrates that vitrified material, thanks to its properties, can constitute a full-value reinforcing material that can ultimately replace more expensive engineering materials in composites.

Free Vibration and Buckling Analyses of Functionally Graded Plates With Graphene Platelets Reinforcement

Abstract While existing research has focused on using graphene platelets (GPLs) as reinforcement for homogeneous matrices, this study proposes a new nanocomposite for plate structures consisting of GPLs incorporated into a conventional functionally graded matrix with the aim of enhancing their overall stiffness. The performance of such plates is evaluated via free vibration and buckling analyses in the present study. Note that the matrix phase is graded continuously with the power law distribution across the plate's thickness, whereas various GPL dispersion patterns along the thickness are studied. The material properties of the typical functionally graded matrix are determined by the rule of mixture, and then those of the composite are estimated by the modified Halpin–Tsai model as well as the rule of mixture. Based on Hamilton's principle and the novel four-unknown refined plate theory (RPT4), the governing equations of the plate are developed. The Navier-type solution scheme is then adopted to get the critical buckling load and natural frequency of the nanocomposite plate. Numerical findings are examined to evaluate the novel nanocomposite plate model, and a parametric study is also conducted. In addition, high-accurate results are provided via the Navier-type solution here as benchmark solutions for further studies on functionally graded material structures reinforced by GPLs.

The resonance effect for the CP asymmetry associated with the process $\omega \rightarrow \pi^{+}\pi^{-}\pi^{0}$

Abstract The direct CP asymmetry in the weak decay process of hadrons is commonly attributed to the weak phase of the CKM matrix and the indeterminate strong phase. We propose a method to generate a significant phase difference through the interference between $\rho$ and $\omega$ mesons, taking into account the G-parity allowed decay process of $\omega \rightarrow \pi^{+}\pi^{-}\pi^{0}$ and the G-parity suppressed decay process of $\rho^{0} \rightarrow \pi^{+}\pi^{-}\pi^{0}$ in B meson decays. 
It can lead to a significant CP asymmetry changes in the interference region. 
Besides, we also calculate the integral results of different phase space regions for the four-body decay process. We hope that our work can offer valuable theoretical guidance for future experimental investigations on CP asymmetry in these decays.Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Article funded by SCOAP3 and published under licence by Chinese Physical Society and the Institute of High Energy Physics of the Chinese Academy of Science and the Institute of Modern Physics of the Chinese Academy of Sciences and IOP Publishing Ltd.

Anodic Dissolution Behavior of DD6 Nickel-Based Single Crystal Superalloy for Electrochemical Machining Applications

Abstract Nickel-based single crystal superalloys have been widely used in turbomachinery components. Electrochemical machining (ECM) is an essential method for shaping such high-performance alloys. Understanding the fundamentals of ECM for these alloys is crucial for the design and optimization of the process. This study investigated the anodic dissolution of DD6 nickel-based single crystal superalloy in concentrated NaCl and NaNO3 electrolytes under ECM conditions. Polarization curves showed a passive-transpassive transition behavior in both electrolytes. Galvanostatic experiments demonstrated unique current efficiency characteristics contradicting the empirical ECM knowledge. Surface analyses revealed that the anomalous current efficiency of >100% in the NaNO3 electrolyte results from the falling of γ’ phases from anodic surfaces due to the preferential dissolution of the γ matrix phase. The transition from selective to uniform dissolution with increased current density and reduced electrolyte flow velocity leads to decreased current efficiency in NaNO3 electrolyte. The removal of both γ and γ’ phases depends entirely on electrochemical dissolution in NaCl electrolyte, ensuring that current efficiency maintains a normal value. A schematical anodic interface model was proposed to describe the dissolution behavior.

