Phase Change Material Research Articles

An investigation of the physic-mechanical properties of the expanded perlite mortars with thermal-activated concrete waste and microencapsulated paraffin

In the transition to zero waste and sustainable development, it becomes essential to use phase change materials and recycled cement in construction projects to improve energy efficiency and encourage sustainable building practices. The primary goal of this study is to determine how the properties of expanded perlite mortars are affected when Portland cement is partially replaced with recycled cement, produced by thermally treating concrete waste at 550˚C. Recycled cement substituted Portland cement in various percentages (10%, 30%, and 50%). Also, microencapsulated phase change material (m-PCM) was incorporated into the mortar in a proportion of 2 wt.% and 5 wt.%. Cement-based mortars with a 1:3 aggregate volume ratio have been developed for evaluation. The mortars were analyzed in terms of mechanical strength (flexural and compressive), water absorption, thermal properties, differential scanning calorimetry, and microstructure. The experimental results revealed a decrease in mechanical strength values when Portland cement is substituted by recycled cement, regardless of percentage. Recycled cement in proportion of 30% positively influenced the water absorption. The thermal conductivity of reference mortar was higher than that of 30% recycled cement. The reference mortar's specific thermal conductivity values were 0.466 W/(m·K) at 25°C, 0.525 W/(m·K) at 30°C, and 0.589 W/(m·K) at 35°C. On the other hand, the mortar containing 30% recycled cement exhibited much lower heat conductivity throughout these temperatures, suggesting superior insulating qualities. DSC analysis verified that adding m-PCM to the mortars increased their thermal storage capacity, which is essential for raising the energy efficiency of building materials. Nevertheless, the mechanical strength decreased as m-PCM was added. Despite decreases, all mortars satisfied the SR EN 998–1 standard's CS IV classification for interior plaster applications, which is based on compressive strength requirements. Overall, this study shows how using m-PCM and recycled materials can improve the performance of cement-based materials.

Thermal management system for prismatic lithium-ion batteries coupling with U-type channels and pyrolytic graphite honeycomb fins

The battery thermal management system (BTMS) is crucial for the safety and lifespan of electric vehicles. This paper proposes a hybrid BTMS combining liquid cooling plates arranged on the side and pyrolytic graphite honeycomb fins (PGHF). The cold plate contains two U-type channels with staggered inlets, and the phase change material (PCM) is filled in the honeycomb fins. The internal resistance and entropic coefficient of the battery are obtained experimentally and used to model the battery’s heat production. The heat dissipation capabilities of six different BTMS are compared at a discharge rate of 3C. Compared with traditional serpentine cold plate cooling, the designed BTMS reduces the maximum temperature, maximum temperature difference, and pressure drop by 5.32 K, 6.82 K, and 462.94 Pa, respectively, indicating significant improvements in cooling performance and substantial reductions in system power consumption. In this paper, the effects of different inlet mass flow rates and honeycomb fin porosity on the heat dissipation of the system are investigated to determine their optimal values. Results indicate that when the mass flow rate is 1.0 g∙s−1 and the honeycomb fin porosity is 45.68 %, the maximum temperature of the battery is 310.38 K, the maximum temperature difference is 1.82 K, and the pressure drop is 279.35 Pa, which represents the optimal cooling performance.

Injected phase change seismic source construction and monitoring experiment

Scientific assessment of the transport channels and distribution of oil, gas, water, and other fluids is the key to enhancing oil and gas production capacity and ensuring the safe and efficient development of mineral resources. Traditional microseismic monitoring has been suffering from limitations such as ambiguous attribute characteristics of the seismic source and low signal-to-noise ratios of the data, leading to poor location accuracy and large uncertainties. We develop a phase change seismic source monitoring method that allows for a detailed characterization of the spatial distribution of subsurface fluid transport by accurately locating the equivalent seismic source within supportive fractures. A phase change seismic source is developed and constructed based on the phase change material, enabling control over phase change temperature, source energy, and source scale through the principle of phase change energy storage. The source introduces an active approach to seismic signal generation, diverging from the conventional passive method reliant on rock rupture. Then, 3D homogeneous models are constructed for ground monitoring and in-well monitoring using impulse source propagation theory. The numerical simulation of the wavefield uses the finite-difference method, and the equivalence of discrete sources is confirmed using the Pearson correlation function. The reliability of the monitoring method is verified through a seismic monitoring experiment and comprehensive feasibility analysis.

