Pesticide Leaching Research Articles

Nano-Enabled Pesticides in Agriculture: Budding Opportunities and Challenges

Nano enabled plant protectant is an advancement approach to deal with the difficulties of dosedependent toxicity, solubility, degradation, leaching and health issues of conventional pesticides. The main idea behind incorporation of nanoformulation is their controlled delivery and release to prevent premature degradation of active ingredient under the influence of changing environment conditions. Nanocarriers (nanocapsules, nanospheres, micelles, nanogels, nanoemulsions, nanodispersion and inorganic material) alters the properties of active ingredients and provide controlled release kinetics with, better dissolvability, low dose, enhanced stability and long lasting pest-control efficiency. This review critically assesses the incredible potential of various nanocarriers, their methods of preparation and biological effectiveness. It additionally features the potential and issues with nanoformulations of botanical insecticides and essential oils. The study also accounts performances of nano-enabled products, their challenges with respect to field application and assessment of new environmental risks.

Effect of Organic Residues on Pesticide Behavior in Soils: A Review of Laboratory Research

The management of large volumes of organic residues generated in different livestock, urban, agricultural and industrial activities is a topic of environmental and social interest. The high organic matter content of these residues means that their application as soil organic amendments in agriculture is considered one of the more sustainable options, as it could solve the problem of the accumulation of uncontrolled wastes while improving soil quality and avoiding its irreversible degradation. However, the behavior of pesticides applied to increase crop yields could be modified in the presence of these amendments in the soil. This review article addresses how the adsorption–desorption, dissipation and leaching of pesticides in soils is affected by different organic residues usually applied as organic amendments. Based on the results reported from laboratory studies, the influence on these processes has been evaluated of multiple factors related to organic residues (e.g., origin, nature, composition, rates, and incubation time of the amended soils), pesticides (e.g., with different use, structure, characteristics, and application method), and soils with different physicochemical properties. Future perspectives on this topic are also included for highlighting the need to extend these laboratory studies to field and modelling scale to better assess and predict pesticide fate in amended soil scenarios.

Retention and distribution of pesticides in planted filter microcosms designed for treatment of agricultural surface runoff.

Pesticides in agricultural surface water runoff cause a major threat to freshwater systems. Installation of filter systems or constructed wetlands in areas of preferential run-off is a possible measure for pesticides abatement. To develop such systems, combinations of filter materials suitable for retention of both hydrophilic and hydrophobic organic pesticides were tested for pesticide removal in planted microcosms. The retention of six pesticides frequently detected in surface waters (bentazone, MCPA, metalaxyl, propiconazole, pencycuron, and imidacloprid) was evaluated in unplanted and planted pot experiments with novel bed material mixtures consisting of pumice, vermiculite, water super-absorbent polymer (SAP) for retention of ionic and water soluble pesticides, and synthetic hydrophobic wool for adsorption of hydrophobic pesticides. The novel materials were compared to soil with high organic matter content. The highest retention of the pesticides was observed in the soil, with a considerable translocation of pesticides into the plants, and low leaching potential, in particular for the hydrophobic compounds. However, due to the high retention of pesticides in soil, environmental risks related to their long term mobilization cannot be excluded. Mixtures of pumice and vermiculite with SAP resulted in high retention of i) water and ii) both hydrophilic and hydrophobic pesticides but with much lower leaching potential compared to the mineral systems without SAP. Mixtures of such materials may provide near natural treatment options in riparian strips and also for treatment of rainwater runoff without the need for water containment systems.

Triple-Smart Eco-Friendly Chili Anthracnose Control Agro-Nanocarrier.

Pesticide leaching and soil contamination are major issues in the present agriculture formulations. Hence, here 2D graphene oxide in combination with cationic, anionic, or nonionic polymers were tested for runoff resistance and targeted release behavior. Cationic polymer supplemented the binding of rGO on leaf surface by 30% more than control and reduced off-target leaching in soil by 45% more than control. Further, to enhance the fruit rot control caused by Colletotrichum capsici in chili crop, the rGO was decorated with Cu2-xSe nanocrystals, which provided combined disease control with captan. The chitosan coating in the nanocomposite added targeted pH-responsive fungal inhibition behavior and could reduce the C. capsici growth by ∼1/2 times compared to captan control.

