Chloride-induced corrosion of steel in concrete structures is a significant issue. As an environmentally-friendly building material, rubber concrete has been proven to have the potential to resist chloride-induced permeation. In this paper, the transport behavior of chloride ion in rubber concrete was investigated by electrochemical impedance spectroscopy (EIS) approach. A novel electrochemical equivalent circuit Rs(Q1(Rct1W1)) (Q2(Rct2W2)) was used to study the electrochemical properties of rubber concrete systems and compare with other equivalent circuits by evaluation indicator. The results demonstrate that Rs(Q1(Rct1W1)) (Q2(Rct2W2)) is more suitable for the study of rubber concrete system and the increase of rubber will enhance the resistance to chloride ion transmission. The equation was established by the relation between the equivalent circuit parameter (Rct1) and the migration depth of chloride ion. On this basis, the EIS method can be utilized to predict the depth of chloride ion penetration in rubber concrete.
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