Green hybrid composites partially reinforced with flax woven fabric and coconut shell waste-based micro-fillers

This research is focused on hybrid green composites using flax woven fabric in which the matrix phase was further reinforced with coconut shell waste-based cellulosic microparticles as fillers. Mesoscale mechanical models were successfully developed to simulate the tensile properties of such hybrid composites based on hybridization of fibers and biobased materials using epoxy resin. S-glass fabrics with plain, twill and biaxial constructions, were used as the outer layers, while plain-woven flax fabric was used as the middle layer. A high level of agreement was observed between the experimental and predicted values. The static tensile tests were followed by cyclic tensile tests, microscopic analysis of fracture surfaces and dynamic mechanical analysis. The influence of the hybrid fabric geometry and combination with biowaste-based micro cellulosic material was observed to significantly influence the tensile properties determined by both experimental and numerical analysis. Dynamic mechanical analysis also validated the quasistatic measurements. A higher storage modulus and loss modulus were registered for the hybrid composites impregnated with a 1 % bio filler-based matrix. The damping factor (tan delta) was lower for the hybrid composites than for the nonhybrid samples and the control samples from the pure matrix. This difference is attributed to the stronger interface between the fibers and the particle-based matrix, which restricts the molecular mobility and increases the stiffness of the composites. Fractographic images were obtained by scanning electron microscopy (SEM) to study the failure modes and mechanisms of the composite samples. The microparticles were uniformly dispersed in the epoxy resin and thus enabled microcracking rather than macrocracks. The failure mainly occurred due to fiber failure, matrix cracking and delamination. Such hybrid composites are useful for exterior and interior components in automotive applications.

Influence of Solid Solution Time on Microstructure and Precipitation Strengthening of Novel Maraging Steels

Effective subsequent heat treatment is crucial for achieving the desired microstructure and excellent mechanical properties in laser-deposited high-performance maraging steel. In this paper, we systematically investigate the synergistic relationship and tuning mechanism of different solution treatment times on the microstructure-property synergy of new maraging steels fabricated using laser direct energy deposition (LDED). To determine the optimal heat treatment process, solution treatment was conducted at 840°C for varying durations, followed by aging at 530°C for 2 hours to induce precipitation strengthening. The results indicate that after 2 hours of solution treatment, the alloy exhibits optimal ductility with an elongation of 7.90% ± 0.15%, attributed to the refinement of the martensitic matrix and precipitated phases, along with the formation of a small amount of residual austenite. When the solution treatment time is extended to 4 hours, the alloy achieves its highest tensile strength, reaching 1958 ± 24 MPa. However, the elongation decreases to 7.31% ± 0.12% due to the coarsening of the martensite and secondary phase particles. After 6 hours of solution treatment, significant coarsening and aggregation of the martensite and Fe2Mo intermetallic compounds markedly reduce the hardness, strength, and toughness of the alloy. By adjusting the solution treatment time, the size, morphology, and distribution of the martensitic matrix, Fe2Mo, and nanoscale precipitated phases play a critical role in the strengthening and fracture processes. Therefore, optimizing the precipitation behavior of the martensitic matrix and Fe2Mo intermetallic compounds through rational solution heat treatment is key to enhancing the mechanical properties of laser-deposited new maraging steels.

Microstructural features and mechanical properties of in-situ remelting welding of TC4 titanium alloy and T2 copper welded joint by electron beam

In order to achieve high-quality welding of titanium copper dissimilar metals, the in-situ remelting welded joints of TC4 and T2 were obtained by using a time-sharing dual electron beam(TDEB). A welded joint consisting of the IMCs layer, FZ zone, copper weld zone, and titanium side HAZ is formed in the TC4/T2 interface area. The microstructure and morphology of IMCs layers in welded joints with TDEB welding and copper offset welding were observed by using SEM and TEM. Multiple forms of IMCs were observed in the IMCs layer, including columnar Ti2Cu, granular Ti3Cu4, and sheet-like TiCu4, clarifying the orientation relationship between some precipitates and matrix phases. The TC4/T2 joint welded with TDEB welding achieved micro zone remelting of the IMCs layer. The thickness of the IMCs layer has significantly decreased, and the number of copper-rich phases in the IMCs layer has increased, which improves the mechanical properties of the welded joint. The TC4/T2 joint welded by time-sharing dual beam electron beam has a tensile strength of 215.9MPa and an elongation of 6.14%. The joint exhibits brittle quasi dissociation fracture. The main factor causing fracture is the high brittleness and hardness of titanium-rich phases such as TiCu and Ti2Cu. This study provide a new welding method for titanium copper dissimilar metals, as well as research ideas for dissimilar metal welding.