A novel photocurable polymeric solid–solid phase change material for intelligent temperature regulators

The advancement of solid–solid phase change materials (SSPCMs) with crystalline segments embedded onto crosslinked polymer backbones offers a promising solution to the leakage problems associated with traditional phase change materials. Despite its potential, this technology faces challenges, including energy-intensive synthesis processes of SSPCMs and difficulties in custom designing materials for confined spaces. Herein, we introduce a novel strategy for the rapid preparation of polyurethane acrylate-based SSPCMs via UV-initiated polymerization. By leveraging crystalline segments from polyethylene glycol, the resulting SSPCM exhibits an impressive enthalpy of 110.4 J⋅g−1, enabling seamless transitions from rigid to soft states during solid–solid phase changes. When applied in portable electronic devices, this SSPCM can be synthesized in-situ to meet various size requirements, demonstrating exceptional temperature regulation performance based on latent thermal energy storage mechanisms. Furthermore, by integrating thin layers of carbon nanotubes (CNTs) onto the rough surfaces of SSPCM films and employing a face-to-face configuration to convert temperature-sensitive mechanical changes into electric resistance variations, we have engineered high-temperature alarms for SSPCM-based temperature regulators. The advantages of this preparation strategy, combined with the thermal regulation capabilities and innovative temperature alarm design, underscore the significant potential for intelligent and adaptive applications of SSPCMs in advanced technological landscapes.

Experimental investigation of high-temperature latent heat storage packed bed using alloy-based phase change materials

This study explores the effectiveness of a high-temperature latent heat thermal energy storage (LTES) system incorporating Al-Si-based microencapsulated phase change material (MEPCM) composite pellets within a cylindrical packed bed. A parametric analysis was conducted to examine the impact of varying pellet sizes (1, 3, and 5 mm) and airflow rates (20–50 L min−1) on the efficiency of heat storage and discharge. The experimental approach included controlled charging and discharging cycles at temperatures ranging from 500 to 800 °C, with Reynolds numbers between 17.6 and 261. The findings indicate that the system achieved a maximum round-trip efficiency of 0.93, with no substantial gains observed beyond a Reynolds number of 150. Additionally, the results reveal the importance of minimizing heat loss to improve system efficiency, particularly during the discharge phase. These insights are crucial for optimizing the design and operational parameters of high-temperature LTES systems to enhance energy storage efficiency.

Machine learning analysis for heat transfer enhancement in nano-encapsulated phase change materials within L-shaped enclosure with heated blocks

Phase change materials(PCMs) are crucial to energy storage systems due to their enhanced thermal properties. They significantly boost energy efficiency and promote sustainability. Nevertheless, the low thermal conductivity of PCMs presents a significant challenge, which is addressed by utilizing nano-encapsulation to enhance energy efficiency in energy storage systems. Motivated by this, the current study conducts a theoretical investigation to explore the heat transfer characteristics in a buoyancy-driven Nano-Encapsulated Phase Change Materials(NEPCM) nanofluid within an L-shaped porous enclosure with the impacts of a heated block and magnetic field. Furthermore, the fusion temperature plays a crucial role in initiating phase change in NEPCM, thereby impacting the heat transfer process. Hence, identifying the optimal fusion temperature is essential. To accomplish this, a machine learning approach was employed to identify the ideal fusion temperature. A dataset of 160 data points across four different fusion temperature values was used in this analysis. Additionally, the machine learning model analyzed how variations in fusion temperatures impact physical parameters. An in-house Matlab code is utilized to solve the dimensionless fluid transport equations employing the finite difference method. The results indicate that increasing the nanoparticle volume fraction significantly enhances the heat transfer rate across all physical parameters. Specifically, under higher thermal buoyancy force, increasing the volume fraction from 1% to 5% results in a 90.04% increase in the heat transfer rate. The numerical analysis demonstrates that heat transfer rates improve significantly when the fusion temperature is adjusted to 0.5, a result further validated by machine learning techniques. At this temperature, thermal buoyancy force increases by 0.98% and 2.68% compared to values of 0.1 and 0.9, respectively, while the Stefan number shows increases of 159.42% and 87.48% under these conditions; thereby, the heat transfer rate increases at this value. This computational study provides important insights into the significance of fusion temperature, emphasizing the need to determine its optimal value for improving heat transfer. Identifying this optimal value can enhance the efficiency of thermal energy storage systems and improve cooling performance in electronic devices.