Plants affect the dissipation and leaching of anilide pesticides in soil mesocosms: Insights from compound-specific isotope analysis (CSIA)

The soil-plant system can act as a prevailing zone of pesticide dissipation in agroecosystems, which may influence pesticide leaching following rainfall events. Here we examined the contribution of leaching, dissipation and degradation of widely used anilide pesticides in planted and unplanted mesocosms with contrasting vineyard and forest soils. The mesocosms were spiked at 25 mg/kg with acetochlor, alachlor, S-metolachlor, butachlor and metalaxyl, and followed-up for 75 days. Successive rainfalls were applied on days 45, 60 and 75 to collect pesticide leachates. Bulk soil and rhizosphere samples were collected to evaluate pesticide dissipation. Up to 14% of initially spiked pesticides was exported by leaching. The first rainfall accounted for 69–99% of the total pesticide leaching. Pesticide dissipation in soil mesocosms on day 75 ranged from 58 to 99% and was larger in planted than in unplanted mesocosms. Compound-specific stable isotope analysis (CSIA) of the pesticides showed that biodegradation in both the vineyard and forest soil mesocosms occurred mainly in the soil solution that was leached following rainfall events rather than in the bulk soil. Changes in carbon isotope values (Δδ13C up to 13.9 ± 0.5‰) of acetochlor, alachlor, S-metolachlor and butachlor in leachates were more pronounced in planted than in unplanted mesocosms, indicating predominant pesticide degradation in the planted mesocosms. Pesticide biodegradation was favoured in the soil solution of soil-plant systems, independently of the soil type. Leaching of the soil solution, pesticide ageing and biodegradation in the bulk soil and the rhizosphere were the main processes of pesticide dissipation. Overall, this study emphasizes the variability of leaching and degradation of anilide pesticides in agricultural soils, and proposes a framework using CSIA to examine the contribution of dissipation processes in soil-plant systems.

Sorption and leaching characteristics of pesticides in volcanic ash soils of Jeju Island, Korea

It is important to evaluate leaching behavior in agricultural soils to prevent the pollution of groundwater by pesticides. We identified the distribution coefficients (Kd) of ten pesticides with different physicochemical properties and compared their leaching characteristics using wick lysimeters from three distinct soil types on Jeju Island. The Kd values varied by pesticide and soil, but were within the range of 1.2 to 4231 L kg−1. Based on the European standard (Kd < 10 L kg−1), six pesticides (alachlor, ethoprophos, carbofuran, napropamide, tebuconazole, and etridiazole) were mobile in at least one tested soil, and their soil organic carbon affinity was ≤ 5.811. This value differed greatly from the other pesticides (16.533 and higher). The solubility of the six mobile pesticides was ≥ 32 mg L−1, which substantially differed from the other pesticides (≤ 0.71 mg L−1). Thus, we conclude that our mobility assessment, which is based on Kd values, can be used to predict the leaching of pesticides in the volcanic ash soils of Jeju Island. The use of pesticides should be strictly controlled to reduce the possibility of groundwater contamination.

Wheel track loosening can reduce the risk of pesticide leaching to surface waters

AbstractWheel tracks can lower topsoil infiltrability and increase water ponding in agricultural fields. A seedbed harrow mounted with two goosefeet tine points, the eradicators, was used to investigate track loosening at different depths on a sandy loam soil as a way of mitigating compaction effects and reducing the risk of pesticide transport to surface waters. Loosening strongly affected air permeability and steady‐state infiltration. The agro‐ecological system model Daisy was used to simulate the effects of soil structural and hydraulic changes on pesticide leaching to subsurface drain lines over a 332‐year period. Measured properties of the topsoil were combined with a representative subsoil and weather series and with realistic management scenarios. The loads of pesticide in the drains for 3 months after loosening were calculated for each year, and the risk was defined as the 90th percentile of the load. We focused on three different herbicides used in sugar beet cultivation in spring: glyphosate, metamitron and phenmedipham. Our simulations showed that for all pesticides loosening could lower the risk by 10% on average for a 3‐m working width, and the tracks contribution to the risk by 34%, for all drain spacing and working width settings. Wheeling did not affect the risk but this result was sensitive to the parameterization of the hydraulic conductivity in the compacted soil layer, showing potentially higher risk under certain conditions. These results showed that wheel track loosening is an effective strategy for reducing the risk of surface water contamination from pesticides used in agriculture.