Tunable impact resistant materials: Synergistic enhancement of paraffin/MRP/re-entrant structures

In the realm of safety protection, there is a critical demand for materials capable of superior energy absorption and adaptability across diverse application scenarios. Here, this study presents integrated two-phase negative Poisson’s ratio (NPR) composites with adjustable mechanical properties sensitive to magnetic field, temperature and impact load. It is achieved by substituting the vacancy of re-entrant structures (frame phase) with soft paraffin/magnetorheological plastomer (MRP) fillers (matrix phase). The paraffin/MRP exhibits temperature-sensitive properties, enhanced magnetorheological (MR) effect (up to 4178%) and shear thickening (ST) effect (up to 2365%). Through quasi-static compression and dynamic impact tests, the composites demonstrate remarkable adaptability in impact resistance. Specifically, the first peak force exhibits responsiveness to changes in magnetic flux density, temperature, and impact velocity, with respective variations of 80.6%, 68.2%, and 30.3%. The design strategy paves the way for tunable impact resistant materials with potential for extreme environment buffering applications.

A rate-dependent crack bridging model for dynamic fracture of CNT-reinforced polymers

Carbon nanotubes (CNTs) improve the fracture toughness of polymer-based matrix composites by bridging the crack growth path. This research presents a finite element (FE) rate-dependent crack bridging model of Mode-I dynamic crack growth in CNT-reinforced polymers accounting for rate of loading and rapid crack growth. Two distinct CNT bridging and matrix cracking damage mechanisms are taken into account in the fracture process zone (FPZ) accounting for the dissipation of fracture energy. A viscoelastic-viscoplastic material model is adapted for the matrix phase to capture the strain rate effects. The crack in the matrix phase is modeled using cohesive zone elements characterized by experimental data. A rate-dependent traction-separation law obtained from CNT pull-out simulation at relevant crack opening speeds is used to simulate the CNT bridging in the FPZ. Considering the given traction-separation law as a constitutive equation, the CNTs are replaced with non-linear spring elements to facilitate the FE simulation of crack bridging with numerous CNTs in the FPZ. The proposed rate-dependent FE model for crack bridging enables the study of the effect of key CNT factors such as length, orientation, waviness, volume fraction, and agglomeration on fracture energy dissipation at various crack speeds. The developed model can simultaneously consider the interactive effects of all CNT parameters which is useful for considering all processing-induced uncertainties in analyzing the effects of CNTs on the dynamic fracture toughness of nanocomposites.

Effect of grain size on precipitation and microstrain of nanocrystalline NiTi alloys

The effect of aging treatment on the microstructure, phase transformation behavior and mechanical properties of nanocrystalline NiTi alloy was studied. The nanocrystalline NiTi alloys with different grain sizes were acquired by cold drawing followed by annealing at 350–500 °C for 10 min. The annealed samples were aged at 250–400 °C for 48 h. The Ti3Ni4 precipitates were found in aged nanocrystalline NiTi alloys. In the sample with smaller average nanograin size, the precipitates were found at the edge of grain boundaries and little lattice strain was shown in R phase matrix. In the sample with larger average grain size, the precipitates were found in the nanograins and exhibited a coherent interface with the matrix. The nanocrystalline R phase NiTi matrix exhibited a significant compressive stress at the end of the coherent precipitate. The coherent precipitates in sample aged at 250 °C after annealing at 500 °C suppress the stress-induced R → B19′ phase transformation and increased the upper plateau stress. The precipitation in sample aged at 250 °C after annealing at 350 °C unable to suppress the martensitic transformation effectively.

Investigation of the Effects of Different Phases of TiO2 Nanoparticles on PVA Membranes

Introduction: PVA/TiO2 nanocomposite membranes are prepared by solution casting technique where different phases of TiO2 nanoparticles like brookite, brookiterutile and rutile are dispersed in PVA matrix. Sol-gel method was employed to prepare TiO2 nanoparticles, while different phases of TiO2 have been obtained by controlling the calcination temperature. Methods: PVA/TiO2 nanocomposite membranes were characterized by XRD, FTIR, AFM, TEM, UV-visible and PL techniques. XRD results confirmed the presence of different phases of TiO2, exhibiting 3.3 nm, 8.4 nm, and 35.7 nm mean crystalline size. The XRD studies also confirmed that TiO2 nanoparticles became properly dispersed to the PVA matrix, leading to increased PVA crystallinity after doping of different phases of TiO2 nanoparticles. UV-visible analysis revealed an increase in absorption intensity and peak position shifts slightly towards longer wavelengths, which indicates that nanofillers tuned the band gap of PVA. The doping of the TiO2 (brookite) phase in the PVA matrix results in a decreased in PL intensity. Results: This suggests that the PVA/TiO2 (brookite) membrane exhibits a greater degree of photocatalytic activity in comparison to the other two composites. According to the FTIR investigation, the hydroxyl (OH) groups present in PVA interact with the dopants Ti+ ions via intra- and intermolecular hydrogen bonds to produce charge transfer complexes (CTC). The AFM study shows surface roughness details for PVA and PVA/TiO2 composite membranes. The average grain size of TiO2 nanoparticles calculated from TEM images is in good agreement with the grain size calculated by XRD. Conclusion: By adjusting the phase of TiO2 nanoparticles into PVA matrix, composites can be developed that are optimized for a variety of applications such as water purification, UV protection, self-cleaning surfaces, lithium-ion batteries, and optoelectronic devices.