Investigation of the Arrangement of Aluminum Fins on the Thermal Behavior of Lauric Acid as a Phase Change Material in a Two-pipe Heat Exchanger by CFD Simulation

BackgroundPhase change material (PCM) thermal storage systems store more thermal energy per unit volume than sensible heat storage systems. PCMs offer a potential solution to reduce energy consumption in various thermal engineering applications. This study aimed to examine how fin arrangement affected the thermal efficiency and melting time of PCMs. MethodsA two-dimensional numerical analysis of the melting process of lauric acid in a heat exchanger featuring two pipelines and fins was conducted using CFD simulation. In most previous investigations, the heat transfer fluid was a single-phase liquid. An enthalpy-porosity technique was used to model the solid and liquid phases of PCM. The governing equations were solved using the commercial software ANSYS Fluent 2021, and the pressure and velocity equations were coupled using the SIMPLE algorithm. Significant FindingsThe best model among the 13 tested was Model 5, which featured 6 fins and a consistent angle of 60 degrees. For Model 5, the melting time was 1818.3 seconds. Due to sensible heating, the fin's temperature (Temp) rose gradually from 300 K to 318 K. Temp then gradually increased as the PCM melted in the phase transition zone between 316.5 K and 321.2 K. Once the phase transition was complete, the PCM's Temp steadily rose from 324 K to 340 K. In Model 5, the inner wall Temp and the maximum Temp of the PCM were closest, at 327.34 K and 333.55 K, respectively. The thermal shock between the PCM and the ambient Temp caused a peak heat flux at the beginning of the PCM loading process.

Improving the adsorption of cloud concrete stone porous aggregate to phase change materials by alkali modification

In this paper, the pore structure of cloud concrete stone (CCS) was optimized by alkaline hydrothermal treatment to improve its adsorption capacity for phase change materials (PCMs), thus enhancing the heat storage effect of phase change composite aggregates. The results showed that the adsorption rate of CCS modified by alkaline solution for 36 h was 21.49%, which increased by 30.64% relative to that without modification. The macroscopic and microscopic morphology showed that the 24-hour modified CCS appeared small cracks in the surface and the internal pores became more numerous. The 48-hour modified CCS appeared exfoliated on the surface and the internal pores and cracks increased. Hydrothermal treatment changes the pore structure of CCS, making it more conducive to the adsorption of PCM.

Energy and exergy analysis of a multipass macro-encapsulated phase change material/expanded graphite composite thermal energy storage for domestic hot water applications

This study presents the development and performance evaluation of an innovative thermal energy storage (TES) system utilizing a commercially available bioderived organic phase change material (PCM) for domestic hot water production. The primary objective of this research is to enhance the efficiency and effectiveness of thermal energy storage solutions by macro-encapsulating the PCM-expanded graphite (EG) compressed modules in a multi-pass tube arrangement. A comprehensive experimental setup was employed to investigate the thermal performance of the proposed TES unit, focusing on charging and discharging cycles. Key findings reveal that conduction is the dominant mode of heat transfer, with the system achieving a significant maximum average charging power of 1440 W and a discharging power of 1990 W. The thermal energy storage capacity reached an impressive 12.6 MJ, enabling the discharge of 90 % of stored energy within 90 min. Furthermore, the exergy analysis indicated high exergy efficiencies, with charging efficiencies reaching 98 % and overall exergy efficiency at 18 %.The implications of this research are significant, demonstrating the feasibility of using bioderived organic PCM for sustainable energy applications. It highlights the potential of the modular structure of the system to integrate with heat pump and solar energy systems, thereby enhancing efficiency and sustainability in domestic hot water applications. This work significantly contributes to the advancement of sustainable thermal energy storage technologies and establishes a solid foundation for future studies aimed at optimizing TES systems for domestic hot water production.