Combined leaching and plant uptake simulations of PFOA and PFOS under field conditions

Per- and polyfluoroalkyl substances (PFASs) are used in industrial production and manufacturing but were repeatedly detected in agricultural soils and therefore in cash crops in recent years. Dissipation of perfluoroalkyl acids (PFAAs), a sub-group of PFASs, in the environment was rather attributed to the formation of non-extractable residues (NER) than to degradation or transformation. Currently, there are no models describing the fate of PFAAs in the soil-plant continuum under field conditions, which hampers an assessment of potential groundwater and food contamination. Therefore, we tested the ability of the pesticide-leaching model MACRO to simulate the leaching and plant uptake of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in a field lysimeter using two concepts of adsorption: a kinetic two-side sorption concept usually applied for pesticide leaching (scenario I) and the formation of NER (scenario II). The breakthrough of substances could be simulated adequately in scenario II only. Scenario I, however, was not able to reproduce sampled leaching concentrations. Plant uptake was simulated well in the first year after contamination but lacked adequacy in the following years. The model results suggest that more than 90% of PFOA and PFOS are in the pool of NER after 8 years, which is more compared with other studies. However, since NER formation was hypothesized to be a kinetic process and our study used a PFASs leaching time series over a period of 8 years, the results are reasonable. Further research is required on the formation of NER and the uptake of PFAAs into plants in order to gain a better model performance and extend the simulation approach to other PFAAs.

Diverse effects of wetting and drying cycles on soil aggregation: Implications on pesticide leaching

The important effect of soil wetting and drying cycle (WDC) on soil structure, and the consequent effect on pollutant fate is underexplored. We thoroughly investigated the changes in soil structure and in leaching of Alion (indaziflam) and Express (tribenuron methyl), pre and post WDC, from two clayey soils and two loamy soils under different land uses (uncultivated, field crops, and orchards). Soil stability was quantified by an aggregate durability index we recently developed. WDC did not affect the stability of the sandy-loam soils, as expected. However, for the sandy-clay-loam with high CaCO3 content aggregation was observed. For the clayey soils with similar CaCO3, aggregation and disaggregation were obtained, for a soil with relatively low and high SOM, respectively. The stability trends are reflected by the ratio between the contents of inorganic carbon and soil organic matter (SOM), CaCO3/SOM, normalized to the clay content. Aggregation was explained by CaCO3 cementation, while disaggregation was attributed to high clay content and to alterations in SOM conformation post WDC. These opposite trends, obtained for the two clayey soils, were confirmed by analyzing changes in soil packing employing X-ray tomography (micro-CT). Our results clearly demonstrated that soil aggregation and disaggregation, induced by a WDC, suppresses and enhances herbicide mobility, respectively. However, the effect of WDC on herbicide leaching was not noticeable for Alion upon its high adsorption to a clayey soil, indicating that herbicide physical-chemical properties may dominate. Finally, WDC induces micron-scale changes in aggregate structure, which have a notable effect on pollutant mobility and fate in the environment.