Effect of neodymium on microstructure, mechanical properties, and corrosion behavior of Mg-2Si-xNd alloys fabricated by powder metallurgy

In the present work, the effects of neodymium (Nd) on microstructure, mechanical performance, and corrosion behavior of powder metallurgy Mg-2Si-xNd (x = 0.05 wt%, 0.15 wt%, and 0.20 wt%) alloys were investigated. Microstructures were examined by optical and scanning electron microscopes combined with an energy-dispersive spectrometer. Hardness and compressive tests were used to study the mechanical properties of alloys. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), Mott-Schottky analysis, and the hydrogen evolution test were applied to characterize the corrosion behavior of alloys in Hanks’ solution. The microstructure of Mg-2Si-xNd alloys mainly consists of α-Mg matrix, Mg2Si, and MgNd phases. The increase in Nd content tends to decrease the aspect ratio of α-Mg grains, which leads to the enhancement of the ultimate-compressive strengths and hardness of the alloys. Potentiodynamic polarization shows that increasing Nd content leads to a lower corrosion current density in the Mg-2Si-xNd alloys. The EIS results confirm that a higher addition of Nd suppresses the dissolution kinetics of the alloys due to the increasing charge transfer resistance. Mott-Schottky analysis reveals the formation of an n-type semiconductive passive film on the alloy surfaces, where the interstitial and oxygen vacancies predominate over the metal vacancies. The X-ray photoelectron spectroscopy (XPS) reveals that a mixture of Mg(OH)2, MgO, MgCO3, and Nd2O3 has formed as the corrosion products on the Mg-2Si-xNd alloy surfaces after a longer immersion time in Hanks’ solution.

Achieving ultrahigh strength and ductility in biodegradable Zn-xCu alloys via hot-rolling and tailoring Cu concentration

In this present paper, a biodegradable Zn-xCu alloys with an ultrahigh strength and ductility can be achieved via hot-rolling and tailoring Cu concentration, and the role of Cu concentration on the microstructure and texture evolution in the Zn-xCu alloys during hot-rolling were investigated by XRD, EBSD and TEM analysis. The results show that the microstructure of as-cast Zn-xCu alloys consisted of large sized CuZn5 phase and Zn matrix grains before hot-rolling, and numerous submicron CuZn5 phase can dynamically precipitate during hot-rolling of Zn-xCu alloys. The existence of CuZn5 phase can result in the particle stimulated nucleation of recrystallization (PSN), and then result in the formation of fine recrystallized grains. Moreover, three texture components including 0001<112¯0>, 101¯1<1¯012> and 112¯0<0001> textures can form in the Zn-xCu alloys after hot-rolling. With boosting Cu concentration, the intensity of 112¯0<0001> texture gradually reduced, while the intensity of 0001<112¯0> and 101¯1<1¯012> texture components firstly raised with the augment of Cu concentration, and then reduced. For the Zn-xCu alloys with 8 wt%Cu concentration, a combination of high yield strength, ultimate tensile strength and elongation (269.7 MPa, 322.9 MPa and 26.3 %) can be achieved, which can meet the high-performance demands of biodegradable metal vascular stents.