Thermal performance of a double-layer pipe-embedded phase change wall system in wood structures coupled with solar energy

In this study, we propose a dual-layer, pipe-embedded phase change wall system for wooden structures that integrates sky radiation cooling and solar heat collection for cross-seasonal operation. This system harnesses renewable energy and reduces the operational energy consumption of buildings. The primary focus of this study is the performance improving of the system during winter conditions. In winter, the system captures solar energy for daytime indoor heating and load reduction and stores excess heat in phase-change material (PCM) embedded within the wooden wallboard. The stored heat is then released at night to further reduce building loads. To assess the thermal performance of the proposed wall system under winter conditions, experiments were conducted across four different scenarios and a reference system was established for comparative analysis. The results indicate that the proposed wall system significantly improves the indoor thermal environment. Specifically, this integration increased the average indoor air temperature by 6.0 °C compared to the reference system and substantially increased the temperature of the wallboard. The inclusion of PCM notably enhanced the thermal performance by reducing nighttime heat loss. Consequently, the average indoor temperature in systems equipped with PCM-enhanced wallboards was 3.0 °C higher than that in the reference system.

Effect of Source-Sink Misalignment and Sink Cavity Aspect Ratio on the Thermal Performance of Gallium Heat Sinks

Herein, we numerically investigated methods to improve heat dissipation from the base of a phase-change material (PCM) heat sink exposed to high heat flux (15 W/cm2). The sink cavity exhibited a rectangular cross-section with two opposite vertical walls of high thermal conductivity. These walls serve as heat-dissipating fins. We used gallium, a metallic PCM with high thermal conductivity and a low melting point to improve heat dissipation by leveraging buoyancy-driven circulations within the molten gallium. We adopted a method to position the sink base on top of the heat source surface in such a way to augment temperature gradients within the liquid to induce imbalances in gallium density and consequent internal circulations. In this technique, one vertical wall is subjected to forced-convective heat exchange with the surroundings, while the other remains adiabatic. Subsequently, for the case which showed optimum performance, we relaxed the adiabatic thermal boundary condition applied at one of the vertical walls and replaced it with convective heat transfer condition, and assessed the sink performance based on that. Further, we analyzed the impact of various aspect ratios of the sink cavity on the induced internal circulations and base cooling. Sink cavities with aspect ratios of 1.33, 0.96, and 0.64 corresponding to sink heights of 20, 17, and 14 mm, respectively, were examined under a consistent heat flux applied across a 15-mm base length. We also investigated the precise positioning of the sink base relative to the heat source surface and explored its influence on temperature gradients and gallium density imbalances crucial for induced internal circulations. Results indicate that a sink cavity aspect ratio of 0.96 yields the optimal heat dissipation from the base. Further, aligning the left bottom edge of the sink base with the left edge of the heat source surface maximizes heat dissipation to the ambient surroundings, thereby prolonging latent-heat dumping into the sink before the gallium completely melts. Any misalignment between the sink base and the surface of the heat source may have a profound impact on the temporal evolution of induced internal circulations within the molten gallium, essentially affecting heat dissipation from the sink base.

Analysis of a Novel Nano Phase Change Materials for Thermal Energy Storage Suitable in Cold Climates

Analysis of a Novel Nano Phase Change Materials for Thermal Energy Storage Suitable in Cold Climates

Enhancing the sustainability of interfacial evaporation to mitigate solar intermittency via phase change thermal storage

Solar-driven interfacial water evaporation is a low-carbon footprint strategy for addressing global water scarcity. However, the operation of the evaporator requires continuity of solar radiation. Herein, the key to overcoming the intermittency of sunlight lies in utilizing the heat storage/release cycle of phase change materials. Additionally, the synergistic effect of high thermal conductivity materials and increased heat transfer area addresses the nonuniform spatial temperature within the heat storage device caused by the low thermal conductivity of molten paraffin. Although the heat transferred to the paraffin reduces the evaporation rate under illumination, the thermal storage/release capacity of paraffin increases the evaporation mass by 171.5% in darkness. Ultimately, after one light–dark cycle, the total evaporation mass over the entire period increased by 11.5%. Finally, although paraffin undergoes sensible and latent heat absorption and release across various temperature ranges during multiple light–dark cycles and prolonged operation, the phase change delays at different internal locations still ensure stable dark-state evaporation compensation for the evaporator, thereby enhancing the sustainability of the evaporation process.