Field insights into leaching and transformation of pesticides and fluorescent tracers in agricultural soil

The frequent detection of residues from pesticides in various natural water types has raised public awareness. This study investigated the pesticide transformation in soil and their loss to shallow groundwater in a small agricultural catchment in Northern Germany. The pesticide Flufenacet and its transformation product Flufenacet ESA were examined in Luvisol and Colluvic Gleyosol under field conditions during two consecutive years. In the second year, a fluorescent tracer experiment applying Uranine and Sulforhodamine - B was carried out to gain additional insights into leaching and formation of transformation products in soil during and after a drought. We found preferential flow in response to low precipitation as an important transport pathway for Flufenacet in dry soil, as a Flufenacet concentration (1.57 μg L−1) was detected in shallow groundwater within 10 days after application. Leaching of Flufenacet to shallow groundwater by preferential flow posed greater risks during the dry than during the wet period. In contrast, Flufenacet ESA was detected in all groundwater samples. During the dry period, we detected no formation of TP510 (tracer transformation product) in the immediate topsoil. A fraction of both tracers remained there, suggesting also long-term residues of pesticides in the topsoil caused by limited living conditions for microorganisms under dry conditions. Newly formed transformation products of Uranine and Flufenacet were mainly trapped in upper soil if capillary flow was marginal. Formation of TP510 could be related to a soil water optimum and a soil temperature threshold. The occurrence of increased TP510 amounts in soil after drought was concurrent with the main peak of Flufenacet ESA in shallow groundwater. This suggested similar retention and transformation processes of fluorescent tracers and organic pesticides inside the soil. This study contributed to an extended understanding of the leaching and transformation of organic pollutants in agricultural soil under real field conditions.

Water and pesticide transfers in undisturbed soil columns sampled from a Stagnic Luvisol and a Vermic Umbrisol both cultivated under conventional and conservation agriculture

The main goals of conservation agriculture are to enhance soil fertility and to reduce soil degradation especially through erosion. However, conservation agriculture practices can exhibit a higher risk of contamination through vertical flows. The objectives of this study were to (i) characterise water and pesticide transfers in two different soils both managed under conventional and conservation agriculture and (ii) assess the effects of pesticide properties, soil type and agricultural system on pesticide fate. We studied the behaviour of two herbicides (nicosulfuron and mesotrione) and a molluscicide (metaldehyde) in percolation experiments in undisturbed soil columns. A series of two rain events (one with a high, the other with a low intensity) separated by a two-day flow interruption was applied three days after the pesticides and bromide application. Batch sorption coefficients, Kd, were also measured. While the Pesticides Properties Data Base (2020) indicated a decrease of sorption in the order mesotrione > metaldehyde > nicosulfuron, the measured Kd, decreased in the order mesotrione (2.3 ± 1.4 L.kg−1) > nicosulfuron (0.7 ± 0.4 L.kg−1) > metaldehyde (0.1 ± 0.1 L.kg−1). We highlighted distinct behaviour of pesticide leaching depending mainly on soil type, agricultural practices and pesticide properties. For low degree of preferential flow, pesticide leaching can be related to the sorption properties of pesticides. Nicosulfuron and mesotrione delays are more pronounced under conservation management while metaldehyde always arrived with no delay. During the high intensity rain event, on one soil type, high degree of preferential flow masked sorption effect on leaching since every pesticide arrived at the same time as the tracer and amounted to up to 21% of pesticide recovery compared to 4% on the other soil type. Conservation agriculture was found to improve the vertical transfers of water and pesticides while, on one of the studied soil type, the presence of a low conductive plough pan significantly limits water drainage.

Indigenous biobed to limit point source pollution of imidacloprid in tropical countries

Point pollution of pesticides originating from the washing of spraying machines could be controlled by biobed system and it is in use in temperate countries. The biobed system is yet to be established in tropical countries. An indigenous biobed system was prepared using local resources like rice straw, farm yard manures (FYM) and paddy field soil to suit the tropical climate. Lowermost 3 cm layer of the biobed system was filled with rice husk biochar to prevent leaching of pesticides from the system. This model system was tested with high doses of imidacloprid (178 mg/column), a commonly used pesticide against number of insect-pests in different crops, for its degradation. The bio-mix trapped a major part of the imidacloprid on the top most layer of the biobed column and only a very small part of imidacloprid recovered from the leachate. The biobed system could degrade 70.13% of applied imidacloprid within 15 days of the experiment and only 5.27% of the total pesticide recovered 90 days after incubation. Addition of biochar layer adsorbed imidacloprid from the outgoing leachate from the biobed column. Biomixture boosted microbial activity more particularly fungal population, which might be responsible for imidacloprid degradation. Microbial biomass carbon, and soil enzymes indicated faster dissipation of imidacloprid from the top layer of the biobed. This simple but efficient biobed system using local resources can fulfill the need of the small and marginal farmers of Asian countries for pesticide decontamination.