Design of toughed bio-based polylactide/polyamide 11 blends with regulatable size of dispersed phase and spherulites by interfacial stereocomplex crystallites

Enhancing the ductility of polylactide (PLA) through toughening modification to expand the application range of PLA aligns with the requirements of green development. In this study, eco-friendly bio-based plastic polyamide 11 (PA11) was chosen to modify poly(l-lactide) (PLLA). PA11 and poly(d-lactide) (PDLA) were grafted onto the main chain of ADR via simple reactive processing and utilized as reactive compatibilizers to improve toughening efficiency of PA11. The successful preparation of the graft copolymer was confirmed through 1H NMR, FT-IR and DSC, and a detailed investigation was conducted on how the composition and concentration of the compatibilizer influence the mechanical properties, phase morphology, crystallization, and nucleation behaviors of PLLA/PA11 blends. Elongation at break of the 5 % PDLA/PA11 graft copolymers toughed PLLA was as high as 222 % at 30 % PA11 content, which was 17 times greater than the PLLA toughened by pristine PA11 without compromising the strength. PLLA and PA11 were immiscible binary blends with PA11 droplet/PLLA matrix phase separated morphologies in the molten state. Based on the calculation of interfacial tension, the grafted copolymer would be mainly distributed at the interface between the two phases. The dispersion of PA11 droplet in PLLA matrix was improved since the interfacial interaction force was enhanced through in-situ reaction. The increase of the nucleation site and decrease of the spherulites size were worked synergistically by stereocomplex (SC) crystallites and PA11. Under the impact of reducing the size of the dispersed phase and spherulites, the toughness of blends was enhanced. This study provided valuable insights into the control of PLLA immiscible blend morphology and elucidated the relationship between the size of dispersed phase and spherulites and the ultimate mechanical performance of bio-based PLA materials.

Preparation and Application of Weak Cation Exchange Resin Based on Thiol Click Reaction.

Using poly(styrene-divinylbenzene) microspheres as stationary phase matrix and mercaptosuccinic acid as a modifier, a new weak cation exchange resin was synthesized by thiol click reaction. The conditions for thiol-chlorine click reaction and thiol-alkene click reaction were optimized. The surface morphology and chemical composition of the modified microspheres were characterized by scanning electron microscopy, Fourier-transform infrared spectroscopy, and an elemental analyzer. The stationary phase can achieve the separation of six common cations within 25min. A homemade weak cation chromatographic column was used to determine the impurities of Na+ and K+ and the content of tetramethylammonium ions in tetramethylammonium hydroxide samples. The method showed a good linear correlation in the range of 0.1-500.0mg/L with correlation coefficients of 0.9998-0.9999, and the limits of detection (signal-to-noise ratio ≥ 3) were 0.01-0.20mg/L. The intra-day relative standard deviations (RSDs) were in the range of 1.1%-4.4%, and the inter-day RSDs were in the range of 0.8%-14.8%. The spiked recoveries were in the range of 91.92%-119.86%. The results showed that the prepared stationary phase exhibited effective separation ability and good reproducibility, which was suitable for the analysis of the impurities of Na+, K+, and the content of tetramethylammonium in the tetramethylammonium reagents.

High-Strength and High-Temperature-Resistant Structural Battery Integrated Composites via Polymeric Bi-Continuous Electrolyte Engineering.

Structural battery integrated composites (SBICs) combining outstanding strength and heat resistance are highly desirable candidates for next generation high speed aircraft. Here, a novel high-temperature-resistant bi-continuous electrolyte based on phthalonitrile resin is presented, allowing the construction of SBICs capable of stable operation across a wide temperature range. Excellent mechanical strength and high ionic conductivity can coexist in a bi-continuous structure electrolyte (PL50) where the phthalonitrile resin serves as the matrix phase and the ionic liquid electrolyte serves as the conductive phase. Benefiting from the thermal stability of the phthalonitrile resin, SBICs assembled with a PL50 bi-continuous electrolyte deliver excellent mechanical performance even at temperatures exceeding 200°C, with a flexural strength of 299MPa and a flexural modulus of 31.8GPa. Additionally, with an increase in operating temperature, PL50@SBICs demonstrated enhanced rate performance while maintaining good cycling stability. The demonstration of resisting mechanical abuse at high temperatures and flame retardance further suggests the promise of SBICs with PL50 bi-continuous electrolytes operating under extreme conditions.