LC3 cementitious binder incorporating microencapsulated phase change materials for self-defrosting traffic surfaces

Exposed surfaces of bridge decks, viaducts and pavements incur ice formation and accumulation of snow in cold seasons, which threatens traffic safety. Mitigating this problem using traditional methods such as deicing salts have caused ecosystem damage and inflicted substantial reinforcement corrosion and surface scaling to bridge decks and pavements, thus compromising their service life and causing colossal economic loss. This paper presents an alternative solution to overcome this problem through the development of a sustainable LC3 cementitious material incorporating micro-encapsulated phase change material (MEPCM) with low phase transition temperature to delay the surface temperature drop and mitigate snow accumulation and ice formation. MEPCM was incorporated in the cementitious matrix at 0 %, 10 % and 20 % by binder mass. Paste and mortar mixtures were prepared to investigate the microstructural, mechanical, physical, and thermal properties. Test results showed that incorporating MEPCM in the LC3 matrix achieved adequate compressive strength. Thermal simulations and visual observations conducted on mortar samples in the laboratory and outdoor exposure showed that MEPCM can effectively regulate the surface temperature of the LC3 matrix and mitigate temperature drops as well as snow accumulation. Analysis of temperature data in the 2023–2024 winter season of Hamilton, Ontario, Canada indicated that the MEPCM incorporated in mortar samples could effectively regulate 40 % of the total days considered and mitigate surface ice formation and snow accumulation, which provides both economic and environmental benefits.

Thermal and hydrodynamic characteristics of microencapsulated phase change materials slurry flow in wavy microchannels

Thermal and hydrodynamic characteristics of microencapsulated phase change materials slurry flow in wavy microchannels

Porous diamond Co-MOF and polyethylene glycol composites as form-stable phase change materials for thermal energy storage

Porous diamond Co-MOF and polyethylene glycol composites as form-stable phase change materials for thermal energy storage

Comparing different battery thermal management systems for suppressing thermal runaway propagation

Thermal runaway (TR) stands as a critical risk in battery applications. Even though various battery thermal management systems (BTMSs) have been proposed to mitigate thermal runaway propagation, a comprehensive comparison remains elusive. This study evaluates the performance of three types of BTMSs with 5 configurations, which include: liquid cooling with cold plates added on the bottom (BTMS-1a), liquid cooling with cold plates added on the sides (BTMS-1b), liquid cooling with cold plates added between batteries (BTMS-1c), integrating thermal insulation materials between batteries (BTMS-2), and implementing phase change materials between batteries (BTMS-3). The highest temperature, propagation time, temperature uniformity, cooling rate, mass energy density, and volume energy density are used as key performance indicators for comparison. In general, BTMS-2 and BTMS-3 show advantages in energy density, however, their performances on TR suppression and battery thermal management are poor. BTMS-1c can suppress TR effectively at high flowrates, whereas it can lead to poor temperature uniformity. Suggestions are also provided regarding the selection of BTMSs for different applications: BTMS-1b, BTMS-1c, and BTMS-3 are recommended for small EVs, large EVs and large scale battery energy storage systems (BESSs), and small BESSs, respectively.

Graphene functionalized nanoencapsulated composite phase change material based nanofluid for battery cooling: An experimental investigation