Mapping of Agricultural Subsurface Drainage Systems Using a Frequency-Domain Ground Penetrating Radar and Evaluating Its Performance Using a Single-Frequency Multi-Receiver Electromagnetic Induction Instrument.

Subsurface drainage systems are commonly used to remove surplus water from the soil profile of a poorly drained farmland. Traditional methods for drainage mapping involve the use of tile probes and trenching equipment that are time-consuming, labor-intensive, and invasive, thereby entailing an inherent risk of damaging the drainpipes. Effective and efficient methods are needed in order to map the buried drain lines: (1) to comprehend the processes of leaching and offsite release of nutrients and pesticides and (2) for the installation of a new set of drain lines between the old ones to enhance the soil water removal. Non-invasive geophysical soil sensors provide a potential alternative solution. Previous research has mainly showcased the use of time-domain ground penetrating radar, with variable success, depending on local soil and hydrological conditions and the central frequency of the specific equipment used. The objectives of this study were: (1) to test the use of a stepped-frequency continuous wave three-dimensional ground penetrating radar (3D-GPR) with a wide antenna array for subsurface drainage mapping and (2) to evaluate its performance with the use of a single-frequency multi-receiver electromagnetic induction (EMI) sensor in-combination. This sensor combination was evaluated on twelve different study sites with various soil types with textures ranging from sand to clay till. While the 3D-GPR showed a high success rate in finding the drainpipes at five sites (sandy, sandy loam, loamy sand, and organic topsoils), the results at the other seven sites were less successful due to the limited penetration depth of the 3D-GPR signal. The results suggest that the electrical conductivity estimates produced by the inversion of apparent electrical conductivity data measured by the EMI sensor could be a useful proxy for explaining the success achieved by the 3D-GPR in finding the drain lines.

Assessing Specific Vulnerability of Shallow Aquifers to Pesticide Using GIS Tools. Data Needs and Reliability of Index-Overlay Methods: An Application to the San Giuliano Terme Agricultural Area (Pisa, Italy)

Pesticides play a crucial role in regulating crop production by reducing crop losses and increasing crop yield and quality. However, they may threaten surface and groundwater, a phenomenon occurring at global scale, potentially causing environmental damage and prohibition of water use or high treatment costs for drinking water. Assessing spatially-defined aquifer vulnerability to pesticide is then important, as it may allow defining agricultural areas where pesticides should be used following well-defined agronomic practices/limitations. In this study, after a brief review of recent studies on aquifer vulnerability assessment to pesticide, we applied the Vulnerability Index method to the agricultural area of the Municipality of San Giuliano Terme (Pisa, Italy) in order to focus on the data needs and discuss the reliability of this method (as an example of index-overlay methods). The proposed method needs a relatively small number of parameters compared to other more complex ones. Despite a such a small number of parameters, some were not easily available in our case study. Thus, some assumptions were made. This led to vulnerability maps with reduced reliability, no validation with groundwater samples, and little practical use. This means that to produce robust but static vulnerability assessments, large datasets are needed. In turn, the cost of data gathering may be high. The value of these data may, however, be increased, and the cost better justified if the analyses are based on process-based or advanced statistical methods. While the future for vulnerability assessment methods is the use of process-based/advanced statistical methods, index-overlay methods, as a preliminary step for process-based simulation analysis, may still provide initial and relatively quick insights on potential leaching of pesticides. This in turn may support extension services in delivering timely and relevant advices on the use of such pesticides to farmers and owners of plant nurseries and greenhouses.