Effect of SiC addition on the microstructure and properties of Ti6Al4V by selective laser melting

The fine crystalline behavior of SiC/Ti6Al4V is revealed in this study. Titanium matrix composites (TMCs) with different types, amounts, and morphologies of second phases were prepared in situ by adding different contents of SiC. The grain refinement mechanism of multi-phase synergistic was analyzed, and the synergistic contribution of the in-situ second phases (TiC, Ti5Si3, and Ti3Si) as well as the fine grain organization to the strengthening of the materials was quantitatively evaluated. The results show that the quasi-continuous network structure formed by the in situ TiC and Ti5Si3 phases inhibits grain growth and completes the equiaxed transformation of β-grains. Meanwhile, the TiC phase provides a large number of nucleation sites for the α-Ti phase, which promotes the nucleation of the matrix phase. Finally, the aspect ratio of the α phase was reduced from 5.8 to 3.1, while the β grain size was refined from 20.0 to 1.7 µm. The matrix hardness (6.3 GPa) and compressive yield strength (1692 MPa) of TMC were increased by 37 % and 67.4 % respectively compared with Ti6Al4V. Fine grain strengthening accounted for 71.2 % of the total strengthening increase. The load-bearing strengthening caused by TiC, Ti5Si3 and Ti3Si accounted for 6.0 %, 11.6 % and 3.0 % of the total strengthening increase, respectively.

Influence of cryogenic treatment and tempering temperature on microstructural evolution and dry sliding wear behavior of AISI D3 cold-work tool steel

Abstract AISI D3 cold work steel was shallow and deep cryogenically treated and double tempered at 150, 250, and 350 °C temperatures. Cryogenic processes transformed the retained austenite into martensite, while double tempering produced Fe, Cr, and W-rich carbides. The wear losses of cryogenically treated specimens decreased by up to 60% compared to conventionally heat-treated samples. Worn surfaces mainly experienced abrasive and adhesive wear mechanisms. Due to the formation of homogeneously dispersed fine carbides at 250 °C, oxidative wear occurred at the matrix phase, resulting in the lowest wear rate. The samples tempered at 150 °C suffered from the severe abrasive action of hard carbide particles, while the samples treated at 350 °C failed because of carbide coarsening.

Two-dimensional non-Abelian Thouless pump

Non-Abelian Thouless pumps are periodically driven systems designed by the non-Abelian holonomy principle, in which quantized transport of degenerate eigenstates emerges, exhibiting noncommutative features such that the outcome depends on the pumping sequence. The study of non-Abelian Thouless pump is currently restricted to 1D systems, while extending it to higher-dimensional systems will not only provide effective means to probe non-Abelian physics in high-dimensional topological systems, but also expand the dimension and type of associated non-Abelian geometric phase matrix for potential applications. Here, we propose the design and experimental realization of 2D non-Abelian Thouless pumps on a photonic chip with 2D photonic waveguide arrays, where degenerate photonic modes are topologically pumped simultaneously along two real-space directions. We reveal the associated non-Abelian group and experimentally demonstrate the non-Abelian feature by measuring the pumping sequence dependent output. The proposed 2D non-Abelian Thouless pump shows promising applications for robust optical interconnections and optical computing.

Heterogeneous phase deformation in a dual-phase tungsten alloy mediated by the tungsten/matrix interface: Insights from compression experiments and crystal plasticity modeling

Tungsten heavy alloy (WHA) is a typical multiphase alloy material consisting of hard tungsten (W) and soft matrix (γ) phases. When loaded, the two phases deform quite differently due to the large difference in their mechanical properties. At present, our understanding of phase deformation and behavior in the multiphase context is relatively poor compared to the single phase case. Such insight is necessary, however, for the design of multiphase alloys having optimal phase microstructure and corresponding material behavior. By combining mechanical testing and crystal plasticity modeling, the relationship between phase microstructure and multiphase alloy deformation behavior is systematically investigated in this work. The results demonstrate that deformation in the W and γ phases is quite different and related to the contrast in material properties between the two phases. Deformation heterogeneity in the multiphase alloy is characterized by the strain gradient near/across the W/γ interface and differences in phase deformation states in relation to the contrast in phase material properties and phase volume fraction. It is found that dislocation pile-up and twinning are the main mechanisms mediating heterogeneous deformation in the region around W/γ interfaces. Based on this insight, a novel design strategy for multiphase alloys is proposed based on optimization of the contrast in phase mechanical properties and the phase volume fractions. This strategy can be employed to design new tungsten alloys and other multi-phase alloys.