The graphene-nano encapsulated composite phase change material (GnePCM) based nanofluid holds great potential as a coolant for batteries in electric vehicles. The current work focuses on the synthesis and study of the cooling performance of GnePCM-based nanofluid. Few layered graphene (FLG) was synthesized via the liquid phase exfoliation method. Mini-emulsion polymerization was adopted to encapsulate composite PCM (octadecane: paraffin wax) within polystyrene shell and distribute these nanoballs across the graphene flakes of FLG to obtain GnePCM. Differential Scanning Calorimetry (DSC) was used to optimize the composition of composite PCM based on the melting range and latent heat. GnePCM was characterized by Scanning Electron Microscope (SEM), Transmission Electron Microscopy (TEM), DSC, Fourier Transform Infrared (FTIR) spectroscopy, and Raman Spectroscopy. Nanofluid was made by mixing GnePCM slurry with the base fluid (ethylene glycol − water mixture) and its thermo-physical properties were estimated. The analysis of thermal conductivity and specific heat capacity showed a 14.7 % and 56 % increase for the nanofluid compared to the base fluid. The optimal concentration of nanofluid for maximum stability was 10 % v/v based on zeta potential measurements. The heat transfer studies and pressure drop studies were conducted on a set of 10 cylindrical heaters, mimicking a 18,650 battery cell pack. The nanofluid could potentially achieve a maximum reduction of 5 °C in average surface temperatures of the cells as compared to the base fluid. The enhanced cooling efficiency of nanofluid could be related to the increased thermal conductivity and heat capacity of GnePCM, as well as the absorption of latent heat during its melting process. Enhancement in heat transfer parameters was found to be more prominent at lower flow rates for the nanofluids. The results reveal that the flow rate and power input play a significant role in the cooling performance of the nanofluid. Due to the increased viscosity of the nanofluid, a slight increase in the pressure drop and pumping power was observed at higher flow rates, as compared to base fluid.

Performance of sandwich type fire-resistant flexible composite phase change material PEE@EBF for battery thermal management and runaway protection

To mitigate the risks of overheating and thermal runaway in lithium-ion batteries, this study proposes a novel sandwich-type fire-resistant flexible composite phase change material (CPCM), referred to as PEE@EBF. The core material (PEE) was created by melt-blending paraffin wax (PW), expanded graphite (EG), and ethylene–vinyl acetate copolymer (EVA). The outer layer, a fire-resistant coating (EBF), was applied to the surface of PEE and consists of epoxy resin (EP), boron nitride (BN), and the composite flame retardant (CFR). Test results demonstrated that PEE@EBF maintained structural integrity, exhibiting no significant deformation or leakage after being heated at 80 °C for 5 h. PEE@EBF also displayed a high latent heat of 166.6 J/g, thermal conductivity of 0.8 W/(m∙K), and excellent electrical insulation properties. Furthermore, it achieved a UL94 V-0 flame retardant rating, with notable reductions in peak heat release rate (PHRR) and peak smoke production rate (PSPR) by 67.8 % and 81.8 %, respectively. During long-term cycling at 4C, the peak temperature (PT) and maximum temperature difference (MTD) of batteries in the module incorporating PEE@EBF were reduced by 11.8 °C and 4 °C, respectively, compared to natural convection cooling. In addition, the heat generated during the battery thermal runaway was efficiently absorbed and transferred by PEE@EBF, delaying the irreversible thermal runaway process by 633 s. This indicated that the sandwich-type PEE@EBF was suitable for thermal management and fire protection in lithium-ion batteries or energy storage devices.

Phase Change Thermal Interface Materials with Interface Adaptability and Self-Healing Properties

Thermal stress resulting from excessive temperatures is a major cause of electronic device failure. In this work, with easy installation and good interface adaptability, Phase Change Thermal Interface Materials (PCTIMs) which possess high thermal conductivity were prepared. By incorporating phase change material stearic acid (SA) into the thermal interface material, the instantaneous heat absorption during the solid-liquid phase transition of SA effectively alleviates the problem of instantaneous high heat flux impacting electronic devices. Additionally, the solid-liquid transition reduces the modulus of TIMs, thereby minimizing the contact thermal resistance between the heat source and the heat sink during mechanical installation. To further enhance performance, the thermal interface material utilizes a dynamically cross-linked polyolefin elastomer (POE) with borate bonds, which effectively restricts the flow of SA even at its phase change point due to the three-dimensional cross-linked framework. By constructing a thermal conductive network using carbon fibers and aluminum nitride of different dimensions, the thermal conductivity of the thermal interface material reached 1.82 W∙m−1K−1 with a filler content of only 30 vol% . At 70°C, with a force of 50 N applied to a sample area of 400 mm², the contact thermal resistance was only 2.39×10−4K∙m2W−1. Furthermore, the PCTIMs exhibits excellent self-healing ability under thermal conditions, assuring the permanent encapsulation of small electronic devices.