Assessment of the Environmental Risk of Pesticides Leaching at the Watershed Scale under Arid Climatic Conditions and Low Recharge Rates

The assessment of the vulnerability of soil and groundwater resources to pesticide contamination is important to reduce the risk of environmental pollution. The applicability of the expanded attenuation factor (EAF) to assess leaching potential of 30 pesticides was investigated under four recharge rates (0.0003–0.002 m d−1) in the arid environment of the Jazan watershed. EAF results revealed that Picloram, Carbofuran, Monocrotophos, and 2,4-D pesticides showed high leaching potential, mainly because of their low K O C , and relatively longer t 1 / 2 . In addition, medium leaching potential was observed with six more pesticides (Atrazine, Aldicarb, Simazine, Methomyl, Oxamyl, and Lindane). Regardless of the recharge rate, all other pesticides showed a very low leaching potential in the Jazan watershed. Sensitivity analysis revealed that the output of the EAF index is most sensitive to the fraction of organic carbon ( f o c ) , water content at field capacity ( θ F C ) , recharge rate ( q ) , and partition coefficient ( K O C ) , and least sensitive to soil bulk density ( ρ b ) and air-filled porosity ( n a ). The areal extent of areas with larger leaching potential in the Jazan watershed was consistent with soils having f o c &lt; 0.3, θ F C &gt; 10 m3 m−3, and ρ b &lt; 1450 kg m−3, and were mostly associated with the loamy sand soils, followed by the sand and silt loam soils. EAF index model performed well in assessing relative rankings of leaching potential and delineating areas that are more susceptible to pesticide leaching. At the lowest recharge rate, general risk maps showed that the risk of leaching potential was very low for all pesticides in the entire area of the Jazan watershed. On the other hand, under the worst case scenario (0.002 m d−1), only Picloram and Carbofuran showed very high leaching potential in areas that represented 10.8 and 8.2% from the total area of the Jazan watershed, respectively. The information gained from this research can help farmers and decision-makers to implement regulations and best management practices to reduce the risk of environmental pollution, and protect soil and groundwater resources in Jazan watershed.

Mobility monitoring of two herbicides in amended soils: A field study for modeling applications

This paper reports the mobility and total balance of chlorotoluron (CTL), flufenacet (FNC) and bromide ion (Br−) throughout a sandy soil profile after the application of spent mushroom substrate (SMS) and green compost (GC). Obtaining mobility dataset is crucial to simulate the herbicides' fate under amended soil scenarios by application pesticide leaching models with regulatory application (FOCUS models). The application of organic residues is nowadays increased to improve the crop yields and there is a gap in the simulations of this kind of amended scenarios. A two-year field experiment involving unamended soil (S) and SMS- or GC-amended soil plots was conducted. CTL, FNC, and Br− were annually applied and their residual concentrations were determined in soil profiles (0–100 cm) regularly sampled. In all the treatments the order of mobility is followed as FNC < CTL < Br−. SMS and GC increased herbicide retention in the top 10 cm by the higher organic carbon (OC) content than the unamended soil, and their ability to increase the soil's water-holding capacity and to decrease water percolation. Simultaneously dissolved organic carbon (DOC) content facilitated herbicide transport being it favoured by the initial soil moisture content and the rainfall shortly after the chemicals' initial application. Over the first year, residual amounts (<2.6%) of Br−, CTL and FNC were leached down to 90–100 cm depth in the three treatments. However, over the second year low CTL and FNC amounts (<1.0%) reached the bottom layer only in S + SMS although high Br− concentrations did so in the three treatments (<20%). According to the total balance of Br−, CTL, and FNC in the soil profiles other processes (degradation, mineralisation, bound residues formation, and/or crop uptake) different from leaching below 1 m depth might play a key role in their dissipation especially in the amended soil profiles. SMS and GC are likely to be used as organic amendments to preserve the soil and water quality but in the case of SMS, its higher DOC content could imply a higher potential risk for groundwater contamination than GC.

Evaluation of α- and β-Endosulfan Residues in Teas and Yerba Mate Infusions by Bar Adsorptive Microextraction and Large Volume Injection-Gas Chromatography Mass Spectrometry

Tea and yerba mate are traditional beverages prepared through the infusion of leaves of Camellia sinensis and Ilex paraguariensis, respectively. During this process, the leaching of pesticides onto the beverage, such as endosulfan, may occur. In this study, a bar adsorptive microextraction (BAµE) method prior to large gas chromatography mass spectrometry analysis was developed to analyze a- and b-endosulfan in teas and yerba mate infusions. Different sorbent coatings for BAµE were compared and the hydrophilic-lipophilic balanced polymer showed the best selectivity for endosulfan isomers. The method was validated providing good recoveries (varying from 80.4 ± 1.8 to 108 ± 4.9%) and linearities (r2 > 0.99), limits of detection from 8.0 to 4.0 µg kg-1 and limits of quantification from 40 to 20 µg kg-1 for a- and b-endosulfan, respectively. The application of the method in the analysis of real samples showed all free of endosulfan at the limit of detection of the analytical method.

Parameter sensitivity of SWAP–PEARL models for pesticide leaching in macroporous soils

AbstractPesticide transport simulation by SWAP–PEARL (Soil–Water–Atmosphere–Plant and Pesticide Emission Assessment at Regional and Local scales) models can help to predict pesticide leaching at regional scales. For reasons of economic and time efficiency, measurement efforts should be prioritized towards critical parameters. The objective of this research is to perform a Morris screening and Sobol–Jansen sensitivity analysis to SWAP–PEARL models, using a reasonable worst‐case scenario. Three pesticide compounds were analyzed:, bentazon (zero sorption), imidacloprid (moderately sorbed), and compound I (highly sorbed). Initial macropore and pesticide parameter values were varied by ±20% to generate parameter ranges. The outputs analyzed were the concentration in drainage water, the average concentration in groundwater between 1 and 2 m, and the concentration in the soil system at 100‐cm depth. Influential parameters found through the Morris method were analyzed using the Sobol–Jansen method. The results for bentazon indicate that the degradation half‐life (DT50), the bottom depth of the internal catchment (zic), and the proportion of the internal catchment at the soil surface (pic_0) are critical parameters in all the outputs analyzed. For imidacloprid and compound I, the most relevant parameters for drainage output are the Freundlich sorption exponent (Fexp) and zic; for groundwater, the relevant parameters are Fexp, the bottom depth of static macropores (zst), and pic_0; and for soil concentrations at 100‐cm depth, the relevant parameters are Fexp, zic, and pic_0. The Morris and Sobol–Jansen methods produce the same results for the first position in the ranking. Measurement efforts should be performed to update national soil databases, including critical pesticide and macropore parameters.

Migration of cyantraniliprole in fractured soils: calibration of pesticide leaching model by using experimental data

The phenomenon of preferential migration of substances can increase the risk of pesticides. In the first year of the experiment, in 7 days after application cyantraniliprole penetrated to a depth of 25 cm in agrosoddy-podzolic soil. In the next year on the 7th day after application the pesticide was detected at a depth of 15 cm. The pesticide migrated deeper than the unconfigured PERL model took into account. The calibration of the PERL model by using experimental data (soil experimental support) allowed to reduce the error of prediction. The obtained data can be used to create new standard soil and climate scenarios for pesticide leaching models.

The Geological Survey of Denmark and Greenland (GEUS): from classical geological services to long-term environmental monitoring programmes, energy transformation and advice on political sensitive topics

Abstract The Geological Survey of Denmark and Greenland (GEUS) has a long history and over the years there has been a strong focus on traditional survey work such as geological mapping, research and advice to authorities on questions related to geological and natural resources. Many of the services provided are continuing in the years to come but modern, complex society engenders new questions, where decisions must be based on the best available knowledge, and geological surveys are key players to provide this knowledge to governments. In the new millennium, GEUS has entered into a number of long-term environmental monitoring programmes and several political sensitive projects. Key examples described include groundwater monitoring, assessment of the risk of pesticide leaching to the groundwater, disposal of low-radioactive waste, Carbon Capture and Storage the Continental Shelf Project of the Kingdom of Denmark, monitoring of the Greenland Inland Ice, and other activities on the ice shield. It is expected that GEUS will be involved in even more such studies in the coming years and that the modernization of classical studies will continue. The revised strategy of GEUS to be launched in 2020 will be focused on the institutions input to meet the United Nations sustainable goals.